Filtry
wszystkich: 1340
wybranych: 1011
-
Katalog
Filtry wybranego katalogu
wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: ELECTROCHEMICAL CAPACITORS
-
Polymer derived SiOC/Sn nanocomposites from a low-cost single source precursor as anode materials for lithium storage applications
PublikacjaMetal- based materials capable of lithium (Li) alloy formation are key to realization of the next generation of high-energy density anodes for Li-ion batteries, owing to their high storage capacity. Designing a good sup- porting matrix is essential for homogeneously nesting these metallic nanodomains, to effectively utilize their high capacity while tackling the volume expansion issues. Silicon oxycarbides (SiOC), obtained via...
-
Single-phase, Five-level Inverter with SPWM-Based Neutral Point Voltage Balancing Scheme
PublikacjaMultilevel inverter topologies provide several advantages over two-level inverter configuration. These benefits are the reason for the growing interest in multilevel topologies among research society. One of the most popular topological concepts (diode and active switch clamping) requires neutral-point potential balancing due to series-connected capacitor banks across the input dc link in such derived inverter configurations. This...
-
Bioactive compounds and the antioxidant capacity in new kiwi fruit cultivars
PublikacjaThe aim of this investigation was to find the best among seven different kiwi fruit cultivars (‘Hayward’, ‘Daheung’, ‘Haenam’, ‘Bidan’, ‘Hort16A’, ‘Hwamei’ and ‘SKK12’) for human consumption and to classify them as groups. Therefore, the contents of bioactive compounds and the level of antioxidant capacities of these cultivars were determined in four different extracts and compared. It was found that the contents of the bioactive...
-
Effect of TiO2 Concentration on Microstructure and Properties of Composite Cu–Sn–TiO2 Coatings Obtained by Electrodeposition
PublikacjaIn this work, Cu–Sn–TiO2 composite coatings were electrochemically obtained from a sulfate bath containing 0–10 g/L of TiO2 nanoparticles. The effect of TiO2 particles on kinetics of cathodic electrodeposition has been studied by linear sweep voltammetry and chronopotentiometry. As compared to the Cu–Sn alloy, the Cu–Sn–TiO2 composite coatings show rougher surfaces with TiO2 agglomerates embedded in the metal matrix. The highest...
-
Application of quartz crystal microbalance and dynamic impedance spectroscopy to the study of copper corrosion inhibitors
PublikacjaThe study investigates the application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) and Electrochemical Quartz Crystal Microbalance (EQCM) techniques to examine the corrosion inhibition of copper by Benzotriazole and Sodium Folate in a 0.1 M NaCl solution. DEIS, an advanced version of Electrochemical Impedance Spectroscopy (EIS), allows for real-time monitoring of non-stationary electrochemical systems,...
-
Design of a SiC based triple active bridge ceil for a multi-megawatt DC-DC converter
PublikacjaThe paper describes the design methodology of a novel Triple Active Bridge cell used as the building block for modular DC-DC converters. The intended application is for Medium Voltage Direct Current grids, such as the DC collector for offshore wind farms. The latest generation of SiC MOSFET semiconductors is utilized to operate in the medium frequency range while optimizing the efficiency. The dimensioning of the main cell components,...
-
Phospholipid-functionalized gold electrode for cellular membrane interface studies - interactions between DMPC bilayer and human cystatin C
PublikacjaThis work describes the electrochemical studies on the interactions between V57G mutant of human cystatin C (hCC V57G) and membrane bilayer immobilized on the surface of a gold electrode. The electrode was modified with 6-mercaptohexan-1-ol (MCH) and 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC). DMPC was used as a membrane mimetic for monitoring electrochemical changes resulting from the interactions between the functionalized...
-
Diamond protection for reusable ZnO coated fiber-optic measurement head in optoelectrochemical investigation of bisphenol A
PublikacjaDue to the global problem with plastic contaminating the environment, with bisphenol A (BPA) being one of the highest demand, effective monitoring and purification of the pollutants are required. The electrochemical methods constitute a good solution but, due to polymerization of electrochemical oxidation bisphenol A products and their adsorption to the surfaces, measurement head elements are clogged by the formed film. In this...
-
In-situ monitoring of electropolymerization processes at boron-doped diamond electrodes by Mach-Zehnder interferometer
PublikacjaIn this work, the Mach-Zehnder interferometer was designed to monitor the electrochemical processes conducted at boron-doped diamond electrode surface. The diamond electrodes were synthesized via Microwave Plasma-Assisted Chemical Vapor Deposition on optical grade quartz glass. The achieved transmittance in working are of diamond electrodes reached 55 %. A cage system-based Mach-Zehnder interferometer was used which allowed the...
-
Silicon oxycarbide ceramics as anodes for lithium ion batteries: influence of carbon content on lithium storage capacity
PublikacjaWe report here on the synthesis and characterization of silicon oxycarbide (SiOC) in view of its application as a potential anode material for Li-ion batteries. SiOC ceramics are obtained by pyrolysis of various polysiloxanes synthesized by sol–gel methods. The polysiloxanes contain different organic groups attached to silicon, which influence the chemical composition and the microstructure of the final ceramic product. The structure...
-
A High-Efficient Low-Voltage Rectifier for CMOS Technology
PublikacjaA new configuration of rectifier suiting CMOS technology is presented. The rectifier consists of only two nchannel MOS transistors, two capacitors and two resistors; for this reason it is very favourable in manufacturing in CMOS technology. With these features the rectifier is easy to design and cheap in production. Despite its simplicity, the rectifier has relatively good characteristics, the voltage and power efficiency, and...
-
Potentiometric Oxygen Sensor with Solid State Reference Electrode
PublikacjaThe concentration or the partial pressure of oxygen in an environment can be determined using different measuring principles. For high temperature measurements of oxygen, ceramic-based sensors are the most practical. They are simple in construction, exploration and maintenance. A typical oxygen potentiometric sensor consists of an oxygen ion conducting solid electrolyte and two electrodes deposited...
-
Zaawansowane utlenianie odcieków składowiskowych - przegląd metod
PublikacjaPrzedstawiono rozwiązania unieszkodliwiania odcieków składowiskowych metodami zaawansowanego utleniania, takimi jak: reakcja Fentona, utlenienie ozonem i nadtlenkiem wodoru, utlenienie elektrochemiczne, utlenienie w warunkach nadkrytycznych oraz mokre utlenienie powietrzem. Podstawy teoretyczne tych metod, ich efektywność oraz stosowane reagenty. Uwarunkowania stosowania poszczególnych metod.
-
Temperature distribution of supercapacitors prepared by various technologies
PublikacjaSupercapacitors, also known by different names such as electrostatic double-layer capacitors (EDLCs) or ultra-capacitors, are electrical storage devices still in development. These devices require fast and reliable methods of assessing their state-of-health. Thermographic imaging is a method which can be applied with this aim due to its popularity, and the high negative impact of overheating on a supercapacitor’s parameters. Moreover,...
-
Phase I and phase II metabolism simulation of antitumor-active 2-hydroxyacridinone with electrochemistry coupled on-line with mass spectrometry.
PublikacjaHere, we report the metabolic profile and the results of associated metabolic studies of 2-hydroxyacridinone (2-OH-AC), the reference compound for antitumor-active imidazo- and triazoloacridinones. Electrochemistry coupled with mass spectrometry was applied to simulate the general oxidative metabolism of 2-OH-AC for the first time. The reactivity of 2-OH-AC products to biomolecules was also examined. The usefulness of the electrochemistry...
-
Sensorless Control of Induction Machine Supplied by Current Source Inverter
PublikacjaThe paper describes the voltage control technique of induction machines supplied by a current source inverter. The control system is based on proposed new multi-scalar variables, which are named “r.” The control system contains the output filter capacitor's model. In the sensorless control system the Z type backstepping speed observer was applied. The mathematical dependences are confirmed by simulation and experimental research.
-
Space-vector pulsewidth modulation for a seven-level cascaded H-bridge inverter with the control of DC-link voltages
PublikacjaThe control strategy of DC-link voltages for a seven-level Cascaded H-Bridge inverter is proposed in this paper. The DC-link voltage balancing is accomplished by appropriate selection of H-Bridges and control of their duty cycles in Space-Vector Modulation (SVM) algorithm. The proposed SVM method allows to maintain the same voltage level on all inverter capacitors. Regardless of the balancing function, the...
-
Enhanced photoelectrochemical and photocatalytic performance of iodine-doped titania nanotube arrays
PublikacjaThe paper discusses the synthesis and performance of iodine doped titania nanotube arrays exhibited under irradiation. The doping procedure was performed as an additional, electrochemical process carried out after formation of nanotube arrays via anodization of Ti substrate. The optical and structural properties were characterized using Raman, UV-vis, photoluminescence and X-ray photoelectron spectroscopy. The surface morphology...
-
Enhancing Seismic Performance of Semi-rigid Connection Using Shape Memory Alloy Bolts Considering Nonlinear Soil–Structure Interaction
PublikacjaSteel Moment-Resisting Frames (SMRFs) have their lateral resistance for their rigid connections, while real conditions have shown that the rigidity of a connection depends on the bolts and the end-plate thickness, which may not provide the assumed rigidity in design process. In this research, the main goal is to enhance the semi-rigid connections using shape memory alloy (SMA) bolts and explore their effects on the seismic limit-state...
-
Simultaneous impedance and volumetric studies and additionally potentiodynamic polarization measurements of molasses as a carbon steel corrosion inhibitor in 1M hydrochloric acid solution
PublikacjaThe inhibition effect of molasses on the corrosion of low carbon steel in 1M hydrochloric acid solution was investigated by volumetric and electrochemical measurements. Potentiodynamic polarization and dynamic electrochemical impedance spectroscopy (DEIS) results were obtained and compared with to those, obtained with the hydrogen evolution technique. All results indicate that molasses functioned as a good inhibitor in 1M hydrochloric...
-
The influence of thermal treatment on electrocatalytic properties of Mn-Co nanofilms on nickel foam toward oxygen evolution reaction activity
PublikacjaThis work evaluates electrodeposited and differently treated Mn-Co catalysts for their oxygen evolution reaction activity. Catalysts are evaluated in the as-deposited and heat treated state: after 350 C and 600 C. Results show that the highest electrochemical activity is obtained for the as-deposited Mn-Co oxyhydroxide, which possibly possess a layered double hydroxide structure. After the heat treatment process, especially after...
-
Conducting polymers for biodegradable metallic implants
PublikacjaNowadays permanent metallic cardiovascular stents are long-term implants. The long-time presence of such an implant in human body can cause overgrowth of tissue within the treated portion of the vessel, blockage of the circulatory system and many other clinical complications, such as thrombosis, prolonged physical irritations or chronic inflammation. Therefore, in recent years, there is an interest to create biodegradable metallic...
-
Differential analysis of dynamic immittance spectra
PublikacjaThis work presents a new approach to the analysis of immittance spectrograms of systems characterised by non-stationarity. The possibility of linking the evolution of the immittance response with changes in the parameters describing the system is achieved by introducing a spectrum in differential form. By using the above procedure, it becomes possible to separate elements with a dependence (or lack thereof) from an independent...
-
Hydrothermal Cobalt Doping of Titanium Dioxide Nanotubes towards Photoanode Activity Enhancement
PublikacjaDoping and modification of TiO2 nanotubes were carried out using the hydrothermal method. The introduction of small amounts of cobalt (0.1 at %) into the structure of anatase caused an increase in the absorption of light in the visible spectrum, changes in the position of the flat band potential, a decrease in the threshold potential of water oxidation in the dark, and a significant increase in the anode photocurrent. The material...
-
Impedance monitoring of fuel cell stacks
PublikacjaThis paper presents an innovative, electrochemical impedance method for monitoring of electrochemical behaviour of a multi-cell, direct methanol fuel cell (DMFC) device. This method not only provides classical voltage changes at successive cells but also allows their detailed impedance behaviour to be presented. Impedance characteristics of individual cells within a fuel cell stack (depending on actual operating conditions) are...
-
A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix
PublikacjaLithium-ion batteries (LIBs) are widely used all over the world. The LIBs belong to a renewable energy source and energy storage devices. The increase in energy demand causes that new materials of higher energy and higher power densities are still under investigation. Herein, we compare electrochemical properties of bismuth vanadate (BiVO4) embedded and not embedded into carbonaceous matrix as an anode material along with structural...
-
Determination of Antioxidant Activity of Vitamin C by Voltammetric Methods
PublikacjaVoltammetric methods—cyclic (CV) and differential pulse voltammetry (DPV) are considered the most appropriate way to evaluate antioxidant activity of redox active compounds. They provide information about both mechanism and kinetics of electrochemical oxidation of antioxidants as well as their physical and chemical properties such as the redox potential or the number of electrons transferred. These methods are helpful for understanding...
-
Electromagnetic-based derivation of fractional-order circuit theory
PublikacjaIn this paper, foundations of the fractional-order circuit theory are revisited. Although many papers have been devoted to fractional-order modelling of electrical circuits, there are relatively few foundations for such an approach. Therefore, we derive fractional-order lumped-element equations for capacitors, inductors and resistors, as well as Kirchhoff’s voltage and current laws using quasi-static approximations of fractional-order...
-
Exploring multi-step glucose oxidation kinetics at GOx-functionalized nanotextured gold surfaces with differential impedimetric technique
PublikacjaFor a few past years, we can observe the enormous growth of investigations related to ultrasensitive electrochemical sensors capable of reliable determination of important body parameters and analytes. Utilized procedures rely on standard electrochemical methods, demanding electrode polarization, and information about the initial characteristics of the working electrode. More and more complex electrode materials are characterized...
-
BADANIE WPŁYWU INDUKCJI REMANENCJI NA STAN PRZEJŚCIOWY JEDNOFAZOWEGO UKŁADU TRANSFORMATOROWEGO
PublikacjaW referacie przedstawiono wyniki badań eksperymentalnych i symulacyjnych wpływu indukcji remanencji w rdzeniu transformatora jednofazowego na jego stan przejściowy przy jego pracy jałowej. Badany obiekt jest układem transformatorowym o dwóch uzwojeniach nawiniętych na zwijanym z blachy anizotropowej rdzeniu w kształcie toroidu. Doświadczenia eksperymentalne polegały na rozładowywaniu kondensatora przez uzwojenie strony pierwotnej...
-
Predicting the seismic collapse capacity of adjacent structures prone to pounding
PublikacjaIn crowded cities, many structures are often constructed in a very close vicinity; therefore, during severe earthquakes, pounding phenomenon occurs due to out-of-phase vibrations of adjacent structures. In this study, pounding of adjacent structures is investigated up to the occurrence of total collapse. The novelty of this study is performing incremental dynamic analyses to compute the seismic collapse capacities of both pounding...
-
Sodium nitrite as a corrosion inhibitor of copper in simulated cooling water
PublikacjaThe corrosion inhibition behavior of sodium nitrite (NaNO2) towards pure copper (99.95%) in simulated cooling water (SCW) was investigated by means of electrochemical impedance spectroscopy (EIS) and dynamic electrochemical impedance spectroscopy (DEIS). NaNO2 interferes with metal dissolution and reduce the corrosion rate through the formation or maintenance of inhibitive film on the metal surface. Surface morphologies illustrated...
-
Properties of Composite Oxide Layers on The Ti13Nb13Zr Alloy
PublikacjaThe development of composite oxide layers on the Ti13Nb13Zr alloy, their structure and properties have been demonstrated. Two subsequent methods were applied to prepare the composite layers. During the first stage gas oxidation produced a solid oxide layer, and subsequently oxide nanotubes were produced by using an electrochemical method. Scanning electron microscopy (SEM), chemical analysis, energy dispersive X-ray spectroscopy...
-
Influence of friction stir welding technological parameters on the properties of the joints of selected aluminum alloys
PublikacjaThe purpose of this dissertation was to determine the effect of friction stir welding technological parameters on the properties of selected aluminum alloy joints, with consideration of the residual stresses and dislocation density in the joints. The goal of the present work was also to produce defect-free joints with high mechanical and electrochemical properties. In the dissertation, similar welds of AA6082 alloy and dissimilar...
-
Direct amination of boron-doped diamond by plasma polymerized allylamine film
PublikacjaA novel microwave pulsed-plasma based method for the modification of the hydrogen-terminated polycrystalline boron-doped diamond (BDD) with a thin film of polymerized allylamine (PPAAm) is reported. A modified BDD surface is resistant to hydrolysis and delamination and is characterized by a high density of positively charged amino groups. Pulsed microwave plasma was applied to improve the degree of cross-linking and bonding of...
-
Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo-15-crown-5) derivatives
PublikacjaGlassy carbon electrodes modified by conductive polymers and membrane with derivatives of bis(benzo-15-crown-5) were tested as solid contact ion selective electrodes for K+ ions concentration determination. PEDOT with PSS, Cl- and ClO4- counter ions was electrochemically deposited onto glassy carbon substrates using four different electrochemical approaches (potentiostatic, galvanostatic, potentiodynamic and potentiostatic pulses)....
-
Harmonics produced by traction substations – computer modelling and experimental verification
PublikacjaVoltage and current harmonics have a detrimental effect on the components of a power system. Current harmonics may result in the overload and damage to power transformers. Voltage harmonics may result in, for example, damage to capacitor banks used to compensate reactive power. Devices which contribute to both current and voltage distortion include traction rectifiers. This paper presents results of the computer investigation of...
-
The forming and emission of high power electromagnetic pulses
PublikacjaAn impulse energy source, a power conditioning system and an electromagnetic field emitter are essential to generate an electromagnetic field pulse (EMFP) with a specific frequency bandwidth. Selected simulation results for a power conditioning system consisting of a fuse opening switch and a paraboloidal electromagnetic emitter have been presented in this article. The synthetic system examined in the simulation is powered by an...
-
Nanotubular Titanium Oxide Layers for Enhancement of Bone-Implant Bonding and Bioactivity
PublikacjaThe present paper describes the techniques to improve the bioactivity of titanium and enhance the bone-implant bonding ability by the electrochemical anodization to fabricate titania nanotube arrays (TiO2).
-
Degradation of protective coatings in steel chimneys of flue gas desulfurisation system
PublikacjaThis paper presents problems associated with corrosion of steel stacks and changes in philosophy of corrosion protection when implemented into flue gas desulphurization systems. In-situ tests were taken by means of electrochemical impedance spectroscopy at the stack which discharges flue gas before wet lime/limestone desulphurization. A very quick electrolyte absorption by the spherical infill vinylester coating was found using...
-
An Analog Sub-Miliwatt CMOS Image Sensor With Pixel-Level Convolution Processing
PublikacjaA new approach to an analog ultra-low power medium-resolution vision chip design is presented. The prototype chip performs low-level image processing algorithms in real time. Only a photo-diode, MOS switches and two capacitors are used to create an analog processing element (APE) that is able to realize any convolution algorithm based on a full 3x3 kernel. The proof-of-concept circuit is implemented in 0.35 µm CMOS technology,...
-
Electrochemistry/mass spectrometry (EC/MS) for fast generation and identification of novel reactive metabolites of two unsymmetrical bisacridines with anticancer activity.
PublikacjaThe development of a new drug requires knowledge about its metabolic fate in a living organism, regarding the comprehensive assessment of both drug therapeutic activity and toxicity profiles. Electrochemistry (EC) coupled with mass spectrometry (MS) is an efficient tool for predicting the phase I metabolism of redox-sensitive drugs. In particular, EC/MS represents a clear advantage for the generation of reactive drug transformation...
-
Composite Materials Based on Silicon Oxycarbide as Anodes for Lithium-Ion Batteries
PublikacjaIn this work, the properties of binary SiOC/graphite and SiOC/tin, as well as ternary SiOC/graphite/tin obtained from various preceramic precursors are described. During the first step, the materials were synthesized using various techniques such as sol-gel and hydrosilylation. To prevent sedimentation and agglomeration of graphite particles during the gelation stage without using surfactants and thickeners, a new gelation technique...
-
Preliminary evaluation of selected mineral adsorbents used to remove phosphorus from domestic wastewater = Wstępna ocena przydatności wybranych adsorbentów mineralnych do usuwania fosforu ze ścieków bytowych
PublikacjaFour grinded mineral materials were studied for their ability of P sorption from the aq. phosphate solns. in 24-h tests by using equations of Langmuir and Freundlich isotherms. The particular sorbents contained mainly SiO254,5% Ca) 29.6%, Fe2O3 69,4% and showed the sorption capacities 56, 159, 285 or 2.4 mg/g resp.
-
Aqueous Molybdate Provides Effective Corrosion Inhibition of WE43 Magnesium Alloy in Sodium Chloride Solutions
PublikacjaCorrosion and corrosion inhibition of WE43 magnesium alloy were investigated in NaCl solutions containing different amounts of sodium molybdate. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. Electrochemical data showed that Na2MoO4 inhibitor provides reliable inhibition at concentrations at and above 100 mM. Raman and XPS spectroscopy demonstrated...
-
The inhibition effect of mad Honey on corrosion of 2007-type aluminium alloy in 3.5% NaCl solution
PublikacjaThe inhibition effect of mad honey on corrosion of 2007-type aluminium alloy in 3.5% NaCl solution was investigated by Tafel extrapolarisation (TP), electrochemical impedance spectroscopy (EIS) and dynamic electrochemical impedance spectroscopy (DEIS). All the studied parameters exhibited good anti-corrosive properties against corrosion of 2007-type aluminium alloy in the test solution; the corrosion rates decreased with the increase...
-
The forming and emission of high power electromagnetic pulses
PublikacjaAn impulse energy source, a power conditioning system and an electromagnetic field emitter are essential to generate an electromagnetic field pulse (EMFP) with a specific frequency bandwidth. Selected simulation results for a power conditioning system consisting of a fuse opening switch and a paraboloidal electromagnetic emitter have been presented in this article. The synthetic system examined in the simulation is powered by...
-
Power Surge Compensator based on a Four Level Diode Clamped Inverter for ship application. Average model
PublikacjaPaper presents continuous average value model of Power Surge Compensator based on a Four Level Diode Clamped Inverter with super capacitor as a energy storage device. This conditioner is design for power surge or fluctuation elimination, by compensating it with energy stored in ESD. Continuous average value model of multilevel S-PWM has been presented also. Summary of raised problem is a simulation model made in PowerSim Psim 8...
-
A novel sensor for measuring temperature profile during the thermoablation
PublikacjaAbstract — A novel approach for monitoring a temperature distribution inside a tissue during thermoablation is presented in the paper. A thermal profile is measured using a set of serially connected thermistors each bypassed by a capacitor. This technique allows a two-wire and simultaneous multi- point measurements using a multi-frequency measurement of electrical impedance. It is...
-
Optimal retrofit strategy using viscous dampers between adjacent RC and SMRFs prone to earthquake‑induced pounding
PublikacjaNowadays, retrofitting-damaged buildings is an important challenge for engineers. Finding the optimal placement of Viscous Dampers (VDs) between adjacent structures prone to earthquake-induced pounding can help designers to implement VDs with optimizing the cost of construction and achieving higher performance levels for both structures. In this research, the optimal placement of linear and nonlinear VDs between the 3-story, 5-story,...