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Enhanced acceptor concentration, proton conductivity, and hydration in multicomponent rare‐earth ortho‐niobates
PublikacjaThe structural properties of (La0.2Nd0.2Sm0.2Gd0.2Eu0.2)1−xCaxNbO4−δ (x = 0–0.05) series have been studied by X-ray powder diffraction at room temperature. The thermal properties were investigated using thermogravimetry, from which the concentration of proton defects was determined. Additionally, dilatometry studies were carried out, from which the thermal expansion coefficients and the phase transition temperature between low-...
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Effective method of treatment of effluents from production of bitumens under basic pH conditions using hydrodynamic cavitation aided by external oxidants
PublikacjaUtilization of cavitation in advanced oxidation processes (AOPs) is a promising trend in research on treatment of industrial effluents. The paper presents the results of investigations on the use of hydrodynamic cavitation aided by additional oxidation processes (O3/H2O2/Peroxone) to reduce the total pollution load in the effluent from the production of bitumens. A detailed analysis of changes in content of volatile organic compounds...
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Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides
PublikacjaIn this work, BaxSr1−xTi1−yFeyO3−δ perovskite-based mixed conducting ceramics (for x = 0, 0.2, 0.5 and y = 0.1, 0.8) were synthesized and studied. The structural analysis based on the X-ray diffraction results showed significant changes in the unit cell volume and Fe(Ti)–O distance as a function of Ba content. The morphology of the synthesized samples studied by means of scanning electron microscopy has shown different microstructures...
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Biodegradable polymer packaging materials - influence on environment
PublikacjaAwareness of the waste problem and its impact on the environment has awakened new interest in the area of biodegradable polymers. Biodegradation of various polymers have been studied under diverse environments like in soil, in sewage sludge, in compost conditions and in sea water by different research groups. The aim of this paper is to present the research methods on the biodegradation of the commercially available biodegradable...
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Superconducting properties of vn-sio 2 sol-gel derived thin films
Publikacjain this work studies of structure and superconducting properties of vnsio2 films are reported. the films were obtained through thermal nitridation (ammonolysis) of solgel derived v2o3sio2 coatings (in a proper v2o3/sio2 ratio) at 1200 ◦c. this process leads to the formation of disordered structure with vn metallic grains dispersed in the insulating sio2 matrix. the structural transformations occurring in the lms as a result...
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The use of modified vegetable oil from Crambe abyssinica as a lubricant base for the food industry
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Effect of underwater wet welding conditions on the diffusible hydrogen content in deposited metal
PublikacjaIn the study mercury displacement method was used for determination of diffusible hydrogen amount in deposited metal obtained during underwater wet welding with covered electrodes in laboratory conditions according to a two-level full factorial design for three factors. The factors and their levels were chosen among conditions and parameters of welding in accordance with the results of own preliminary studies. A statistical analysis...
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Influence of Gd deposition on the oxidation behavior and electrical properties of a layered system consisting of Crofer 22 APU and MnCo2O4 spinel
PublikacjaIn the study, the surface of the Crofer 22APU ferritic steel was modified with gadolinium oxide nanoparticles and a protective-conducting layer consisting of the MnCo2O4 spinel. This system was studied in the context of application in IT-SOFC interconnects. Four types of samples were studied: unmodified steel, steel coated with a manganese-cobalt spinel layer, steel modified with gadolinium oxide nanoparticles, and a system consisting...
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Analysis of Ceramic Elements with Ring-Crack Defects in Lubricated Rolling Contact
PublikacjaThe properties of ceramics, specifically low density, high hardness, high temperature capability and low coefficient of thermal expansion are of most interest to rolling element manufacturers. Surface ring cracks on lubricating rolling contact fatigue failure has been studied using numerical fracture analysis. Such cracks are very often found on ceramic bearing balls and decrease fatigue life rapidly. The numerical calculations...
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The influence of sonication time on the biogenic amines formation as a critical point in uncured dry-fermented beef manufacturing
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Effect of Genetically Modified Feeds on Physico-Chemical Properties of Pork
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Strategies to improve the nutritional value of meat products: incorporation of bioactive compounds, reduction or elimination of harmful components and alternative technologies
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The Influence of Microstructure on the Passive Layer Chemistry and Corrosion Resistance for Some Titanium-Based Alloys
PublikacjaThe effect of microstructure and chemistry on the kinetics of passive layer growth and passivity breakdown of some Ti-based alloys, namely Ti-6Al-4V, Ti-6Al-7Nb and TC21 alloys, was studied. The rate of pitting corrosion was evaluated using cyclic polarization measurements. Chronoamperometry was applied to assess the passive layer growth kinetics and breakdown. Microstructure influence on the uniform corrosion rate of these alloys...
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New Carvone-Based Deep Eutectic Solvents for Siloxanes Capture from Biogas
PublikacjaDuring biogas combustion, siloxanes form deposits of SiO2 on engine components, thus shortening the lifespan of the installation. Therefore, the development of new methods for the purification of biogas is receiving increasing attention. One of the most effective methods is physical absorption with the use of appropriate solvents. According to the principles of green engineering, solvents should be biodegradable, non-toxic, and...
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Novel 2-(2-arylmethylthio-4-chloro-5-methylbenzenesulfonyl)-1-(1,3,5-triazin-2-ylamino)guanidine derivatives: Inhibition of human carbonic anhydrase cytosolic isozymes I and II and the transmembrane tumor-associated isozymes IX and XII, anticancer activity, and molecular modeling studies
PublikacjaA series of novel 2-(2-arylmethylthio-4-chloro-5-methylbenzenesulfonyl)-1-(6-substituted-4-chloro-1,3,5-triazin-2-ylamino)guanidine derivatives 9–20 have been synthesized by substitution of chlorine atom at the 1,3,5-triazine ring in compounds 5–8 with 3- or 4-aminobenzenesulfonamide and 4-(aminomethyl)benzenesulfonamide hydrochloride. All the synthesized compounds were evaluated for their inhibitory activity toward hCA I, II,...
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Sustainable bioethanol production from first- and second-generation sugar-based feedstocks: Advanced bibliometric analysis
PublikacjaBioethanol is produced from carbohydrate-containing feedstocks through fermentation. Based on a bibliometric review of studies published between 2012 and 2021, we analyzed those on sustainable bioethanol production. The Web of Science main collection yielded 1647 publications, which were analyzed using VOSViewer, CiteSpace, and ArcMap software. More than half of these publications originated from some Asian countries, corresponding to...
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Oxylipin profiling for clinical research: Current status and future perspectives
PublikacjaOxylipins are potent lipid mediators with increasing interest in clinical research. They are usually measured in systemic circulation and can provide a wealth of information regarding key biological processes such as inflammation, vascular tone, or blood coagulation. Although procedures still require harmonization to generate comparable oxylipin datasets, performing comprehensive profiling of circulating oxylipins in large studies...
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Integrated Photocatalytic Advanced Oxidation System (TiO2/UV/O3/H2O2) for Degradation of Volatile Organic Compounds
PublikacjaSeveral advanced oxidation processes (AOPs) including photocatalytic processes were studied for effective treatment of complex model wastewater containing a wide variety of VOCs. The studies revealed synergistic effects of TiO2 based processes for improved degradation of the VOCs. A peroxone combined with TiO2/UV system (TiO2/UV/O3/H2O2) with a ratio between the oxygen source from the oxidant to chemical oxygen demand (COD) of...
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High temperature proton conduction in LaSbO4
PublikacjaLanthanum orthoantimonate was synthesized using a solid‐state synthesis method. To enhance the possible protonic conductivity, samples with the addition of 1 mol% Ca in La‐site, were also prepared. The structure was studied by the means of X‐ray diffraction, which showed that both specimens were single phase. The materials crystallized in the space group P2 1 /n. Dilatometry revealed that material expands non‐linearly with the...
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Isotope shifts of multipole lines of Pb I and Pb II
PublikacjaStudies of isotope shifts of three multipole lines between levels of the ground configuration 6s26p2 of Pb I, i.e.: 461.9 nm(1S0→3P1), 531.5 nm(1S0→3P2) and 733.2 nm(1D2→3P1), as well as 710.2 nm line (6s26p2P3∕2→6s26p2P1∕2) of Pb II are presented. We determined the isotope shifts between four stable isotopes: 204, 206, 207, 208. By the use of King plot analysis we were able to separate the mass and the field shifts. We found that...
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Environmentally acceptable lubricants (EAL) compared with a reference mineral oil as marine stern tube bearing lubricant – Experimental and theoretical investigations
PublikacjaThe purpose of this research is to indicate the potential differences in bearing characteristics resulting from the application of different lubricant types with the same viscosity grade. The effect of different environmentally acceptable lubricants (EALs) on hydrodynamic journal bearing properties is studied experimentally and compared to the properties obtained after lubrication with a reference mineral oil. The results of the...
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Numerical analysis of crack propagation in silicone nitride
PublikacjaThe properties of ceramics, specifically low density, high hardness, high temperature capability and low coefficient of thermal expansion are of most interest to rolling element manufacturers. The influence of ring crack size on rolling contact fatigue failure has been studied using numerical fracture analysis. Such cracks are very often found on ceramic bearing balls and decrease fatigue life rapidly. The numerical calculation...
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Signals Features Extraction in Radioisotope Liquid-Gas Flow Measurements using Autocorrelation Function
PublikacjaKnowledge of the two-phase flow structure is essential for the proper conduct of industrial processes. Description of liquid-gas flow regimes is possible by using of data analysis in time, frequency, or state-space domain. In this research studies, the autocorrelation function is applied for analysis of signals obtained for liquid-gas flow by use gamma-ray absorption. The experiments were carried out on the laboratory hydraulic...
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Transition Metal Oxides influence on phosphate and borate glasses structure
PublikacjaBorate and phosphate glasses possess many potential luminescence and optical applications. With their low melting point, they are one of the most often studied amorphous materials. In recent years these glasses, doped with transition metal oxides (TMO), gained much attention due to their tunable structural and thermal properties. Review of systems containing TMOs was presented. Additionally synthesis of binary MnO-P2O5 and MnO-B2O3...
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Changes on the Surface of the SiO2/C Composite, Leading to the Formation of Conductive Carbon Structures with Complex Nature of DC Conductivity
PublikacjaSol–gel layers have been the subject of many studies in recent decades. However, very little information exists about layers in which carbon structures are developed in situ. Using the spin-coating method, we obtained thin iron-doped SiO2/C composite films. The results of Raman spectroscopy showed that our samples consisted of graphitic forms and polymers. The latter’s contribution decreases with rising temperature. FTIR and EDS...
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Inteligentny transformator dystrybucyjny SN/nn dla sieci Smart Grid o aktywnym udziale prosumentów
PublikacjaWraz z rozwojem sieci dystrybucyjnych i ich stopniowym przekształcaniem w inteligentne sieci typu Smart Grid będzie rosłoznaczenie i udział sterowanych układów przekształtnikowych mocy stosowanych jako interfejsy pomiędzy źródłami energii a sieciąoraz pomiędzy siecią a odbiorcami. W artykule rozwinięto koncepcję wymiany konwencjonalnych transformatorów dystrybucyjnych50 Hz na inteligentne transformatory dystrybucyjne. Zaproponowano...
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Smart MV/LV distribution transformer for Smart Grid with active prosumer participation
PublikacjaWraz z rozwojem sieci dystrybucyjnych i ich stopniowym przekształcaniem w inteligentne sieci typu Smart Grid będzie rosłoznaczenie i udział sterowanych układów przekształtnikowych mocy stosowanych jako interfejsy pomiędzy źródłami energii a sieciąoraz pomiędzy siecią a odbiorcami. W artykule rozwinięto koncepcję wymiany konwencjonalnych transformatorów dystrybucyjnych50 Hz na inteligentne transformatory dystrybucyjne. Zaproponowano...
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Synergistic effect of TiO2 photocatalytic advanced oxidation processes in the treatment of refinery effluents
PublikacjaDifferent types of photolytic and photocatalytic advanced oxidation processes (AOPs) were used for treatment of refinery effluents from bitumen production. The treatment efficiency was evaluated by analyzing chemical oxygen demand (COD), biological oxygen demand (BOD5), volatile organic compounds (VOCs) and sulfide ions concentration. The studies revealed a synergistic effect of application of external oxidants (O3, H2O2, O3/H2O2)...
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Complex Monitoring of the Coastal Cliffs on the Example of Cliff in Jastrzebia Gora, Poland
PublikacjaThe cliff coasts, which are in total about 100 km long, are especially vulnerable to abrasion. The mean regression of the studied object which is the seacliff in Jastrzebia Gora depends on time. For example, from 1875 to 1937 the cliff regress 90 m in mean pace of 1.4 meter a year. Besides of natural factors causing the degradation, there is also an anthropogenic activity, which speeds up the abrasion process. Based on these informations,...
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Self-assemblies of novel magnesium porphyrins mimicking natural chlorosomal bacteriochlorophylls
PublikacjaSelf-assembling porphyrins are promising materials to mimic natural bacteriochlorophylls c, d, or e encountered in the chlorosomes of photosynthetic bacteria. We have studied four novel magnesium porphyrins mimicking this chlorosomal antenna system. In contrast to previous articles reporting synthetic Zn-porphyrins, our studies focus on porphyrins with Mg as the central atom, which mimic more closely the natural bacteriochlorophylls....
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Influence of Phase Composition on Dielectric Properties of Bismuth-Based Ceramics with Scheelite-Type Structure
PublikacjaGoal of the present research was to study dielectric properties of BiNbO4 ceramics fabricated by solid state reaction route followed with pressureless sintering. The samples were fabricated from the mixture of oxides, viz. Nb2O5 and Bi2O3. Apart from stoichiometric amount an excess of 3%, 5% and 10% by mole of Bi2O3 was used. It was found that an excess amount of Bi2O3 oxide caused formation of Bi5Nb3O15 minor phase in amount of...
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Recenzja: Mirosław Lenart, Patavium, Pava, Padwa. Tło kulturowe pobytu Jana Kochanowskiego na terytorium Republiki Weneckiej, Instytut Badań Literackich PAN Wydawnictwo, Warszawa 2013 ("Studia Staropolskie Series Nova", t. XXXIII), ss. 257, Indeks nazwisk, il.
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Degradation of Gel-Coat Layer in Glass/Polyester Laminate in Seawater Environment
PublikacjaGlass/polyester laminate coated with gelcoat layer of different thickness 0,5; 1,5; 3 mm was studied in terms of blistering behaviour and water sorption in hot water environment. Blistering was found to be accelerated for thin (0,5 mm) gel-coat layer compared to the thick (1,5; 3 mm), however no significant difference in blistering behaviour was observed between the laminates with gel-coat thickness 1,5 and 3 mm which may suggest...
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Superconductivity on a Bi Square Net in LiBi
PublikacjaWe present the crystallographic analysis, superconducting characterization and theoretical modeling of LiBi, that contains the lightest and the heaviest nonradioactive metal. The compound crystallizes in a tetragonal (CuAu-type) crystal structure with Bi square nets separated by Li planes (parameters a = 3.3636(1)Å and c = 4.2459(2) Å, c/a = 1.26). Superconducting state was studied in detail by magnetic susceptibility and heat...
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Selected nutrients determining the quality of different cuts of organic and conventional pork
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The effect of corn or beet pulp silage supplemented diet on production parameters, oxidative stability of muscles and fatty acid composition of abdominal fat in geese
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Microstructure and functional properties of sorbitol-plasticized pea protein isolate emulsion films: Effect of lipid type and concentration
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Investigation on environmental chemistry changes in the Antarctic Special Management Area (ASMA 1): King George Island, South Shetlands Islands
PublikacjaThe doctoral dissertation included a review of the scientific literature that resulted in the selection of the research area, type of samples and chemical species that were marked. The published series of articles contains an in-depth description of the results of chemical analyses of surface water, sediment and snow samples from the Antarctic Specially Managed Area (ASMA 1) – King George Island. In addition, studies have been...
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REGULACJA MOCY BIERNEJ W MIKROSIECIACH Z ŹRÓDŁAMI WYTWÓRCZYMI
PublikacjaW ramach projektu badawczo-rozwojowego Narodowego Centrum Badań i Rozwoju w Katedrze Automatyki Napędu Elektrycznego został zaprojektowany i wykonany system zarzą-dzania energią oraz sterowania źródłami energii o nazwie ECV-10. System zainstalowano w zakładzie produkcyjnym firmy Infracorr SP. Z o.o. wraz z źródłami energii z fotowoltaiki, wiatru i gazu ziemnego. System umożliwia pomiar ośmiu prądów i sześciu napięć, co w połączeniu...
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Treatment of bitumen post oxidative effluents by sulfate radicals based advanced oxidation processes (S-AOPs) under alkaline pH conditions
PublikacjaSulfate radicals based Advanced Oxidation Processes (S-AOPs), namely Persulfate and peroxymonosulfate, were used for the treatment of post oxidative effluents from a production of petroleum bitumens under alkaline pH. Studies on the identification and monitoring of the volatile organic compounds (VOCs) along with COD, BOD and sulfide ions reduction were performed. Persulfate with a ratio between the oxygen from the oxidant and...
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Superconductivity in LiGa2Ir Heusler type compound with VEC = 16
PublikacjaPolycrystalline LiGa2Ir has been prepared by a solid state reaction method. A Rietveld refnement of powder x-ray difraction data confrms a previously reported Heusler-type crystal structure (space group Fm-3m, No. 225) with lattice parameter a= 6.0322(1) Å. The normal and superconducting state properties were studied by magnetic susceptibility, heat capacity, and electrical resistivity techniques. A bulk superconductivity with...
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Ocena efektywności procesu dyplomowania na studiach pierwszego stopnia w polskich publicznych uczelniach technicznych
PublikacjaW artykule przedstawiono analizę i ilościową ocenę funkcjonowania 18 polskich uczelni technicznych uwzględniającą dwa podstawowe problemy: rezygnację ze studiów w trakcie pierwszego roku oraz wskaźniki ukończenia studiów w nominalnym czasie. Do oceny efektywności procesu dyplomowania wykorzystano prostą metodę wskaźnikową oraz nieparametryczną metodę Data Envelopment Analysis (DEA). Ocenę przeprowadzono dla studiów pierwszego stopnia...
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Aggregation of nonionic surfactants in imidazolium ionic liquids
PublikacjaMicellar aggregation of surfactants in aqueous solutions has been described in terms of the balance between dispersive interactions of the hydrocarbon part of the amphiphilic molecule, and the hydration and electrostatic repulsive effects of hydrophilic head group. Changing the interactions by replacing water with another polar solvent, such as amides or glycols, has been studied to a smaller extent (Singh, Saleem et al. 1980;...
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Characterization of metabolites in different kiwifruit varieties by NMR and fluorescence spectroscopy
PublikacjaIt is known from our previous studies that kiwifruits, which are used in common human diet, have preventive properties of coronary artery disease. This study describes a combination of 1H NMR spectroscopy, multivariate data analyses and fluorescence measurements in differentiating of some kiwifruit varieties, their quenching and antioxidant properties. A total of 41 metabolites were identified by comparing with literature data...
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Szacowanie wydatku basenów nawadniających w warunkach sztucznej infiltracji
PublikacjaZapewnienie odpowiedniej jakości wód powierzchniowych przeznaczonych do zaopatrzenia ludności w świetle restrykcyjnych norm wody zaczyna napotykać coraz większe trudnosci. Jednym z rozwiązań jest wprowadzenie wody powierzchniowej w obszar sztucznej infiltracji, na który składają się stawy infiltracyjne oraz systemy odbioru wód przefiltrowanych (studnie, głębinowe, studnie lewarowe, drenaż podziemny). Obliczenia zdolności filtracyjnych...
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Cellular Effects of Selected Unsymmetrical Bisacridines on the Multicellular Tumor Spheroids of HCT116 Colon and A549 Lung Cancer Cells in Comparison to Monolayer Cultures
PublikacjaMulticellular tumor spheroids are a good tool for testing new anticancer drugs, including those that may target cancer stem cells (CSCs), which are responsible for cancer progression, metastasis, and recurrence. Therefore, we applied this model in our studies of highly active antitumor unsymmetrical bisacridines (UAs). We investigated the cellular response induced by UAs in 2D and 3D cultures of HCT116 colon and A549 lung cancer...
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Nanosize effect of clay mineral nanoparticles on the drug diffusion processes in polyurethane nanocomposite hydrogels
PublikacjaStudies of swelling and release of naproxen sodium (NAP) solution by polyurethane nanocomposite hydrogels containing Cloisite® 30B (organically modified montmorillonite (OMMT)) have been performed. Polyurethane nanocomposite hydrogels are hybrid, nontoxic biomaterials with unique swelling and release properties in comparison with unmodified hydrogels. These features enable to use nanocomposite hydrogels as a modern wound dressing....
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The Influence of the Electrodeposition Parameters on the Properties of Mn-Co-Based Nanofilms as Anode Materials for Alkaline Electrolysers
PublikacjaIn this work, the influence of the synthesis conditions on the structure, morphology, and electrocatalytic performance for the oxygen evolution reaction (OER) of Mn-Co-based films is studied. For this purpose, Mn-Co nanofilm is electrochemically synthesised in a one-step process on nickel foam in the presence of metal nitrates without any additives. The possible mechanism of the synthesis is proposed. The morphology and structure...
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Zanieczyszczenie obecne w próbkach śniegu pobranego z warstw jako źródło informacji o stanie środowiska w dużej aglomeracji miejskiej = Pollutants present in snow samples collected from various layers of snow cover as a source of information about the state of environment in a big urban agglomeration
PublikacjaPróbki śniegu pobierano przez okres około miesiąca z 12 miejsc zlokalizowanych na terenie Trójmiasta. Sześć z nich znajdowało się w pobliżu dróg komunikacyjnych o różnym natężeniu ruchu. Każde z nich miało swój punkt odniesienia oddalony od niego o około 200 m. W próbkach śniegu oznaczano pH, przewodność, zawartość wybranych anionów i kationów. Wartości pH wyznaczono przy użyciu elektrody szklanej połączonej z pH/tlenomierzem mikrokomputerowym,...
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Legal and Economic Conditions of the Creating and Activity of Entrepreneursin Poland. VATT Governement Inst. Econ. Res. C**2002 [nr] 290 s. 153- 162 bibliogr. 10 poz. Discussion papers. Workshopon Studies for Nordther. Kalastajatorrpa,30-31 May 2002.Prawne i ekonomiczne uwarunkowania działalności przedsiębiorców w Polsce.
PublikacjaW artykule przedstawiono warunki prawne, które muszą być spełnione przyuruchamianiu działalności gospodarczej w Polsce. Wskazano również co sprzyjai co hamuje rozwój działalności przedsiębiorców w naszym kraju.