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Search results for: CHITOSAN FILM
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Substrate Dependence in the Formation of Au Nanoislands for Plasmonic Platform Application
PublicationIn this work, the influence of the various substrates on Au nanoisland formation has been studied. Nanostructures were obtained via annealing of thin Au films. In order to determine nanoisland formation mechanisms, correlation between an initial film thickness and temperature of formation, shapes, and dimensions of nanostructures was examined. For the surface morphology studies, nanograin structure, and chemical composition analysis,...
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Determination of dryout localization using a five-equation model of annular flow for boiling in minichannels
PublicationDetailed studies have suggested that the critical heat flux in the form of dryout in minichannels occurs when the combined effects of entrainment, deposition, and evaporation of the film make the film flow rate go gradually and smoothly to zero. Most approaches so far used the mass balance equation for the liquid film with appropriate formulations for the rate of deposition and entrainment respectively. It must be acknowledged...
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The effect of alkyl chain length on synergistic effects in micellization and surface tension reduction in nonionic gemini (S-10) and anionic surfactants mixtures
PublicationMixtures of nonionic gemini surfactant S-10 ( α, α'-[2,4,7,9-tetrametyl-5-decyne-4,7-diyl]bis[ω-hydroxy -polioxyetylene] with anionic SRS (sodium alkylsulfates) and SRSO3 (sodium alkylsulfonates) of different alkyl chain length (from 10 to 14 carbon atoms) were investigated. Surface tension measurements were used to find the cmc values and other adsorption parameters. The Clint, Rubingh’s and Rosen theories were applied for evaluation...
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Preparation and characterization of TiO2 nanostructures for catalytic CO2 photoconversion
PublicationThe titanium dioxide target (99.7%) of 1 cm in dia was ablated in vacuum by laser pulses(6 ns) at 266 nm and at repetition rate of 10 Hz. During deposition the laser fluence between 1 and 3.5 J/cm2 and the O2 pressure from the range of 10-2 - 1 Pa were applied. The thin TiO2 films were deposited on glass substrate (1 × 1 cm2) heated up to 500 °C. The chemical composition of the film and samples produced by annealing were investigated...
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The importance of individual spray properties in performance improvement of a urea-SCR system employing flash-boiling injection
PublicationThe appropriate mixing of a urea–water solution (UWS) with exhaust gases in a selective catalytic reduction system is crucial to efficiently reduce nitrogen oxides and diminish the deposition of liquid wall film. One of the methods to enhance the mixing of the UWS with the exhaust gases is a flash-boiling injection. Its positive effect has been linked with a reduced Sauter mean diameter (SMD) and improved evaporation, but the...
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Logistyczny proces wyboru dostawcy w tworzeniu marki własnej produktów spożywczych. Analiza przypadku polskich firm spożywczych na rynku afrykańskim
PublicationTematem głównym artykułu była analiza procesu wyboru dostawcy w tworzeniu marki własnej produktów spożywczych. W/w analiza dotyczyła przypadku polskich firm spożywczych na rynku afrykańskim. Dane do artykułu zostały zebrane przez autora w trakcie trzyletniego procesu selekcji dostawców marek własnych, dla czołowej sieci handlowej z RPA, oraz nadzorowania dostaw do sześciu krajów afrykańskich. Badanie prezentuje praktyczną metodę...
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Optical and structural properties of polycrystalline CVD diamond films grown on fused silica optical fibres pre-treated by high-power sonication seeding
PublicationIn this paper, the growth of polycrystalline chemical vapour deposition (CVD) diamond thin films on fused silica optical fibres has been investigated. The research results show that the effective substrate seeding process can lower defect nucleation, and it simultaneously increases surface encapsulation. However, the growth process on glass requires high seeding density. The effects of suspension type and ultrasonic power were...
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The influence of hydrophobic substances on water vapor permeability of fish gelatin films modified with transglutaminase or 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC)
PublicationFolie z niemodyfikowanej, a także usieciowanej enzymatycznie (transglutaminazą) lub chemicznie (EDC) żelatyny rybnej wykazują nadmierną przepuszczalność pary wodnej. Polepszenie właściwości barierowych w stosunku do wody uzyskano poprzez wprowadzenie w struktury folii substancji hydrofobowych. Dodatek oleju z amarantusa lub wosku pszczelego spowodował zmniejszenie WVP folii o ok. 20-90% w zależności od stężenia tych substancji...
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Electrochemicalsynthesis of 3D nano-/micro-structured porous polypyrrole
PublicationIn this work, electrosynthesis of electroactive, 3D nano-/micro-structured porous polypyrrole film is presented. The PPy film was synthesized potentiostatically in a one-step process from aqueous solution of pyrrole and lithium perchlorate. The growth mechanism of such structure included: the formation of typical globular PPy film, followed by the formation of the PPy fibers, which then took part in the formation of 3D highly porous...
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Corrigendum to “Ordered titanium templates functionalized by gold films for biosensing applications – Towards non-enzymatic glucose detection” [Talanta 166 (2017) 207–214]
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Deposition and characterization of organic polymer thin films using a dielectric barrier discharge with different C2Hm/N2 (m = 2, 4, 6) gas mixtures
PublicationOrganic polymer thin films have been deposited on Si(100) and aluminum coated glass substrates by a dielectric barrier discharge (DBD) operated at medium pressure using different C2Hm/N2 (m = 2, 4, 6) gas mixtures. The deposited films were characterized by various spectroscopic techniques. Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS) revealed the chemical functional groups present in the films. The surface...
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Simultaneous Recovery of Precious and Heavy Metal Ions from Waste Electrical and Electronic Equipment (WEEE) Using Polymer Films Containing Cyphos IL 101
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Subjective tests for gathering konwledge for applaying color grading to video clips automatically
PublicationThe analysis of film music concerning caused emotions may allow for a more accurate adaptation of the color of the film in the context of color grading. Therefore, this paper aims to gather knowledge on the correlation between the applied color palette to a video clip, music associated with a particular shot,and emotions evoked. For that purpose, subjective tests are prepared in which several video clips are presented with...
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Subjective tests for gathering knowledge for applying color grading to video clips automatically
PublicationThe analysis of film music concerning caused emotions may allow for a more accurate adaptation of the color of the film in the context of color grading. Therefore, this paper aims to gather knowledge on the correlation between the applied color palette to a video clip, music associated with a particular shot, and emotions evoked. For that purpose, subjective tests are prepared in which several video clips are presented with or...
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Biomass-Derived Nitrogen Functionalized Carbon Nanodots and Their Anti-Biofouling Properties
PublicationThe prevalence of the antibiotic resistant bacteria remains a global issue. Cheap, sustainable and multifunctional antibacterial membranes are at the forefront of filtrating materials capable of treating multiple flow streams, such as water cleansing treatments. Carbon nanomaterials are particularly interesting objects shown to enhance antibacterial properties of composite materials. In this article, amino-functionalized, photoluminescent...
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New plasmonic platform for enhanced luminescence of Valrubicin
PublicationLuminescence enhanced by new structure of plasmonic platform with aluminum oxide (Al2O3) buffer layer deposited on gold nanostructures is investigated. Regularly distributed gold nanostructures of average dimension of 50 nm formed the active part of plasmonic platforms. They were manufactured on Corning 1737 glass substrate by melting of gold thin film. The nanostructures were coated by dielectric Al2O3 thin film with thickness...
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Influence of electropolymerization temperature on corrosion, morphological and electrical properties of PPy doped with salicylate on iron
PublicationIn this work, the influence of the electropolymerization temperature on corrosion, morphological and electrical properties of polypyrrole (PPy) film is studied. Polypyrrole is electrochemically synthesized on iron in the presence of sodium salicylate. The X-ray diffraction and scanning electron microscopy are performed in order to study the structure and morphology of electrodeposited PPy. The electroactive surface area, corrosion...
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Electrolytic deposition of reactive element thin films on Crofer 22 APU and evaluation of the resulting high-temperature corrosion protection properties at 700 °C–900 °C
PublicationThis article presents electrolytic deposition of thin Rare Earth (RE) coatings on Crofer 22 APU stainless steel substrates for high temperature applications, such as interconnects in solid oxide cell stacks. The deposition of coatings based on yttrium-, gadolinium-, lanthanum-, and cerium nitrates is discussed. The high temperature corrosion properties of surface-modified steels were examined using thermogravimetry and electrical...
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Experimental study of boiling heat transfer in the stagnation point of water microjet
PublicationIn the paper presented is a comparison of computational model with experimental data. Numerical model of liquid film with phase change in the stagnation zone due to impingement of the microjet is more widely presented in authors previous work. The radius on which theevaporation process is taking place can be determined from the energy balance on the element of the plate. That radius has also been confirmed experimentally in the...
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Enhanced capacitance of composite TiO2 nanotube / boron-doped diamond electrodes studied by impedance spectroscopy
PublicationWe report on the novel composite nanostructures based on boron-doped diamond thin film grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (~200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2...
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Flow visualization and heat transfer investigations on the flat plate with streamwise pressure gradient
PublicationPaper presents experimental investigations results for film cooling on a flat plate. The main objective of the design is the streamwise pressure distribution on the flat plate as in the blade cascade. The transient and steady-state technique with liquid crystals for the surface temperature distribution with film cooling has been used in experiments in a low speed wind tunnel.
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Running characteristics of aerodynamic bearing with self-lifting capability at low rotational speed
PublicationAn aerodynamic journal bearing that is capable of self-generating squeeze-film pressure is presented and its dynamic characteristics investigated numerically and experimentally. A numerical method based on a time marching static model was applied to assess the orbit trajectory path of the rotor upon a perturbation. Experimental results were obtained to validate the effect of the self- generated squeeze-film pressure on the stability...
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The effect of transglutaminase or 1-ethyl-3-(3-dimethyl amino propyl) carbodimide (EDC) on the properties of two-component films fromfish-skin gelatin and other natural polymers
PublicationBadania dotyczą wpływu transglutaminazy na rozpuszczalność, właściwości mechaniczne oraz przepuszczalność pary wodnej dwuskładnikowych folii z żelatyny rybnej z dodatkiem kazeiny, białek soi, białek jaja kurzego lub pektyn. Dla porównania przeprowadzono równolegle modyfikacje chemiczne przy użyciu EDC.
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Salt melt synthesis of curved nitrogen-doped carbon nanostructures: ORR kinetics boost
PublicationImplementing metal-free electrocatalysts for the oxygen reduction reaction (ORR) and revealing crucial chemical or topographical parameters driving their activity are vital for the development of power cells. The carbon-based catalysts are very often synthesized through carbonization of biopolymers, in particular, those one containing nitrogen groups such as chitosan. Unfortunately, the resulting carbonaceous materials usually...
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Support Materials of Organic and Inorganic Origin as Platforms for Horseradish Peroxidase Immobilization: Comparison Study for High Stability and Activity Recovery
PublicationIn the presented study, a variety of hybrid and single nanomaterials of various origins were tested as novel platforms for horseradish peroxidase immobilization. A thorough characterization was performed to establish the suitability of the support materials for immobilization, as well as the activity and stability retention of the biocatalysts, which were analyzed and discussed. The physicochemical characterization of the obtained...
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MODELE TRANSFERU BIZNESU DOSTOSOWANE DO POTRZEB FIRM RODZINNYCH Z SEKTORA MSP W REGIONIE MORZA BAŁTYCKIEGO – CELE I ZADANIA W PROJEKCIE INBETS BSR
PublicationOpisano kontekst i cele projektu Innovative Business Transfer Models for SMEs in the BSR (INBETS BSR) współfinansowanego z Europejskiego Funduszu Rozwoju Regionalnego w ramach Programu Regionu Morza Bałtyckiego w latach 2014-2020. W projekt zaangażowanych jest czternastu partnerów z regionu Morza Bałtyckiego: Danii, Estonii, Finlandii, Litwy, Łotwy, Niemiec, Polski, Rosji i Szwecji. Rolę lidera projektu pełni Baltic Sea Academy...
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Effects of metallic silver island films on resonance energy transfer between N,N´-(dipropyl)-tetramethylindocarbocyanine (Cy3)- and N,N´-(dipro- pyl)-tetramethylindodicarbocyanine ( Cy5 )-labeled DNA.
PublicationZbadano nową metodę zwiększania odległości rezonansowego przekazywania energii poprzez umieszczanie znakowanych donorami i akceptorami oligomerów DNA pomiędzy dwoma płytkami pokrytymi nanocząsteczkami metalicznego srebra.
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The impact of brand communication on brand equity through Facebook
PublicationPurpose The purpose of this study is to fill the gap in the discussion of the ways in which firm-created and user-generated social media brand communication impacts consumer-based brand equity metrics through Facebook. Design/methodology/approach We evaluated 302 data sets that were generated through a standardized online-survey to investigate the impact of firm-created and user-generated social media brand communication on brand...
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Induced-fit binding of laccase to gold and carbon electrodes for the biological fuel cell applications
PublicationAnalogues of laccase natural substrates (syringic, veratric, ferulic, vanillic, isovanillic, 3,5-dimethoxybenzoic aldehydes) were employed to bind and orient laccase molecules in a way which facilitates adsorption of the catalyst molecules and their electrical connection with the conductive support. Laccase was bound efficiently to these substrates both on gold and carbon electrodes forming, respectively, 2D and 3D films sensitive...
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Room temperature depinning of the charge-density waves in quasi-two-dimensional 1T-TaS2 devices
PublicationWe report on the depinning of nearly commensurate charge-density waves in 1T-TaS2 thin films at room temperature. A combination of the differential current–voltage measurements with the low-frequency noise spectroscopy provides unambiguous means for detecting the depinning threshold field in quasi-2D materials. The depinning process in 1T-TaS2 is not accompanied by an observable abrupt increase in electric current—in striking contrast...
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Photocatalytic Decomposition of Air Pollutants using Electrodeposited Photocatalysts on Stainless Steel
PublicationThe aim of research was to develop an immobilization method for photocatalysts, which is an alternative to the sol-gel or dip coating methods and can be simply scaled up for technical applications. The investigated photocatalyst was TiO2, which was electrochemically deposited onto a cathode made of stainless steel. This deposited film was photocatalytically active. In order to enhance the photoactivity of the TiO2 film, commercially...
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Exploring the interfacial effects at the ETL/perovskite boundary in the semitransparent perovskite solar cells
PublicationThe recent focus has been made on the perovskite solar cells (PSCs) with an inverted configuration, where substantial improvements have been already achieved. However, the p–i–n structure needs a buffer layer for most of the configurations to modify the work-function of a deposited electrode. Additionally and very importantly, such a layer can also serve as a protective film that improves a stability of solar cells. Here, we study...
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Physicochemical and Mechanical Performance of Freestanding Boron-Doped Diamond Nanosheets Coated with C:H:N:O Plasma Polymer
PublicationThe physicochemical and mechanical properties of thin and freestanding heavy boron-doped diamond (BDD) nanosheets coated with a thin C:H:N:O plasma polymer were studied. First, diamond nanosheets were grown and doped with boron on a Ta substrate using the microwave plasma-enhanced chemical vapor deposition technique (MPECVD). Next, the BDD/Ta samples were covered with nylon 6.6 to improve their stability in harsh environments and...
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Antibacterial Porous Systems Based on Polylactide Loaded with Amikacin
PublicationThree porous matrices based on poly(lactic acid) are proposed herein for the controlled release of amikacin. The materials were fabricated by the method of spraying a surface liquid. Description is given as to the possibility of employing a modifier, such as a silica nanocarrier, for prolonging the release of amikacin, in addition to using chitosan to improve the properties of the materials, e.g., stability and sorption capacity....
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Experimental tests for the determination of mechanical properties of PVC foil
PublicationThe paper presents an application of the PVC film in civil engineering. Mechanical behaviour of the PVC film applied for suspended ceilings, in the form of a stretch ceiling is investigated under uniaxial and biaxial tensile tests. The study is focused on the determination of mechanical properties from experimental data (uniaxial and biaxial tensile tests). The uniaxial cyclic tests are performed in order to observe a variation...
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Predicting emotion from color present in images and video excerpts by machine learning
PublicationThis work aims at predicting emotion based on the colors present in images and video excerpts using a machine-learning approach. The purpose of this paper is threefold: (a) to develop a machine-learning algorithm that classifies emotions based on the color present in an image, (b) to select the best-performing algorithm from the first phase and apply it to film excerpt emotion analysis based on colors, (c) to design an online survey...
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Influence of Fragment Size on the Time and Temperature of Ethylene Vinyl Acetate Lamination Decomposition in the Photovoltaic Module Recycling Process
PublicationPhotovoltaics is a commercially available and reliable technology with significant potential for long-term growth in nearly all global regions. Several research institutes and companies are working on recycling concepts for thin film modules and modules with crystalline cells. The establishment of recycling and reuse technologies appropriate and applicable to all photovoltaics (PV) modules is a key issue to be addressed as part...
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Electrochemical Activity and Electrical Properties of Optimized Polypyrrole Coatings on Iron
PublicationIn this work, electrochemical activity and electrical properties of polypyrrole (PPy) coated iron electrodes have been investigated. PPy film was electrochemically polymerized from sodium salicylate aqueous solution under conditions, which provided an increase of iron corrosion resistance. It was noticed that the pH of the solution and the applied electrode potential range during the study of the polymer properties had an influence...
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Biopolymer based nanomaterials in drug delivery systems: A review
PublicationDrug delivery systems (DDS) are used to achieve a higher therapeutic effects of a pharmaceutical drug or natural compound in a specific diseased site with minimal toxicological effect and these systems consists of liposomes, microspheres, gels, prodrugs and many. Nanotechnology is a rapidly developing multi-disciplinary science that ensures the fabrication of the polymers to nanometer scale for various medical applications. Uses...
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Characterization and Technical Application of Fine Photocatalytical Particles - A Study of the Immobilization of Photocatalysts
PublicationThe main aim of this dissertation was the transfer of photocatalytical laboratory scale experiments to semi-technical scale. Preliminary experiments of the purification of organic chlorine-loaded waters and the immobilization of photocatalysts were performed, which yielded the research back to the roots of synthesis. The first applied research was carried out on treatment of recreational water. Several light sources, particularly...
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Tilting pad thrust bearing with novel material selection - experimental comparison of low and medium speed operation
PublicationThe advances in material engineering led to the development of hard carbon based coatings applied in numerous applications in order to prevent or minimize wear of the parts in contact. With Triondur® coatings, the bearing company Schaeffler has succeeded in halving the friction losses in the valve trains of passenger cars. The coatings are optimized for high abrasive wear protection and low sliding friction moments. Altogether...
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A subset of two adherence systems, acute pro-inflammatory pap genes and invasion coding dra, fim, or sfa, increases the risk of Escherichia coli translocation to the bloodstream
PublicationAn analysis of the phylogenetic distribution and virulence genes of Escherichia coli isolates which predispose this bacteria to translocate from the urinary tract to the bloodstream is presented. One-dimensional analysis indicated that the occurrence of P fimbriae and α-hemolysin coding genes is more frequent among the E. coli which cause bacteremia. However, a two-dimensional analysis revealed that a combination of genes coding...
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Unraveling the role of boron dimers in the electrical anisotropy and superconductivity in boron-doped diamond
PublicationWe use quantum mechanics (QM) to determine the states formed by B dopants in diamond. We find that isolated B sites prefer to form BB dimers and that the dimers pair up to form tetramers (BBCBB) that prefer to aggregate parallel to the (111) surface in the <110> direction, one double layer below the H-terminated surface double layer. These tetramers lead to metallic character (Mott metal Insulator Transition) with holes in the...
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Chemorezystancyjny czujnik gazu na bazie polimeru przewodzącego PEDOT
PublicationPolimery przewodzące, takie jak Poli(3,4-etylenodioksytiofen) (PEDOT) są atrakcyjnymi materiałami elektrodowymi, które posiadają takie zalety, jak biokompatybilność, duża przewodność i elastyczność. Elektroprzewodzące polimery można otrzymać w wyniku chemicznej polimeryzacji lub elektropolimeryzacji. W niniejszej pracy przedstawiono zostanie koncepcja czujnika gazów składająca się z elektrody grzebieniowej oraz polimeru przewodzącego...
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Study of the electrochemical stability of polypyrrole coating on iron in sodium salicylate aqueous solution
PublicationIn this work electrochemical stability of optimized PPy film on iron in aqueous solution of sodium salicylate is studied. The main drawback of conducting polymers is their possibility to undergo an irreversible degradation (overoxidation). The overoxidized polymers lose their properties, for example, conductivity and redox activity, what excludes them from some practical applications. This study demonstrates that lowering the concentration...
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Experimental and theoretical investigation of microjet cooling in metalurgical applications
PublicationW pracy zaprezentowano model wrzącej strugi uderzającej o powierzchnię i wytwarzającej cienki film cieczowy, w którym tworzą się pęcherzyki pary.
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Influence of Road Wetness on Tire-Pavement Rolling Resistance
PublicationRolling resistance of tires is one of the most important factors influencing energy consumption of road vehicles, especially on rural roads. For practical reasons, most of rolling resistance measurements are usually performed for dry road conditions. Based on the fact that roads are wet during a considerable time over the year and as part of the projects MIRIAM, ROLRES and ROSANNE, the TUG (Technical University of Gdańsk) in Poland...
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Influence of Surface Modification of Titanium and Its Alloys for Medical Implants on Their Corrosion Behavior
PublicationTitanium and its alloys are often used for long-term implants after their surface treatment. Such surface modification is usually performed to improve biological properties but seldom to increase corrosion resistance. This paper presents research results performed on such metallic materials modified by a variety of techniques: direct voltage anodic oxidation in the presence of fluorides, micro-arc oxidation (MAO), pulse laser treatment,...
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Role of nitrogen in evolution of sp2/sp3 bonding and optical band gap in hydrogenated carbon nitride
PublicationDrastic changes in the bonding are found in amorphous hydrogenated carbon nitride (a-CNx:H) film as a function of nitrogen concentration (or N/C ratio). The total C-sp3 fraction and hardness shows a sharp decrease (at N/C = 0.40) whereas optical band gap and resistivity shows a gradual increase as nitrogen concentration increases from 0.07 to 0.58. Raman spectrum of a-CNx:H film is fitted with both Gaussian (integrated intensity...
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High resolution X-ray diffractometry and reflectometry of semiconductor nano- and micro- structures based on X-ray refractive optics
PublicationIn this thesis proposed, discussed and studied novel synchrotron X-ray diffractometry and reflectometry methods based on a refractive optics. The experimental results obtained from the ID06 beamline at ESRF, Grenoble, France are presented and analyzed in this work to demonstrate a high angular and space resolution in addition to the opportunity to manage in situ and on operando experiments with the help of proposed X-ray optical...