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Search results for: YIELD OPTIMIZATION
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Geminate-pair dissociation yield in systems with exponential energetic disorder — A Monte Carlo study
PublicationGeminate electron–hole recombination in systems with exponential energetic disorder is studied by Monte Carlo method. The field and temperature dependencies of geminate-pair dissociation probability are calculated. It is established that the dissociation yield of carrier pairs depends mainly on the extent of carrier thermalization, which influences the Einstein relationship. The approximate limiting temperature is given by Te =...
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Alternative Methods of Preparation of Soluble Keratin from Chicken Feathers
PublicationHuge amount of keratinous waste, especially birds’ feathers, demands more value-added application instead of dumping. The present work reports the results of experiments aimed at preparing soluble keratin useful for novel bioproduct formation. The effect of thermo-chemical treatments with various reducing agents, i.e. 2-mercaptoethanol, dithiothreitol, sodium m-bisulphite, and sodium bisulphite, as well as sodium hydroxide, on...
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Maximizing Bio-Hydrogen and Energy Yields Obtained in a Self-Fermented Anaerobic Bioreactor by Screening of Different Sewage Sludge Pretreatment Methods
PublicationEgypt faces significant challenges in managing its sewage sludge generated in large quantities from wastewater treatment plants. This study investigates the feasibility of utilizing sewage sludge as a renewable resource for hydrogen production through anaerobic digestion at the 100 L bioreactor level. Hydrogen is considered a promising alternative energy source due to its high energy content and environmental benefits. To optimize...
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Rheology of potato starch chemically modified with microwave-assisted reactions
PublicationNative potato starch was sulfated, selenated, borated, silicated and zincatated by means of microwave-assisted reactions with varying doses of relevant reagents. Resulting products were characterized involving rheological behavior of pastes, their weight-average molecular weight (Mw), and radius of gyration (Rg). Most of the pastes showed shear-thinning behavior, with the flow behavior index (n) below unity. The pastes of starch...
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Propagation of acoustic pulses in some fluids with yield stress
PublicationThis study is devoted to the derivation of approximate equations governing acoustic pulses in flows with yieldstress, including some time-dependent flows with a slow dependence on time of yield stress and apparent viscosity. Themodeling of yield stress and apparent viscosity in the vicinity of a zero deformation rate allows us to consider a thixotropicfluid as a Bingham plastic with coefficients that are dependent on time. The...
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Variable-fidelity response feature surrogates for accelerated statistical analysis and yield estimation of compact microwave components
PublicationAccounting for manufacturing tolerances is an essential part of a reliable microwave design process. Yet, quantification of geometry and/or material parameter uncertainties is challenging at the level of full-wave electromagnetic (EM) simulation models. This is due to inherently high cost of EM analysis and massive simulations necessary to conduct the statistical analysis. Here, a low-cost and accurate yield estimation procedure...
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SHEAR YIELD STRESSES AND FRACTURE TOUGHNESS OF SCOTS PINE (PINUS SYLVESTRIS L.) ACCORDING TO THE RAW MATERIAL PROVENANCE
PublicationIn this paper values of the fracture toughness and of shear yield stress in the shear zone of Scots pine are presented. Tests of cutting were carried on samples of Scotch pine (Pinus sylvestris L.) wood of five provenances from Poland. These experimentally cutting tests were carried on the sash gang saw PRW-15M and the values of cutting power were obtained. The values of fracture toughness and shear yield stress based on Atkins’s...
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Hydrological responses to large-scale changes in land cover of river watershed: Review
PublicationDespite many studies on the hydrological responses to forest cover changes in micro and mesoscale watersheds, the hydrological responses to forest cover alterations and associated mechanisms through the large spatial scale of the river watershed have not been comprehensively perceived. This paper thus reviews a wide range of available scientific evidence concerning the impacts exerted by the forest removal on precipitation, water...
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Influence of β-cyclodextrin on coupling reactions of o-nitrobenzenediazonium salt with pyrrole
PublicationThe influence of -cyclodextrin on o-nitrobenzenediazonium salt coupling with pyrrolehas been studied analyzing the yield and products distribution.
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Distinctive properties of Scots pine (Pinus sylvestris L.) originating from the Carpathian and Great Poland-Pomeranian of Nature and Forest Land
PublicationIn this paper values of properties of Scots pine, the fracture toughness and of shear yield stress in the shear zone are presented. Samples of Scotch pine (Pinus sylvestris L.) wood of two provenances from Poland were tested. These properties were determined from the values of cutting power obtained experimentally on the saw frame PRW-15M. The values of fracture toughness and shear yield stress based on the Atkins model for cutting...
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SAWING PROCESS AS A NEW ALTERNATIVE WAY OF DETERMINING SOME WOOD PROPERTIES
PublicationCutting forces (power) could be considered from a point of view of modern fracture mechanics. The developed cutting model, derived from fracture mechanics, includes work of separation (fracture toughness) in addition to plasticity and friction, and also dullness of the cutting edge described by the cutting edge radius. Moreover, forecasting of the shear plane angle for the cutting models, broaden possibilities of energetic effects...
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An Improved Synthesis of Trisodium (R)-Homocitrate from Citric Acid
PublicationA method of synthesis of trisodium (R)-homocitrate starting from citric acid is reported. The procedure affords the final product of high optical purity with satisfactory yield.
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Comparison of Ozonation and Evaporation as Treatment Methods of Recycled Water for Bioethanol Fermentation Process
PublicationThe paper compared the performance of the ethanol yield after alcoholic fermentation with samples of rejected (RW) and permeate water (PW), RW and PW treated by oxidation with ozone (O3) (5 and 15 min) and evaporation, aiming the recirculation back to the bioethanol process. RW and PW were collected after an anaerobic bioreactor (AnBR) used for stillage treatment. Nine types of fermentations were made, where one used 100% tap...
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An optimal designed experiment for the alkaline hydrolysis of feather keratin
PublicationFeathers, burdensome waste from the poultry industry, can be a cheap source of keratin, a protein with excellent physico- chemical, biological, and mechanical properties. Acid and alkaline hydrolyses are usually adopted for isolation of keratin from its natural resources. This study aimed at assessing the statistically significant effect of input variables in the alkaline hydrolysis of keratin from chicken feathers on the process...
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Cutting model parameters from frame sawing of natural and impregnated Scots pine (Pinus sylvestris L.)
PublicationIn this paper, absolute and density normalized cutting model parameters of natural and impregnated Scots pine (Pinus sylvestris L.) are shown and a method for the calculation of their corresponding material properties in the principal material directions of wood is presented. The parameters were determined from measurements of cutting power on a sash gang saw, and are in detail the fracture toughness and the shear yield strength...
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Characterization of novel trehalose synthase from Deinococcus geothermalis.
PublicationThe method of trehalose extraction from yeast or othernatural sources is unsuitable for industrial production becauseof its low yield and high cost. Thus, the trehalose synthesizingenzyme systems that originated from a few microorganisms have been investigated.
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Effect of the Drying Method of Pine and Beech Wood on Fracture Toughness and Shear Yield Stress
PublicationThe modern wood converting processes consists of several stages and material drying belongs to the most influencing future performances of products. The procedure of drying wood is usually realized between subsequent sawing operations, affecting significantly cutting conditions and general properties of material. An alternative methodology for determination of mechanical properties (fracture toughness and shear yield stress) based...
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Efficient Selenenylation of Malonates Using Bis(phosphorothioyl) Diselenide
PublicationBis(O,O-diisopropoxyphosphinothioyl) diselenide reacts readily and quickly with the sodium salt of malonates to give quantitatively stable sodium 2-(O,O-diisopropyl phosphorothioselenenyl)propanedioates. No traces of the corresponding C,C-diselenenylation products were detected. A standard aqueous workup procedure affords the products, albeit in poor yield (about 45%). It was proved that the reaction is reversible due to the presence...
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Dynamics of cutting power during sawing with circular saw blades as an effect of wood properties changes in the cross section
PublicationIn the paper the effect of the method calculation upon the cutting power is presented. In computations were used models in which fracture toughness was incorporated. The comparison concerned models as follows: FM-CM – classic model in which the sum of all uncut chip thicknesses of the simultaneously teeth engaged represented the mean uncut chip thickness, FM-FDM – full dynamical model in which besides variable uncut chip thickness...
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Syntheses and structures of the first terminal phosphanylphosphido complex of hafnium [cp2hf(cl){η1-(me3si)p-p(net2)2}] and the firstzirconocene-phosphanylphosphinidene dimer [cp2zr{μ2-p-p(net2)2}2zrcp2]
PublicationReactions of (Et2N)2P-P(SiMe3)Li with [Cp2MCl2] (M= Zr, Hf) in toluene or pentane yield the related terminal phosphanylphosphido complexes [Cp2M(Cl){η1-(Me3Si)P-P(NEt2)2}]. The solid statestructure of [Cp2Hf(Cl){η1-(Me3Si)P-P(NEt2)2}] was established by single crystal X-ray diffraction. The reaction of (Et2N)2P-P(SiMe3)Li with [Cp2ZrCl2] in THF or DME solutions leads to the formationof deep red crystals of the first neutral diamagnetic...
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A grey box model of glucose fermentation and syntrophic oxidation in microbial fuel cells
PublicationIn this work, the fermentative and oxidative processes taking place in a microbial fuel cell (MFC) fed with glucose were studied and modeled. The model accounting for the bioelectrochemical processes was based on ordinary, Monod-type differential equations. The model parameters were estimated using experimental results obtained from three H-type MFCs operated at open or closed circuits and fed with glucose or ethanol. The experimental...
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Ultimate strength of stiffened plates subjected to compressive load and spatially distributed mechanical properties
PublicationThe present study deals with the ultimate strength of stiffened plates subjected to spatially distributed mechanical properties and compressive load. Normally, mean values of mechanical properties based on tensile tests are used to validate the numerical assessment with experimental results. However, mechanical properties may vary within a single specimen. To investigate the impact of that, random fields of yield stress and Young...
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Oversizing the photovoltaic generator capacity in a micro photovoltaic plant
PublicationA significant part of photovoltaic micro installations in Poland is characterized by photovoltaic generator oversizing in relation to the inverter. The idea of oversizing, however, still raises doubts among some plant owners. In the paper, the energy yield of installation with an oversized and not oversized photovoltaic generator is presented on selected examples, showing the legitimacy of oversizing.
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Biorefinery Approach for H2 and Acids Production Based on Uncontrolled pH Fermentation of an Industrial Effluent
PublicationIn this work, the feasibility of uncontrolled pH acidogenic fermentation of industrial organic effluent from corn-bioethanol production was studied and modelled by using a Monod-based mathematical model. In order to do that, several tests were carried out at different initial pH values, ranging from 4 to 6. The experimental data showed a pH reduction during the fermentation process due to the generation of short-chain acids. When...
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The effect of aeration mode (intermittent vs. continuous) on nutrient removal and greenhouse gas emissions in the wastewater treatment plant of Corleone (Italy)
PublicationThe paper reports the results of an experimental study aimed at comparing two configurations of a full-scale wastewater treatment plant (WWTP): conventional activated sludge (CAS) and oxic-settling-anaerobic process (OSA) with intermittent aeration (IA). A comprehensive monitoring campaign was carried out to assess multiple parameters for comparing the two configurations: carbon and nutrient removal, greenhouse gas emissions, respirometric...
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Estimation of fracture toughness and shear yield stress of orthotropic materials in cutting with rotating tools
PublicationThe cutting force is an energetic effect of splitting material, and might be considered from a point of view of modern fracture mechanics. Forecasting of the shear plane angle in cutting broaden possibilities for modelling of the cutting process even for thin uncut chips. Such mathematical model has been developed here for description of the orthotropic materials’ cutting on the base of fracture theory, and includes work of separation...
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Arabinoxylans: A review on protocols for their recovery, functionalities and roles in food formulations
PublicationArabinoxylans (AXs) are compounds with high nutritional value and applicability, including prebiotics or supplementary ingredients, in food manufacturing industries. Unfortunately, the recovery of AXs may require advanced separation and integrated strategies. Here, an analysis of the emerging techniques to extract AXs from cereals and their by-products is discussed. This review covers distinct methods implemented over the last...
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Rapid Multi-band Patch Antenna Yield Estimation Using Polynomial Chaos-Kriging
PublicationYield estimation of antenna systems is important to check their robustness with respect to the uncertain sources. Since the Monte Carlo sampling-based real physics simulation model evaluations are computationally intensive, this work proposes the polynomial chaos-Kriging (PC-Kriging) metamodeling technique for fast yield estimation. PC-Kriging integrates the polynomial chaos expansion (PCE) as the trend function of Kriging metamodel...
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Vacuum ultraviolet photoionization and ionic fragmentation of the isoxazole molecules
PublicationThe photofragmentation of the isoxazole molecules producing ionized atomic and molecular fragments was investigated in the photon energy range of 9e32 eV, using synchrotron radiation excitation combined with ion time-of-flight spectrometry. Twenty-one well resolved cations were identified in the mass spectra of the isoxazole, and their appearance energies were determined. The yield curves of these cations were obtained in the photon...
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Konzetrationslöschung durch Energieübertragung bei der Lumineszenz von Lösungen
PublicationThe absorption spectra and quantum yields of the fluorescence of rhodamine 6 G are investigated in two different water-glycerol mixtures as a function of the rhodamine concentration. The observed concentration quenching is attributed to the formation of rhodamine dimers and the decrease in quantum yield is compared with theoretical concepts about concentration quenching by energy transfer to the dimers.
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Fast Algorithms for Identification of Time-Varying Systems with Both Smooth and Discontinuous Parameter Changes
PublicationThe problem of noncausal identification of a time-varying linear system subject to both smooth and occasional jump-type changes is considered and solved using the preestimation technique combined with the basis function approach to modeling the variability of system parameters. The proposed estimation algorithms yield very good parameter tracking results and are computationally attractive.
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Determiantion of optimal conditions for the isolation of oil from the fishing industry offal
PublicationFish processing generates significant amounts of offal, which usually is converted into fodder meal or is stored into landfills. However, some part of this offal could serve as a source of valuable products, such as fish oil, collagen or gelatin. the aim of the study was to determine the conditions of oil isolation from salmon skins ensuring high yield and quality of the product.
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Sawing Processes as a Way of Determining Fracture Toughness and Shear Yield Stresses of Wood
PublicationA new computational model, based on fracture mechanics, was used to determine cutting forces. Unlike traditional computing methods, which depend on many coefficients reflecting the machining of solid wood, the new model uses two main parameters: fracture toughness and shear yield stresses. The aim of this study was to apply this new method to determine these parameters for the tooth cutting edge principal positions and longitudinal...
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Reactions of the Lithiated DiphosphinetBu2P-P(SiMe3)Li with [(η6-C6H6)RuCl2]2in the Presence of Tertiary Phosphines
PublicationtBu2P–P(SiMe3)Li reacted with [(η6-C6H6)RuCl2]2at–40 °C in the presence of PR3(PR3=PEt3,PEt2Ph, PEtPh2) by the nucleophilic addition of the tBu2P–P(SiMe3) moiety to the benzene ring to yield solely the complexes [(R3P)2Ru(Cl)-{η5-C6H6(Me3SiP–PtBu2)}] (1). These products decomposed slowly at ambient temperature to yield benzene, Ru clusters, and small amounts of the dinuclear ruthenium complexes [{(R3P)2Ru}2(μ,η2:2-P2)2Ru(PR3)2](Ru–Ru)(6)....
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Ultrasound assisted extraction
PublicationThe use of green and sustainable extraction techniques is very popular topic in the multidisciplinary area of chemistry, biology and technology. There is no doubt that extraction constitutes a very important step of analytical procedures of separation, detection, identification and determination of wide spectrum analytes from samples characterized by complex and very often nonhomogeneous composition of matrix. Traditional techniques...
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5-Selenocyanato and 5-trifluoromethanesulfonyl derivatives of 2′-deoxyuridine: synthesis, radiation and computational chemistry as well as cytotoxicity
Publication5-Selenocyanato-2′-deoxyuridine (SeCNdU) and 5-trifluoromethanesulfonyl-2′-deoxyuridine (OTfdU) have been synthesized and their structures have been confirmed with NMR and MS methods. Both compounds undergo dissociative electron attachment (DEA) when irradiated with X-rays in an aqueous solution containing a hydroxyl radical scavenger. The DEA yield of SeCNdU significantly exceeds that of 5-bromo-2′-deoxyuridine (BrdU), remaining...
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Nanoparticle-assisted biohydrogen production from pretreated food industry wastewater sludge: Microbial community shifts in batch and continuous processes
PublicationBiohydrogen production from industrial waste has gained a significant attention as a sustainable energy source. In this study, the enrichment of biohydrogen production from pretreated dissolved air flotation (DAF) sludge, generated from food industry wastewater treatment plants, was investigated using SiO2@Cu-Ag dendrites cor- e–shell nanostructure (NS). The effect of NS on the changes of the microbial community and biohydrogen...
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Fracture Toughness and Shear Yield Strength Determination for Two Selected Species of Central European Provenance
PublicationWhen offcut of wood is formed by shearing, Atkins’s analyses of sawing processes can be applied. Using this modern approach, it is possible to determine the fracture toughness and shear yield strength of wood. This model is only applicable for the axial-perpendicular cutting direction because both of these parameters are suitable for the given direction of cutting edge movement and cannot be considered material constants. Alternatively,...
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FROM HARVESTING TO DISTILLATION - EFFECT OF ANALYTICAL PROCEDURES ON THE YIELD AND CHEMICAL COMPOSITION OF RHODODENDRON TOMENTOSUM (LEDUM PALUSTRE) ESSENTIAL OIL
PublicationRhododendron tomentosum possesses the anti-inflammatory, analgesic and antimicrobial properties, determined by the chemical composition of its essential oil. The effects of place (Miszewko, Lubichowo) and time of harvesting (June, November) as well as drying (air-drying, oven-drying, freeze-drying) and isolation (in Deryng, Clevenger and Likens-Nickerson apparatus) procedures on the yield and quality of R. tomentosum essential...
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AN ALTERNATIVE WAY OF DETERMINING MECHANICAL PROPERTIES OF WOOD BY MEASURING CUTTING FORCES
PublicationThe cutting force is an energetic effect of splitting material, and might be therefore considered from a point of view of modern fracture mechanics. The dedicated mathematical model developed for description of the wood cutting has been developed here on the base of fracture theory, and includes work of separation (fracture toughness) in addition to the material plasticity and friction. The effect of the cutting edge dullness is...
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Examination of Spectral Properties of Medicinal Plant Leaves Grown in Different Lighting Conditions Based on Mint Cultivation
PublicationCultivation in controlled environmental conditions can provide good quality medicinal herbs with consistent properties. A sensing system that can determine the contents of medicinal substances in plants using spectral characteristics of leaves would be a valuable tool. Viability of such sensing approach for mint had to be confirmed experimentally, as no data correlating contents of medicinal substances with spectral characteristics...
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Effect of Cyclodextrins on Coupling of o-Ethoxybenzenediazonium Salt with Pyrrole, Imidazole and 2-Methylimidazole
PublicationThe effect of b-cyclodextrin on o-ethoxybenzenediazonium salt coupling with pyrrole, imidazole and 2-methylimidazole has been studied. The differences in the reaction course, the overall yield and products distribution have been analyzed. Experiments without cyclodextrins and selected reactions with a- and c-cyclodextrins have been performed for comparison. The results are discussed in terms of co-conformation of azole molecules...
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Report for the Short Term Scientific Mission within COST Action FP1101: development of the in-field sensor for estimation of fracture toughness and shear strength by measuring cutting forces
PublicationKnowledge on the fracture properties of materials is essential to assure structural integrity and proper design of mechanical connections in timber constructions. Measurement of this property is, however, a very challenging task. The linear fracture mechanics is usually used for its assessment assisted with experimental data acquired by means of various techniques, usually of destructive nature. The cutting force is an energetic...
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Biopolyols obtained via microwave-assisted liquefaction of lignin: structure, rheological, physical and thermal properties
PublicationThe present study examined the application of polyols obtained via microwave-assisted liquefaction of lignin in the production of rigid polyurethane foam. Lignin was liquefed in crude glycerol and 1,4-butanediol at diferent temperatures (130–170 °C), without a catalyst and using various biomass concentrations (15 and 30 wt%). The physicochemical properties, process yield, and FTIR-based identifcation of the obtained polyols were...
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VALUATION OF EMBEDDED OPTIONS IN NON-MARKETABLE CALLABLE BONDS: A NEW NUMERICAL APPROACH
PublicationThe issue of how to price options embedded in callable bonds has attracted a lot of interest over the years. The usual bond valuation methods rely on yield curves, risk premium, and other parameters to estimate interest rates used in discounted cash flow calculations. The option to retire the bond is, however, neglected in the standard pricing models, causing a systematic overvaluation of callable bonds. In the event of a decline...
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A graphical approach to yield and boundary surfaces of selected hypoplastic constitutive equations
PublicationThe article describes how to identify the boundary and yield surface for hypoplastic constitutive equations proposed by Wu, Gudehus and Bauer. It is shown how to identify and plot the surfaces for any equation in this class. Calculation errors are analyzed characteristic for appleid set of numerical formulas. In the paper there are computer links to the source code prepared in the MATLAB system, based on istructions in the article....
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Spectral Analysis of Capital Markets
PublicationIn this paper the problem of cycles existence in capital markets is addressed. A spectral analysis algorithm, which reduces signal-to-noise ratio, is proposed to derive cycle periodograms for the yield function of DJIA, WIG~20, and NIKKEI 225 indices. Peaks of the the periodograms provide premises to postulate the existence of some possible cycles. The 3.5 year periodicity in all 3 indices, which can be related to Kitchin cycle...
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Modelling of cutting by means of fracture mechanics
PublicationThe suitability of modern fracture mechanic theory was proved for the estimation of the cutting force and the cutting specific resistance. This paper shows modification of Ernst-Merchant theory and its application for determination some other properties of wood sample. This theory is acceptable for evaluation of shear yield stresses and shear plane angle. Sawing by gang saw machine was used as a process similar to the orthogonal...
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MODELLING OF CUTTING BY MEANS OF FRACTURE MECHANICS
PublicationThe suitability of modern fracture mechanic theory was proved for the estimation of the cutting force and the cutting specific resistance. This paper shows modification of Ernst-Merchant theory and its application for determination some other properties of wood sample. This theory is acceptable for evaluation of shear yield stresses and shear plane angle. Sawing by gang saw machine was used as a process similar to the orthogonal...
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Quaternion Encryption Method for Image and Video Transmission
PublicationQuaternions are hyper-complex numbers of rank 4. They are often applied to mechanics in 3D space and are considered to be one of the best ways of representing rotations. In this paper a quaternion encryption method, based on algorithm by Nagase et al. (2004) has been proposed. According to a computer-based simulation the results of the performed research yield a high level of security, which is additionally strengthened by the...