Wyniki wyszukiwania dla: cationic fragmentation
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Self-organization of imidazolium ionic liquids in aqueous solution
PublikacjaW pracy przeanalizowano i podsumowano wyniki badań nad samoorganizacją oraz tworzeniem micel cieczy jonowych w roztworach wodnych otrzymane przez wiele zespołów badawczych. Średnio i długołańcuchowe imidazoliowe ciecze jonowe wykazują aktywność powierzchniową zależną od długości łańcucha alkilowego w kationie, analogicznie do kationowych surfaktantów. Wskazano na liczne zagadnienia, które wymagają dalszych systematycznych badań
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Fabrication of ILs-Assisted AgTaO3 Nanoparticles for the Water Splitting Reaction: The Effect of ILs on Morphology and Photoactivity
PublikacjaThe design of an active, stable and ecient photocatalyst that is able to be used for hydrogen production is of great interest nowadays. Therefore, four methods of AgTaO3 perovskite synthesis, such as hydrothermal, solvothermal, sol-gel and solid state reactions, were proposed in this study to identify the one with the highest hydrogen generation eciency by the water splitting reaction. The comprehensive results clearly show that...
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Artificial neural network prophecy of ion exchange process for Cu (II) eradication from acid mine drainage
PublikacjaThe removal of heavy metal ions from wastewater was found to be significant when the cation exchange procedure was used effectively. The model of the cation exchange process was built using an artificial neural network (ANN). The acid mine drainage waste’s Cu(II) ion was removed using Indion 730 cation exchange resin. Experimental data from 252 cycles were recorded. In a column study, 252 experimental observations validated the...
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Total electrical conductivity data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Dane BadawczeThis dataset includes electrical conductivity measurements results measured by van der pauw technique up to 900oC.
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Increasing efficiency of technological process by limiting impact of corrosive environment on operation of spiral classifiers
PublikacjaMost of the technological operations related to the preparation of the output to be enriched and to the production of the final copper concentrate take place with the use of water environment. Water management, besides using innovative technical and technological solutions, is a significant factor in the whole copper ore enrichment process. Mine water resources and surface water of the tailing pond named "Żelazny Most" are the...
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Modified Manganese Phosphate Conversion Coating on Low-Carbon Steel
PublikacjaConversion coatings are one of the primary types of galvanic coatings used to protect steel structures against corrosion. They are created through chemical reactions between the metal surface and the environment of the phosphating. This paper investigates the impact that the addition of new metal cations to the phosphating reaction environment has on the quality of the final coating. So far, standard phosphate coatings have contained...
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Method of sacrificial anode dual transistor-driving in stray current field
PublikacjaIn order to control a magnesium anode in a stray current interference field, a dual transistor driving system has been proposed. It consisted of a combination of PNP and NPN transistors. Dual transistor driven system and direct anode to cathode connection were electrochemically tested in 3% NaCl solution. The dual transistor driven system increased the anode efficiency and reduced hydrogen evolution and the risk of embrittlement....
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Structure recognition in MD-simulated materials: a case study of boroxyl rings in borate glasses
PublikacjaZanalizowano statystyczne właściwości geometryczne losowo deformowanej jednostki strukturalnej AC_3, gdzie trzy kationyC znajdują się w wierzchołkach trójkąta równobocznego, a anionA - w jego środku. W szczególności opisano rozkłady kątów AAA,ACA i CAA oraz dwóch estymatorów kształtu w funkcji amplitudydeformacji trójkąta. Wyniki analizy stochastycznej zastosowanodo ilościowej oceny stopnia nieuporządkowania w szkle B_2O_3,symulowanym...
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Gradient versus proper gradient homotopies
PublikacjaWe compare the sets of homotopy classes of gradient and proper gradient vector fields in the plane. Namely, we show that gradient and proper gradient homotopy classi cations are essentially different. We provide a complete description of the sets of homotopy classes of gradient maps from R^n to R^n and proper gradient maps from R^2 to R^2 with the Brouwer degree greater or equal to zero.
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Experimental examination and modification of chip suction system in circular sawing machine
PublikacjaThe article presents the results of experimental examination of the wood chip suction system in the existing sliding table saw before and after its modifi cation. The studies focused on the extraction hood of the mentioned system. The methodical experimental research of the pressure distribution inside the hood during wood chip removal for the selected rotational speed of saw blades of 3500 and 6000 min-1 with a diameter of 300...
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Reactivity of Phosphanylphosphinidene Complex of Tungsten(VI) toward Phosphines: A New Method of Synthesis of catena-Polyphosphorus Ligands
PublikacjaThe reactivity of an anionic phosphanylphosphinidene complex of tungsten(VI), [(2,6-i-Pr2C6H3N)2(Cl)- W(η2-t-Bu2P=P)]Li·3DME toward PMe3, halogenophosphines, and iodine was investigated. Reaction of the starting complex with Me3P led to formation of a new neutral phosphanylphosphinidene complex, [( 2,6-i-Pr2C6H3N)2(Me3P)W(η2-t-Bu2P=P)]. Reactions with halogenophosphines yielded new catena-phosphorus complexes. From reaction with...
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Cytocompatibility of stabilized black phosphorus nanosheets tailored by directly conjugated polymeric micelles for human breast cancer therapy
PublikacjaThe novel procedure of few-layer black phosphorus (FLBP) stabilization and functionalisation was here proposed. The cationic polymer PLL and non-ionic PEG have been involved into encapsulation of FLBP to allow sufficient time for further nanofabrication process and overcome environmental degradation. Two different spacer chemistry was designed to bind polymers to tumor-homing peptides. The efficiency of functionalisation was examined...
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The role of isolated farmsteads in the open landscape protection on the example of Kashubia
PublikacjaAs a result of the social and economic transformation of rural areas, open landscapes are disappearing. Former farmsteads are being devastated or beginning to lose their landscape context due to the spread of residential building development. At the same time, in many places, the farmstead form is clearly legible and remains an element with which the view is structured and enriched. The article was aimed at drawing attention to...
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Sensitive determination of isoprostanes in exhaled breath condensate samples with use of liquid chromatography-tandem mass spectrometry
PublikacjaOxidative stress is the hallmark of various inflammatory lung diseases. Increased concentrations of reactive oxygen species in the lungs are reflected by elevated concentrations of oxidative stress markers in the breath, airways, lung tissue and blood. The aim of this work was to develop a method for the fast measurement of F2 isoprostanes in exhaled breath condensate (EBC) samples using equipment which is nowadays available and...
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Chemical and biological evaluation of antioxidant activity of endogenous redox-active compounds compared to plant-derived exogenous antioxidants
PublikacjaThe research conducted so far has shown that endogenous antioxidants, despite being regarded as the first line of antioxidant defense, may not be sufficient to maintain redox homeostasis in cells exposed to oxidative stress. The results obtained in the doctoral dissertation show that endogenous redox-active compounds were moderate or weak scavengers of ABTS and DPPH radicals, while in cellular setting, their impact on the reducing...
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Learning sperm cells part segmentation with class-specific data augmentation
PublikacjaInfertility affects around 15% of couples worldwide. Male fertility problems include poor sperm quality and low sperm count. The advanced fertility treatment methods like ICSI are nowadays supported by vision systems to assist embryologists in selecting good quality sperm. Computer-Assisted Semen Analysis (CASA) provides quantitative and qualitative sperm analysis concerning concentration, motility, morphology, vitality, and fragmentation....
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Multisource model of ship electric field
PublikacjaA steel-hulled ship in sea water produces an electric field around itself. The source of this field are electrochemical processes and ship's cathodic protection. The analysis of the electric field around the ship is important by the reason of the ship's identification and counter-mine protection. The paper presents a simplified model of the ship's multisource electric field, which allows to calculate the electric field distribution...
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Potential energy curves and spectroscopic parameters of the diatomic silver anion and neutral silver dimer
Dane BadawczeThe process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag is theoretically studied. The ground state potential energy curves (PECs) of the neutral silver dimer and anionic silver diatomic molecule are calculated using the single reference...
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The spontaneous electron emission and rotational predissociation lifetimes of the diatomic silver anion
Dane BadawczeThe process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag is theoretically studied. The ground state potential energy curves (PECs) of the neutral silver dimer and anionic silver diatomic molecule are calculated using the single reference...
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Access to Side-On Bonded Tungsten Phosphanylphosphinidene Complexes
PublikacjaMetathesis reactions between diimido complexes of tungsten(VI)[(ArN)2WCl2] (Ar = 2,6-iPr2C6H3) and lithium derivatives of diphosphanes R2P-P(SiMe3)Li (R = tBu and iPr) yield two anionic diimido complexes of tungsten with side-on bonded phosphanylphosphinidene ligands, [(ArN)2WCl(η2-R2P-P)]-. Both complexes are structurally characterized. A possible reaction mechanism and the role of donor solvents are discussed on the basis of...
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The influence of polarization of titania nanotubes modified by a hybrid system made of a conducting polymer PEDOT and Prussian Blue redox network on the Raman spectroscopy response and photoelectrochemical properties
PublikacjaIn this work we show the impact of applied potential on network vibrations and photoelectrochemical properties of a composite material containing hydrogenated titania nanotubes and poly (3,4-ethylenedioxythiophene) with iron hexacyanoferrate (H-TiO2/pEDOT:Fehcf) acting as a redox centre. For this purpose, Raman spectroscopy measurements under the working electrode (WE) polarization were carried out, allowing investigation of changes...
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Cathodically activated Au/TiO2 nanocomposite synthesized by a new facile solvothermal method: An efficient electrocatalyst with Pt-like activity for hydrogen generation
PublikacjaWe report here a facile, template-free and one-step solvothermal approach for the synthesis of high-temperature stable gold/titania nanocomposite (NCs), providing a new, simple, quick and inexpensive wet-chemical route. Our approach is based on the assembly of gold salt and titanium butoxide in dimethyl sulfoxide (DMSO). Also, we present here, for the first time, a cathodically activated Au/TiO2 catalyst with Pt/C activity for...
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Underwater Electrochemical Offshore Tests of a Paint Coating Applied in Water on the Legs of an Oil Production Platform
PublikacjaThis paper presents the methodology developed for underwater measurements using electrochemical impedance spectroscopy (EIS) technique, aimed at determining the resistance of an epoxy coating applied in seawater to the legs of an oil production platform. Performing such underwater tests in an offshore environment was technically challenging. The results of measurements obtained on the platform were confronted with comparative results...
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Polyacrylamide substrate viscosity impact on temozolomide activity in glioblastoma cells by flow cytometry and rheological measurements
Dane BadawczeDataset includes raw data on cell lines LN-229 and LN-18 treated with temozolomide measured by flow cytometry, rheometry and cell projections. It also includes calculations necessary for creation of figures and conclusions based on those figures in the publication titiled: "Substrate viscosity impairs temozolomide-mediated inhibition of glioblastoma...
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Dissociative ionization dynamics of dielectric gas C3F7CN
PublikacjaFluoronitrile C3F7CN is a promising candidate for the replacement of SF6 dielectric gas in high-voltage insulation. We present a combined experimental and theoretical study on its ionization dynamics probed in the 0-100 eV energy range. We exploited the total ion collection technique to determine the absolute ionization cross section, mass spectrometry to determine the fragment branching ratios and ab initio nonadiabatic molecular...
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Morphology, surface properties and photocatalytic activity of the bismuth oxyhalides semiconductors prepared by ionic liquid assisted solvothermal method
PublikacjaThis is the first report of the effect of the ILs cation type (imidazolium, pyridinium and pyrrolidinium) on the morphology, surface properties and photoactivity of BiOX semiconductors type obtained by solvothermal method in glycerol. The various ionic liquids (IL) cation type as a halogen source and templating agent for the synthesis of the bismuth oxyhalides nanoparticles has been systematically investigated. The role of ILs...
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Azo and azoxythiacrown ethers: synthesis and properties
PublikacjaA series of 16- and 18-membered azo- and azoxythiacrown ethers have been synthesized by reductive macrocyclization of the respective bis(nitrophenoxy)oxaalkanes. The aromatic residues located in the polyether region of the molecule were introduced to macrocyclic skeletons and their affinities toward different groups of metal cations in ion-selective electrodes were described. X-ray structures for one dinitropodand and one azoxybenzothiacrown...
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Decomposition of halogenated nucleobases by surface plasmon resonance excitation of gold nanoparticles
PublikacjaHalogenated uracil derivatives are of great interest in modern cancer therapy, either as chemotherapeutics or radiosensitisers depending on their halogen atom. This work applies UV-Vis spectroscopy to study the radiation damage of uracil, 5-bromouracil and 5- uorouracil dissolved in water in the presence of gold nanoparticles upon irradiation with an Nd:YAG ns-pulsed laser operating at 532nm at dierent uences. Gold nanoparticles...
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Ewa Wagner-Wysiecka dr hab. inż.
OsobyEwa Wagner-Wysiecka absolwentka Wydziału Chemicznego PG (Kierunek Technologia Chemiczna, kierunek dyplomowania: Technologia Nieorganiczna, specjalność: Analityka Techniczna i Przemysłowa). Pracę magisterską pt. ”Identyfikacja zanieczyszczeń występujących w farmakopealnej sulfachinoksalinie” zrealizowała pod kierunkiem prof. dr hab. inż. Jana F. Biernata. Po ukończeniu studiów magisterskich (1997 r.) rozpoczęła studia doktoranckie....
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Measurement methods for assessing insulation condition of underground pipelines
PublikacjaThe paper discusses the most frequently applied measurement methods for assessing the quality of external insulation along pipelines and detecting defect locations in the protective coating. The quality of coating along a given pipeline section under investigation is assessed by determining unitary resistance of the coating, which is calculated on the basis of measurement results obtained along a pipeline subjected to cathodic...
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Protection of bridges against stray current corrosion
PublikacjaA case study of Siennicki Bridge stray current corrosion hazard is presented. A corrosion risk was caused by incorrectly designed tram line traction which goes over the bridge. No dielectric insulation between running rails and bridge steel construction was used. A variety of protection methods against stray currents are described. Characteristics of the endangered bridge were described. Impressed current cathodic protection system...
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Study of anticorrosion and microwave absprption properties of NiZn ferrite pigments
PublikacjaPurpose - The purpose of this paper is to report the electrochemical verification of anticorrosive properties of NiZn ferrites as pigments in protective coatings and evaluation of their microwave absorbing properties. Design/methodology/approach - Ferrites, represented by formula NixZn(1-x)Fe2O4, where x=0, 0.2, 0.4, 0.6, 0.8, 1.0, were synthesized using a ceramic method. The samples of ferrites were examined by X-ray diffraction...
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Identification and characterization of the Indian Yellow dyestuff and its degradation products in historical oil paint tube by liquid chromatography mass spectrometry
PublikacjaAn analytical protocol for identification of dyes using reversed phase liquid chromatography-mass spectrometry with atmospheric pressure electrospray ionization (LC-ESI/MS) is presented. The developed method has been successfully applied in identification of euxanthic acid and euxanthone, the main components of the Indian Yellow dye in a historical oil paint tube produced by Richard Ain`es, a recognizable French company supplying...
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Convenient identification of desulfoglucosinolates on the basis of mass spectra obtained during liquid chromatography-diode array-electrospray ionisation mass spectrometry analysis: Method verification for sprouts of different Brassicaceae species extracts
PublikacjaOver the past decade, glucosinolates (GLs) present in different tissues of Brassicaceae and their breakdown products, especially isothiocyanates formed after myrosinase catalyzed hydrolysis, have been regarded as not only environment friendly biopesticides for controlling soilborne pathogens, but most importantly as promising anticarcinogenic compounds. For these reasons, the identification and quantitative determination of the...
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MINERAL MATTER IN MUNICIPAL SOLID WASTE
PublikacjaMunicipal solid waste (MSW) contains mineral materials which are seldom considered as a potential resource. Currently, the waste management sector pays attention to recyclable parts, biodegradable material, waste-to-energy fraction, and residues after waste reuse and recycle. In contrast, this study focus as on the mineral matter in MSW. The aim was to analyze and discuss the sources of mineral matter in MSW, the impact which the...
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Kinetics of molecular decomposition under irradiation of gold nanoparticles with nanosecond laser pulses—A 5-Bromouracil case study
PublikacjaABSTRACT Laser illuminated gold nanoparticles (AuNPs) efficiently absorb light and heat up the surrounding medium, leading to versatile applications ranging from plasmonic catalysis to cancer photothermal therapy. Therefore, an in-depth understanding of the thermal, optical, and electron induced reaction pathways is required. Here, the electrophilic DNA nucleobase analog 5-Bromouracil (BrU) has been used as a model compound to...
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Relationship between conversion rate of glucosinolates to isothiocyanates/indoles and genotoxicity of individual parts of Brassica vegetables
PublikacjaThe studies on the characterisation of glucosinolates (GLs) and their breakdown products in Brassicaceae species focus mainly on the edible parts. However, other products, e.g., dietary supplements, may be produced also from non-edible parts such as roots or early forms of growth: seeds or sprouts. Biological activity of these products depends on quantitative and qualitative GL composition, but is also strictly determined by GL...
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Linear revitalization - problems and challenges. Discursive article
PublikacjaThe aim of the article, defined by the author as discursive, is to give the answer as to whether within ‘revitalization’ we should distinguish the notion of ‘linear revitalization’ – not yet defined in Polish and English-language literature. The author presents the thesis that we should do so by presenting the idea, its specific character and its role. This kind of action seems to have, in the author’s opinion, a positive influence...
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Molecular mechanism of proton-coupled ligand translocation by the bacterial efflux pump EmrE
PublikacjaThe current surge in bacterial multi-drug resistance (MDR) is one of the largest challenges to public health, threatening to render ineffective many therapies we rely on for treatment of serious infections. Understanding different factors that contribute to MDR is hence crucial from the global “one health” perspective. In this contribution, we focus on the prototypical broad-selectivity proton-coupled antiporter EmrE, one of the...
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Hydrogenation process ofTiO2/BiVO4/PEDOT:PSS observed by XPS method
Dane BadawczeTitania nanotubes synthesis was based on a two-stage anodization process at water/ethylene glycol (5%/95%) electrolyte containing 0.27 M NH4F and 1 M H3PO4 described previously. Anodization process was performed in two-electrode cell compartment using platinum mesh as a cathode. The distance between electrodes was about 2 cm. The anodization voltage...
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Instantaneous Impedance Analysis of Non-Stationary Corrosion Process: a Case Study of Carbon Steel in 1M HCl
PublikacjaThe paper concerns the problem of evaluation of stationarity of carbon steel corrosion in 1M HCl. Comparison of corrosion rate with addition of corrosion inhibitor to the reference measurement is the most often used way of evaluating inhibitor efficiency. Such an approach is valid only if corrosion rate is a stationary process. Two complementary techniques were used simultaneously: volumetric analysis of evolved hydrogen and instantaneous...
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Synthesis and application of tetrazole di and triamide derivatives in ion-selective membrane electrodes
PublikacjaA number of tetrazole diamides and triamides have been synthesized and applied as ion carries in ion-selective membrane electrodes. Their selectivity and sensitivity were studied towards alkali, alkaline earth, transition and heavy metal cations. it was found that membranes doped with 3 and 2-nitrophenyl octyl ether exhibit an almost theoretial Nernstian response for NH+ over relatively wide concentration range. Elestrodes with...
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Synthesis and properties of new 'N,'N-phenyltetrazole podand
PublikacjaThe synthesis of a new chromogenic N,N-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity...
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Surface active fatty acid ILs: Influence of the hydrophobic tail and/or theimidazolium hydroxyl functionalization on aggregates formation
PublikacjaNine structurally-related fatty acid ionic liquids have been prepared and their thermal behavior as well as their ability to self-assemble in water has been investigated. The thermal properties were studied by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC), while the aggregation behavior was analyzed by tensiometry, isothermal titration calorimetry (ITC), conductometry, dynamic light scattering (DLS),...
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Density, sound velocity, viscosity, and refractive index of new morpholinium ionic liquids with amino acid-based anions: Effect of temperature, alkyl chain length, and anion
PublikacjaIn this work, room temperature synthesis of twenty new ionic liquids (ILs) based on the N-alkyl-N-methylmorpholinium ([Mor1,R], R = 2, 3, 4, 6, 8) cation and N-acetyl-L-amino acid anions (L-alaninate, L-valinate, L-leucinate, L-isoleucinate) was described. The synthesized ILs were characterized by various spectroscopic techniques and high-resolution mass spectrometry. Furthermore, density (ρ), sound velocity (v), viscosity (η)...
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The speciation of organotin compounds in sediment and water samples from the port of Gdynia
PublikacjaOrganotin compounds (OTC) are toxic towards all living organisms. The application of organitin-based antifouling systems is becoming the main source of OTC in the ocean. Harbor sediments and water contain large deposits of organotin compounds due to application of antifouling systems in the shipping industry. OTC contamination presents a potential risk to the marine environment. Sediment and water samples were collected in 2009...
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Tracking of the broadband source of the underwater noise in the very shallow water conditions
PublikacjaThe paper contains the result s, both theoretical and experimental , connected with the tracking of the underwater noise source as small ships, pontoon , diver and so on. The pro blem of security in the shallow water area is the challenge for underwater acousticians. In this paper there is take n into account the detection of the sources that move on the surface of the sea or underwater in shallow...
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Structural, physicochemical and anticancer study of Zn complexes with pyridyl-based thiazolyl-hydrazones
PublikacjaThiazolyl-hydrazones (THs) exhibit a wide spectrum of biological activity that can be enhanced by complexation with various metal ions. Zn(II) complexes with α-pyridine-1,3-TH ligands may represent an alternative to the standard platinum-based chemotherapeutics. In addition, they show photoluminescence properties and thus can be regarded as multifunctional materials. In this study, we synthesized and characterized three neutral...
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Evaluating calibration and robustness of pedestrian detectors
PublikacjaIn this work robustness and calibration of modern pedestrian detectors are evaluated. Pedestrian detection is a crucial perception com- ponent in autonomous driving and here we study its performance under different image corruptions. Furthermore, we provide analysis of classifi- cation calibration of pedestrian detectors and we show a positive effect of using style-transfer augmentation technique. Our analysis is aimed as a step...
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The Effect of Increasing the Amount of Indium Alloying Material on the Efficiency of Sacrificial Aluminium Anodes
PublikacjaAl-Zn-In alloys having 4.2% zinc content and various indium content in the range of 0.02–0.2% were tested with respect to the most important electrochemical properties of sacrificial anodes in a cathodic protection, i.e., the current capacity and potential of the operating anode. The distribution of In and Zn in the tested alloys was mapped by means of the EDX technique, which demonstrated that these elements dissolve well in the...