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Search results for: CORE-SHELL POLYMERS
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Rheology of liquid crystalline polymers
PublicationLiquid crystallinity was invented in the 19th century. It was sometimes called the fourth state of matter because of the ability of macromolecules to generate liquid crystal phases. The main classification divided liquid crystalline polymers (LCPs) into lyotropic and thermotropic types. Interpretation of the rheological behavior of LCP is more complicated than for other polymers. Ordinary polymers are characterized by a normal...
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A higher order shell element for wave propagation in isotropic shell structures
PublicationThe presents the new multi mode higher order shell element for wave propagation problems in shell structures.
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Junctions In Shell Structures: A Review
PublicationMany shell structures used in modern technology consist of regular shell parts joined together along their common boundaries. We review different theoretical, numerical, and experimental approaches to modelling, analyses and design of the compound shell structures with junctions. Several alternative forms of boundary, continuity and jump conditions at the singular midsurface curves modelling the shell junction are reviewed. We...
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Shape-Memory Polyurethane Polymers
PublicationPolyurethanes (PUs) are one of the most widely used polymers in research and industry. They can be synthesized from chemical sources and natural sources. PUs are a very useful class of polymers and exhibit many desirable properties that can be exploited in various applications. PUs are formed by the reaction between polyols and isocyanates. A wide variety of polyols and isocyanates are available for synthesis, and hence we can...
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Polymers doped by Ca or P. Chemical composition investigations
Open Research DataThe calcium and phosphorus doped polyurethane polymers (PU) were analyzed by XPS method. A series of samples with various content of Ca and P dopand - from 0% up to 21%) were selected for measutements. The chemical composition and valence state of elements were measurements using OmicronNatechnology UHV system wih Argus hemispherical photoelectron...
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A Nonlinear Model of a Mesh Shell
PublicationFor a certain class of elastic lattice shells experiencing finite deformations, a continual model using the equations of the so-called six-parameter shell theory has been proposed. Within this model, the kinematics of the shell is described using six kinematically independent scalar degrees of freedom — the field of displacements and turns, as in the case of the Cosserat continuum, which gives reason to call the model under consideration...
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On Wrinkling in Sandwich Panels with an Orthotropic Core
PublicationThis paper deals with the local loss of stability (wrinkling) problem of a thin facing of a sandwich panel. Classical solutions to the problem of facing instability resting on a homogeneous and isotropic substructure (a core) are compared. The relations between strain energy components associated with different forms of core deformations are discussed. Next, a new solution for the orthotropic core is presented in detail, which...
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Synthesis and electrochemical characteristics of novel dithiocarbamate polymers
PublicationNovel dithiocarbamate compounds have been obtained by reacting a linear poly(ethylenimine)polymer, MW 50,000, with CS2. The resulting anionic polymers contain, depending on the reaction conditions, up to two sulfur atoms per one nitrogen atom (approx. 40% w/w). The polymers are soluble in dimethylsulfoxide and insoluble in acetonitrile solutions. In both solvents they are electrochemically active, in the latter case as a cast film...
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SciPost Physics Core
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Water Footprint Assessment of Selected Polymers, Polymer Blends, Composites, and Biocomposites for Industrial Application
PublicationThis paper presents a water footprint assessment of polymers, polymer blends, composites, and biocomposites based on a standardized EUR-pallet case study. The water footprint analysis is based on life cycle assessment (LCA). The study investigates six variants of EUR-pallet production depending on the materials used. The system boundary included the production of each material and the injection molding to obtain a standardized...
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ON AXIALLY SYMMETRIC SHELL PROBLEMS WITH REINFORCED JUNCTIONS
PublicationWithin the framework of the six-parameter nonlinear resultant shell theory we consider the axially symmetric deformations of a cylindrical shell linked to a circular plate. The reinforcement in the junction of the shell and the plate is taken into account. Within the theory the full kinematics is considered. Here we analyzed the compatibility conditions along the junction and their in uence on the deformations and stressed state.
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Synthesis and polymerisation techniques of molecularly imprinted polymers
PublicationMolecularly Imprinted Polymers (MIPs) are materials that has been processed using the molecular imprinting technique which permit to obtain well-defined three-dimensional cavities, with affinity to a template molecule, in the polymer matrix. Technology involves three strategies, i.e., covalent, non-covalent and semi-covalent approach, but the most popular is non-covalent approach. The most important components for the synthesis...
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Novel Biomass-Based Polymers: Synthesis, Characterization, and Application
PublicationA wide range of polymers were prepared from biomass-derivatives, using different polymerization mechanisms. Well-defined, fully hydroxy-functional polyesters based on aliphatic diols were synthesized, using either conventional metal-based catalysts or the organic superbase 1,5,7-triazabicyclododecene (TBD). Unsaturated polyesters were also made, offering additional functionality to these biobased resins. Metal-catalyzed or enzymatic...
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On mechanics of piezocomposite shell structures
PublicationThis study presents an original and novel investigation into the mechanics of piezo-flexo-magneto-elastic nanocomposite doubly-curved shells (PFMDCSs) and the ability to detect the lower and higher levels of electro-magnetic fields. In this context, by utilizing the first-order shear deformation shell model, stresses and strains are acquired. By imposing Hamilton's principle and the von Kármán approach, the governing equations...
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REACTIVE & FUNCTIONAL POLYMERS
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Polymers in High-Efficiency Solar Cells: The Latest Reports
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The progress in technology of biodegradable polymers
e-Learning CoursesKurs obejmuje 15 godz. Wykładów (18-22.01. 2021)z zagadnień związanych z omówieniem różnych polimerów biodegradowalnych, ich syntezą i postąpami w otrzymywaniu, analizie, zastosowaniu.
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On the generalized model of shell structures with functional cross-sections
PublicationIn the present study, a single general formulation has been presented for the analysis of various shell-shaped structures. The proposed model is comprehensive and a variety of theories can be used based on it. The cross-section of the shell structure can be arbitrarily analyzed with the presented equations. In other words, various types of shell structures, including cylindrical, conical, spherical, elliptical, hyperbolic, parabolic,...
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Method of determining the residual fluxes in transformer core
PublicationThe article presents the method of calculating the residual induction in transformer columns. The method is based on measurement of the magnetic induction in selected points around the transformer core. The values of residual induction are calculated as linear combination of the results of measurement.
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Torsional stability capacity of a nano-composite shell based on a nonlocal strain gradient shell model under a three-dimensional magnetic field
PublicationThis paper considers a single-walled composite nano-shell (SWCNS) exposed in a torsional critical stability situation. As the magnetic field affects remarkably nanostructures in the small size, a three-dimensional magnetic field is assessed which contains magnetic effects along the circumferential, radial and axial coordinates system. Based on the results of the nonlocal model of strain gradient small-scale approach and the first-order...
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Biodegradable polymers for food packaging - factors influencing their degradation and certification types - a comprehensive review
PublicationIn the paper an overview of novel biodegradable polymers for food packaging can be found. The aim was to present factors influencing polymer degradation and biodegradation in various environments. It was noted that biodegradable polymers are imperfect alternative for classical polymers and its decomposition strongly depends on degradation environment.
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PU Polymers, Their Composites, and Nanocomposites: State of the Art and New Challenges
PublicationThe chapter is a review of the polyurethane(PU)-based composites and nanocomposites. The chapter details different components in the manufacturing of PU polymers, composites, and nanocomposites. The different types of glycols, isocyanates, and catalysts that are used for the synthesis of different polyurethanes are discussed. The applications and specialties of polyurethane composites and nanocomposites are also elaborated on.
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MAKING OF FERROMAGNETIC ELLIPTICAL SHELL IN TRANSVERSE MAGNETIC
PublicationA ferromagnetic object, located in the Earth’s magnetic field, changes its distribution. Through measuring such disturbances, one can locate the object and destroy it. To conceal the object, a special winding is placed inside its ferromagnetic shell, and its task is to eliminate the disturbances in the distribution of the Earth’s magnetic field.
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HEAT TRANSFER CHARACTERISTICS OF ENHANCED SHELL AND COIL HEAT EXCHANGER
PublicationIn the paper authors presented their own constructions of shell and tube heat exchangers with intensified heat transfer. The shell and coils heat exchangers are in common use in heat ventilations and air conditioning systems. Those types of recuperators are quite simple constructions, the low value of pressure drops and good conditions of heat transfer. The present study shows an experimental investigation of the heat transfer...
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Star Polymers vs. Dendrimers: Studies of the Synthesis Based on Computer Simulations
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Bringing a New Flexible Mercaptoacetic Acid Linker to the Design of Coordination Polymers
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Ni-based compounds in multiwalled graphitic shell for electrocatalytic oxygen evolution reactions
Open Research DataThis study investigates Ni-based compounds (Ni, NiO, Ni3C) coated with a graphitic shell as electrocatalysts for the oxygen evolution reaction (OER). Electron paramagnetic resonance (EPR) and X-ray diffraction (XRD) are employed to identify the presence and contribution of Nickel ions (Ni0, Ni2+, Ni3+) and determine the phase composition. Electrochemical...
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Photovoltaic bulk heterojunctions with interpenetrating network based on semiconducting polymers
PublicationPhotovoltaic cells are supposed to be the most common generators of useful electricity in the nearest future as they utilize inexhaustible carriers of renewable energy called photons. Despite the fact that 95% of worldwide applied photovoltaic devices are based on inorganic semiconductors the area of organic photovoltaics grows successively due to possibility of considerable reduction of manufacturing costs. Since the Heeger's...
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IP Core of Coprocessor for Multiple-Precision-Arithmetic Computations
PublicationIn this paper, we present an IP core of coprocessor supporting computations requiring integer multiple-precision arithmetic (MPA). Whilst standard 32/64-bit arithmetic is sufficient to solve many computing problems, there are still applications that require higher numerical precision. Hence, the purpose of the developed coprocessor is to support and offload central processing unit (CPU) in such computations. The developed digital...
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Computations of critical load value of composite shell with random geometric imperfections
PublicationThe work presents the numerical analysis of composite shell with geometric imperfections subjected to compression along its generatrix. The imperfections are described as single indentations and random fields with random parameters of shape and correlation. The fields are generated with the use of the authors made program. Using the authors’ FEM software as well as commercial package Femap with NX Nastran, the critical load values...
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Multi Queue Approach for Network Services Implemented for Multi Core CPUs
PublicationMultiple core processors have already became the dominant design for general purpose CPUs. Incarnations of this technology are present in solutions dedicated to such areas like computer graphics, signal processing and also computer networking. Since the key functionality of network core components is fast package servicing, multicore technology, due to multi tasking ability, seems useful to support packet processing. Dedicated...
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Molecularly imprinted polymers for the detection of volatile biomarkers
PublicationIn the field of cancer detection, the development of affordable, quick, and user-friendly sensors capable of detecting various cancer biomarkers, including those for lung cancer (LC), holds utmost significance. Sensors are expected to play a crucial role in the early-stage diagnosis of various diseases. Among the range of options, sensors emerge as particularly appealing for the diagnosis of various diseases, owing to their cost-effectiveness,...
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Correlation between natural frequencies and buckling load in a stiffened shell
PublicationThe paper deals with correlation between natural frequencies and buckling load of a stiffened shell composed of corrugated sheets and vertical stiffeners (columns). The simplified shell segment represents the buckling behaviour of a whole silo with sparsely distributed columns. The paper covers variants of linear buckling anal-yses, dynamic eigenvalue analyses and geometrically non-linear analyses of a segment modelled with shell...
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The point estimate method in a reticulated shell reliability analysis
PublicationThe objective of this paper is to present an application of the point estimate method (PEM) that can determine the probabilistic moments for engineering structures. The method is reasonably robust and adequately accurate for a wide range of practical problems. It is a special case of numerical quadrature based on orthogonal polynomials. The main advantage of this method is that, unlike FORM or SORM, it is not necessary to carry...
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On rotational instability within the nonlinear six-parameter shell theory
PublicationWithin the six-parameter nonlinear shell theory we analyzed the in-plane rotational instability which oc- curs under in-plane tensile loading. For plane deformations the considered shell model coincides up to notations with the geometrically nonlinear Cosserat continuum under plane stress conditions. So we con- sidered here both large translations and rotations. The constitutive relations contain some additional mi- cropolar parameters...
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Multi-core and Multiprocessor Implementation of Numerical Integration in Finite Element Method
PublicationThe paper presents techniques for accelerating a numerical integration process which appears in the Finite Element Method. The acceleration is achieved by taking advantages of multi-core and multiprocessor devices. It is shown that using multi-core implementation with OpenMP and a GPU acceleration using CUDA architecture allows one to achieve the speedups by a factor of 5 and 10 on a CPU and GPUs, respectively.
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E-POLYMERS
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PLASMAS AND POLYMERS
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Polyurethanes modified with natural polymers for medical application. I. Polyurethanes/ Chitosan and polyurethane/collagen.
PublicationFor over three decades polyurethanes (PUR or PU) have been reported for application in a variety of medical devices. These polymers consist of hard and soft segments, which allow for more subtle control of their structure and properties. By varying the composition of the different segments, properties of PURcan be tuned up for use in many areas of medicine. Recently there is a great interest in modification of biomedical PUR with...
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Marine polymers in tissue bioprinting: Current achievements and challenges
PublicationBioprinting has a critical role in tissue engineering, allowing the creation of sophisticated cellular scaffolds with high resolution, shape fidelity, and cell viability. Achieving these parameters remains a challenge, necessitating bioinks that are biocompatible, printable, and biodegradable. This review highlights the potential of marine-derived polymers and crosslinking techniques including mammalian collagen and gelatin along...
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Elastoplastic law of Cosserat type in shell theory with drilling rotation
PublicationWithin the framework of six-parameter non-linear shell theory, with strain measures of the Cosserat type, we develop small-strain J2-type elastoplastic constitutive relations. The relations are obtained from the Cosserat plane stress relations assumed in each shell layer, by through-the-thickness integration employing the first-order shear theory. The formulation allows for unlimited translations and rotations. The constitutive...
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The Point Estimate Method in a Reticulated Shell Reliability Analysis
PublicationThe objective of this paper is to present an application of the point estimate method (PEM) to determine the probabilistic moments for engineering structures. Reliability analysis is illustrated by two examples: an estimation of the critical force in linear elastic buckling analysis and a reticulated shell limit load determinations. Calculations were also made using Monte Carlo method. It has been shown the practical usefulness...
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Shell model of multiple-row moment I-section end-plate joint
PublicationThe paper deals with a problem of application of shell elements in the models of multiple-row moment end-plate connections. The extended connection of I-section with a cross-section W760x265x220 made of steel S355 was analyzed. Comparison analysis of FEM, complex volume and shell models has been done. Three cases with different end-plate thickness: 14, 18 and 36 mm were analyzed and compared with the reference results. Comparison...
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Chitin nanowhiskers from shrimp shell waste as green filler in acrylonitrile-butadiene rubber: Processing and performance properties
PublicationIn this work, chitin nanowhiskers with high crystallinity index were obtained from shrimp shells waste using acid hydrolysis method and then comprehensively characterized. Subsequently, the impact of chitin nanowhisker content on processing and performance of acrylonitrile-butadiene rubber based nanocomposites was evaluated. The results showed that the addition of chitin nanowhiskers increased tensile strength and tear strength...
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Effect of modified soybeen oil amount on rheological characteriza-tion of polyurethane pre-polymers
PublicationPolyurethanes (Pu’s) are the polymeric materials which have got urethane groups in the structure. The properties of Pu’s depend both on the method of preparation and monomers used. Polyurethanes are produced by two methods known as one step or two step method called as “pre-polymers method”, especially for the case of segmented polyurethanes (SPU’s). These materials are thermoplastic block copolymers of the (AB)n type consisting...
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Thermal Energy Storage with PCMs in Shell-and-Tube Units: A Review
PublicationThe paper presents a survey of the experimental and numerical studies of shell-and-tube systems in which phase change material (PCM) is used. Due to the multitude of design solutions for shell-and-tube systems, the emphasis is placed on double-tube (DT), triplex-tube (TT), and multitube (MT) units. Additionally, only single-pass systems are considered. Particular attention is paid to the method of heat transfer intensification....
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Catalysis, process design and industrial production of polymers
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On jump conditions at non-material singular curves in the resultant shell thermomechanics
PublicationThe global, refined, resultant, two-dimensional (2D) balance laws of mass, linear and angular momenta, and energy as well as the entropy inequality were formulated by Pietraszkiewicz (2011) as exact implications of corresponding laws of 3D rational thermomechanics. In case of a shell with the regular base surface and all resultant surface fields differentiable everywhere on it and at any time instant, the local laws of the resultant...
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Performance of the domestic micro ORC equipped with the shell-and-tube condenser with minichannels
PublicationIn this paper, the original compact shell-and-tube heat exchanger with circular minichannels of in-house design and manufacturing is presented as the condenser for the domestic micro heat and power plant investigations as well as other future technical applications. The heat exchanger is equipped with turbulizing baffles inside the shell. The shell itself is made of a tubular sleeve having an inner diameter of 0.067 m and the length...
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Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
PublicationThree novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The...