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Wyniki wyszukiwania dla: EFFECT OF WATER
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Why the solvation water around proteins is more dense than bulk water
PublikacjaThe main aim of this work is to propose a rational explanation of commonly observed phenomenon of increasing water density within solvation shell of proteins. We have observed that geometry of the water-water hydrogen bond network within solvation layer differs from the one in bulk water and it is the effect of interactions of water molecules with protein surface. Altered geometry of the network reflects changes in the structure...
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Water sorption and blistering of GFRP laminates with varying structures
PublikacjaThe microstructures, water absorption as well as blistering was studied for bi- and tri- axial glass fibre vinyl ester and polyester -matrix laminates coated with gel coat layer and uncoated. The effect of manufacturing technique on water sorption characteristics was considered. It was found that water sorption characteristics of GFRP depend on manufacturing methods. The least water intake was found for specimens having perfect...
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Effect of alkyl sulfate on the phase behavior of microemulsions stabilized with monoacylglycerols
PublikacjaIn this study the effect of an anionic surfactant (sodium dodecyl sulfate SDS) and oils (hydrocarbons: C12-C16) on the formation and phase behavior of the systems of oil/monoacylglycerols (MAG):SDS/propylene glycol/water has been investigated. The effects of the surfactant mixture on the phase behavior and the concentrationof water or oil in the systems were studied at three temperatures (50, 55, 60 C). Electrical conductivity...
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Numerical Modeling of Water and Ice Dynamics for Analysis of Flow Around the Kiezmark Bridge Piers
PublikacjaThis paper presents the results of a numerical model study on the effect of ice on the proposed bridge piers in the Vistula River outlet and its effect on flow conditions in the river. The model DynaRICE is used in this study, which is a two-dimensional hydro-ice dynamic numerical model developed for dynamic ice transport and jamming in rivers. To simulate river hydrodynamics in the vicinity of the bridge piers, 2-dimensional numerical...
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The effect of dehydration/rehydration of bacterial nanocellulose on its tensile strength and physicochemical properties
PublikacjaBacterial nanocellulose (BNC) is a natural biomaterial with a wide range of biomedical applications. BNC contains 99 % of water which makes it too thick to be used as a bioimplant material. The aim of the work was to determine the effect of the BNC dehydration followed by rehydration on its mechanical and physicochemical properties, in the context of the use of BNC as bio-prostheses in the cardiovascular system. Dehydration involved the...
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Influence of Added Water Mass on Ship Structure Vibration Parameters in Virtual and Real Conditions
PublikacjaModelling of ship structures in a virtual environment is now standard practice. Unfortunately, many engineers forget to consideri the influence of added water on the frequency values and the amplitude of natural vibrations. The article presents the effect of water damping on the frequency values of the individual natural vibration modes. The tests were carried out in two stages. First, the mentioned values were determined using...
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Rain Water: Atmospheric Deposition
PublikacjaWater is transferred from the atmosphere to the land surface mainly via various forms of atmospheric precipitation; however, the contribution of surface condensation/deposition (e.g., dew, hoar frost, occult precipitation) should not be neglected. Rainwater and liquid deposits (dew, hoar frost, rime) are components of the physical and geographical environment that are easily assimilated and transported. Thus, they are generally...
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Performance of the PVT solar collector operated with water-Al2O3 nanofluid
PublikacjaAn experimental investigation of the hybrid module photovoltaic panel -solar collector (PVT) cooled by water-Al2O3 nanofluids has been conducted. The weight fractions of the nanoparticles were 1% and 3%. Thermal efficiency, power efficiency and overall efficiency have been determined for artificial source of light and sunlight. No noticeable effect of the nanoparticle concentration on the overall efficiency of the PVT module has...
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PERFORMANCE OF THE PVT SOLAR COLLECTOR OPERATED WITH WATER –AL2O3 NANOFLUID
PublikacjaAn experimental investigation of the hybrid module photovoltaic panel -solar collector (PVT) cooled by water-Al2O3 nanofluids has been conducted. The weight fractions of the nanoparticles were 1% and 3%. Thermal efficiency, power efficiency and overall efficiency have been determined for artificial source of light and sunlight. No noticeable effect of the nanoparticle concentration on the overall efficiency of the PVT module has...
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The effect of cable duct diameter on the ampacity of high-voltage power cables
PublikacjaThe ampacity of power cables depends, among others, on the conditions of heat dissipation from the cable to the environment. Cables are usually laid directly in the ground, but in some sections, they may be placed in ducts, which adversely affects the ampacity of the cable line. The paper presents heat transfer phenomena for cables installed in pipe-type ducts filled with air. The effect of cable duct diameter on this ampacity...
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The impact of sediment, fresh and marine water on the concentration of chemical elements in water of the ice-covered lagoon
PublikacjaThe common use of chemical elements by man has been contributing to their extraction for centuries. As a consequence, they have been directly or indirectly introduced into the biogeochemical cycle. In the framework of many conventions, mining and processing of elements are currently subject to many restrictions. However, their large load that has already been deposited in the soil and bottom sediments can be remobilised and...
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The Use of Cluster Analysis to Evaluate the Impact of COVID-19 Pandemic on Daily Water Demand Patterns
PublikacjaProper determination of unitary water demand and diurnal distribution of water consumption (water consumption histogram) provides the basis for designing, dimensioning, and all analyses of water supply networks. It is important in the case of mathematical modelling of flows in the water supply network, particularly during the determination of nodal water demands in the context of Extended Period Simulation (EPS). Considering the...
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Structural and dynamic properties of water within the solvation layer around various conformations of the glycine-based polypeptide
PublikacjaSeveral conformations of the solvated glycine-based polypeptides were investigated using molecular dynamics simulations. Some properties of water in the neighbouring space around these molecules were investigated. It was found, that water forms a well-defined layer - the first solvation shell - around the peptide molecule, and thickness of this layer is independent of the peptide structure, and it equals to approximately 0.28 nm....
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Durability of Asphalt Concrete Subjected to Deteriorating Effects of Water and Frost
PublikacjaThe paper presents testing of the detrimental effects of water and frost on asphalt pavements. It included laboratory testing of 5 fatigue life of asphalt concrete that was subjected to action of water and frost and field testing of damages caused by water and frost on 6 existing asphalt pavements, such as stripping, raveling, and potholes. Laboratory simulation of water and frost action was based on the 7 original AASHTO T283...
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Water-lubricated stern tube bearing - experimental and theoretical investigations of thermal effects
PublikacjaThe paper presents research results of thermal phenomena accompanying operation of a water-lubricated stern tube bearing with axial grooves. Experimental tests revealed, that intensity of forced axial flow has strong influence on bush temperature. Numerical simulations focused on investigation of the thermal phenomena under operation of water-lubricated journal bearing showed, that restricted axial flow promotes backflow of the...
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Bioaugmentation of a sequencing batch reactor with Archaea for the treatment of reject water
PublikacjaIn this study, the bioaugmentation of a sequencing batch reactor (SBR) for the treatment of reject water from wastewater treatment plant was evaluated. For the bioaugmentation step a product containing an enrichment of microorganisms from the Archaea domain was used to enhance the performance of the reactor for treating reject water. The experiment was carried out in two parallel lab-scale sequencing batch reactors. The first one...
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Structural and Dynamic Properties of Water within the Solvation Layer around Various Conformations of the Glycine-based Polypeptide
PublikacjaSeveral conformations of the solvated glycine-based polypeptides were investigated using molecular dynamics simulations. Some properties of water in the neighboring space around these molecules were investigated. It was found that water forms a well-defined layer—the first solvation shell—around the peptide molecule, and thickness of this layer is independent of the peptide structure and is equal to approximately 0.28 nm. Within...
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The Effect of Steaming Beech, Birch and Maple Woods on Qualitative Indicators of the Surface
PublikacjaThis work presents the effect of steaming beech, birch and maple woods on the resulting quality of the milled wood surface. The steaming process of the studied woods results in a targeted change in the color of the wood, which changes from the original light white-gray color to fine reddishbrown to dark brown color shades that are more or less saturated depending on the temperature of the saturated water steam. The color changes...
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The lethal effect of hydrotechnical concrete on freshwater Bivalvia
PublikacjaMost hydrotechnical buildings under construction demand the concrete mixture to be set directly under water. The main reason for such a procedure is to limit the washing away of the the concrete binding mixture and to increase the efficiency of organisation of work so as to ensure continuity in concreting. The impact on the aquatic environment of recent developments in concrete technology and the use of new components has not yet...
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Performance of the flat plate solar collector operated with water-Al2O3 nanofluid
PublikacjaThe paper discusses the effect of application of water-Al2O3 nanofluid, as a working fluid, on the efficiency of a flat plate solar collector. The mass concentration of nanoparticles was 0.1%, 0.2% and 0.4%. The tests were conducted for two values of radiation of about 1050 W/m2 and 400 W/m2, and volume flow rates of 60 l/h, 120 l/h and 170 l/h. The efficiency was calculated according to recommendations of the Polish Standard....
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Comparison of state feedback and PID control of pressurizer water level in nuclear power plant
PublikacjaThe pressurizer water level control system in nuclear power plant with pressurized water reactor (PWR) is responsible for coolant mass balance. The main control goal is to stabilize the water level at a reference value and to suppress the effect of time-varying disturbances (e.g. coolant leakage in primary circuit pipeline system). In the process of PWR power plant operation incorrect water level may disturb pressure control or...
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Influence of Osmolytes on Protein and Water Structure: A Step To Understanding the Mechanism of Protein Stabilization
PublikacjaResults concerning the thermostability of hen egg white lysozyme in aqueous solutions with stabilizing osmolytes, trimethylamine-N-oxide (TMAO), glycine (Gly), and its N-methyl derivatives, N-methylglycine (NMG), N,N-dimethylglycine (DMG), and N,N,N-trimethylglycine (betaine, TMG), have been presented. The combination of spectroscopic (IR) and calorimetric (DSC) data allowed us to establish a link between osmolytes’ influence on...
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Simulations of air and water flow in a model dike during overflow experiments
PublikacjaFlow in flood dikes, earth dams, and embankments occurs in variably saturated conditions, with pores of the earth material filled partly with water and partly with air. In routine engineering analysis, the influence of pore air is neglected and the air pressure is assumed equal to atmospheric. In some circumstances, for example, during overtopping of the dike by water, the effect of pore air on water flow and stability of the structure...
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Influence of water and mineral oil on the leaks in satellite motor commutation unit clearances
PublikacjaThe article describes the flow rates of mineral oil and water flowing, as working media, through the commutation unit of a hydraulic satellite motor. It is demonstrated that geometrical dimensions of commutation unit clearances change as a function of the machine shaft rotation angle. Methods for measuring the rate of this flow and the pressure in the working chamber are presented. The results of pressure measurements in the working...
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Potential Toxic Effects of Airport Runoff Water Samples on the Environment
PublikacjaDespite the positive aspects of the intensive development of aviation, airports are considered large-scale polluters. Pollution caused by runoff water (stormwater) is one of the major problems related to airport operations. The aim of this study was to characterize the potential toxic impact on aquatic life from runoff water discharges from four international airports in Europe. Samples of stormwater were collected at airports...
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Kazimierz Darowicki prof. dr hab. inż.
OsobyStudia wyższe ukończyłem w czerwcu 1981 roku po zdaniu egzaminu dyplomowego i obronie pracy magisterskiej. Opiekunem pracy magisterskiej był dr hab. inż. Tadeusz Szauer. W roku 1991, 27 listopada uzyskałem stopień naukowy broniąc pracę doktorską zatytułowaną „Symulacyjna i korelacyjna analiza widm immitancyjnych inhibitowanej reakcji elektrodowej”. Promotorem pracy był prof. dr hab. inż. Józef Kubicki (Wydział Chemiczny...
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Wettability of Horizontal Stainless Steel Tube by Nanofluid Droplets
PublikacjaThe goal of the present work was the experimental determination of the contact angle of three nanofluids, i.e. water-Al2O3, water-Cu and water-TiO2 on horizontal stainless steel tube of 1.6 mm OD. Of particular interest was the effect of nanoparticle concentration (0.01%, 0.1%, and 1% by weight) on droplet contact angle.
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Wettability of Horizontal Stainless Steel Tube by Nanofluid Droplets
PublikacjaThe goal of the present work was the experimental determination of the contact angle of three nanofluids, i.e. water-Al2O3, water-Cu and water-TiO2 on horizontal stainless steel tube of 1.6 mm OD. Of particular interest was the effect of nanoparticle concentration (0.01%, 0.1%, and 1% by weight) on droplet contact angle.
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The effect of microemulsion composition on the morphology of Pd nanoparticles deposited at the surface of TiO2 and photoactivity of Pd-TiO2
PublikacjaA series of microemulsion (ME) system, constituted by different water to surfactant molar ratios (Wo) and oil to surfactant mass ratios (S), have been applied for Pd-TiO2 preparation. The effect of ME properties on the morphology of Pd nanoparticles formed at TiO2 surface and an effect of Pd size and distribution on the surface and photocatalytic properties of Pd-TiO2 were investigated. Microemulsion systems were characterized...
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Combination of hydrodynamic cavitation and SR-AOPs for simultaneous degradation of BTEX in water
PublikacjaHydrodynamic cavitation (HC) is an emerging technology gaining interest in water treatment for use in elimination of a wide range of organic pollutants. The energy released during cavitation phenomenon has number of applications and, particularly, it can be utilized for activation of persulfate (PS) and peroxymonosulfate (PMS). In the present study, hybrid techniques: HC combined with persulfates – HC-PS and HC-PMS were tested...
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublikacjaAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Optimization of vortex-assisted supramolecular solvent-based liquid liquid microextraction for the determination of mercury in real water and food samples
PublikacjaA novel method was developed for sample preparation for spectrophotometric determination of Hg(II) in water and food samples. The method was based on vortex-assisted supramolecular solvent-assisted liquid-liquid microextraction (VA-SUPRASs-LLME). Analytical parameters such as pH, chelating agent, solvent type and volume, vortex time and salting out effect were optimized. Surface and normal probability plots were drawn for the variables...
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Spectroscopic studies of a ring opening process between epoxy- and aminosilanes and imine formation reactions in aqueous solutions
PublikacjaNMR and Raman spectroscopy studies were performed for different 3-aminopropyl(trimethoxy)- and 3-glycidoxypropyl (trimethoxy)silane based sol-gel systems containing different ketones. Exceptionally stable imine products were obtained depending on a reaction system at alkaline pH conditions and in the presence of water. These imine formation reactions were carried out without further catalyst. In addition, effect of water for the...
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The hydration of selected biologically relevant molecules – the temperature effect on apparent molar volume and compression
PublikacjaThe densities and sound velocities at T = (288.15, 293.15, 298.15, 303.15 and 308.15) K were measured for aqueous solutions of glycine, trimethylamine-N-oxide, taurine and N-methylacetamide. From these data, the apparent molar volumes, V the apparent molar isentropic compressions, KS,, and the Passynski hydration numbers of solutes were determined. The concentration dependencies of the calculated quantities, their limiting values...
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Solubility of Methane in Water: Some Useful Results for Hydrate Nucleation
PublikacjaIn this paper, the solubility of methane in water along the 400 bar isobar is determined by computer simulations using the TIP4P/Ice force field for water and a simple LJ model for methane. In particular, the solubility of methane in water when in contact with the gas phase and the solubility of methane in water when in contact with the hydrate has been determined. The solubility of methane in a gas–liquid system decreases as temperature...
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Examination of fresh water chemistry in maritime Antarctica during austral summer 2017
PublikacjaDue to the fact that Antarctica is one of the least polluted places on Earth, it is a perfect place to observe the spread of global pollution. Therefore, research conducted on this continent is important due to the possibility of investigating the type of pollution and their way of transport. This work considers presence of organic contaminants in Maritime Antarctica in unexplored until now, Lions Rump headland. Qualitative and...
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Effect of underwater local cavity welding method conditions on diffusible hydrogen content in deposited metal
PublikacjaOne of the methods with great potential for applications in underwater repairs is local cavity welding. In local cavity method, cooling conditions and diffusible hydrogen amount in weld metal are nearly the same as those existed during welding in the air. This paper presents the results of literature survey and preliminary tests of the effect of local cavity welding conditions on diffusible hydrogen amount in a deposited metal....
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Solubility of carbon dioxide in water: Some useful results for hydrate nucleation
PublikacjaIn this paper, the solubility of carbon dioxide (CO2) in water along the isobar of 400 bar is determined by computer simulations using the well-known TIP4P/Ice force field for water and the TraPPE model for CO2. In particular, the solubility of CO2 in water when in contact with the CO2 liquid phase and the solubility of CO2 in water when in contact with the hydrate have been determined. The solubility of CO2 in a liquid–liquid...
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Marine propeller shaft bearings under low-speed conditions: water vs. oil lubrication
PublikacjaThe bearings used in shipbuilding, hydropower, and water pumps have undergone a metamorphosis in recent decades. Because of environmental regulations, lubrication with grease or mineral oil is prohibited. Thus, the standard solutions include water-lubricated bearings with polymer bushings or sealed systems lubricated with oil. When properly designed, assembled, and operated, bearings can operate reliably for years. However, specific...
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Experimental study of pressure rise at the evaporator of capillary pumped loop with acetone and water as working fluids
PublikacjaIn this work studied is the possibility of fluid pumping using capillary forces in the capillary pumped loop. Experimental and theoretical studies have been performed to understand the phenomena associated with heat transfer in porous structure of the evaporator. The capillary effect was studied during operation of two different capillary porous structures with two different working fluids, namely water and acetone. The results...
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SESSILE DROPLET CONTACT ANGLE OF WATER-Al2O3, WATER-TiO2 AND WATER-Cu NANOFLUIDS
PublikacjaThe goal of the present work was the experimental determination of the contact angle of droplets of three nanofluids on various substrates. Of particular interest was effect of nanoparticle concentration on droplet contact angle.
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The effect of lyophilization on selected biologically active components (vitamin c, catalase, lysozyme), total antioxidant capacity and lipid oxidation in human milk
PublikacjaHuman milk is rich in polyunsaturated fatty acids, as well as lysozyme, vitamin C and other bioactive compounds. The effect of lyophilization on the content of antioxidants (vitamin C and catalase CAT), bactericidal compounds (lysozyme), total antioxidant capacity (TAC) and lipid peroxidation in human milk was investigated in this study. Samples of mature human milk were collected from five healthy women who gave birth on the scheduled...
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Water Solubilization Using Nonionic Surfactants from Renewable Sources in Microemulsion Systems
PublikacjaIn this study the effect of temperature, NaCl andoils (hydrocarbons: C8-C16) on the formation and solubilizationcapacity of the systems of oil/monoacylglycerols(MAG):ethoxylated fatty alcohols (CEO20)/propylene glycol(PG)/water was investigated. The effects of the surfactantmixture on the phase behavior and the concentration ofwater or oil in the systems were studied at three temperatures(50, 55, 60 C) and with varied NaCl solutions...
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Assessment of River Water Quality and Pollution Status Using Physicochemical and Biometrics, Awetu River, Ethiopia
PublikacjaThe surface water is contaminated by a variety of synthetic organic and inorganic compounds, chemicals, and nutrients; due to this reason, the quality of the water resources of Ethiopia is declining at an alarming rate, resulting in severe environmental degradation. The main objective of the study was to recognize the pollution status river for the study area by physicochemical parameters and the extent of microbial environmental...
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Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review
PublikacjaAdvanced oxidation processes (AOPs) hold great promise in the removal of organic contaminants. Reactive oxygen species (ROS) produced in AOPs react with target pollutants to initially form several intermediate compounds that finally undergo complete mineralization. Such observations are reported, especially for laboratory-scale experiments performed in pure water. On the other hand, while considering real contaminated wastewater...
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The concept of capillary forces supported evaporator for application to domestic ORC unit
PublikacjaIn the paper presented are studies on the investigation of the capillary forces effect inducted in the porous structure of a loop heat pipe. The potential application of such heat exchanger is for example an evaporator of the domestic micro CHP unit. Preliminary analysis of the results indicates water as having the best potential, however taking into account all issues it can be said that the best effect is obtained using ethanol.
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Numerical modeling of PFAS movement through the vadose zone: Influence of plant water uptake and soil organic carbon distribution
PublikacjaIn this study, we investigated the effects of soil organic carbon (SOC) distribution and water uptake by plant roots on PFAS movement in the vadose zone with a deep groundwater table under temperate, humid climate conditions. Two series of numerical simulations were performed with the HYDRUS computer code, representing the leaching of historical PFOS contamination and the infiltration of water contaminated with PFOA, respectively. We...
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The ab initio and experimental study of the spectroscopic and magnetic properties of Ho(III)-EDTA
Dane BadawczeIn this dataset, the ab initio calculations of the electronic structure and the magnetic properties are discussed in the context of the experimental data for the Ho–EDTA complex. In the calculations different models of the cluster have been applied to examine the influence of various parts of the environment of the Ho(III)-EDTA complex on its properties....
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Performance of the AMOEBA Water Model in the Vicinity of QM Solutes: A Diagnosis Using Energy Decomposition Analysis
PublikacjaThe importance of incorporating solvent polarization effects into the modeling of solvation processes has been well-recognized, and therefore a new generation of hybrid quantum mechanics/molecular mechanics (QM/MM) approaches that accounts for this effect is desirable. We present a fully self-consistent, mutually polarizable QM/MM scheme using the AMOEBA force field, in which the total energy of the system is variationally minimized...
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Determination of selected parameters/ analytes in surface water samples collected in the surroundings of the capital of Spitsbergen (Longyearbyen)
PublikacjaPolar regions are extremely sensitive to pollution such as harmful gases, particles or toxic substances which affect the Arctic climate and ecosystems. Spitsbergen, as well as all Arctic region, because of its geographically distant location and lack of industry sector, should be free of chemical pollution. Despite this, many pollutants could be found in the Polar environment, for example in freshwaters. Their occurrence is related...