Wyniki wyszukiwania dla: ORGANIC SYNTHESIS
-
PARTICLE SIZE ANALYSIS OF SUSPENSIONS IN REMOVING OF ORGANIC MATTER AND PHOSPHORUS FROM WASTEWATER AND SURFACE WATER
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake water and wastewater treated in the Ecological Treatment Systems (ETS) was analyzed. The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal wastewater, while object in Kartuzy has task to remove a phosphorus from...
-
Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublikacjaHydrolysis is an important process in biological wastewater treatment and has been known as the rate limiting step in organic carbon removal from municipal or industrial wastewater. The biodegradation of XS is initiated by hydrolysis which is an integral part of activated sludge models, such as the Activated Sludge Model no. 2d (ASM2d). The aim of this study was to evaluate different concepts of modeling the hydrolysis process...
-
Removal of persistant organic pollutants from landfill leachates treated in three constructed wetland systems
PublikacjaThe objective of the study was assessment of occurrence and removal of two groups of persistent organic pollutants: polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in landfill leachate (LL) treated in three constructed wetland systems (CWs) of different construction and flow regime. Two subsurface flow systems (SSF) were analyzed: one with horizontal flow and the second one consisting of two vertical...
-
Removal of Volatile Organic Compounds (VOCs) from Air: Focus on Biotrickling Filtration and Process Modeling
PublikacjaBiotrickling filtration is a well-established technology for the treatment of air polluted with odorous and volatile organic compounds (VOCs). Besides dozens of successful industrial applications of this technology, there are still gaps in a full understanding and description of the mechanisms of biotrickling filtration. This review focuses on recent research results on biotrickling filtration of air polluted with single and multiple...
-
Generalized Einstein relation in disordered organic semiconductors: Influence of the acoustic phonons–charge carriers scattering
PublikacjaIn this work, we analyze the generalized Einstein relation for disordered organic semiconductors with a non-equilibrium Druyvesteyn-type distribution function. The Druyvesteyn behavior of hot electrons in a solid state is associated with the acoustic phonons–charge carriers scattering. Such a case has been experimentally demonstrated in electroluminescent inorganic rare–earth–doped zinc chalcogenides. Therefore, we can assume that,...
-
Bio-mitigation of organic pollutants using horseradish peroxidase as a promising biocatalytic platform for environmental sustainability
PublikacjaA wide array of environmental pollutants is often generated and released into the ecosystem from industrial and human activities. Antibiotics, phenolic compounds, hydroquinone, industrial dyes, and Endocrine-Disrupting Chemicals (EDCs) are prevalent pollutants in water matrices. To promote environmental sustainability and minimize the impact of these pollutants, it is essential to eliminate such contaminants. Although there are...
-
Acylic congener of cucurbituril: synthesis and recognition properties.
PublikacjaZaprezentowano syntezę analogów acyklicznych cucurbiturilu oraz ich zdolności do kompleksowania wybranych 16 amin, dioli, kwasów dikarboksylowych, pochodnych guanidyny oraz pirydyny. Obserwowane tworzenie kompleksów przebiegało około 180 razy słabiej niż dla cucurbiturilu. Wyniki te świadczą o potencjalnych możliwościach zbliżonych do analogów cyklicznych pod względem tworzenia kompleksów i rozpoznawania wyżej wymienionych...
-
Poly(ferrocenylsilane-block-methacrylates) via sequential anionic and atom transfer radical polymerization.
PublikacjaArtykuł przedstawia sposób otrzymywania kopolimerów blokowych poli(ferrocenylosilanów) (PFS) i poli(metakrylanu metylu) (PMMA). W pierwszej kolejności syntezowany jest anionowo blok PFS, który po odpowiedniej terminacji służy jako makroinicjator dla syntezy bloku PMMA. Synteza ta jest realizowana przy użyciu polimeryzacji rodnikowej z przeniesieniem atomu (ATRP), katalizowanej przez kompleksy rutenu. Otrzymane w ten sposób kopolimery...
-
Morphology, Thermo-Mechanical Properties and Biodegradibility of PCL/PLA Blends Reactively Compatibilized by Different Organic Peroxides
PublikacjaReactive blending is a promising approach for the sustainable development of bio-based polymer blends and composites, which currently is gaining more and more attention. In this paper, biodegradable blends based on poly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) were prepared via reactive blending performed in an internal mixer. The PCL and PLA content varied in a ratio of 70/30 and 55/45. Reactive modification of PCL/PLA...
-
Kinetics of the Organic Compounds and Ammonium Nitrogen Electrochemical Oxidation in Landfill Leachates at Boron-Doped Diamond Anodes
PublikacjaElectrochemical oxidation (EO) of organic compounds and ammonium in the complex matrix of landfill leachates (LLs) was investigated using three different boron-doped diamond electrodes produced on silicon substrate (BDD/Si)(levels of boron doping [B]/[C] = 500, 10,000, and 15,000 ppm—0.5 k; 10 k, and 15 k, respectively) during 8-h tests. The LLs were collected from an old landfill in the Pomerania region (Northern Poland) and were...
-
Dielectric Barrier Discharge Systems with HV Generators and Discharge Chambers for Surface Treatment and Decontamination of Organic Products
PublikacjaThe article presents applications of systems with power electronic converters, high voltage transformers, and discharge chambers used for nonthermal, dielectric barrier discharge plasma treatment of a plastic surface and decontamination of organic loose products. In these installations, the inductance of the high voltage transformers and the capacitances of the electrode sets form resonant circuits that are excited by inverters....
-
Visible-light-driven lanthanide-organic-frameworks modified TiO2 photocatalysts utilizing up-conversion effect
PublikacjaHighly efficient and quite stable composite with core-shell-like architecture reported herein, responds to the challenge of sunlight-driven photocatalysts. The Ln(ndc)/TiO2 photocatalytic system comprises active lanthanide-carboxylate coordination networks (Nd, Er, Ho, and Tm as metal ions, and 2,6-naphthalene dicar-boxylic acid as the organic linker) and inert titanium dioxide and allow to convert incompatible visible radiation...
-
The Quantum Efficiency Roll-Off Effect in Near-Infrared Organic Electroluminescent Devices with Iridium Complexes Emitters
PublikacjaThe electroluminescence quantum efficiency roll-off in iridium(III)-based complexes, namely Ir(iqbt)2(dpm) and Ir(iqbt)3(iqbt=1 (benzo[b]thiophen-2-yl)-isoquinolinate, dpm=2,2,6,6-tetramethyl-3,5-heptanedionate) utilized as near-infrared emitters in organic light emitting diodes with remarkable external quantum efficiencies, up to circa 3%, 1.5% and 1%, are measured and analyzed. With a 5–6 weight % of emitters embedded...
-
Integrated Photocatalytic Advanced Oxidation System (TiO2/UV/O3/H2O2) for Degradation of Volatile Organic Compounds
PublikacjaSeveral advanced oxidation processes (AOPs) including photocatalytic processes were studied for effective treatment of complex model wastewater containing a wide variety of VOCs. The studies revealed synergistic effects of TiO2 based processes for improved degradation of the VOCs. A peroxone combined with TiO2/UV system (TiO2/UV/O3/H2O2) with a ratio between the oxygen source from the oxidant to chemical oxygen demand (COD) of...
-
Photovoltaic effect in the single-junction DBP/PTCBI organic system under low intensity of monochromatic light
PublikacjaPhotoelectric properties of the planar ITO/MoO3/DBP/PTCBI/BCP/Ag system were characterized on the basis of short-circuit current, open-circuit voltage and absorption spectra, and current-voltage measurements in the dark and under monochromatic illumination of low intensity. Photovoltaic performance of the system was compared with the performance of ideal semiconductor and excitonic cells of chosen bandgaps. Such analysis shows,...
-
Persistent organic pollutants (POPs) as an indicator of surface water quality in the vicinity of the Polish Polar Station, Horsund
PublikacjaSurface waters were collected in the vicinity of the Polish Polar Station in Hornsund (Svalbard) to determine their concentration of various persistent organic pollutants (POPs), such as polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). In addition, parameters such as pH, SEC and TOC were measured. In total, 15 samples of lake water from and 15 samples of stream water were analysed. The sampling took...
-
Investigating the potential influence of biochar and traditional organic amendments on the bioavailability and transfer of Cd in the soil–plant system
Publikacja -
Formation of nitrogen functionalities in biochar materials and their role in the mitigation of hazardous emerging organic pollutants from wastewater
Publikacja -
Comparison of Chemical Composition and Colour Parameters of Different Mentha Genus Plants Grown under Organic Conditions
Publikacja -
Electrochemical sensor for measurement of volatile organic compounds = Elektrochemiczny czujnik do oznaczania lotnych związków organicznych
PublikacjaPrzedstawiono rezultaty badań prototypowego czujnika do oznaczania benzaldehydu i formaldehydu w powietrzu. Określono czułość wskazań czujnika i jego granice oznaczalności wykorzystując jako technikę detekcyjną woltamperometrię fali prostokątnej (SWV). Elektrodę roboczą i przeciwelektrodę stanowiły elektrody z Pt. Elektrolitem wewnętrznym były ciecze jonowe: chlorek 1-heksylo,3- metyloimidazolinowy i bis(trifluorometylosulfonylo)imidek...
-
On small signal capacitance spectra of organic diode formed by ITO-palladium phthalocyanine-Al sandwich system
PublikacjaPraca poświęcona jest widmom małosygnalowej pojemności w zakresie 25 Hz-1 MHz i charakterystyce prądowo-napięciowej planarnego układu utworzonego przez ITO/ftalocyanina palladu/Al.
-
Analysis of the image force effects on the recombination at the donor-acceptor interface in organic bulk heterojunction solar cells
PublikacjaWe consider the influence of image force effects on the recombination at the donor-acceptor interface in organic bulk heterojunction solar cells. The conclusion is that the charge carriers of one sign located in the material with lower permittivity recombine at the boundary between donor and acceptor phases. This process competes with the recombination of opposite sign charge carriers, leading to the reduction of the Langevin-type...
-
Design analysis of turbines for co-generating micro-power plant working in accordance with organic Rankine's cycle
PublikacjaPrzedstawiono wyniki analizy projektowej turbin dla mikrosiłowni kogeneracyjnej pracującej według organicznego obiegu Rankine'a z wykorzystaniem biopaliwa. Rozważono zakres mocy cieplnej od 25kW do 100kW, któremu odpowiadała możliwa do uzyskania moc elektryczna od 2kW do 12kW. Przeanalizowano projekty turbin osiowych (jedno- i wielostopniowych, także z częściowym zasilaniem), turbin promieniowych i promieniowo-osiowych. Porównano...
-
Particle size analysis of suspensions in removing of organic matter and phosphorus from waste water and surface water
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake- and waste- water treated in the Ecological Treatment Systems (ETS) was analyzed.The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal waste water, while object in Kartuzy has task to remove a phosphorus from...
-
The application of isotopically labeled analogues for the determination of small organic compounds by GC/MS with selected ion monitoring
Publikacja -
Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor
Publikacja -
The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublikacjaWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
-
Second harmonic generation on crystalline organic nanoclusters under extreme nanoconfinement in functionalized silica–benzil composites
Publikacja -
Electric-field-induced quenching of photoluminescence in photoconductive organic thin film structures based on Eu3+ complexes
PublikacjaW pracy badano elektrycznopolowe wygaszenie fotoluminescencji w organicznych kompleksach europu Eu(III) rozdyspergowanych w matrycy poliwęglan: dwuamina TPD. W układzie z elektrodami Al/Al obserwowano wygaszenie fotoluminescencji wywołane dysocjacją ekscytonów. W układzie z elektrodami ITO(+)/Au(-) oprócz dysocjacji ekscytonów obserwowano również silne wygaszenie ekscytonów na ładunku elektrycznym wstrzykniętym do próbki. Analiza...
-
Effect of buffer layers on performance of organic photovoltaic devices based on copper phthalocyanine-perylene dye heterojunction
PublikacjaPraca przedstawia wyniki badań układu fotowoltaicznego złożonego z cienkich warstw organicznych tworzących złącze (CuPc i MePTCDI), elektrod (ITO i Ag) oraz z warstw buforowych (MoO3 przy ITO i BCP przy Ag).
-
On the tendency of temperature and electric field dependences of interface recombination in P3HT:PCBM organic bulk heterojunction solar cells
PublikacjaWe demonstrate theoretical explanation of the temperature and electric field dependences of recombination coefficients in an organic P3HT:PCBM bulk heterojunction solar cell. Based onthe model of interface recombination, two analytical formulas describing the relative ratio of the interface (γI ) to the Langevin (γL) recombination coefficients have been derived. Our analysis indicates that the sign of parameters φT and φF determines...
-
Correction: Highly stable organic–inorganic junction composed of hydrogenated titania nanotubes infiltrated by a conducting polymer
Publikacja -
Retention time and peak width in the combined pH/organic modifier gradient high performance liquid chromatography
Publikacja -
Soil organic carbon, macro- and micronutrient changes in soil fractions with different lability in response to crop intensification
Publikacja -
Mixing of excimer and exciplex emission: A new way to improve white light emitting organic electrophosphorescent diodes
PublikacjaW pracy opisano konstrukcję wydajnych diod elektrofosforescencyjnych emitujących światło białe. Emisja diod pochodzi od trypletowych monomerów PtL2Cl, trypletowych ekscymerów (PtL2Cl:PtL2Cl) i trypletowych ekscypleksów m-MTDATA (donor elektronu):PtL2Cl (akceptor elektronu), gdzie PtL2Cl oznacza organiczny kompleks platyny (II), a m-MTDATA - dendrymer aminowy. Kwantowa wydajność EL diody wynosi 6.5% fot./e. Współrzędne charakteryzujące...
-
Evaluation of the simultaneous removal of organic matter, nitrogen and suspended solids in a sshf constructed wetland in capinha, Portugal
PublikacjaCelem pracy była ocena systemu hydrofitowego z podpowierzchniowym przepływem wody (SSHF) usytuowanego w miejscwości Capinha w Portugalii, głównie pod względem usuwania substancji organicznej oraz związków azotu. Podczas czteromiesięcznego monitoringu obiekt wykazał niereguralność w suswaniu zawiesiny ogólnej oraz substancjo organicznej wyrażonej w ChZT. Szybkość usuwania zanieczyszczeń organicznych wynosiła 28 g ChZT/m2d. Uzyskaną...
-
Identification of organic acids as potential biomarkers in the urine of autistic children using gas chromatography/mass spectrometry
Publikacja -
Citropin 1.1 Trifluoroacetate to Chloride Counter-Ion Exchange in HCl-Saturated Organic Solutions: An Alternative Approach
Publikacja -
Binding of anionic Pt(ii) complexes in a dedicated organic matrix: towards new binary crystalline composites
Publikacja -
Synergistic Catalysis of Co(OH)2/CuO for the Degradation of Organic Pollutant Under Visible Light Irradiation
Publikacja -
Dynamics of changes in the concentration levels of organic pollutants in the proglacial waters of the Scott River (Spitsbergen, SW Svalbard)
PublikacjaThe study area covered the NW part of the Wedel Jarlsberg Land. The present study concerns participation of organic pollutants inflow from glacier and seaside plane of Calypsostranda to proglacial waters of the Scott River due to occurrence of precipitation. Concentration ranges for phenols and formaldehyde in water samples are respectively:
-
Electromodulation of fluorescence in hole-transporting materials for organic light-emitting diodes. Part II: Straburst amines
PublikacjaPraca jest kontynuacją artykułu, który został opublikowany wChem. Phys. vol. 256 (2000) s. 351-362. Zaobserwowano silne wygaszenie fluorescencji w dendrymerach aminowych zbudowanych na bazie trifenyloaminy. Efekt ten został przypisany rozpadowi stanów emitujących światło pod działaniem silnego pola elektrycznego.
-
Mono- and bi-metallic plasmonic photocatalysts for degradation of organic compounds under UV and visible light irradiation
PublikacjaTitania powders were surface modified with gold and/or silver nanoparticles (NPs) by photodeposition method. Gold modified titania exhibited much higher photocatalytic activity during methanol dehydrogenation under UV irradiation than titania modified with monometallic silver and bimetallic Au–Ag NPs. Bimetallic photocatalysts exhibited either enhanced or reduced visible light activity, depending on properties of noble metal NPs,...
-
Analysis of Organic Rankine Cycle efficiency and vapor generator heat transfer surface in function of the reduced pressure
PublikacjaIn the paper presented is analysis of the influence of reduced pressure on efficiency and heat transfer area of vapor generator of Organic Rankine Cycle (ORC) in case of subcritical and supercritical parameters of operation. Compared are two cases of subcritical and supercritical ORC featuring a similar arrangement of heat source supply and heat removal, that is featuring the same temperatures of working fluid before the turbine,...
-
The role of slowly biodegradable organic compounds in a full-scale biological nutrient removal activated sludge systems
PublikacjaThe aim of this study was to determine the immediate effects of slowly biodegradable substrates on the denitrification capability and phosphate release/uptake interactions for a full-scale biomass process from two large wastewater treatment plants (WWTPs) located in the cities of Gdansk and Gdynia (northern Poland). Since it is hard to distinguish the slowly biodegradable substrate in a direct way, a novel procedure based on batch...
-
Currently Commercially Available Chemical Sensors Employed for Detection of Volatile Organic Compounds in Outdoor and Indoor Air
PublikacjaThe paper presents principle of operation and design of the most popular chemical sensors for measurement of volatile organic compounds (VOCs) in outdoor and indoor air. It describes the sensors for evaluation of explosion risk including pellistors and IR-absorption sensors as well as the sensors for detection of toxic compounds such as electrochemical (amperometric), photoionization and semiconductor with solid electrolyte ones....
-
Assessment of ecotoxicity and total volatile organic compound (TVOC) emissions from food and children's toy products
PublikacjaThe development of new methods for identifying a broad spectrum of analytes, as well as highly selective tools to provide the most accurate information regarding the processes and relationships in the world, has been an area of interest for researchers for many years. The information obtained with these tools provides valuable data to complement existing knowledge but, above all, to identify and determine previously unknown hazards. Recently,...
-
An Assessment of RASSCF and TDDFT Energies and Gradients on an Organic Donor−Acceptor Dye Assisted by Resonance Raman Spectroscopy
PublikacjaThe excitation energies and gradients in the ground and the first excited state of a novel donor−(π- bridge)−acceptor 4-methoxy-1,3-thiazole-based chromophore were investigated by means of MS-RASPT2/RASSCF and TDDFT in solution. Within both methods, the excitation energies strongly depend on the employed equilibrium structures, whose differences can be rationalized in terms of bond length alternation indexes. It is shown that functionals with...
-
Lanthanide-organic-frameworks modified ZnIn2S4 for boosting hydrogen generation under UV–Vis and visible light
PublikacjaNovel Ln-MOF with microrods shape were successfully combined with ZnIn2S4 (ZIS) microsphere and used for photocatalytic hydrogen generation under UV–Vis and visible light. The Ln-MOFs/ZIS system comprises lanthanide-carboxylate coordination networks (Tm and Gd as metal ions, and 1,3,5-benzenetricarboxylic acid (BTC) as the organic linker) deposited on ZnIn2S4 microspheres. Effect of the amount of ((Tm,Gd)-BTC) (1, 5, 10 wt%) on...
-
Singlet oxygen-dominated peroxymonosulfate activation by layered crednerite for organic pollutants degradation in high salinity wastewater
PublikacjaAdvanced oxidation processes have been widely studied for organic pollutants treatment in water, but the degradation performance of radical-dominated pathway was severely inhibited by the side reactions between the anions and radicals, especially in high salinity conditions. Here, a singlet oxygen (1O2)-dominated non-radical process was developed for organic pollutants degradation in high salinity wastewater, with layered crednerite...
-
Advanced nanomaterials and metal-organic frameworks for catalytic bio-diesel production from microalgal lipids – A review
PublikacjaIncreasing energy demands require exploring renewable, eco-friendly (green), and cost-effective energy resources. Among various sources of biodiesel, microalgal lipids are an excellent resource, owing to their high abundance in microalgal biomass. Transesterification catalyzed by advanced materials, especially nanomaterials and metal-organic frameworks (MOFs), is a revolutionary process for overcoming the energy crisis. This review...
-
Evaluation of bacterial strains for developing effective plant growth promoting strain on chickpea growth and physico chemical properties of soil
PublikacjaThe study was intended to isolate and characterize the plant growth-promoting properties. A collection of microbial consortia called plant growth-promoting microorganisms (PGPM) work to increase crop growth and yield through a variety of direct mechanisms, including as nitrogen fixation, phosphate solubilization, synthesis of PGH, ammonia, and siderophore, as well as indirect mechanisms. The aim of the study was to evaluate the...
-
Progress in development of molecularly imprinted polymers as sorbents for sample preparation
PublikacjaSample preparation has been one of the most often investigated steps in analytical procedures.These investigations are focused on problems such as isolation of analytes from the sample matrix, matrix implification, analyte enrichment to the level above the detection limit of the instrumentation used, and the removal of interfering species to improve the final determination. Techniques based on solid (adsorption) and pseudo liquid...
-
Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review
PublikacjaGreen Chemistry plays a more and more important role in implementing rules of sustainable development to prevent environmental pollution caused by technological processes, while simultaneously increasing the production yield. Ionic liquids (ILs) and deep eutectic solvents (DESs) constitute a very broad group of substances. Apart from many imperfections, ILs and DESs have been the most promising discoveries in the world of Green...
-
Comparison of the Efficiency of Hetero- and Homogeneous Catalysts in Cellulose Liquefaction
PublikacjaBiomass liquefaction is a well-known and extensively described process. Hydrothermal processes are well understood and can be used in the fuel industry. The use of organic solvents can result in full-fledged products for use in the synthesis of polyurethanes. The plastics industry, including polyurethanes, is targeting new, more environmentally friendly solutions. One of these is the replacement of petrochemical polyols with compounds...
-
Novel Biomass-Based Polymers: Synthesis, Characterization, and Application
PublikacjaA wide range of polymers were prepared from biomass-derivatives, using different polymerization mechanisms. Well-defined, fully hydroxy-functional polyesters based on aliphatic diols were synthesized, using either conventional metal-based catalysts or the organic superbase 1,5,7-triazabicyclododecene (TBD). Unsaturated polyesters were also made, offering additional functionality to these biobased resins. Metal-catalyzed or enzymatic...
-
Insights into modification of lignocellulosic fillers with isophorone diisocyanate: structure, thermal stability and volatile organic compounds emission assessment
PublikacjaThis study presents an analysis of the structure and properties of different types of lignocellulosic fillers modified by isophorone diisocyanate (IPDI) to provide insights into the possibility of their application to the manufacturing of wood polymer composites (WPCs). Moreover, it deals with the environmental aspects of modified fillers, by assessment of volatile organic compounds (VOCs) emitted during modification, as well as...
-
Different design aspects of an Organic Rankine Cycle turbine for electricity production using a geothermal binary power plant
PublikacjaIn recent years, pressure has been growing to increase the share of renewable energy sources in electricity generation, which may offer opportunities for the development of geothermal energy in regions that have been so far considered unprofitable in this respect. One such country currently undergoing an energy transition is Poland in which low-temperature geothermal resources are currently used for district heating and recreation...
-
Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
PublikacjaThis paper investigated the impact of type and content of diisocyanate on the structure of modified cellulose fillers. Four the most popular isocyanates were applied – isophorone, hexamethylene, toluene and methylene diphenyl diisocyanate – at loadings of 1–15 wt%. Chemical structure, and its short-term storage stability, were investigated for eight weeks. Moreover, the main volatile organic compounds detected during modification,...
-
Predicting Value of Binding Constants of Organic Ligands to Beta-Cyclodextrin: Application of MARSplines and Descriptors Encoded in SMILES String
PublikacjaThe quantitative structure–activity relationship (QSPR) model was formulated to quantify values of the binding constant (lnK) of a series of ligands to beta–cyclodextrin (β-CD). For this purpose, the multivariate adaptive regression splines (MARSplines) methodology was adopted with molecular descriptors derived from the simplified molecular input line entry specification (SMILES) strings. This approach allows discovery of regression...
-
A field study investigating the potential use of phosphorus combined with organic amendments on cadmium accumulation by wheat and subsequent rice
Publikacja -
Porewater dissolved organic and inorganic carbon in relation to methane occurrence in sediments of the Gdańsk Basin (southern Baltic Sea)
Publikacja -
TiO2 Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics
Publikacja -
Decolorization of organic dyes solution by atmospheric pressure glow discharge system working in a liquid flow-through mode
Publikacja -
Large-scale converting waste coffee grounds into functional carbon materials as high-efficient adsorbent for organic dyes
Publikacja -
Response to abiotic and organic substances stimulation belongs to ontologic groups significantly up-regulated in porcine immature oocytes
Publikacja -
Modelowanie procesów migracji zanieczyszczeń organicznych w środowisku wodnym = Modelling of migration of organic xenobiotics in aquatic environment
PublikacjaPrzedstawiono zagadnienia związane z modelowaniem migracji związków chemicznych w środowisku. Zamieszczono także sposób konstruowania modeli i przegląd najważniejszych typów modeli migracji wraz z przykładami oraz wyniki, jakie można uzyskać za pomocą poszczególnych grup modeli. W pracy zawarto również podział modeli migracji ze względu na sposób przedstawienia transportu zanieczyszczeń, poziom kompilacji i zakres obszaru modelowania....
-
Small signal spectra of complex capacitance obtained on organic heterojunction formed from copper phthalocyanine and perylene dye
PublikacjaPraca przedstawia małosygnałowe widma zespolonej pojemności otrzymane na strukturze z heterozłączem organicznym CuPc/Py-PTC w zakresie 25Hz-1MHz.
-
Determination of fluoride as fluorosilane derivative using reversed-phase HPLC with UV detection for determination of total organic fluorine
Publikacja -
Removal of organic compounds from natural underground water in sorption and sono-sorption processes on selected activated carbons
Publikacja -
Perspectives on the replacement of harmful organic solvents in analytical methodologies: a framework toward the implementation of a generation of eco-friendly alternatives
PublikacjaVolatile organic solvents derived from non-renewable fossil feedstocks are commonplace in analytical laboratories. In spite of their convenient performance in countless unit operations, their environmental, health and safety issues represent a major area of concern. The progressive replacement of organic solvents obtained from fossil resources by eco-friendly alternatives would involve remarkable advances within the framework of...
-
The estimation of total volatile organic compounds emissions generated from peroxide cured natural rubber/polycaprolactone blends
PublikacjaNatural rubber (NR)/polycaprolactone (PCL) blends at the ratio of 90/10% wt. (NR/PCL90/10) and 70/30% wt. (NR/PCL70/30), with a constant amount of dicumyl peroxide, were prepared by compounding in an internal mixer. Obtained NR/PCL bio-based blends were cured at three different temperatures (150 °C, 160 °C and 170 °C). The total content of volatile organic compounds (TVOC) as a function of the NR/PCL blends ratio, and their curing...
-
Dissolved and colloidal organic nitrogen removal from WWTP effluents and reject waters using physical-chemical processes
PublikacjaFour physical-chemical processes were compared in terms of the efficiencies of dissolved and colloidal organic nitrogen (DON and CON) removal from the secondary effluents (SE) and reject water from full-scale biological nutrient removal activated sludge systems. Adsorption on activated carbon was most efficient and allowed to remove from the SE up to 80% and 100% of DON and CON, respectively. High efficiencies of DON removal from...
-
Fluctuation in the organic matter decomposition rate and nitrogen speciation in vegetation and outside vegetation seasons in a hybrid wetland system.
PublikacjaIlość ścieków doprowadzana do obiektu była mniejsza, a stężenia zanieczyszczeń wyższe w okresie poza wegetacyjnym. Obniżona skuteczność przemian związków azotu w okresie poza wegetacyjnym została potwierdzona przez niższe wartości stałych szybkości reakcji, które wynosiły 60% wartości osiąganych dla okresu wegetacyjnego.
-
Automated high-capacity sorption probe for extraction of organic compounds in aqueous samples followed by gas chromatographic analysis.
PublikacjaOpracowano zautomatyzowany zestaw wyposażony w próbnik o dużej pojemności sorpcyjnej do oznaczania związków śladowych z zastosowaniem chromatografii gazowej. Zestaw łączy prostotę SPME z wysoką wydajnością techniki ekstrakcji z zastosowaniem ruchomego elementu sorpcyjnego (SBSE). Procedura pobierania próbek była przeprowadzana z zastosowaniem podajnika automatycznego. Ze względu na pełną automatyzację zestawu, możliwa jest bezobsługowa...
-
Separation of Volatile Oxygen-containing Organic Compounds by Gas Chromatography - selectivity comparison of different polarity stationary phases
PublikacjaThis paper present a results of the separation of 36 reference compounds belonging to the group of Volatile Oxygen-Containing Organic Compounds (OVOCs) using capillary gas chromatography with flame ionization detector (GC-FID) and three stationary phases of different polarity. A selectivity has been studied regarding to OVOCs and n -alkanes. The most useful for the separation of the group OVOCs is a polar ionic liquid stationary...
-
A comparative study of organic pollutants in seawater, sediments and oyster tissues at Hab River Delta, Balochistan coast, Pakistan
PublikacjaThis chapter is about a Comparative Study of Organic Pollutants in Seawater, Sediments, and Oyster Tissues at Hab River Delta, Balochistan Coast, Pakistan.
-
Multivariate Statistical Analysis for Mutual Dependence Assessment of Selected Polyphenols, Organic Acids and Metals in Cool-Climate Wines
PublikacjaPolyphenols, organic acids and metal ions are an important group of compounds that affect the human health and quality of food and beverage products, including wines. It is known that a specific correlation between these groups exist. While wines coming from the New World and the Old World countries are extensively studied, wines coming from cool-climate countries are rarely discussed in the literature. One of the goals of this...
-
Evaluation of polycaprolactone as a new sorbent coating for determination of polar organic compounds in water samples using membrane–SPME
PublikacjaCommercially available solid-phase microextraction fibers used for isolation of polar analytes are based on the adsorption phenomenon. In consequence, typical limitations bonded with analytes displacement and matrix effects are very frequent. In the present study, alternative solution is described. Polycaprolactone (PCL) was used for the first time as sorbent to isolate polar organic compounds from water samples using the membrane–solid-phase...
-
Usefulness of separation techniques for identification and determination of Oxygenated Volatile Organic Compounds used in process analytics of water and wastewater
PublikacjaW pracy przedstawiono przegląd i porównanie metodyk identyfikacji i oznaczania Lotnych Związków Tlenoorganicznych (LZT). Porównano metodyki klasyczne umożliwiające oznaczanie wybranej grupy związków chemicznych należących do LZT lub dokonywanie oznaczeń sumarycznej zawartości z metodykiami wykorzystującymi techniki rozdzielania. Lotne związki tlenoorganicze, do których zaliczane są aldehydy, alkohole, ketony, estry, etery oraz...
-
Ionic Liquid Assisted Dissolution of Dissolved Organic Matter and PAHs from Soil Below the Critical Micelle Concentration
PublikacjaIncreased use and production of ionic liquids (ILs) may result in emissions into the environment. Particularly vulnerable are industrial areas and landfills where ILs are utilized and ultimately disposed of. This study investigates how IL contamination can affect soil properties and the sorption of pre-existing contaminants. The commonly used IL 1-methyl-3-octyl imidazolium chloride ([OMIM][Cl]) was added at various quantities...
-
Highly effective degradation of selected groups of organic compounds by cavitation based AOPs under basic pH conditions
PublikacjaCavitation has become on the most often applied methods in a number of industrial technologies. In the case of oxidation of organic pollutants occurring in the aqueous medium, cavitation forms the basis of numerous advanced oxidation processes (AOPs). This paper presents the results of investigations on the efficiency of oxidation of the following groups of organic compounds: organosulfur, nitro derivatives of benzene, BTEX, and...
-
Zr‐Based Metal‐Organic Framework UiO‐66/Ultem® 1000 Membranes for Effective CO2/H2 Separation
PublikacjaMixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting...
-
Singlet oxygen in the removal of organic pollutants: An updated review on the degradation pathways based on mass spectrometry and DFT calculations
PublikacjaThe degradation of pollutants by a non-radical pathway involving singlet oxygen (1O2) is highly relevant in advanced oxidation processes. Photosensitizers, modified photocatalysts, and activated persulfates can generate highly selective 1O2 in the medium. The selective reaction of 1O2 with organic pollutants results in the evolution of different intermediate products. While these products can be identified using mass spectrometry...
-
Kinga Kaniewska-Laskowska dr inż.
OsobyWykształcenie Studia I stopnia - inżynierskie, kierunek CHEMIA 2013: Politechnika Gdańska, Wydział Chemiczny, Katedra Chemii Nieorganicznej Tytuł pracy inżynierskiej: „Kompleksy żelaza z ligandami fosfinidenowymi” Promotor: dr hab. inż. Rafał Grubba Studia II stopnia - magisterskie, kierunek TECHNOLOGIA CHEMICZNA, spec. Technologia Organiczna 2014: Politechnika Gdańska, Wydział Chemiczny, Katedra Chemii Nieorganicznej Tytuł pracy...
-
Mesophilic and thermophilic dark fermentation course analysis using sensor matrices and chromatographic techniques
PublikacjaProduction of biofuels from biomass is expected to benefit the society and the environment. At present, bio waste residues processing includes hydrolysis, dark fermentation, photofermentation, pyrolysis, gasification, and chemical synthesis. As the composition and the chemical structure of organic substances affect the efficiency of mentioned processes, it is believed that the glucose concentration is a crucial parameter for the...
-
Pincer Complexes Based on Phosphinoaminopyridines: Synthesis, Structural Characterization and Catalytic Applications
Publikacja -
Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups
PublikacjaRe(L1)–Re(L3), a series of rhenium(I) tricarbonyl chloride complexes with bpy-R2 derivatives L1–L3 (bpy = 2,2′-bipyridine, R represents the substitution at the 4- and 4′-positions), and their corresponding trishomoleptic Ru(L1)3–Ru(L3)3 as well as heteroleptic ruthenium(II) complexes Ru(tbbpy)2(L1) and Ru(tbbpy)2(L2) have been synthesized and characterized. Their applicability as immobilizable metal–organic chromophores in solar...
-
Synthesis and Characterization of Poly(zwitterionic) Structures for Energy Conversion and Storage
PublikacjaZwitterions are unique class of molecules that possess two functional groups bearing electric charges, one positive and second negative. This setup results in peculiar properties such as high water retention and anti-fouling capability. Therefore, zwitterionic coatings and gels are commonly applied in e.g. biosensing and bioelectronic devices. Despite those applications, there are other perspectives for zwitterionic materials....
-
A correlation between electron-hole pair radii and magnetomodulation of exciplex fluorescence in electron donor-electron acceptor organic systems
PublikacjaElectric field dependencies of electromodulated photoluminescence and magnitudes of the magnetic-field effect on photoluminescence havebeen measured in vacuum-evaporated films of m-MTDATA [4,4',4"-tris(N-(3-methylphenyl)-N-phenylamino)triphenylamine]:bathophe-nanthroline, m-MTDATA:BCP (bathocuproine), as well as 4,4',4"-tris[2-naphthyl(phenyl)amino]triphenylamine:BCP. The Sano-Tachiya-Noolandi-Hong extension of standard Onsager...
-
Organic Acids and Polyphenols Determination in Polish Wines by Ultrasound-Assisted Solvent Extraction of Porous Membrane-Packed Liquid Samples
PublikacjaIn the near future, Poland is going to have more and more favorable conditions for viticulture. Organic acids and polyphenols are among the most commonly analyzed compounds due to their beneficial properties for human health and their importance in the winemaking process. In this work, a new technique involving ultrasound-assisted solvent extraction of porous membrane-packed liquid samples (UASE-PMLS) was for the first time described...
-
Hydrodynamic cavitation based advanced oxidation processes: Studies on specific effects of inorganic acids on the degradation effectiveness of organic pollutants
PublikacjaThe use of cavitation in advanced oxidation processes (AOPs) to treat acidic effluents and process water has become a promising trend in the area of environmental protection. The pH value of effluents – often acidified using an inorganic acid, is one of the key parameters of optimization process. However, in the majority of cases the effect of kind of inorganic acid on the effectiveness of degradation is not studied. The present...
-
The effect of land use in the catchment and meteorological conditions on the riverine transport of dissolved organic carbon into the Puck Lagoon (southern Baltic)
Publikacja -
Self-Sensitized Photocatalytic Degradation of Colorless Organic Pollutants Attached to Rutile Nanorods—Experimental and Theoretical DFT+D Studies
Publikacja -
Predicting enthalpy of vaporization for Persistent Organic Pollutants with Quantitative Structure–Property Relationship (QSPR) incorporating the influence of temperature on volatility
Publikacja -
Nutritional Value of Jerusalem Artichoke Tubers (Helianthus tuberosus L.) Grown in Organic System under Lithuanian and Polish Conditions
Publikacja -
Studies of the Variability of Sugars, Vitamin C, and Chlorophylls in Differently Fermented Organic Leaves of Willowherb (Chamerion angustifolium (L.) Holub)
Publikacja -
Ratio of selenium concentrations between soil, forage plants and blood serum of beef cattle studied in organic and conventional farms
Publikacja -
Membrane-SPME the best 'green' sample preparation technique for the gas chromatographic determination polar organic pollutants in polar media
PublikacjaOne of the most popular technique for sample preparation, which fulfill requirements of green analytical chemistry, is solid phase microextraction (SPME). Because of the undoubted advantages of SPME technique, solvent-free character of the extraction process and the enormous potential in analytical practice, a series of studies has been undertaken to develop new technical solutions, where improving the sensitivity and the extraction...
-
Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
Publikacja