Filtry
wszystkich: 1330
wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: SELECTIVE LASER MELTING
-
Novel anticancer strategy aimed at targeting shelterin complexes by the induction of structural changes in telomeric DNA: hitting two birds with one stone.
PublikacjaThe ends of chromosomes in mammals are composed of telomeric DNA containing TTAGGG repeats, which bind specific proteins called shelterins. This telomeric DNA together with shelterins form a cap that protects the ends of chromosomes from being recognized as sites of DNA damage and from chromosomal fusions. Many very successful antitumor drugs used in the treatment of cancer patients bind to DNA, some of them with a prominent sequence...
-
A New Expression System Based on Psychrotolerant Debaryomyces macquariensis Yeast and Its Application to the Production of Cold-Active β-D-Galactosidase from Paracoccus sp. 32d
PublikacjaYeasts provide attractive host/vector systems for heterologous gene expression. The currently used yeast-based expression platforms include mesophilic and thermotolerant species. A eukaryotic expression system working at low temperatures could be particularly useful for the production of thermolabile proteins and proteins that tend to form insoluble aggregates. For this purpose, an expression system based on an Antarctic psychrotolerant...
-
Surface Structure of Components Created by Stereolitography
PublikacjaStereolithography is an additive rapid prototyping method. This method is based on the principle of solidifying a liquid photopolymer (resin) by laser radiation. Models obtained with this method are characterized by a specific surface structure called “stairstep effect”. It causes that, the surface should be processed by additional finishing (postprocessing). To minimize the additional machining process, the model should be set...
-
Functionalized azobenzocrown ethers as sensor materials—The synthesis and ion binding properties
PublikacjaNew 13- and 16-membered azobenzocrown ethers with aromatic amino, amide, ether–ester or ether–amide residue in para position to an azo moiety were obtained. Acid–base properties and ion binding ability of the colored compounds were studied by spectroscopic methods: UV–vis, fluorimetry and 1H NMR spectroscopy. Selected azobenzocrowns were tested as ionophores in ion-selective membrane electrodes (ISEs) – classic and miniature all...
-
Lower rim substituted p-tert-butyl-calix[4]arene. Part 17. synthesis, extractive and ionophoric properties of p-tert-butylcalix[4]arene appended with hydroxamix acid moieties
PublikacjaThe synthesis and characterization of four p-tert-butylcalix[4]arene-hydroxamic acidc are reported. The dependence of the metal ion binding, assessed by liquid extraction of the metal nitrates from water into dichloromethane in individual and competitive experiments, on the ligand structure, is presented. The results showed that those ligands could be successfully used in separation process of trnasition and heavy metals often...
-
Ionic Liquids and Deep Eutectic Mixtures: Sustainable Solvents for Extraction Processes
PublikacjaIn recent years, ionic liquids and deep eutectic mixtures have demonstrated great potential in extraction processes relevant to several scientific and technological activities. This review focuses on the applicability of these sustainable solvents in a variety of extraction techniques, including but not limited to liquid- and solid-phase (micro) extraction, microwave-assisted extraction, ultrasound-assisted extraction and pressurized...
-
Synthesis and properties of new 'N,'N-phenyltetrazole podand
PublikacjaThe synthesis of a new chromogenic N,N-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity...
-
The structure of lead-silicate glasses and nanocomposites doped with iron oxide
Dane BadawczeThe structure of iron-doped glasses and glass-ceramics were studied. Samples has the composition of 50SiO2–(50−x)PbO–xFe2O3, where x=15, 20 and 25 (in mol%). All samples were prepared by the conventional melt quenching technique; the melting was conducted in air at 1623 K in alumina crucibles. The melts were poured on a brass plate preheated to 573...
-
The morphology of vanadate glass-ceramics containing BaTiO3 measured with the use of AFM
Dane BadawczeThe structure of vanadate glass-ceramics doped with BaTiO3 was measured by AFM technique. Samples of the composition of x[BaO,TiO2]–(80 − x)V2O5–20Bi2O3 where x = 5, 10 and 15 in mol% were prepared by a conventional melt quenching technique. The melting was performed in alumina crucibles at the temperature of 1273 K–1373 K. The melts were poured on...
-
The morphology of lead-silicate glasses and nanocomposites doped with iron oxide
Dane BadawczeThe topography of iron-doped glasses and glass-ceramics were studied. Samples has the composition of 50SiO2–(50−x)PbO–xFe2O3, where x=15, 20 and 25 (in mol%). All sampleswere prepared by the conventional melt quenching technique; the melting was conducted in air at 1623 K in alumina crucibles. The melts were poured on a brass plate preheated to 573...
-
Linear impedance of Bi2VO5.5 glass-ceramic measured with impedance spectroscopy method at low temperature region
Dane BadawczeThe linear electrical properties of Bi2VO5.5 glass-ceramic prepared by traditional melt quenching technique was measured by impedance spectroscopy method.
-
Bioactive quaternary ammonium ionic liquids.
PublikacjaAn ionic liquid (IL) is an organic compound that contains at least one ionic bond. It consists of an organic cation and an organic or inorganic anion. It is an organic salt having a melting point below 100C. A very interesting group of IL are those with a long chain quaternary ammonium cation. They are formed by direct synthesis or by an anion-exchange reaction in quaternary ammonium halides. Popular and cheap precursors for the...
-
3D MODELLING OF CYLINDRICAL-SHAPED OBJECTS FROM LIDAR DATA - AN ASSESSMENT BASED ON THEORETICAL MODELLING AND EXPERIMENTAL DATA
PublikacjaDespite the increasing availability of measured laser scanning data and their widespread use, there is still the problem of rapid and correct numerical interpretation of results. This is due to the large number of observations that carry similar information. Therefore, it is necessary to extract from the results only the essential features of the modelled objects. Usually, it is based on a process using filtration, followed by...
-
EVALUATION OF 3D MODEL OF REBAR FOR QUANTITATIVE PARAMETERS
PublikacjaThe construction industry practices and processes are evolving constantly, and with the emergence of Industry 4.0, the use of technologies is expanding. Construction progress monitoring is an essential project lifecycle process; project success and timely completion are linked with effective progress monitoring operations and adopted tools. In the domain of automated construction progress monitoring, 3D modeling techniques have...
-
Gas bubble dynamics - experiment and fractal analysis.
PublikacjaPrzedstawiono nieliniowe aspekty generowania pęcherzyków gazowych z dysz szklanych umieszczonych pod powierzchnią cieczy. W badaniach eksperymentalnych zastosowano układ laser diodowy- fotodetektor oraz hydrofon. Sygnały z fotodetektora i hydrofonu były wzmacniane, rejestrowane za pomocą karty dźwiękowej, a następnie poddane analzie fraktalnej. W wyniku obliczeń ustalono mapy występowania chaosu w funkcji strumienia objętości gazu.
-
The luminescence study of CsPbI3 nanoparticles embedded in Cs4PbI6 crystals.
Dane BadawczeCs4PbI6, as a rarely investigated member of the Cs4PbX6 (X is a halogen element) family, has been successfully synthesized atlow temperatures by collaborators from National Taiwan University. Strong red to near-infrared (NIR) emission properties have been detected, and its optical emission centers have been identified to be numerous embedded perovskite-type...
-
Depth chemical profile in a CeIr3 sample
Dane BadawczeThe polycrystalline sample of CeIr3 used in the present studies was synthesized by arc-melting cerium (4N) and iridium (3N5) in an arc furnace on a water-cooled copper hearth using a tungsten electrode under a high purity argon atmosphere. A piece of zirconium was used as an oxygen getter. First, a button of Ir was prepared by arc-melting the iridium...
-
Immunosuppressive properties of amino acid and peptide derivatives of mycophenolic acid
PublikacjaMycophenolic acid (MPA) was coupled with amino acids and biologically active peptides including derivatives of tuftsin to modify its immunosuppressive properties. Both amino acid unit in the case of simple MPA amides and modifications within peptide moiety of MPA - tuftsin conjugates influenced the observed activity. Antiproliferative potential of the obtained conjugates was investigated in vitro and MPA amides with threonine methyl...
-
The structure of lead-silicate glasses containing nanocrystallites of iron oxides
Dane BadawczeThe structure of iron-doped glasses and glass-ceramics were studied. Samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO–xFe2O3, where x = 2, 5, 10, 15, 20 and 25 (in mol%). All samples were prepared by the conventional melt quenching technique; the melting was conducted in air at 1623 K in alumina crucibles. The melts were poured on a brass...
-
The morphology of lead-silicate glasses containing nanocrystallites of iron oxides
Dane BadawczeThe topography of iron-doped glasses and glass-ceramics were studied. Samples has the composition of (50 − 0.5x)SiO2–(50 − 0.5x)PbO–xFe2O3, where x = 2, 5, 10, 15, 20 and 25 (in mol%). All sampleswere prepared by the conventional melt quenching technique; the melting was conducted in air at 1623 K in alumina crucibles. The melts were poured on a brass...
-
Prototypowe urządzenie laserowe do femtosekundowej mikroobróbki materiałów
PublikacjaW artykule przedstawiono prototypowe urządzenie do laserowej mikroobróbki materiałów. Urządzenie to wykorzystuje femtosekundowy laser światłowodowy oparty na krysztale Yb:KYW. Wykorzystanie ultrakrótkich impulsów laserowych w mikroobróbce materiałów oferuje dużą przewagę nad mikroobróbką długoimpulsową ze względu na zminimalizowanie szkodliwego wpływu oddziaływań cieplnych. Pozwala to na bardzo precyzyjne i czyste cięcia oraz wysoki...
-
numerical prediction of vortex generated by hydrofoil
PublikacjaW pracy przedstawiono wyniki obliczeń programami Fluent i Comet dla płata śruby napędowej. Pola prędkości oraz wirowość za płatem porównano z wynikami pomiarów (LDA- Laser Doppler Anemometry) w tunelu kawitacyjnym Centrum Techik Okrętowych (CTO). Przedstawiono wpływ adaptacji siatki wg różnych kryteriów (lokalnej wirowości lub prędkości) na zgodność wyników obliczeń z danymi eksperymentalnymi.
-
Modeling of active fiber Bragg grating underwater acoustic sensor.
PublikacjaW pracy przedstawiono wyniki modelowania nowego typu przetwornika hydroakustycznego wykorzystującego światłowodową siatkę Bragga. Siatka ta, domieszkowana jonami pierwiastków ziem rzadkich, pracuje jako laser z rozłożonym sprzężeniem zwrotnym, co pozwala na znaczne zwiększenie czułości tego prztwornika w porównaniu z rozwiązaniami wykorzystującymi siatki pasywne. W celu uzyskania równomiernego rozkładu naprężeń siatki zastosowano...
-
Effect of heat treatment on the diffusion intermixing and structure of the Cu thin film on Si (111) substrate: a molecular dynamics simulation study
PublikacjaThis work is devoted to the study of the diffusion process at the interface between copper films with a thickness of 2, 3, 4, 7 and 10 atomic monolayers and silicon substrate by molecular dynamics simulation method. For this purpose, the variation of the concentration of copper and silicon along the perpendicular direction to the interface was investigated. An analysis of the density profile along this direction made it possible...
-
Synthesis, structure and physical properties of new intermetallic spin glass-like compounds RE2PdGe3 (RE = Tb and Dy)
PublikacjaNew intermetallic compounds Tb2Pd1.25Ge2.75 and Dy2Pd1.25Ge2.75 have been synthesized using the arc-melting method. The crystallographic structure and magnetic, electronic transport, and thermal properties are reported. The crystal structure obtained from powder x-ray diffraction analysis suggests that these compounds crystallize in the AlB2-type structure (space group P6/mmm, no. 191) with lattice parameters a = 4.228 53(5)/4.230 54...
-
New plasmonic platform for enhanced luminescence of Valrubicin
PublikacjaLuminescence enhanced by new structure of plasmonic platform with aluminum oxide (Al2O3) buffer layer deposited on gold nanostructures is investigated. Regularly distributed gold nanostructures of average dimension of 50 nm formed the active part of plasmonic platforms. They were manufactured on Corning 1737 glass substrate by melting of gold thin film. The nanostructures were coated by dielectric Al2O3 thin film with thickness...
-
Effect of Variation of Hard Segment Content and Graphene-Based Nanofiller Concentration on Morphological, Thermal, and Mechanical Properties of Polyurethane Nanocomposites
PublikacjaThis study describes the development of a new class of high-performance polyurethane elastomer nanocomposites containing reduced graphene oxide (RGO) or graphene nanoplatelets (GNP). Two types of polyurethane elastomers with different contents of hard segments (HS) were used as a polymer matrix. The developed nanocomposites were characterized by thermal analysis (DSC, TG), dynamic mechanical testing (DMA), hardness testing, mechanical...
-
Characterization of structural, thermal and mechanical properties of bismuth silicate glasses
Publikacjahe influence of heating and reduction processes on the structural, thermal and mechanical properties of bismuth-silicate glasses has been investigated. Two compositions of glasses: 40Bi2O3–60SiO2 (Bi0.57Si0.43Ox) and 27Bi2O3–73SiO2 (Bi0.43Si0.57Ox) were fabricated by a typical melt quenching technique. Then the reduction in hydrogen at 380 °C for 20, 42 or 67 h was performed. It was found that a 50 μm-thick layer was formed on...
-
Stability Investigation of the PCM Nanocomposites
PublikacjaEnsuring the stability is a key issue to be solved for the technical application of nanocomposites. In this work, fatty acid P1801 served as base phase change material (PCM)P1801, and its main ingredients are palmitic acid (58%) and stearic acid (38%). Titania (TiO2) and alumina (Al2O3) with mass concentrations of 1% and 5% were selected as nanoparticles, while polyvinylpyrrolidone (PVP) or oleic acid (OA) with mass concentrations...
-
Detailed studies of superconducting properties of Y2Pd1.25Ge2.75
PublikacjaWe report a successful synthesis of a high-purity intermetallic germanide Y2Pd1.25Ge2.75, crystallizing in the disordered variant of the AlB2-type structure. A single-phase sample was obtained via arc-melting by deliberately tuning the composition out of the ideal 2:1:3 ratio. Specific heat, electrical resistivity and magnetization measurements show that the compound is a weakly-coupled (λ e-p = 0.58) type-II superconductor with...
-
Investigation of sour substances by five-channel potentiometric taste sensor containing all-solid-state-electrodes ( ASSEs)
PublikacjaAn elaboration of taste sensor for discrimination of different food products is of great importance for food industry. Potentiometric taste sensor containing ion selective electrodes with lipid/polymer membranes has already been applied commercially in food industry. However, time-consuming and demanding preconditioning method of ions selective electrodes as well as maintenance of electrodes’ bodies are disadvantages of this taste...
-
INVESTIGATION OF SOUR SUBSTANCES BY FIVE-CHANNEL POTENTIOMETRIC TASTE SENSOR CONTAINING ALL-SOLID-STATE- ELECTRODES (ASSEs)
PublikacjaAn elaboration of taste sensor for discrimination of different food products is of great importance for food industry. Potentiometric taste sensor containing ion selective electrodes with lipid/polymer membranes has already been applied commercially in food industry. However, time-consuming and demanding preconditioning method of ions selective electrodes as well as maintenance of electrodes’ bodies are disadvantages of this taste...
-
Nanofiltration-Assisted Concentration Processes of Phenolic Fractions and Carotenoids from Natural Food Matrices
PublikacjaIn new food formulations, carotenoids and phenolic compounds are likely to be the most sought after food ingredients according to their bioactivity, nutraceutical, nutritional value, and compatibility properties once incorporated into food formulations. Such solutes are naturally present in many plant-based sources, and some portions are directly consumed when enriching food products and formulations; however, some portions, which...
-
Singlet oxygen in the removal of organic pollutants: An updated review on the degradation pathways based on mass spectrometry and DFT calculations
PublikacjaThe degradation of pollutants by a non-radical pathway involving singlet oxygen (1O2) is highly relevant in advanced oxidation processes. Photosensitizers, modified photocatalysts, and activated persulfates can generate highly selective 1O2 in the medium. The selective reaction of 1O2 with organic pollutants results in the evolution of different intermediate products. While these products can be identified using mass spectrometry...
-
Quality control of cheese samples for the presence of natamycin preservative – A natural deep eutectic solvent (NADES) based extraction coupled with HPLC
PublikacjaA new protocol for the determination of natamycin – an antifungal agent used as a food preservative - in cheese samples – is described. This new method is based on a natural deep eutectic solvent (NADES) green extraction procedure. High-performance liquid chromatography (HPLC) was used for detection and quantification. NADESs with different molar ratios were evaluated for efficient and selective extraction. NADES made of thymol...
-
Fracture Energy of Bonded Joints with 2D Elastic Adhesive Layer
PublikacjaWhen bonded joint is subjected to mode I fracture loading, the adhesive joints analytical solutions treats the adhesive layer, usually, as not existing or 1D Hooke elastic layer. In the case of 1D elastic layer, represented as Hookes spring element, is acting, only, in direction contrary to the applied load. Basing on the information yielded from sensitive laser profilometry technique, where deflections of bonded part of the joint...
-
Preparation and characterization of TiO2 nanostructures for catalytic CO2 photoconversion
PublikacjaThe titanium dioxide target (99.7%) of 1 cm in dia was ablated in vacuum by laser pulses(6 ns) at 266 nm and at repetition rate of 10 Hz. During deposition the laser fluence between 1 and 3.5 J/cm2 and the O2 pressure from the range of 10-2 - 1 Pa were applied. The thin TiO2 films were deposited on glass substrate (1 × 1 cm2) heated up to 500 °C. The chemical composition of the film and samples produced by annealing were investigated...
-
Accuracy improvement of the prestressed concrete structures precise geometry assessment by use of bubble micro-sampling algorithm
PublikacjaPrestressed concrete structures are well-known technology for a vast period, but nevertheless, this very technology is a leading solution, currently used in construction industry. Prestressed concrete structures have a huge advantage over conventional methods because it uses the properties of concrete in a very efficient way. The main idea behind this technology is to introduce into the cross-section of the structure, the internal...
-
Coherent-wave Monte Carlo method for simulating light propagation in tissue
PublikacjaSimulating propagation and scattering of coherent light in turbid media, such as biological tissues, is a complex problem. Numerical methods for solving Helmholtz or wave equation (e.g. finite-difference or finite-element methods) require large amount of computer memory and long computation time. This makes them impractical for simulating laser beam propagation into deep layers of tissue. Other group of methods, based on radiative...
-
Low-Level Aerial Photogrammetry as a Source of Supplementary Data for ALS Measurements
PublikacjaThe development of laser scanning technology ALS allows to make high-resolution measurements for large areas result-ing in significant reduction of costs. The main stakeholders at heights data received from the airborne laser scanning is mainly state administration. The state institutions appear among projects such as ISOK. Each point is classified in ac-cordance with the standard LAS 1.2, our research focuses on the class 6 -...
-
Genotyping Techniques for Determining the Diversity of Microorganisms
PublikacjaTyping of microbial pathogens, or identifying bacteria at the strain level, is particularly important for diagnosis, treatment, and epidemiological surveillance of bacterial infections. This is especially the case for bacteria exhibiting high levels of antibiotic resistance or virulence, and those involved in nosocomial or pandemic infections. Strain typing also has applications in studying bacterial population dynamics. The part...
-
The morphology of lead-borate glasses and nanocomposites doped with iron oxide
Dane BadawczeThe topography of iron-doped borate glasses and glass-ceramics were studied. Samples of composition of xFe2O3–(100 − x)(B2O3–2PbO) (2.5 < x < 37 in mol%) were prepared by the conventional meltquenching technique. The melting was conducted in alumina crucibles at the temperature of 1523 K. The melts were poured on a preheated (573 K) brass plate...
-
The structure of lead-borate glasses containing nanocrystallites of iron oxides
Dane BadawczeThe structure of iron-doped glasses and glass-ceramics were studied. Glass samples of composition of xFe2O3–(100 − x)(B2O3–2PbO) (2.5 b x b 37, in mol%) were prepared by the conventional melt quenching technique. The melting was conducted in alumina crucibles at the temperature of 1523 K. The melts were poured on a preheated (573 K) brass plate and...
-
The topography of Bi2VO5.5 ceramics prepared by melt-quenching technique was measured with confocal microscope
Dane BadawczeThe topography of Bi2VO5.5 ceramics prepared by melt-quenching technique was measured by confocal microscope.
-
Linear impedance of strontium–borate glass measured with impedance spectroscopy method at low temperature region
Dane BadawczeThe linear electrcial properties of strontium–borate glass was measured by impedance spectroscopy method.
-
Linear impedance of Bi2VO5.5 glass-ceramic annealed at 423 K measured with impedance spectroscopy method at low temperature region
Dane BadawczeThe linear electrical properties of Bi2VO5.5 glass-ceramic annealed at 423 K prepared by traditional melt quenching technique was measured by impedance spectroscopy method.
-
Te use of acoustic emission for assessment of the oil lubricity in a four-ball tester
Publikacjain view of the increased dynamic and temperature load in the compression-ignition engine tribological systems, particular attention is drawn to the problem of such lubrication of the friction nodes that after breaking the boundary layer it could be restored without any wear occurring. therefore, an idea has been devised of introducing to friction nodes, with the lubrication oils, of new substances (operational preparations) modifying...
-
Chromogenic macrocyclic derivatives of azoles - synthesis and properties,
PublikacjaNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
-
Azomacrocyclic derivatives of imidazole: synthesis, structure, and metal ion complexation properties
PublikacjaNew azocrown ethers comprising imidazoles in the macrocycle have been synthesized. Imidazole, 2-methyl-, 4-methyl-, and 4-phenylimidazole were incorporated to form macrocyclic units by coupling with the appropriate bis-diazonium salts. The syntheseswere performed under high dilution conditions. The X-ray structure of a water adduct of the 21-membered crown ether derivative of 4-methylimidazole 8 has been solved. Metal...
-
Label‐free optical detection of cyclosporine in biological fluids
PublikacjaIn this paper, a spectroscopic method for determination of cyclosporine concentrations in biological fluids is presented. Blood plasma and hemoglobin solutions are chosen for the experiment. For various cyclosporine concentrations in blood plasma and hemoglobin, absorbance measurements in spectra range from 600 to 1100 nm are performed. The measurement results are analyzed by the use of a dedicated algorithm. The obtained data...