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Wyniki wyszukiwania dla: KOMPOZYTY DIAMENT-METAL
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Ziarna i mikroziarna diamentowe. Rodzaje ścierniw i przykłady zastosowania
PublikacjaW książce zawarto podstawowe informacje technologiczne i wyniki prac nad ziarnami i mikroziarnami diamentowymi. Przedstawiono właściwości mechaniczne, termiczne, chemiczne, magnetyczne, elektryczne i optyczne diamentu. Omówiono pochodzenie diamentów, charakteryzując diamenty naturalne oraz wytwarzane w statycznych warunkach wysokiego ciśnienia i temperatury oraz w warunkach dynamicznych. Scharakteryzowano diamentowe kompozyty polikrystaliczne,...
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The (Bi,Pb)4Sr3Ca3Cu4Ox glass-ceramics: disordered metal and superconductor
PublikacjaAmorficzny materiał (Bi,Pb)4Sr3Ca3Cu4Ox wygrzewany w odpowiednich warunkach staje się granulastym metalem i nadprzewodnikiem. Może być uważany za silnie nieuporządkowany metal. Ma duży opór i zazwyczaj ujemny współczynnik temperaturowej zależności oporu. Nieuporządkowanie i granulasty charakter materiału ujawnia się również w jego właściwościach nadprzewodzących.
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FEM approach to estimate the behaviour of biocomposite metal-surface coating system
PublikacjaA three dimensional (3D) model of biocomposite metal-surface coating system, which is influenced byknown external forces, is proposed. This model consists of the metallic substrate (Ti6Al4V) and thehydroxyapatite (HA) coating. Using FEM (finite element method), strain-stress maps of model weregenerated for investigating relations between the extreme stress of HA coating and the magnitude ofexternal force and the thickness of the...
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Kompozyty termoelektryczne z nanostrukturami węglowymi
PublikacjaJedną z badanych możliwości poprawy własności materiałów termoelektrycznych jest wytwarzanie kompozytów zawierających nanostrukturalne formy węgla. Opisano najważniejsze wnioski z doniesień naukowych nad takimi materiałami. Oczekuje się, że w wyniku rozpraszania na granicach węgiel - materiał termoelektryczny nastąpi rozpraszanie prowadzące do zmniejszenia przewodności cieplnej. Jednocześnie obserwuje się zmniejszenie przewodności...
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Starch–metal complexes and metal compounds
PublikacjaRecently, metal derivatives of starch evoked considerable interest. Such metal derivatives can take a form of starch compounds bearing metal atoms and metal carrying moieties either covalently bound or complexed. Starch metal complexes may have a character of either Werner, inclusion, sorption or capillary complexes. In this publication, preparation, structure, properties and numerous current and potential applications of those...
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Włókna i kompozyty aramidowe - możliwości i ograniczenia
PublikacjaW pracy przedstawiono budowę i zastosowania nowoczesnych włókien poliparafenylenotereftalamidu PPTA znanych pod nazwą handlową Kevlar firmy Du Pont , rozsławionych dzięki zastosowaniom w produkcji kamizelek kuloodpornych. Przedstawiono zastosowania tych włókien jako wzmocnień w zaawansowanych kompozytach polimerowych , między innymi dla okrętownictwa. Ograniczeniem w wykorzystaniu tych kompozytów jest ich słaba wytrzymałość na...
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Kompozyty cementowo-popiołowe modyfikowane dodatkiem włókien stalowych.
PublikacjaPraca dotyczy określenia wpływu niewielkiej ilości włókien stalowych na właściwości techniczne kompozytów popiołowo-cementowych. W opracowaniu przedstawiono wyniki badań kompozytów w zakresie zmian wytrzymałości na rozciąganie przy zginaniu, zmian wytrzymałości na rozciąganie przy rozłupywaniu, zmian wytrzymałości na ściskanie.
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(Bi,Pb)-Sr-Ca-Cu-O glass-ceramics - superconductor and granular metal
PublikacjaW materiale o składzie (Bi,Pb)-Sr-Ca-Cu-O wskutek stosowania różnych warunków wytwarzania można otrzymać materiały o różnorodnych właściwościach. W efekcie wygrzewania materiał amorficzny częściowo krystalizuje. To powoduje wzrost rozmiaru i zawartości przewodzących i nadprzewodzących granul oraz zmniejszenie szerokości izolujących barier pomiędzy granulami. Zależność temperaturowa oporu słabo skrystalizowanego materiału jest funkcją...
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From metal dithiocarbamates to metal sulfides
PublikacjaLigandy ditiokarbamianowe są szeroko stosowane w chemii koordynacyjnej. Układy zawierające metal mogą być z powodzeniem wykorzystane do otrzymania odpowiednich siarczków. W pracy przedstawiono syntezę, strukurę, właściwości, zastosowanie związków z tej grupy. Scharakteryzowano ich rozkład termiczny, jak równeiż zaprezentowano metody umożliwiające wykorzystanie ich jako pojedyncze prekursory molekularne
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Self-lubricating epoxide composites Kompozyty epoksydowe o właściwościach samosmarujących
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The degradation of metal implants
PublikacjaThe presence of metal implants in the human body causes some dangers, which result from introducing another object into organism. There may occur a biocorrosion, which causes different modifications of implant surface.
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Phosphoroorganic Metal Complexes in Therapeutics
PublikacjaThe present mini-review highlights recent developments on antitumor activity of metal-based therapeutics which have been a subject of researches for the last few decades. In 1965, Rosenberg found that during an electrolysis on platinum electrodes a complex of Pt is generated which inhibited to a great extent a binary fission in Escherichia coli bacteria. This discovery started a new chapter in medicinal chemistry and the interesting...
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Kompozyty poliuretanowo-gumowe wulkanizowane siarką = Polyurethane-rubber composites vulcanization of sulphur
PublikacjaW artykule przedsawiono wyniki badań statycznych i dynamicznych właściwości mechanicznych oraz analizę mikroskopową nowych kompozytowych materiałów poliuretanowo-gumowych wulkanizowanych siarką otrzymanych z kauczuków uretanowych wulkanizowanych siarką i recyklatu gumowego w postaci granulatu o wielkości ziarna do 1 mm uzyskanego z poużytkowych opon samochodowych. Osnowy poluretanowe napełniano recyklatem w ilościach od 10 do 80%...
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Metal nanoparticles-assisted early diagnosis of diseases
PublikacjaEarly diagnosis is essential for the effective illness treatment, but traditional diagnostic approaches inevitably have major downsides. Recent advancements in nanoparticle-based biosensors have created new opportunities for accelerating diagnosis. High surface area, exceptional sensitivity, high specificity, and optical characteristics of metal and metal oxide nanoparticles have made it possible to detect a variety of health conditions...
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Superconductivity in Metal-Rich Chalcogenide Ta2Se
PublikacjaThe metal–metal bond in metal-rich chalcogenide is known to exhibit various structures and interesting physical properties. Ta2Se can be obtained by both arc-melting and solid-state pellet methods. Ta2Se crystallizes a layered tetragonal structure with space group P4/nmm (No. 129; Pearson symbol tP6). Each unit cell consists of four layers of body-centered close-packing Ta atoms sandwiched between two square nets of Se atoms, forming...
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Insulator to correlated metal transition in V1−xMoxO2
PublikacjaDyskutowane jest przejście typu izolatro - metal w domieszkowanym atomami Molibdenu związku V1-xMoxO2. Prezentowany jest diagram fazowy.
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Electrical Transport and Magnetic Properties of Metal/Metal Oxide/Metal Junctions Based on Anodized Metal Oxides
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Electrical Transport and Magnetic Properties of Metal/Metal Oxide/Metal Junctions Based on Anodized Metal Oxides
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Kompozyty o mieszanym przewodnictwie jonowo-elektronowym na bazie domieszkowanego donorowo tytanianu strontu
PublikacjaPrzedstawiono właściwości kompozytów na bazie tytanianu strontu domieszkowanego niobem do zastosowań w ogniwach SOFC
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Metals and metal-binding ligands in wine: Analytical challenges in identification.
PublikacjaBackground Due to important role of metals in the vinification process as well as their impact on the human health, their content in this alcoholic beverage has been extensively studied by many researchers. It is already known that speciation of metals determines their toxicity and bioavailability as well as influences their activity. Understanding the chemistry and knowing the structures of metal complexes could have relevant...
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Calixthioamides as ionophores for transition and heavy-metal cations
PublikacjaThere is an increasing interest in applying p-tert-butylcalix[4]arenes as sensing materials in ion-selective electrodes(ISEs). Considerable efforts were made to design calixarenes that are selective for some heavy- or transitionmetal ions to be used in ISEs for controlling and monitoring the level of such pollutants in the environment. It has been reported that introduction of softer sulfur atoms instead of oxygen atoms in calix[4]arene...
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NOBLE METAL MODIFIED TiO2 FOR PHOTOCATALYTIC AIR PURIFICATION
PublikacjaTiO2 was surface modified with silver, gold, palladium and platinum ion clusters to improve its photocatalytic activity. The effect of metal content, the kind of dopant used during preparation procedure on the photoactivity were investigated. in toluene removal which was used as a model volatile organic compound. Toluene, at the concentration of about 100 ppm, was irradiated over noble metal modified TiO2 using light-emitting diodes...
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Studies of the mechanism of metal metal dusting of 10CrMo9-10 steel after 10 years of operation in trhe semi-regenerative catalytic reformer
PublikacjaThe study showed that metal dusting mechanism of 10CrMo9-10 steel operated in industrial environment differs from models developed in laboratories. Significant differences lie in the fact that the models developed in laboratories only assume the formation of metastable carbide M3C, while studies have shown that the formation of M3C carbides is associated with the transformation of primary carbides and in the next stage is preceded...
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Membranes for toxic- and heavy-metal removal
PublikacjaSince time ago, membranes have greatly attracted the attention of researchers for different types of water-treatment applications, such as wastewater treatment, water purification, removal of microorganisms, chemical compounds, and heavy metals. Nowadays, one of the current challenges of research community definitely deals with the removal of toxic and heavy metals from water. In this regard, the current chapter provides enough...
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Assessment of hydrogenation of deposited metal of P 62 MR covered electrodes
PublikacjaThe determination of diffusible hydrogen content in deposited metal of P 62 MR covered electrodes for manual metal arc welding by mercury method was carried out. The test results indicate that covered electrodes 62 P MR grade generate a mean of 4.02 ml/100g of diffusible hydrogen in deposited metal, which is consistent with H5 class.
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The Effect of Welding Conditions on Diffusible Hydrogen Content in Deposited Metal
PublikacjaThe article presents the results of a literature survey and preliminary tests which set out effects of welding conditions on the amount of diffusible hydrogen in deposited metal. Experiments were conducted by using rutile coated electrodes which generate high contents of diffusible hydrogen in deposited metal. The amount of diffusible hydrogen was determined by a glycerin test.Eleven factors were considered: the electrode angle,...
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Metal-Organic Framework (MOF)/Epoxy Coatings: A Review
PublikacjaEpoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coatings, e.g., adhesion to the substrate, anti-corrosion, mechanical, flame-retardant, and self-healing characteristics. Metal-organic frameworks (MOFs), a subclass of coordinative polymers...
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Mixed conductivity in tungstenite-phosphate glasses containing alkali metal ions
PublikacjaThe conductivity of glasses in the 50WO3-(50-x)P2O5-xA2O (A = Na, K, Cs) system has been investigated as a function of composition. It is shown that in tungstenite-phosphate glasses containing different alkali metal ions the conductivity decreases with an increase in the alkali metal ion content. A decrease in conductivity is larger for heavier ions and reaches more than seven orders of magnitude in the case of glass containing...
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublikacjaAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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A Low-Profile Metal-backed Dipole Loaded with Closely Coupled Arc-shaped Open Stubs for On-metal Tag Design with Wide Frequency Tuning Capability
PublikacjaThis research has presented a single-layer metal-backed dipole antenna, which consists of a feedline loaded with two pairs of closely-coupled arc-shaped open stubs, for designing a metal-mountable tag that features tuning capability over a wide range of frequency. Here, the stubs can generate sufficient inductive reactance for bringing down the tag resonant frequency tunable in both the regulated UHF RFID passbands (North American...
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Recent advancements in molecularly imprinted polymers for the removal of heavy metal ions and dyes
PublikacjaContamination set off by highly toxic metal ions and dyes is a big threat to the environment and living beings. Various industries like metal plating, mining, pesticides, battery manufacturing, and dyeing release metal ions and toxic dyes directly into the water. It is necessary to remove these toxic substances from the environment. Molecular imprinting technology (MIT) got a lot of attention in the last two decades because of...
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Kompozyty poliuretanowo-gumowe otrzymane przy udziale recyklatów gumowych jako sposób na zagospodarowanie poużytkowych opon samochodowych
PublikacjaW pracy doktorskiej przedstawiono wyniki badań dotyczące opracowania oraz charakterystyki właściwości nowych kompozytów poliuretanowo-gumowych (KPG), przydatnych do zastosowań praktycznych, otrzymywanych z trzech typów lanych elastomerów uretanowych (LEU) oraz dwóch odmian recyklatów gumowych (RG), produkowanych w procesach mechanicznego rozdrabniania poeksploatacyjnych opon samochodowych w temperaturze otoczenia i w warunkach...
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Application of 3D printing metal powder technology in the manufacture of components with complex geometries
PublikacjaThe possibilities of using 3D printing powder technologies for making objects with complex geometries were presented. For this purpose, selected examples of elements with different geometries were used, which were built using metal powder methods – DMLS (direct metal laser sintering) / SLM (selective laser melting). Simultaneously, the indicated elements concern those areas of industry where 3D printing technology has been widely...
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Lightweight glass and metal roof structures in the 19th century. Architecture and construction.
PublikacjaThe 19th century brought new construction possibilities. The usage of metal elements in mesh structures, filled in with glass, resulted in creating entirely new types of objects. They have distinguished themselves in architecture and technical solutions. The envelope structures giving spatial interiors were arising very quickly. They have been enabling large light penetration, triggering them extremely bright. Thus these building...
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Effect of underwater wet welding conditions on the diffusible hydrogen content in deposited metal
PublikacjaIn the study mercury displacement method was used for determination of diffusible hydrogen amount in deposited metal obtained during underwater wet welding with covered electrodes in laboratory conditions according to a two-level full factorial design for three factors. The factors and their levels were chosen among conditions and parameters of welding in accordance with the results of own preliminary studies. A statistical analysis...
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Mitigating metal-organic framework (MOF) toxicity for biomedical applications
PublikacjaMetal-organic frameworks (MOFs) are a novel class of crystalline porous materials, consisting of metal ions and organic linkers. These hybrid materials are highly porous and have a large specific surface area, making them of great interest for applications in gas separation, energy storage, biomedical imaging, and drug delivery. As MOFs are being explored for biomedical applications, it is essential to comprehensively assess their...
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Experimental investigation and process parameter optimization of sheet metal bending by line heating method
PublikacjaThe present study is concerned with the experimental investigation of sheet metal deforming by line heating method that incorporates the combined effect of traverse speed of the torch, thickness of the sheet metal, and the number of passes of the torch. For the numerical analysis of metal bending by line heating, the
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Influence of sludge treatment processes on heavy metal speciation
PublikacjaSludge composition is depending on sewage quality and also affected by processing methods such as thickening, stabilization and dewatering. During those processes some of sludge's undesirable properties might be reduced or enhanced.The objective of the study is the assessment of the influence of sludge processing on selected heavy metals partitioning between phases (aqueous and particle) and sludge. Sludge from the WWTP in Gdansk...
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Bioaccumulation of metals in tissues of marine animals, Part II - metal concentrations in animal tissues
PublikacjaThe bioaccumulation of metals in an animal depends on a multitude of factors: biotic ones, like its body dimensions and mass, age, sex, diet, metabolism and position in the trophic web, as well as abiotic ones such as the distribution of metals in its environment, the salinity, temperature and pH of the water, habitat type, interactions with other metals. But it is diet that has the greatest influence on the accumulation of metals...
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Silica xerogel-hydrogen peroxide composite: their morphology, stability, and antimicrobial activity
PublikacjaOpracowano metody otrzymywania stabilnego kompozytu złożonego z kserożelu krzemionkowego i nadtlenku wodoru w szerokim zakresie stężeń H2O2. Przeprowadzono charakterystykę otrzymanego kompozytu. W szczególności określono morfologię kompozytu, stabilność termiczną oraz dokonano oceny właściwości bakteriobójczych preparatu.
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The 15th Workshop on Progress in Trace Metal Speciation for Environmental Analytical Chemistry
PublikacjaArtykuł jest sprawozdaniem z konferencji TRACESPEC - the 15th Workshop on progress in trace Metal Speciation for Environmental Analytical Chemistry, ktora odbyla sie we wrzesniu 2016 na Politechnice Gdańskiej. W artykule przedstawiono głowne cele i załozenia konferencji oraz opisano program naukowy.
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Buckling analyses of cylindrical metal silos containing bulk solids
PublikacjaThe paper presents quasi-static 3D buckling analysis results of thin-walled cylindrical metal silos with and without bulk solids. The behaviour of the bulk solid was described with a hypoplastic constitutive model. Non-linear analyses with geometric and material non-linearity were performed with a perfect and an imperfect silo shell. Different initial geometric imperfections were considered. The influence of internally stored bulk...
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Diffusible hydrogen content in deposited metal of multilayer welded joints
PublikacjaThe article describes manufacturing technology of multilayer joints in terms of control the diffusible hydrogen content. Diffusible hydrogen content in deposited metal for multilayer welded joints made of covered rutile electrodes or covered cellulosic and basic electrodes was determined. It was found that after four beads, the diffusible hydrogen content decreases in the case of the first technology from 36 ml/100 g to 18 ml/100...
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Positron binding to alkali-metal hydrides: The role of molecular vibrations
PublikacjaThe bound vibrational levels for J=0 have been computed for the series of alkali-metal hydride molecules from LiH to RbH, including NaH and KH. For all four molecules the corresponding potential-energy curves have been obtained for each isolated species and for its positron-bound complex (e+XH). It is found that the calculated positron affinity values strongly depend on the molecular vibrational state for which they are obtained...
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Hybrid metal and non-metal activation of Oxone by magnetite nanostructures co-immobilized with nano-carbon black to degrade tetracycline: Fenton and electrochemical enhancement with bio-assay
PublikacjaElectrochemically synthesized magnetite nanostructures (ESMNPs) as a metal activator and nano-carbon black (NCB) as a non-metal activator were co-immobilized by alginate natural polymer to activate Oxone for the degradation of tetracycline (TC) antibiotic. The formation of sulfate radical was indirectly confirmed during the Oxone/ESMNPs/NCB/alginate process via the addition of scavenging compounds. This study revealed the high...
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Speciation of heavy metal compounds in samples of biota from marine ecosystems
PublikacjaIt has become increasingly evident that the toxicity, mobility, bioavailability and bioaccumulation of metals are dependent on the particular physico-chemical form in which the element occurs in the environment. Special attention is paid to metals, which are essential for the proper functioning of organisms if present in appropriate amounts but are toxic if in excess (i.e. Se, Cr, Zn), and also to non-essential elements (i.e. Hg,...
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Recent Advances in Graphene Oxide-Based Membranes for Heavy Metal Ions Separation
PublikacjaGraphene oxide (GO)-based membranes have been widely investigated for separation of dyes, salt ions, heavy metal ions, and biomolecules due to their high mechanical strength, single-layered structure, large surface area, and high affinity. However, due to irregular pore structure, nanochannels, interlayer distance, easy functionalization, swelling effect, and chemical stability under aqueous environment limited their separation...
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Morphology control through the synthesis of metal-organic frameworks
PublikacjaDesignable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal- organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under- standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi- vidual...
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Effect of the welding environment and storage time of electrodes on the diffusible hydrogen content in deposited metal
PublikacjaIn the study the glycerin displacement method was used for determination of diffusible hydrogen content in deposited metal. Specimens were welded in the air and in the water with covered rutile electrodes. The first part of the specimens was made immediately after opening the package of the electrodes. The electrodes were then stored in opened packages in laboratory conditions that allowed for contact with the air for three years....
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Nonlinear FEM analysis of irregular shells composed of fiber metal laminates
PublikacjaThe paper deals with the analysis of failure initiation in shells made of Fiber Metal Laminates (FML). The elas-tic material law for orthotropic lamina is stated accounting for asymmetric in-plane stress and strain measures. The asymmetry results from the employed general nonlinear 6-field shell theory where the generalized dis-placements involve the translation and the proper rotation field. The novelty of the presented results...