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Search results for: ELECTROCHEMICAL CAPACITOR
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Novel fast non-linear electrochemical impedance method for corrosion investigations
PublicationThe paper presents a novel approach to corrosion rate monitoring using non-linear electrochemical impedance spectroscopy. The authors propose a new variant of non-linear impedance measurement using amplitude-modulated multi-frequency ac perturbation signal. It allows shortening of measurement duration so it is possible to monitor corrosion rate of the systems experiencing rapid changes. In this way a limitation resulting from lack...
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Investigation of solid polymer electrolyte gas sensor with different electrochemical techniques
PublicationIn this work solid polymer electrolyte (SPE) amperometric sulphur dioxide sensor is investigated. Nafion was used as a membrane electrode and 1M sulphuric acid as an internal electrolyte. Sensor response to sulphur dioxide was measured. Besides traditional constant voltage amperometry also different electrochemical techniques were used. Results obtained by these methods are compared.
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Evidence for solid state electrochemical degradation within a small molecule OLED
PublicationAcridone derivative have been synthesised and used as OLED (Organic Light Emitting Diode) emitters which were found to be electroactive. Electrochemical investigations showed a side reaction takes place inside an active layer which diminished the overall device efficiency. By using a dopant and host active layer architecture, the formation of the by product was removed. The by-product was identified as a σ-dimer formed inside an...
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Evaluation of the Commercial Electrochemical Gas Sensors for the Monitoring of CO in Ambient Air
PublicationAir pollution is a growing concern of civilized world, which has a significant impact on human health and the environment. Recent studies highlight that the exposure to polluted air can increase the incidence of diseases and deteriorate the quality of life. Hence, it is necessary to develop tools for real-time air quality monitoring. For air pollution monitoring a wide range of stationary gas and particulate analysers can be used....
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Portable Electronic Nose Based on Electrochemical Sensors for Food Quality Assessment
PublicationThe steady increase in global consumption puts a strain on agriculture and might lead to a decrease in food quality. Currently used techniques of food analysis are often labour-intensive and time-consuming and require extensive sample preparation. For that reason, there is a demand for novel methods that could be used for rapid food quality assessment. A technique based on the use of an array of chemical sensors for holistic analysis...
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Application of electrochemical sensors and sensor matrixes for measurement of odorous chemical compounds
PublicationIn this paper describes the principle of operation of the electrochemical sensors and the sensor matrixes comprised of electrochemical sensors intended for measurement of odorous compounds. Critical comparison of these sensors’ advantages and disadvantages has been made. The fields of economy contributing to release of odours and the potential sources of their emission have been identified. Commercially available electrochemical...
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Applications of the regenerative capacity of platelets in modern medicine
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INFLUENCE OF TIME ON THE BEARING CAPACITY OF PRECAST PILES
PublicationOne of the most popular types of foundations in layered subsoil with very differentiated soil shear strengths are precast piles. One of the reasons is a fact that we can well control the driving process during the installation of these piles. The principles of the assessment of bearing capacity and settlements of the piles given by Eurocode 7, concentrate on two main methods, i.e. Static Pile Load Tests (SPLT) and Dynamic Driving...
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Bearing capacity of the working platform with kinematic method
PublicationBearing capacity of the working platform for heavy tracks was analysed using Distinct Layout Optimization (DLO) method. The platform layer constructed from cohesionless soils is resting on weak cohesive subgrade. Different thickness of the platform, its effective angle of internal friction and undrained shear strength of the soft soil were taken into consideration. Kinematic method permits different failure mechanisms to be analyzed....
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A survey on known values and bounds on the Shannon capacity
PublicationIn this survey we present exact values and bounds on the Shannon capacity for different classes of graphs, for example for regular graphs and Kneser graphs. Additionally, we show a relation between Ramsey numbers and Shannon capacity.
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Pressure and capacity in hip joint afte injury.
PublicationPraca przedstawia zarys analitycznego wyprowadzenia równania Reynoldsa do wyznaczania rozkładów wartości ciśnienia w szczelinie sferycznego stawu biodrowego człowieka po udarze w nieustalonym ruchu impulsywnym. W wyprowadzonym modelu uwzględniono lepkosprężyste właściwości cieczy synowialnej oraz stochastyczny opis chropowatości chrząstki stawowej. Numeryczne wartości ciśnienia wyznaczono w programie Mathcad 2001 przy wykorzystaniu...
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Nonadditivity of quantum capacity for multiparty communication channels.
PublicationZbadano scenariusze komunikacji pomiędzy wieloma stronami gdzie informacje są przesyłane od wielu nadawców do wielu odbiorców.
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Methodology of assessing the production capacity of selected shipyards
PublicationW ramach projektu EUREKAΣ!2772 powstały projekty wstępne czterech statków dowozowych (Short Shiping). Dla jednego z nich należało zdefiniować optymalne warunki wykonania, wskazać wstępnie stocznie spełniające kryterium minimum zdolności wykonawczych. Do tego celu opracowano metodykę wskaźnikową, bazującą na wskaźnikach technologicznych i konstrukcyjnych. W oparciu o nie przeprowadzono analizę możliwości produkcyjnych wybranych...
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An Approximation of the Zero Error Capacity by a Greedy Algorithm.
PublicationWe present a greedy algorithm that determines a lower bound on the zero error capacity. The algorithm has many new advantages, e.g., it does not store a whole product graph in a computer memory and it uses the so-called distributions in all dimensions to get a better approximation of the zero error capacity. We also show an additional application of our algorithm.
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An Approximation of the Zero Error Capacity by a Greedy Algorithm
PublicationWe present a greedy algorithm that determines a lower bound on the zero error capacity. The algorithm has many new advantages, e.g., it does not store a whole product graph in a computer memory and it uses the so-called distributions in all dimensions to get a better approximation of the zero error capacity. We also show an additional application of our algorithm.
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The Energy of Finance in Refining of Medical Surge Capacity
PublicationThe availability of resources and their concentration in the place of greatest need, will not allow us to successfully overcome a medical surge without the energy required to activate these resources and activities, and increase their quantities if necessary, that is why the staff and management of healthcare institutions are forced to making ethical crisis decisions about who wins and who loses. This study highlights the versatility...
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Conditions and capacity for implementing Poland’s vision zero
PublicationSince 1991 Poland has been systematically reducing its traffic hazard. Despite considerable progress Poland is still among the most dangerous countries in the European Union. The key types of actions that help to reduce fatalities include enhancement of pedestrian safety, reducing the number of speeding drivers and eliminating or reducing hazard on the road. The paper presents a brief diagnosis of the state of road safety in Poland...
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THE SCIENTIFIC CAPACITY AS AN INNOVATION DETERMINANT OF THE POLISH REGIONS
PublicationEvery Polish region (in the paper understood as a voivodship) is an inspiring ground for comparative studies on the national as well as European scale, i.e. with regard to the administrative units of the other European countries. The aim of the article is to advance the conclusions concerning the Regional Innovation Scoreboard – a European instrument applied to examine the innovation capacity of European regions – with the issues...
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A Note on Shannon Capacity for Invariant and Evolving Channels
PublicationIn the paper we discuss the notion of Shannon capacity for invariant and evolving channels. We show how this notion is involved in information theory, graph theory and Ramsey theory.
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Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones
PublicationTriphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn’t be formed. The results of electrochemical,...
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Core/shell structured Ti/Si/C composite for high-performance zinc-ion hybrid capacitor
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Activity coordination of capacitor banks and power transformer controllers in order to reduce power losses in the MV grid
PublicationOne of the main issues related to the optimization of the MV (middle voltage) network is to reduce losses of active and reactive power. Lower losses of active and reactive power give not only economic advantage, but also improvement of energy quality. The object of regulation that can be used for these purposes are transformer with On-Load Tap Changer and capacitor's banks. This paper presents results of analysis of the possibility...
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Trans-Z-source-like inverter with built-in DC current blocking capacitors
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Elektrochemiczne polaryzacyjne badania korozyjne = Elecrochemical polarisation corrosion testing
PublicationW pracy przedstawiono sposoby określania szybkości korozji metali na podstawie analizy krzywych polaryzacyjnych.
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The influence of precursor selection on electrochemical properties of radiofrequency thermal plasma synthesized graphene
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Electrochemical oxidation of sulphamerazine at boron-doped diamond electrodes: Influence of boron concentration
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Electrochemical investigations of conductive coatings applied as anodes in cathodic protection of reinforced concrete
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Application for novel electrochemical screening of antioxidant potential and phytochemicals in Cornus mas extracts
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Magnesium(ii) 1-(1-adamantylsulfanyl)phthalocyanine – synthesis, photochemical and electrochemical properties
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Bottom up approach of metal assisted electrochemical exfoliation of boron towards borophene
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A facile synthesis method and electrochemical studies of a hierarchical structured MoS2/C-nanocomposite
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Low-Temperature Exfoliated Graphenes: Vacuum-Promoted Exfoliation and Electrochemical Energy Storage
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Deposition of EDOT-Decorated Hollow Nanocapsules into PEDOT Films for Optical and Electrochemical Sensing
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Influence of geometry and annealing temperature in argon atmosphere of TiO2 nanotubes on their electrochemical properties
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Influence of Thermal Modification and Morphology of TiO2 Nanotubes on Their Electrochemical Properties for Biosensors Applications
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Electrochemical stability of TiO2 nanotubes deposited with silver and gold nanoparticles in aqueous environment
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Electrochemical oxidation of sulphamerazine at boron-doped diamond electrodes: Influence of boron concentration
PublicationThe boron-doped diamond (BDD) electrodes with different boron concentrations have been tested as electrode material for sulphamerazine (SRM) oxidation in water solution. An investigation of the electrode morphology and molecular structure was carried out using high resolution scanning electron microscopy (SEM) and Raman spectroscopy. Electrochemical results showed clearly that the kinetics and efficiency of SRM oxidation were dependent...
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Nanocrystalline diamond microelectrode on fused silica optical fibers for electrochemical and optical sensing
PublicationFabrication process of thin boron-doped nanocrystalline diamond (B-NCD) microelectrode on fused silica single mode optical fiber has been investigated. The B-NCD films were deposited on the fibers using Microwave Plasma Assisted Chemical Vapor Deposition (MW PA CVD) at glass substrate temperature of 475 ºC. We have obtained homogenous, continuous and polycrystalline surface morphology with the mean grain size in the range of 100-250...
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Electrochemical activity of composite material poly(3,4-ethylenedioxythiophene) modified by silver hexacyanoferrate
PublicationW pracy przedstawiono sposób slektrochemicznj syntezy materiału składającego się z polimeru przewodzącego poli(3,4-etylenodioksytiofen) (pEDOT) i nieorganicznej sieci typu redox heksacyjanożelazianu srebra (Aghcf). Materiał otrzymano na drodze dwuetapowej. Etap pierwszy polega na galwanostatycznej redukcji srebra na elektrodzie z węgla szklistego. Etap drugi to roztwarzanie srebra z jednoczesną polimeryzacją monomeru. Otrzymany...
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Experimental study of corrosion in reinforced concrete by acoustic emission and electrochemical noise techniques
PublicationTechnika emisji akustycznej jest znaną metodą badań korozji zbrojenia żelbetu. Źródłem aktywności akustycznej są zawsze zjawiska o naturze mechanicznej. Przedstawiono wynik badań akustycznych zbrojonego betonu w warunkach polaryzacji anodowej, przyspieszającej procesy korozyjne. Symultanicznie prowadzona była rejestracja szumu elektrochemicznego. Dla umożliwienia korelacji wyników, uzyskanych obiema technikami, wykonana została...
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Electrochemical investigations of conductive coatings applied as anodes in cathodic protection of reinforced concrete.
PublicationW pracy przedstawiono rezultaty badań elektrochemicznych polimerów przewodzących z pigmentem grafitowym. Wyznaczono parametry elektrochemiczne badanych powłok w trakcie długotrwałej polaryzacji zbrojonego betonu. W oparciu o pomiary impedancyjne wyznaczono parametry elektrochemiczne powłok przewodzących. Wykazano, że badane powłoki mogą być stosowane w ochronie katodowej żelbetu. Badania wykazały, że optymalne stężenie grafitu...
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Production and Properties of the Porous Layer Obtained by the Electrochemical Method on the Surface of Austenitic Steel
Publication: The growing demand for implants has seen increasing interest in the introduction of new technologies and surface modification methods of metal biomaterials. This research aimed to produce and characterize a porous layer grown on austenitic stainless steel 316L, obtained via the anodization process near the micro-arc oxidation, i.e., low voltage micro-arc oxidation (LVMAO). The discussed layer significantly influences the properties...
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Electrochemical performance of thin free-standing boron-doped diamond nanosheet electrodes
PublicationIn the following work we describe preparation and the electrochemical performance of thin and free-standing heavy boron-doped diamond (BDD) nanosheets. The investigated foils were deposited on Ta substrate using microwave plasma-enhanced chemical vapor deposition technique (MPECVD). Foils of two B-dopant densities were investigated, obtained on the base of 10 k and 20 k ppm [B]/[C] ratio in the gas admixture. The obtained foils...
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Synergistic effects of nitrogen-doped carbon and praseodymium oxide in electrochemical water splitting
PublicationHybrid materials featuring perovskite-type metal oxide in conjunction with heteroatom-doped graphene hold immense promise as alternatives to costly noble metal catalysts for electrochemical water splitting, facilitating the generation of environmentally friendly hydrogen. In this study, perovskite-type oxide containing praseodymium, barium, strontium, cobalt, and iron atoms dispersed in a carbon matrix as a catalyst is synthesized...
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Structural, optical and electrochemical performance of black phosphorus and black arsenic-phosphorus nanostructures
PublicationBlack phosphorus (BP)-based nanostructures have drawn a lot of attention due to their tunable bandgap and extraordinary properties such as: high surface-to-volume ratio, large number of active sites, and prominent edges. However, low dimensional structures of black phosphorus oxidize easily, which hamper their application on a broader scale. One way to overcome these difficulties is to modify the black phosphorus structure by substituting...
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Comparison of corrosion resistance of al-alloys by means of dynamic electrochemical impedance spectroscopy
PublicationPrzeprowadzono badania metodą dynamicznej elektrochemicznej spektroskopii impedancyjne stopów 1100 i 5162. Zaproponowano zastępcze modele elektryczne opisujące zachowanie się stopów w warunkach ekspozycji w roztworach zawierających wysokie stężenie jonów chlorkowych. Wyznaczono zmiany podstawowych parametrów elektrycznych układów zastępczych od potencjału. Stwierdzono wyższą podatność na korozję stopu 5162 w porównaniu ze stopem...
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Investigating BiMeVOx compounds as potential photoelectrochemical and electrochemical materials for renewable hydrogen production
PublicationIn this study, BiMeVOx compounds (where Me: Co, Mo, Ce, Zr) were synthesized and characterized as potential photoelectrochemical materials for solar water splitting, the hydrogen evolution reaction (HER), and oxygen evolution reaction (OER). The analysis confirmed the successful formation of phase BiMeVOx compounds with the desired crystal structure. Among the tested materials, BiCoVOx(800) showed the highest photocurrent density...
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Nitrogen-incorporated boron-doped diamond films for enhanced electrochemical supercapacitor performance
PublicationThe electrochemical (EC) supercapacitor, known for its rapid charging, reliability, and versatile applications, demands optimized electrode characteristics and an understanding of their electrochemical behaviour. Although boron-doped diamond (BDD) holds promise as a supercapacitor electrode, a crucial gap exists in comprehending its material behaviour under specific growth conditions. Here, nitrogen-incorporated BDD (N-BDD) films...
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An electrochemical biosensor for the determination of hormone Human Chorionic Gonadotropin (hCG) in human serum
PublicationThis work describes the modification of a gold electrode to create an electrochemical biosensor capable of detecting human chorionic gonadotropin (hCG). The biosensor was obtained by modifying the gold electrode with cysteamine and oligopeptide (PPLRINRHILTR). The modification steps of the gold electrode were confirmed by cyclic voltammetry (CV) and impedance electrochemical spectroscopy (EIS) measurements. The conducted EIS experiments...
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Enhanced Electrochemical Performance of MnCo1.5Fe0.5O4Spinel for Oxygen Evolution Reaction through Heat Treatment
PublicationMnCo1.5Fe0.5O4 spinel oxide was synthesized using the sol−gel technique, followed by heat treatment at various temperatures (400, 600, 800, and 1000 °C). The prepared materials were examined as anode electrocatalysts for watersplitting systems in alkaline environments. Solid-state characterization methods, such as powder X-ray diffraction and X-ray absorption spectroscopy (XAS), were used to analyze the materials’ crystallographic...