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The effect of agro-waste co-digestion and sludge disposal on carbon footprint in municipal wastewater treatment plants
PublikacjaThe study presents analysis of the carbon footprint (CF) in 6 wastewater treatment plants in northern Poland with a special focus on the effect of co digestion of sewage sludge and food waste. Although co-digestion increases the on-site energy production, but it has a negative effect on the total CF. To overcome the negative effect, several sludge disposal scenarios were analysed and their effect on the CF reduction was determined....
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Influence of a lipid bilayer on the conformational behavior of amphotericin B derivatives - A molecular dynamics study.
PublikacjaAmphotericin B (AmB) is an effective but very toxic antifungal antibiotic. In our laboratory a series of AmB derivatives of improved selectivity of action was synthesized and tested. To understand molecular basis of this improvement, comparative conformational studies of amphotericin B and its two more selectivederivatives were carried out in an aqueous solution and in a lipid membrane. These molecular simulation studies revealed...
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The effect of adding a standard on the result of determination of polychlorinated biphenyls in bottom sediment samples
PublikacjaBottom sediments are a very important component of aquatic ecosystems. The sediment matrix is highly diverse and heterogeneous; in consequence, compounds entering the aquatic environment from different sources are considerably enriched at its surface. Bottom sediments are regarded as natural sorbents, since they accumulate many harmful substances, such as heavy metals and stable organic contaminants.Extraction is a key stage in...
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Rhodotorulic Acid and its Derivatives: Synthesis, Properties, and Applications
PublikacjaSiderophores are low molecular weight compounds produced by microorganisms to scavenge iron in iron-deficient environments. Rhodotorulic acid, a natural hydroxamate siderophore, plays a vital role in iron acquisition for fungi and bacteria. As the simplest natural hydroxamate siderophore, it exhibits a high affinity for ferric ions, enabling it to form stable complexes that facilitate iron uptake and transport within microorganisms....
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Detection of vehicles stopping in restricted zones in video from surveillance cameras
PublikacjaAn algorithm for detection of vehicles that stop in restricted areas, e.g. excluded by traffic rules, is proposed. Classic approaches based on object tracking are inefficient in high traffic scenes because of tracking errors caused by frequent object merging and splitting. The proposed algorithm uses the background subtraction results for detection of moving objects, then pixels belonging to moving objects are tested for stability....
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Lattice-commensurate skyrmion texture in a centrosymmetric breathing kagome magnet
PublikacjaSkyrmion lattices (SkL) in centrosymmetric materials typically have a magnetic period on the nanometer-scale, so that the coupling between magnetic superstructures and the underlying crystal lattice cannot be neglected. We reveal the commensurate locking of a SkL to the atomic lattice in Gd3Ru4Al12 via high-resolution resonant elastic x-ray scattering (REXS). Weak easy-plane magnetic anisotropy, demonstrated here by a combination...
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Activation of the C=P bond in phosphanylphosphaalkenes C=P–P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi
PublikacjaThree reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P–P bond is cleavaged and triphosphorus systems [P(Me)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1a'') and [P(nBu)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1b''), respectively, are formed depending on the nucleophilic reagent (biph ¼ biphenyl). In the...
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Intra-subject class-incremental deep learning approach for EEG-based imagined speech recognition
PublikacjaBrain–computer interfaces (BCIs) aim to decode brain signals and transform them into commands for device operation. The present study aimed to decode the brain activity during imagined speech. The BCI must identify imagined words within a given vocabulary and thus perform the requested action. A possible scenario when using this approach is the gradual addition of new words to the vocabulary using incremental learning methods....
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A robust sliding mode observer for non-linear uncertain biochemical systems
PublikacjaA problem of state estimation for a certain class of non-linear uncertain systems has been addressed in this paper. In particular, a sliding mode observer has been derived to produce robust and stable estimates of the state variables. The stability and robustness of the proposed sliding mode observer have been investigated under parametric and unstructured uncertainty in the system dynamics. In order to ensure an unambiguous non-linear...
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A large family of filled skutterudites stabilized by electron count
PublikacjaThe Zintl concept is important in solid-state chemistry to explain how some compounds that combine electropositive and main group elements can be stable at formulas that at their simplest level do not make any sense. The electronegative elements in such compounds form a polyatomic electron-accepting molecule inside the solid, a ‘polyanion’, that fills its available energy states with electrons from the electropositive elements...
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Non-metaldoped TiO2 nanotube arrays for high efficiency photocatalytic decomposition of organic species in water
PublikacjaTitanium dioxide is a well-known photoactive semiconductor with a variety of possible applications. The procedure of pollutant degradation is mainly performed using TiO2 powder suspension. It can also be exploited an immobilized catalyst on a solid support. Morphology and chemical doping have a great influence on TiO2 activity under illumination. Here we compare photoactivity of titania nanotube arrays doped with non-metal atoms:...
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State and control system variables sensitivity to rotor asymmetry in the induction motor drive
PublikacjaThe aim of this paper is to undertake analysis and comparison of the closed-loop and sensorless control systems sensitivity to the broken rotor for diagnostic purposes. For the same vector control system induction motor drive analysis concerning operation with the asymmetric motor, broken rotor fault handling and operation were investigated. Reliability, range of stable operation, fault symptoms and application of diagnosis methods...
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3D Monitoring - Identification of measurement problems at larger movements of the tracked points
PublikacjaAuthors identified the problems associated with the determination of the controlled points coordinates by use of automated Total Station placed behind transparent barrier. Important thing in the mentioned analysis was a large change of controlled points position and not stable Total Station’s stand (because of stand’s thermal drift). This two elements, combined with measurement made through glass plate determine the need for impact...
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The Ellenbogen's "Matter as Software" Concept for Quantum Computer Implementation: II Bonding Between the C60 and X@C60 Molecules as Available Molecular Building Blocks (MBBs) for Tip-Based Nanofabrication (TBN) of Quantum Computing Devices
PublikacjaThe binding energy, BE of the X@C60-X@C60 homodimer and the X@C60-Y@C60 heterodimer resulting from the bond formation between the occupied X@C60 MBB and the C60 molecule was studied by means of semiempirical PM7 calculations, where X and Y denote atoms from H to Bi, excluding Tc and lanthanides. All possible combinations of N = 68 guest atoms were considered, which resulted in K = 2346 of different calculated dimers of (X@C60-Y@C60)...
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Electrochemical and photoelectrochemical characterization of photoanodes based on titania nanotubes modified by a BiVO4 thin film and gold nanoparticles
PublikacjaTitania nanotubes (TNT) modified with thin films of bismuth vanadate (BiVO4) and gold nanoparticles (GNP) were photoelectrochemically characterized as photoanodes for water photooxidation. Presence of bismuth vanadate enhanced efficiency of photocurrent generation in comparison with pristine TNTs under visible light illumination. Besides an extended range of absorbed light, the presence of both BiVO4 and GNP reduced the charge...
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Solution of the dike-break problem using finite volume method and splitting technique
PublikacjaIn the paper the finite volume method (FVM) is presented for the solution of two-dimensional shallow water equations. These equations are frequently used to simulate the dam-break and dike-break induced flows. The applied numerical algorithm of FVM is based on the wave-propagation algorithm which ensures a stable solution and simultaneously minimizes the numerical errors. The dimensional decomposition according to the coordinate...
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Synthesis, structural and spectroscopic properties of asymmetric schiff bases derived from 2,3-diaminopyridine
PublikacjaTwo Schiff base derivatives, 4-(2-amino-3-pyridyliminomethyl)phenol (I) and 3-(2-amino-3- pyridyliminomethyl)nitrobenzene (II ), were synthesised and characterised by spectroscopy. The structure of I was determined by single crystal X-ray diffraction studies. The asymmetric Schiff base derived from 2,3-diaminopyridine selectively recognise transition and heavy metal cations, and some anion. Ligands I and II form stable complexes...
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Folding‐upon‐repair DNA nanoswitches for monitoring DNA repair enzymes activity
PublikacjaWe demonstrate here a new class of DNA‐based nanoswitches that, upon enzymatic repair, could undergo a conformational change mechanism leading to a change in fluorescent signal. Such folding‐upon‐repair DNA nanoswitches are synthetic DNA sequences containing O6‐methyl‐guanine (O6‐MeG) nucleobases and labelled with a fluorophore/quencher optical pair. The nanoswitches are rationally designed so that only upon enzymatic demethylation...
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Computationally Effcient Solution of a 2D Diffusive Wave Equation Used for Flood Inundation Problems
PublikacjaThis paper presents a study dealing with increasing the computational efficiency in modeling floodplain inundation using a two-dimensional diffusive wave equation. To this end, the domain decomposition technique was used. The resulting one-dimensional diffusion equations were approximated in space with the modified finite element scheme, whereas time integration was carried out using the implicit two-level scheme. The proposed...
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Eventual Convergence of the Reputation-Based Algorithm in IoT Sensor Networks
PublikacjaUncertainty in dense heterogeneous IoT sensor networks can be decreased by applying reputation-inspired algorithms, such as the EWMA (Exponentially Weighted Moving Average) algorithm, which is widely used in social networks. Despite its popularity, the eventual convergence of this algorithm for the purpose of IoT networks has not been widely studied, and results of simulations are often taken in lieu of the more rigorous proof....
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A novel method of creating thermoplastic chitosan blends to produce cell scaffolds by FDM additive manufacturing
PublikacjaDue to its remarkable and promising biological and structural properties, chitosan has been widely studied in several potential applications in the biomedical sector. Attempts are being made to use this polymer and its properties in thermoplastics dedicated to 3D printing in FDM technology. However, chitosan can be processed only from acid solution, which limits its applications. The paper presents a new path for the production...
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Combined chemoresistive and in situ FTIR spectroscopy study of nanoporous NiO films for light-activated nitrogen dioxide and acetone gas sensing
PublikacjaThe chemoresistive sensor response of nanoporous NiO films prepared by advanced gas deposition was investigated by combined resistivity and in situ FTIR spectroscopy, with and without simultaneous light illumination, to detect NO2 and acetone gases. The sensitivity towards NO2 increased dramatically under UV irradiation employing 275 nm light. Improved sensitivity was observed at an elevated temperature of 150 °C. In situ FTIR...
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Advances in mass spectrometry for iron speciation in plants
PublikacjaIron is an important nutrient essential for plants and critical for human health. The state-of-the art of methods for iron speciation in cereal grains and plant fluids is critically reviewed. Particular attention is given to the latest developments in the coupling of HPLC with the parallel ICP MS and electrospray ionization (ESI) MS/MS detection, usually QTOF MS or Q-Orbitrap MS, for the identification and quantification of iron...
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Electron interactions with Bis(pentamethylcyclopentadienyl) titanium(IV) dichloride and difluoride
PublikacjaWe present a combined experimental and theoretical study of the interaction of electrons with Bis(pentamethylcyclopentadienyl)titanium(IV) dichloride (Cp∗2TiCl2) and difluoride (Cp∗2TiF2). We report the experimental measurements of partial cross sections for the dissociative electron attachment (DEA) and the electron ionization (EI) mass spectra of isolated molecules. Estimates of the absolute cross sections are done on the basis...
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Composites in energy storing prosthetic feet
PublikacjaComposites reinforced with carbon and glass fibers have become the commonly used material in the production of energy storing prosthetic feet (ESPF/elastic feet prostheses). Their properties ensure a stable and light structure that allows for accumulation, storage and release of energy during walking, thus ensuring an increase in gait efficiency. Depending on the modification of the composite in terms of fiber selection, their...
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Synthesis Methods and Favorable Conditions for Spherical Vaterite Precipitation: A Review
PublikacjaVaterite is the least thermodynamically stable anhydrous calcium carbonate polymorph. It exists very rare in nature, e.g. in some rock formations or as a component of biominerals produced by some fishes, crustaceans or birds. Synthetic vaterite particles are proposed as carriers of active substances in medicines, additive in cosmetic preparations as well as adsorbents. Also, their utilization as a pump for microfluidic flow is...
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Magnetoacoustic Heating in Nonisentropic Plasma Caused by Different Kinds of Heating-Cooling Function
PublikacjaThe nonlinear phenomena which associate with magnetoacoustic waves in a plasma are analytically studied. A plasma is an open system with external inflow of energy and radiation losses. A plasma’s flow may be isentropically stable or unstable. The nonlinear phenomena occur differently in dependence on stability or instability of a plasma’s flow. The nonlinear instantaneous equation which describes dynamics of nonwave entropy mode...
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Thermal degradation assessment of canola and olive oil using ultra-fast gas chromatography coupled with chemometrics
PublikacjaOil blending is often used to enhance the properties of vegetable oils. The admixture of a more thermally stable oil makes the resulting blend more suitable for use in frying. A new method of quality assessment of vegetable oils used in frying is presented in this paper. In this method, ultra-fast gas chromatography coupled with flame ionization detector and chemometrics is employed. Principal component analysis was used for data...
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Effectiveness of toluene separation from gas phase using supported ammonium ionic liquid membrane
PublikacjaAmmonium ionic liquids (ILs) are relatively cheap in synthesis and environmentally benign and despite that they have been very rarely used in gas separation. In this research we used several ammonium ILs as liquid membranes for removal of residual toluene from gas phase. Ionic liquids used in this study were composed of bis(trifluoromethylsulfonyl)imide anion [Tf2N] and trimethylbutylammonium [N1114], trietylbutylammonium [N2224],...
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublikacjaThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Hydrogen Production Mechanism in Low-Temperature Methanol Decomposition Catalyzed by Ni3Sn4 Intermetallic Compound: A Combined Operando and Density Functional Theory Investigation
PublikacjaHydrogen production from methanol decomposition to syngas (H2 + CO) is a promising alternative route for clean energy transition. One major challenge is related to the quest for stable, cost-effective, and selective catalysts operating below 400 °C. We illustrate an investigation of the surface reactivity of a Ni3Sn4 catalyst working at 250 °C, by combining density functional theory, operando X-ray absorption spectroscopy, and high-resolution...
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Post-match recovery profile of leukocyte cell subsets among professional soccer players
PublikacjaThis study assessed the impact of cumulative match time on the distribution of CD45+ cell subtests in the capillary blood of professional soccer players. Twenty-two males (aged 18–30 years) took part in the 36-week study. Participants playing up to 540 in cumulative match time and less than 30 min in each single match during the observation period formed the control group. White blood cell (WBC) phenotyping and creatine kinase...
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ANALYSIS OF THE IMPACT OF THE PLANNED SEWAGE DISCHARGE FROM THE ‘NORTH’ POWER PLANT ON THE VISTULA WATER QUALITY
PublikacjaThe paper presents results of analysis of the industrial sewage discharge impact from the ‘North’ Power Plant on the Vistula water quality around 45+330 of the river kilometer. For the analysis, the two-dimensional models of flow, impurities and temperature transport were used. Hydrological conditions of the analyzed section of the river, characteristic flows and bathymetry of the riverbed in the first instance were defined....
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A Development of a Capacitive Voltage Divider for High Voltage Measurement as Part of a Combined Current and Voltage Sensor
PublikacjaThis article deals with the development of capacitive voltage divider for high voltage measurements and presents a method of analysis and optimization of its parameters. This divider is a part of a combined voltage and current sensor for measurements in high voltage power networks. The sensor allows continuous monitoring of the network distribution status and performs a quick diagnosis and location of possible network failures....
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Pochodne oleju makowego jako związki biologicznie czynne
PublikacjaW pracy przebadano skład kwasów tłuszczowych oleju makowego z nasion maku niskomorfinowego (Michałko, Agat, Mieszko, Zambo, Rubin i Przemko) i wysokomorfinowego (Lazur). Do dalszych badań wybrano olej makowy odmiany Michałko ze względu na wysoką zawartość kwasu linolowego (72,8%), niską zawartość kwasu oleinowego (12,6%) i kwasu linolenowego (0,8%). Kwasy nasycone głównie palmitynowy (11,3%) mogą być usunięte w odrębnym postępowaniu....
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Charakterystyka eksploatacyjna pomp ciepła zainstalowanych w oczyszczalni ścieków
PublikacjaW artykule przedstawiono charakterystykę eksploatacyjną sprężarkowych pomp ciepła zainstalowanych w oczyszczalni komunalnej i wykorzystujących ścieki oczyszczone jako dolne źródło ciepła. Zastosowanie ścieków oczyszczonych jest uzasadnione ich dostępnością oraz stosunkowo wysoką temperaturą (10-25°C). Prawidłowa eksploatacja układu wymaga zastosowania pośredniego obiegu parowacza oraz regularnych zabiegów czyszczenia wymiennika...
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Inwestycja w wino – ocena sommelierów, rocznik i liczba punktów dystrybucji a wycena
PublikacjaW opracowaniu wyznaczono za pomocą współczynników korelacji liniowej Pearsona siłę i kierunek oddziaływania pomiędzy: ceną wina a rocznikiem, ceną wina a oceną sommelierów oraz ceną wina a liczbą punktów dystrybucji. Analizie poddano 8 szczepów winnych z rejonu Bordeaux. Najsilniejszy związek odnotowano pomiędzy ceną wina a rocznikiem trunku. W artykule obliczono także wybrane statystyki opisowe dla ceny wina, oceny przyznawanej...
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Note on the variance of the sum of gaussian functonals
PublikacjaDowodzi się oszacowania wariancji sum funkcjonałów losowych, konstruowanych dla zależnego ciągu gaussowskiego.Let (Xi; i = 1; 2; : : :) be a Gaussian sequence with Xi 2 N(0; 1) for each i and suppose its correlation matrix R = (ij)i;j1 is the matrix of some linear operator R : l2 ! l2. Then for fi 2 L 2(), i = 1; 2; : : : ; where is the standard normal distribution, we estimate the variation of the sum of the Gaussian functionals...
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The Efficiency of Polish Stock Market: Ordinal Patterns Approach
PublikacjaZunino et al. analyzed the problem of discrimination of developed and emergent markets by the use of ordinal patterns methods: number of forbidden patterns and ordinal pattern probability distribution as a basis for entropy and statistical measure of complexity. In this paper we apply the same methodology for the analysis of Polish stock market (index WIG). The results indicate that Polish market belongs neither to developed, nor...
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Investigation of corrosion behavior of 6060 and 6082 aluminum alloys under simulated acid rain conditions
PublikacjaInstantaneous impedance changes of 6060 and 6082 type aluminum alloys in pure water, and simulated acid rain poured into the pure water was investigated by dynamic electrochemical impedance spectroscopy (DEIS). In this way, the influence of aluminum content on the corrosion behavior of 6060 and 6082 type aluminum alloys immersed in simulated acid rain was determined. The corrosion rate of the alloy decreased with increasing Al...
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Analysis of Agricultural and Engineering Systems using Simulation Decomposition
PublikacjaThis paper focuses on the analysis of agricultural and engineering processes using simulation decomposition (SD). SD is a technique that utilizes Monte Carlo simulations and distribution decomposition to visually evaluate the source and the outcome of different portions of data. Here, SD is applied to three distinct processes: a model problem, a nondestructive evaluation testing system, and an agricultural food-water energy system....
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Inverse Analysis as a Key Element of Safety Assessment under the Snow Load For The Large Suspension Roofs Structure
PublikacjaThe paper presents a concept and realization of monitoring system for the Silesian Stadium in Chorzow. The idea of the system lies in fusion of structure monitoring with a calibrated numerical FEM model [1]. The inverse problem is solved. On the base of measured selected displacements, the numerical FEM model of the structure combined with iterative method, develops the current snow load distribution. Knowing the load, we can calculate...
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Multimedia distributed system for visualization of ongoing and archival events for BG
PublikacjaThe paper presents concept of the distributed system designed to gather and provide the information about vehicles, vessels and airplanes present within the area of operations of the Border Guard supplemented with related multimedia. The part of the system related to the map data gathering, distribution and visualization has been already implemented in the preceding project. The presented system is the expansion of the previous...
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Application of Barkhausen method to determine internal stresses in cold-rolled and hot-rolled sheets
PublikacjaThe paper presents investigations on internal stress distribution in plane hot—or cold-rolled sheets dedicated for the cold-formed profiles. The motivation of the research is a new profile design whose bending technology, incorporating a longitudinal welded joint and hot-dip galvanization after bending and welding introduces additional internal stresses. In order to identify the entirety of stresses in the process of sheet production...
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Numerical and experimental investigation of rotational stiffness of zed-purlins connection with sandwich panels
PublikacjaA rotational resistant stiffness of the zed-purlins connection with sandwich panels is investigated. A simple finite element method model of the connection is proposed. The numerical analysis of the model performed by ABAQUS software, in physically linear and geometrically nonlinear ranges, leads to the rotational resistant stiffness sought. The numerical solution obtained is verified experimentally. Two variants of distribution...
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Sharp transitions in low-number quantum dots Bayesian magnetometry
PublikacjaWe consider Bayesian estimate of static magnetic field, characterized by a prior Gaussian probability distribution, in systems of a few electron quantum dot spins interacting with infinite temperature spin environment via hyperfine interaction. Sudden transitions among optimal states and measurements are observed. Usefulness of measuring occupation levels is shown for all times of the evolution, together with the role of entanglement...
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Thermal imaging in automatic rodent’s social behaviour analysis
PublikacjaLaboratory rodent social behaviour analysis is an extremely important task for biological, medical and pharmacological researches. In this work thermal images features that facilitate analysis are presented. Methods to distinguish objects on the basis of thermal distribution are tested. Actions of grooming or biting one rodent by another - important social behaviour incidents - are clearly visible...
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Standing Waves in a Rectangular Resonator Containing Acoustically Active Gases
PublikacjaThe distribution of perturbations of pressure and velocity in a rectangular resonator is considered. A resonator contains a gas where thermodynamic processes take place, such as exothermic chemical reaction or excitation of vibrational degrees of a molecule’s freedom. These processes make the gas acoustically active under some conditions. We conclude that the incident and reflected compounds of a sound beam do not interact in the...
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Multisource model of ship electric field
PublikacjaA steel-hulled ship in sea water produces an electric field around itself. The source of this field are electrochemical processes and ship's cathodic protection. The analysis of the electric field around the ship is important by the reason of the ship's identification and counter-mine protection. The paper presents a simplified model of the ship's multisource electric field, which allows to calculate the electric field distribution...
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Mesoscopic impedance analysis of solid materials surface
PublikacjaSeveral techniques have been developed in order to characterize electrical properties of surfaces in micrometer/nanometer scale. Obtaining of the spatial distribution of sample resistance, capacitance or potential requires separate measurements performed in different scanning modes. On the other hand, analysis of the frequency response of investigated system enables determination of several physical quantities in single measurement...