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A history of the physical and chemical stability of pharmaceuticals : a review
Publication: There is a great need for a broad range review of stability tests of active pharmaceutical ingredients (APIs) in comparison with current requirements contained in the pharmacopoeia. This review focuses on a pharmaceutical history of physical and chemical stability determination. Traditional knowledge must be considered in the context of physical stability, while new knowledge must be applied and acquired in terms of identification...
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Thermally activated persulfate-based Advanced Oxidation Processes — recent progress and challenges in mineralization of persistent organic chemicals: a review
PublicationThermally activated persulfate (TAP) finds application in Advanced Oxidation Processes for the removal of pollutants from contaminated water and soil. This paper reviewed the various cases of TAP in the environmental remediation. The pollutants such as individual pharmaceuticals, biocides, cyclic organic compounds, and dyes are considered in this review. It is interesting to note that most of the organic compounds undergo complete...
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Automatyczne systemy naprowadzania i sterowania środkami transportu
e-Learning CoursesSkładowe nazwy przedmiotu: - automatyczne systemy ® automatyzacja (ang. automation) - systemy naprowadzania i sterowania ® naprowadzanie, nawigacja i sterowanie (ang. guidance, navigation and control system); - środki transportu.
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Persulfates to degrade a mixture of dyes (rhodamine B, methylene blue) in the presence of glucose and visible light
PublicationA treatment process utilizing visible-light-activated (Vis) persulfates (PS) in the presence of an organic promoter (glucose) was developed for the simultaneous decolorization of a rhodamine B (RhB) and methylene blue (MB) mixture. Various doses of glucose, PS concentrations, pH values, initial dye concentrations and process time were tested to find out the most appropriate parameters for degrading the RhB/MB mixture in the...
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Phototransformation of three selected pharmaceuticals, naproxen, 17α-Ethinylestradiol and tetracycline in water: Identification of photoproducts and transformation pathways
PublicationTransformation products (TPs) may be formed during various processes, however, it was proved that one of the main mechanisms responsible for degradation of pharmaceuticals in natural waters is photolysis. Three compounds were selected, tetracycline (TC), 17-α-ethinylestradiol (EE2) and naproxen (NAP), for degradation experiments which were performed using a xenon lamp emitting light with a spectrum closely approximating that of...
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Scheelite-Type Wide-Bandgap ABO4 Compounds (A = Ca, Sr, and Ba; B = Mo and W) as Potential Photocatalysts for Water Treatment
PublicationIn the present study, alkaline-earth metal scheelite-type compounds ABO4 (A = Ca, Sr, Ba, B = Mo, W) synthesized by a hydrothermal method were systematically studied. The as-obtained photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller surface area analysis (BET), UV–Vis diffuse reflectance spectroscopy (DR/UV-Vis), photoluminescence, and thermoluminescence (TL)...
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Study on a polish peat bog “Rucianka” as a source of yeast strains capable of effective phenol biodegradation
PublicationPhenol is one of the most widely distributed environmental pollutants which can be found in wastewaters and industrial effluents. Due to its toxicity and resistance to self-degradation, it could become even lethal for humans and animals. The treatment of this toxic compound is focused on psychical–chemical methods, although biological treatment of phenol is preferable for economic aspects related to relatively...
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Highly Visible-Light-Photoactive Heterojunction Based on TiO2 Nanotubes Decorated by Pt Nanoparticles and Bi2S3 Quantum Dots
PublicationA heterojunction with excellent visible light response and stability based on titanium dioxide nanotubes (TiO2 NTs), bismuth sulfide quantum dots (Bi2S3 QDs), and platinum nanoparticles (Pt NPs) is proposed. Both Pt NPs (3.0 ± 0.2 nm) and Bi2S3 QDs (3.50 ± 0.20 nm) are well distributed on the (i) top parts, (ii) inner walls, and (iii) outer walls of the TiO2 NTs. Visible-light-induced photoreaction was initialized by excitation...
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Importance of model tests in design and operation of watercraft for example CTO
PublicationShip Hydromechanics Division is a specialized research and development department of Ship Design and Research Centre conducting tests and research in the field of hydromechanics, connected with design and operation of ships and other floating structures, in scope of: predictions, numerical analyses, designs of - hull shape optimized with respect to the ship’s functions with the application of modern design tools, screw propellers...
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Design of horizontal axis wind and water turbines
PublicationThe basic hydrodynamic principles of horizontal axis turbines are presented. Computational methods based on vortex theory for design of such turbines and for calculation of their hydro or aerodynamic characteristics are described in detail. These methods are applicable both to wind and water turbines. The influence of detailed turbine geometry on its characteristics is presented. Several practical computational examples of different...
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Assessment of the Positioning Accuracy of DGPS and EGNOS Systems in the Bay of Gdansk using Maritime Dynamic Measurements
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Clustering Bathymetric Data for Electronic Navigational Charts
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Radar and Automatic Identification System Track Fusion in an Electronic Chart Display and Information System
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Assessing Grounding Frequency using Ship Traffic and Waterway Complexity
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Sea Captains’ Views on Automated Ship Route Optimization in Ice-covered Waters
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A unified measure of collision risk derived from the concept of a ship domain
PublicationW artykule zaprezentowano nową miarę ryzyka kolizji dwóch statków, wywiedzioną z koncepcji domeny statku. Jej prostota oraz fakt, że uwzględnia ona kursy obydwu statków czynią ją dobrą alternatywą dla często stosowanego pojęcia odległości największego zbliżenia. Miara ta jest elastyczna, tzn. można korzystać z niej w powiązaniu z dowolną, zadaną domeną statku. Szczegółowo przedstawiono wyprowadzenia wszystkich niezbędnych wzorów...
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Determining the optimal course alteration maneouvre in a multi-target encounter situation for a given ship domain model
PublicationW artykulee przedstawiono nową deterministyczną metodę wyznaczania niezbędnego manewru kursem dla sytuacji spotkania z wieloma obiektami obcymi i dla dowolnej zadanej domeny. Jej prostota i niska złożoność obliczeniowa czynią ją dobrą alternatywą dla obecnie stosowanych metod. Główny algorytm został przedstawiony wprost, tak aby mógł być bezpośrednio zastosowany w pokładowych systemach antykolizyjnych lub w systemach VTS.
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Evolutionary Planning of Safe Ship Tracks in Restricted Visibility
PublicationThe paper presents the continuation of the author's research on ship track planning by means of Evolutionary Algorithms (EA). The presented method uses EA to search for an optimal set of safe tracks for all ships involved in an encounter. Until now the method assumed good visibility – compliance with standard rules of the Convention on the International Regulations for Preventing Collisions at Sea (COLREGS, 1972). However, in restricted...
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THE RESEARCH ON EGNOS SYSTEM IN CONTEXT OF THE ABILITY TO DETERMINE THE SHIP’S HULL SPATIAL ORIENTATION
PublicationThe European Geostationary Navigation Overlay Service (EGNOS) thanks to geostationary satellites covers an area of whole Europe, including Baltic and North Sea. It allows to fix the coordinates of object position with typical absolute accuracy of 1,5 m. Previous research have shown that relative accuracy is usually higher than absolute one [Nowak A., 2010, Nowak A., 2011], so probably it could be possible to use EGNOS to determine...
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Planning emergency manoeuvres
PublicationW artykule poruszono problem planowania manewrów ostatniej szansy i zmian planowanej trajektorii statku w przypadku nieoczekiwanych zachowań obiektów obcych. Wprowadzono dwie metody. Pierwsza z nich jest odpowiedzialna za monitorowanie parametrów obiektów obcych, szacowanie prawdopodobieństwa nieprzepisowego zachowania i aktualizację trajektorii statku własnego. Druga to narzędzie wizualizacyjne umożliwiające nawigatorowi szybki...
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A new method of ship routing on raster grids, with turn penalties and collision avoidance
PublicationArtykuł przedstawia nowy algorytm znajdowania optymalnych tras na siatkach rastrowych. Szczegółowo opisano zastosowane struktury danych, dzięki którym algorytm ma liniową złożoność obliczeniową. Na podstawie algorytmu opracowano metodę wyznaczania tras dla statków, uwzględniającą kwestie unikania kolizji z innymi statkami i przeszkodami nawigacyjnymi.Przedstawiono dwa warianty metody, dedykowane odpowiednio systemom pokładowym...
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Multi-objective Weather Routing with Customised Criteria and Constraints
PublicationThe paper presents a weather routing algorithm utilising a multi-objective optimisation with constraints, namely the Multi-objective Evolutionary Weather Routing Algorithm (MEWRA). In the proposed approach weather route recommendations can be made simultaneously e.g. for passage time, fuel consumption and safety of passage by means of Pareto optimisation. The sets of criteria and constraints in the optimisation process are fully...
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Evolutionary Sets of Safe Ship Trajectories Within Traffic Separation Schemes
PublicationThe paper presents the continuation of the author's research on Evolutionary Sets of Safe Ship Trajectories (ESoSST) methodology. In an earlier paper (Szlapczynski, 2011) the author described the foundations of this methodology, which used Evolutionary Algorithms (EA) to search for an optimal set of safe trajectories for all the ships involved in an encounter. The methodology was originally designed for open waters or restricted...
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Protection of visual data transmission for vessel traffic systems using joint fingerprinting and decryption method based on modified hill cipher
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Finding deformation of the straight rail track by GNSS measurements
PublicationW 2009 roku na Politechnice Gdańskiej i Akademii Marynarki Wojennej w Gdyni zostały przeprowadzone, po raz pierwszy, ciągłe pomiary satelitarne toru kolejowego z wykorzystaniem względnej metody fazowej na bazie polskiej Aktywnej Sieci Geodezyjnej ASG-EUPOS i serwisu czasu rzeczywistego RTK (GPRS) - NAVGEO. Przeprowadzona analiza wykazała silny związek między lokalizacją odbiornika GNSS i dokładnością wyznaczania pozycji, wpływ...
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Local Monitoring of EGNOS Services
PublicationW artukule przedstawiono wyniki lokalnego monitoringu dostępności serwisów satelitarnego systemu nawigacyjnego EGNOS.
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A Target Information Display for Visualising Collision Avoidance Manoeuvres in Various Visibility Conditions
PublicationThe paper introduces a new approach to displaying information on targets. The proposed display visualises three types of information: targets’ motion parameters (typical for target tracking), combinations of own course and speed which collide with those targets (typical for Collision Threat Parameters Area display by Lenart (1983)) and combinations of own course and speed which are not compliant with COLREGS in this case (based...
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METHOD OF ROUTING SHIPS SAILING IN DEDICATED ENVIRONMENT
PublicationThe method for determining the suboptimal route of sailing vessels operating in a restricted area of the sea are proposed in the paper. The dynamics of the environment including weather conditions and speed characteristics of ships sailing are considered. As optimiza-tion criterion, measure sailing time T, and the number of maneuvers performed ω, are taken into account. An heuristic algorithm, and the appropriate application routing...
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Evolutionary Sets Of Safe Ship Trajectories: A New Approach To Collision Avoidance
PublicationThe paper introduces a new method of solving multi-ship encounter situations for both open waters and restricted water regions. The method, called evolutionary sets of safe trajectories combines some of the assumptions of game theory with evolutionary programming and aims to find optimal set of safe trajectories of all ships involved in an encounter situation. In a two-ship encounter situation it enables the operator of an on-board...
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Decolorisation of Methylene Blue with Sodium Persulfate Activated with Visible Light in the Presence of Glucose and Sucrose
PublicationThe paper presents the results of research on the methylene blue (MB) degradation with sodium persulfate (PDS) activated with visible light (Vis) in the presence of glucose and sucrose. The following test were examined: absence and presence of sugars in concentrations of 50–300 mM, presence and absence of Vis radiation, pH of the model solution (6.0–12.0), identification of free radicals, kinetics of the pseudo-first-order reaction....
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Application of BiOClnBrm photocatalyst to cytostatic drugs removal from water; mechanism and toxicity assessment
PublicationThe photocatalytic activity of series of BiOClnBrm photocatalysts toward degradation and mineralization of the cytostatic drugs 5-fluorouracil (5-FU) and imatinib mesylate (IMA) both singly and in their mixture under simulated solar and visible light irradiation has been investigated. Screening test revealed that among BiOClnBrm photocatalysts synthesized by a solvothermal method, the one with molar 1.3Cl/0.7Br ratio was the most...
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Accuracy of marine gravimetric measurements in terms of geodetic coordinates of land reference benchmark
PublicationThe article presents how the values of (3D) coordinates of land reference points affect the results of gravimetric measurements made from the ship in sea areas. These measurements are the basis for 3D maritime inertial navigation, improving ships' operational safety. The campaign verifying the network absolute point coordinates used as a reference point for relative marine gravity measurements was described. The obtained values...
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Trajectory planning for Service Ship during emergency STS transfer operation
PublicationIn this paper trajectory for approaching during emergency STS transfer operation with oil spill is considered as a sequence of navigation manoeuvres in specific navigational environment. The designed way points - ship positions and speed are determined as reference values to support navigator in decision making during steering and to mitigate the risk of collision which mostly results from exceeding the speed limit of approaching....
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International Competitiveness in the Economics Literature: A Bibliometric Study
PublicationThis paper has as its main aim to consolidate the state of the art of academic research on international competitiveness, based on a bibliometric study of the economics literature published over the past 70 years. Citation data is collected from the ISI WEB of Science website, Scopus and Google Scholar and is analysed using Histcite and Vosviewer software. The growth pattern of the international competitiveness literature is investigated...
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Short Term Monitor of Photodegradation Processes in Ranitidine Hydrochloride Observed by FTIR and ATR FTIR
PublicationThe effects of degradation of ranitidine hydrochloride exposed to UVB radiation (l = 310 nm) and oxygen in a weathering chamber were studied by Fourier Transform Infrared spectroscopy (FTIR) and Attenuated Total Reflectance Fourier Transform Infrared spectroscopy (ATR-FTIR). ATR-FTIR profile indicated that the degradation was spatially heterogeneous. Significant amounts of photoproducts were detected only in a directly...
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Mass spectrometric identification of 13C-Labeled metaboloites during anaerobic propanoic acid oxidation
PublicationBiowaste digestion is a possibility to gain biogas as a renewable fuel source. However, the anaerobic food chain may be disrupted by, e.g., substrate overload or by inhibitors, leading to the accumulation of volatile fatty acids (VFAs), predominantly of propanoic acid (PA). VFA Accumulation may cause a rapid pH decrease, less biogas production, or even a total inhibition. To maintain high biogas productivity or to prevent a collapse...
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Stress–strain model of lower corroded steel plates of normal strength for fitness-for-purpose analyses
PublicationThis study investigates the mechanical properties of specimens made of normal strength steel subjected to lower marine immersed corrosion degradation levels (below 25 %). The specimens were corroded in laboratory conditions, and only natural factors were controlled to raise the corrosion rate (reaching the level of 1 mm/year). Three different thicknesses of plates made of normal strength of shipbuilding steel are investigated (between...
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Mass Spectrometric Identification of 13C-Labeled Metabolites DuringAnaerobic Propanoic Acid Oxidation
PublicationBiowaste digestion is a possibility to gain biogas as a renewable fuel source. However, the anaerobic food chain may be disrupted by, e.g., substrate overload or by inhibitors, leading to the accumulation of volatile fatty acids (VFAs), predominantly of propanoic acid (PA). VFA Accumulation may cause a rapid pH decrease, less biogas production, or even a total inhibition. To maintain high biogas productivity or to prevent a collapse...
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A new method for real-time monitoring of volatiles in frying fumes using proton transfer reaction mass spectrometry with time-of-flight analyse
PublicationTo safeguard the consumers’ well-being, it is necessary to develop novel methods for determination of carcinogens in food, including volatiles generated during frying. The currently used procedures for analysis of volatile fraction of vegetable oils are not based on real-time measurements and thus do not enable the determination of carcinogenic compounds in frying fumes; instead, only the headspace or liquid fraction is sampled....
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Biochemistry - Laboratory exercises - Nowy
e-Learning CoursesExerise 1. The ability to accumulate metal cations by edible mushrooms, comparison with edible plants Exercise 2. Measurement of activity of glutathione S-transferases - the detoxifying enzymes present in the cytosol of eukaryotic cells Exercise 3. Cell membranes permeability Exercise 4. Detection of mutagenic substances using Ames test Exercise 5. Gluten content in food products part 1. Exercise 6. Gluten content in food...
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Biochemistry - Laboratory exercises
e-Learning CoursesExerise 1. The ability to accumulate metal cations by edible mushrooms, comparison with edible plants Exercise 2. Measurement of activity of glutathione S-transferases - the detoxifying enzymes present in the cytosol of eukaryotic cells Exercise 3. Cell membranes permeability Exercise 4. Detection of mutagenic substances using Ames test Exercise 5. Gluten content in food products part 1. Exercise 6. Gluten content in food...
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Imaging and chemical investigation of silver coating
Open Research DataThe recovery of silver from materials such as plates, still used in clinical radiography [1], or scrap jewelery is still very popular. The subject of the research, part of which was microscopic imaging, was to recreate the behavior of an electrochemically deposited silver coating. The copper electrodes were covered with a layer of silver obtained from...
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Thermal decomposition of [Cd{SSi(OBut)3}(S2CNC4H8)]2 to CdS “micro-noodles”
PublicationThis work presents studies on thermal degradation of novel heteroleptic complex possessing mixed S-donor ligands, [Cd{SSi(OBut)3}(S2CNC4H8)]2 using TGA, DSC, TGA-IR, SEM and XRD methods.
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Performance of organic coatings upon cyclic mechanical load
PublicationA number of engineering structures fail due to the fatigue damage resulting from cyclic mechanical stress. However, as far as organic coatings are concerned this degradation factor remains underestimated. In the paper the authors propose a methodology combining global electrochemical impedance spectroscopy and local atomic force microscopy measurements for evaluation of coating resistance to an impact of repetitive mechanical stress. Typical...
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NARAŻENIA NAPIĘCIOWE SILNIKÓW INDUKCYJNYCH ZASILANYCH Z FALOWNIKÓW NAPIĘCIA
PublicationW artykule przedstawiono zagadnienia związane z narażeniami izolacji silników pracujących w układach napędowych z falownikami napięcia. Znaczne stromości napięć oraz zjawiska falowe w przewodach zasilających powodują przyspieszoną degradacje izolacji maszyn. Rozwiązaniem jest stosowanie filtrów biernych na wyjściu falownika.
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Awarie mostu Cłowego w Szczecinie
PublicationW artykule przedstawiono historię budowy i eksploatacji mostu Cłowego w Szczecinie. W ciągu 56 lat eksploatacji obiektu wykonano wiele ekspertyz, napraw i remontów. Ostatecznie most został zamknięty z powodu awarii stalowych kabli sprężenia zewnętrznego. Przedstawiono główne przyczyny degradacji obiektu i awarii. Opisano również obliczenia statyczne i wytrzymałościowe wykonane do koncepcji rozbiórki przęseł mostu.
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Most Cłowy w Szczecinie. Historia i przyszłość
PublicationW referacie przedstawiono historię budowy i cykl życia kablobetonu mostu Cłowego w Szczecinie. W trakcie 56-letniego życia obiektu kilka prac eksperckich i naprawy zostało wykonanych. Ostatecznie most został zamknięty po poważnej awarii strukturalnej zewnętrznego kabla sprężenia. Wyjaśniono główne przyczyny degradacji oraz przedstawiono koncepcję projektową remontu.
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Novel decahedral TiO2 photocatalysts modified with Ru or Rh NPs: Insight into the mechanism
PublicationNovel decahedral TiO2 modified with Ru or Rh NPs were successfully synthesized by hydrothermal method. The effect of metal type as well as amount of noble metal precursor (0.05, 0.1, 0.2, 0.3 and 0.5 wt.%) on the photocatalytic activity were investigated. Decahedral TiO2 decorated by Ru and Rh nanoparticles was prepared by photodeposition method, whereas Rh doped TiO2 was obtained by onestep hydrothermal method with introduction...
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Some aspects of the constitutive modelling of natural fine grained soils
PublicationThe monograph deals with selected problems of the constitutive modelling of natural fine grained soils commonly known as clays. The main idea is not to propose a unified model which is capable of describing all known features of mechanical behaviour of fine grained soils. Instead, separate models are proposed describing the mechanical behaviour of heavily overconsolidated, lightly overconsolidated and normally consolidated clays....
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Marek Przyborski dr hab. inż.
PeopleMarek Przyborski (b. March 20, 1964. Chełmża) - His fields of interest are remote sensing and close range photogrammetry. He conducts research on the use of so-called "high-speed cameras" to analyze the rapidly-changing phenomena. Co-author and author of publications dealing with the wide meaning of remote sensing applications related to the construction, transport, engineering, environment and homeland security. He is the author...