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Photoresponsive Amide-Based Derivatives of Azobenzene-4,4′-Dicarboxylic Acid—Experimental and Theoretical Studies
PublikacjaAzobenzene derivatives are one of the most important molecular switches for biological and material science applications. Although these systems represent a well-known group of compounds, there remains a need to identify the factors influencing their photochemical properties in order to design azobenzene-based technologies in a rational way. In this contribution, we describe the synthesis and characterization of two novel amides...
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Analysis of energy efficiency of suburban railway transport network
PublikacjaRising numbers of agglomeration residents cause increased need for people movement on daily basis. Because of congestion of local roads, air pollution and limited parking space, providing mass transit based on electric traction is reasonable. While the electric rail vehicles are considered highly efficient in themselves, they need to be analyzed as a part of a transport network, because energy consumption depends on operating conditions...
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Ranking of Heterogeneous Catalysts Metals by Their Greenness
PublikacjaCatalysis is very important process in industry and laboratory practice, especially from the point of green chemistry principles. However, eco-friendly character of heterogeneous catalysts, containing transition metal components has not been evaluated, yet. Therefore, we perform a comprehensive assessment of 18 heterogeneous metal catalysts (Pd, Pt, V, Co, Ni, Mo, Ru, Mn, Au, Cu, Cd, Zr, Fe, Rh, Ir, Sn, Zn, Ag) using multicriteria...
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Strategic aspects in spatial planning - theory and practice in largest cities of Poland
PublikacjaThe rate of changes and the growing uncertainty rise to the need for a strategic approach to development planning, which is active and flexible in relation to the changing reality. Strategic planning, occurring in companies, was adapted by the social-economic development planning of self-government units. However, there are difficulties in applying the strategic planning in the spatial planning and integration of the two forms...
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Design Methodology for Small Passenger Ships On the Example of the Ferryboat Motława 2 Driven by Hybrid Propulsion System
PublikacjaDynamic development in practically all elds of science and engineering has not passed over shipbuilding . In last years , engineers got to their use computer soware which makes it possible to perform strength and hydrodynamic calculations as well as to visualize design projects in 3 D space [1-4]. At their disposal they have full spectrum of modern solutions associated with the use of advanced materials and technologies [5-7]....
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Agile Methods In Formation of Metropolis Neighbourhood
PublikacjaA study of the zone adjoining the metropolis area of Tricity (Poland) was conducted on the basis of analyses of changes in spatial development, outline planning decisions and local plans of spatial development. Localities placed at several dozen kilometres from strongly urbanized areas do not constitute metropolis outskirts. The vicinity of large urban centres is an obstacle to the development of localities as self-sufficient units...
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Advanced Potential Energy Surfaces for Molecular Simulation
PublikacjaAdvanced potential energy surfaces are defined as theoretical models that explicitly include many-body effects that transcend the standard fixed-charge, pairwise-additive paradigm typically used in molecular simulation. However, several factors relating to their software implementation have precluded their widespread use in condensed-phase simulations: the computational cost of the theoretical models, a paucity of approximate models...
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Correlation between the number of Pro-Ala repeats in the EmrA homologue of Acinetobacter baumannii and resistance to netilmicin, tobramycin, imipenem and ceftazidime
PublikacjaAcinetobacter baumannii coccobacilli are dangerous to patients in intensive care units because of their multidrug resistance to antibiotics, developed mainly in the past decade. This study aimed to examine whether there is a significant correlation between the number of Pro-Ala repeats in the CAP01997 protein, the EmrA homologue of A. baumannii, and resistance to antibiotics. A total of 79 multidrug-resistant A. baumannii strains...
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Social convergence in Nordic countries at regional level
PublikacjaResearch background: Geographical proximity, common historical roots and collaboration within the Nordic Council cause the Nordic countries to be often wrongly treated as monoliths. However, in reality, Nordic regions differ in terms of broadly defined social and economic development. Issues concerning the standard of living are one of the priorities of the Helsinki Treaty signed by Nordic countries. Purpose of the article: The...
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<i>N,N,N</i>-Trimethyl-N-(methyl 5-deoxy-2,3-<i>O</i>-isopropylidene-β-D-ribofuranosid-5- yl)ammonium 4-methylbenzenesulfonate sesquihydrate.
PublikacjaThe structure of the title compound, [C12H24NO4][C7H7O3S]·1.5H2O, contains alternating layers parallel to (001) of hydrophobic and polar character, stabilized by C-H...O hydrogen bonding. The furan ring adopts an envelope conformation with the C(OMe) atom as the flap, and the dioxolane ring is twisted about one of the O-C(methine) bonds. A comparison to related compounds is presented. The tosylate-O atoms were disordered over two...
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Low cost microwave X-band generator
PublikacjaA low cost microwave X-band generator for educational purposes was designed and built. Its simple construction and user's interface makes it suitable for a student laboratory.The generator is based on a single frequency conversion concept. It uses a digitally tunable PLL chip for intermediate frequency generation and an active frequency multiplier for frequency conversion. The generator covers 9,7 - 11 GHz part of the X frequency...
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X-RAY DIFFRACTION STUDY OF BISMUTH LAYER-STRUCTURED MULTIFERROIC CERAMICS
PublikacjaGoal of the present research was to apply a solid state reaction route to fabricate bismuth layer-structured multiferroic ceramics described with the formula Bi5FeTi3O15 and reveal the influence of processing conditions on its crystal structure and phase composition. Simple oxide powders Bi2O3, TiO2 and Fe2O3 were used to fabricate Aurivillius-type bismuth layer-structured ferroelectrics. Pressureless sintering in ambient air was...
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Stability of trusses with linear elastic side-supports
PublikacjaThe present research is devoted to study of a lateral buckling of truss with linear elastic side supports. The elastic support reaction in relation to force in compressed chord and coefficient of buckling length related to side support distance are also calculated. The effect of slope of side support on limit force is also considered. The nonlinear analysis of two roof trusses are carried out. The results are compared to design...
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PCA based Fault Tolerant MPC
PublikacjaThis chapter presents a Fault Tolerant - Model Predictive Control (FT-MPC) schemes for sensor faults accommodation. A Fault Detection and Isolation (FDI) Unit, which is an integral part of FT-MPC system, is based on the Principal Component Analysis (PCA) method. Introduced approach enables efficient bias and drift faults accommodation in single, as well as simultaneous faults case. Simple simulation exercise is presented.Rozdział...
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ECU calibration for gaseous dual fuel supply system in compression ignition engines
PublikacjaThe dual fuel (DF) combustion mode is proven solution that allows to improve or get at the same level engine performance and reduce toxic compounds in exhaust gases which is confirmed by researchers and end-users. DF combustion mode uses two fuels gaseous fuel as a primary energy source and a pilot quantity of diesel fuel as ignition source. However, in order, to fully take advantage of the potential of the dual fuel mode, DF system...
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Concept of a swirling diffuser in batch blending tanks
PublikacjaThe mixing of two or more components belongs to the category of the most common unit operations, both in technology and in nature. One particular version is homogenization (blending), the effectivity of which is strongly related to the blending time. Among many differentiated individual solutions of mixing systems used in blenders, one should distinguish the class of agitators with diffusers. An analysis of the character of the...
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Simulation of Direct-Sequence Spread Spectrum Data Transmission System for Reliable Underwater Acoustic Communications
PublikacjaUnderwater acoustic communication (UAC) system designers tend to transmit as much information as possible, per unit of time, at as low as possible error rate. It is a particularly difficult task in a shallow underwater channel in which the signal suffers from strong time dispersion due to multipath propagation and refraction phenomena. The direct-sequence spread spectrum technique (DSSS) applied successfully in the latest standards...
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Charge density wave and large nonsaturating magnetoresistance in YNiC2 and LuNiC2
PublikacjaWe report a study of physical properties of two quasi-low-dimensional metals YNiC2 and LuNiC2 including the investigation of transport, magnetotransport, galvanomagnetic, and specific heat properties. In YNiC2 we reveal two subsequent transitions associated with the formation of weakly coupled charge density wave at TCDW=318K and its locking in with the lattice at T1=275K. These characteristic temperatures follow the previously...
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Comparative study of operation of condensing and traditional boilers equipped with the ORC module for electricity generation
PublikacjaCondensing technology applied to boilers is to make full use of thermal energy contained in the fuel. That means that additionaly the heat from condensation of exhaust gases can be used for the purposes of heating the domestic hot water and to cover the demand for central heating. The study analyzed the operation of the "traditional" boiler equipped with the ORC module as the similar arrangement but with the condensing boiler....
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La 15 Nb x Ge 9 : a superstructure of the Mn 5 Si 3 structure type with interstitial Nb atoms
PublikacjaThe crystal structure and elementary properties of La15NbxGe9 are reported. Single-crystal X-ray diffraction,from a crystallite with only 0.12 Nb/formula unit, reveals that this compound, although transition metal deficient, crystallizes in a hexagonal “15-1-9”-like structure type, space group P63mc (no. 186) with lattice parameters a = b = 15.5017(2) Å, c = 6.9173(2) Å. The physical properties were examined by specific heat and resistivity...
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A comparative study of English viseme recognition methods and algorithm
PublikacjaAn elementary visual unit – the viseme is concerned in the paper in the context of preparing the feature vector as a main visual input component of Audio-Visual Speech Recognition systems. The aim of the presented research is a review of various approaches to the problem, the implementation of algorithms proposed in the literature and a comparative research on their effectiveness. In the course of the study an optimal feature vector...
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A comparative study of English viseme recognition methods and algorithms
PublikacjaAn elementary visual unit – the viseme is concerned in the paper in the context of preparing the feature vector as a main visual input component of Audio-Visual Speech Recognition systems. The aim of the presented research is a review of various approaches to the problem, the implementation of algorithms proposed in the literature and a comparative research on their effectiveness. In the course of the study an optimal feature vector construction...
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Ac and dc conductivities in v2o5-p2o5 glasses containing alkaline ions
PublikacjaWe investigated the ac and dc conductivity in 50V2O5-(50 − x)P2O5-xA2O (A = Li, Na, K) glasses as a function of temperature. The measurements were carried out in the frequency range from 10−4 to 107 Hz. For all compositions, the dc conductivity decreased with the increasing alkali ion content. The decrease in conductivity was more pronounced for larger alkali ions. The ac conductivity exhibited a universal dynamic response: σac...
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Multiple output CMOS current amplifier
PublikacjaIn this paper the multiple output current amplifier basic cell is proposed. The triple output current mirror and current follower circuit are described in detail. The cell consists of a split nMOS differential pair and accompanying biasing current sources. It is suitable for low voltage operation and exhibits highly linear DC response. Through cell devices scaling, not only unity, but also any current gains are achievable. As...
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From hobbies, straightforward analysis to serious research – the road to phd degree
PublikacjaThe illustration of the main articles goal is an example of author's academic career course, the aim of which is to obtain a doctoral degree in the field of geodesy and cartography. Today, the most important thing for the young scientist is the devotion to research in certain field of science, which is interested for the large community of scientists. From a psychological point of view, a unity of interest and experiments must...
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Nabywanie nieruchomości przeznaczonych pod drogi publiczne
PublikacjaNabywanie nieruchomości przeznaczonych pod drogi publiczne. Polska na rozwój dróg krajowych w latach 2007 - 2013 otrzymała ponad 10 mld euro unijnego wsparcia. W efekcie powstało prawie 1500 km nowych dróg ekspresowych i autostrad. Należałoby przeanalizować przebieg procesu inwestycyjnego i procedur administracyjnych, aby osiągnąć jeszcze lepsze rezultaty i efektywniej wykorzystywać dotacje przeznaczone na...
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Innowacyjne narzędzia zarządzania bezpieczeństwem transportu drogowego na poziomie regionalnym
PublikacjaW referacie przedstawiono założenia i cele Obserwatorium Bezpieczeństwa Ruchu Drogowego funkcjonującego w regionie Warmii i Mazur. Obserwatorium jest pierwszą taką jednostką w Polsce – zarówno na poziomie regionalnym, jak centralnym. Zostało powołane zgodnie z metodyką zaproponowaną w europejskim projekcie SafetyNet i wspólnie z Krajowym Obserwatorium Bezpieczeństwa Ruchu Drogowego, realizowanym przez Instytut Transportu Samochodowego, wejdzie...
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A Noded Carbon Emission Tool (NCET) to Measure Embodied Carbon (EC) in Compositional Cementitious Materials
PublikacjaThe ever evolving modern construction industry is now producing the highest levels of carbon content adversely affecting the construction associated environment. Although, the impact of carbon induced emission is quite large, but still not enough measurable standards and tools to scale these emission are available. This study contributes to the body of knowledge by providing a Grasshopper based definition to calculate the embodied...
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Design and distribution of air nozzles in the biomass boiler assembly
PublikacjaDue to energy crisis as well as increasing pollution of the environment, renewable energy sources usage increases all over the world. These facts encouraged authors to start research over developing a uniform biomass boiler calculation model. This paper presents a design of biomass boiler assembly created for ORC (Organic Rankine Cycle) unit since these systems could achieve strong position in energy industry....
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Combined operation of 900MW power plant with the ORC through the bleed steam extraction point and CO2 recovery system
PublikacjaThe work presented here is aimed at utylisation of waste heat in the reference supercritical power plant in the manner to produce electricity in ORC installation. The waste heat is available in the form of a stream of hot water at 90 C, recovered from the exhaust gases in the amount of 200MW. Such low enthalpy heat source is rather insufficient to produce a good quality vapour to feed the ORC turbine. Therefore an original approach...
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Effect of isovalent substitution on microstructure and phase transition of LaNb1−xMxO4 (M=Sb, V or Ta; x=0.05–0.3)
PublikacjaLaNb1−xMxO4 oxides with pentavalent elements of different ionic sizes (M=Sb, Ta and V, x=0.05–0.3) were synthesized by the solid state reaction method. Special interest was devoted to the antimony substituted lanthanum niobate which is a new material in this group. Rietveld analysis of the X-ray diffraction patterns was used to determine the influence of the material composition on unit cell parameters. On the basis of dilatometric...
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9-Cyano-10-methylacridinium hydrogen dinitrate
PublikacjaThe title compound, C15H11N2+·HN2O6−, crystallizes in the monoclinic space group C2/c with four molecules in the unit cell. The planar 9-cyano-10-methylacridinium cations lie on crystallographic twofold axes and are arranged in layers, almost perpendicular to the ac plane, in such a way that neighbouring molecules are positioned in a `head-to-tail' manner. These cations and the hydrogen dinitrate anions are linked through C—H⋯O...
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Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane
PublikacjaThis paper presents the theoretical screening of 23 low-cost deep eutectic solvents (DESs) as absorbents for effective removal of the main impurities from biogas streams using a conductor-like screening model for real solvents (COSMO-RS). Based on thermodynamic parameters, i.e., the activity coefficient, excess enthalpy, and Henry’s constant, two DESs composed of choline chloride: urea in a 1:2 molar ratio (ChCl:U 1:2), and choline...
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Revisiting Toroidal Dipolar Moment in Planar Metamaterial
PublikacjaThis article revisits the electric, magnetic, and toroidal dipolar moments in the metamaterial structure and presents the flatland design for generating a toroidal dipolar response for the electromagnetic plane wave at normal incidence. Based on the numerical analysis of the surface current, the electric field, the magnetic field, and the quantitative analysis of scattered power supported by the electromagnetic multipole theory,...
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Impacts of Using Exhaust Gas Recirculation and Various Amount of Dimethyl Ether Premixed Ratios on Combustion and Emissions on a Dual-Fuel Compression Ignition Engine
PublikacjaIn the presented research, the authors dealt with the specific properties of the combustion process of dimethyl ether (DME) in a combustion car (Volkswagen Golf IV) engine AJM 1.9 TDI PDE made by Volkswagen factory. Dimethyl ether is an alternative fuel produced most often from natural gas, which can be used in compression ignition engines as a single fuel or co-burned with diesel oil. This work describes the impacts of using exhaust...
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Accuracy, Memory and Speed Strategies in GPU-based Finite-Element Matrix-Generation
PublikacjaThis paper presents strategies on how to optimize GPU-based finite-element matrix-generation that occurs in the finite-element method (FEM) using higher order curvilinear elements. The goal of the optimization is to increase the speed of evaluation and assembly of large finite-element matrices on a single GPU (Graphics Processing Unit) while maintaining the accuracy of numerical integration at the desired level. For this reason,...
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Novel MNZ-type microwave sensor for testing magnetodielectric materials
PublikacjaA novel microwave sensor with the mu-near-zero (MNZ) property is proposed for testing magnetodielectric material at 4.5 GHz. The sensor has a double-layer design consisting of a microstrip line and a metal strip with vias on layers 1 and 2, respectively. The proposed sensor can detect a unit change in relative permittivity and relative permeability with a difference in the operating frequency of 45 MHz and 78 MHz, respectively....
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Investigation of praseodymium and samarium co-doped ceria as an anode catalyst for DIR-SOFC fueled by biogas
PublikacjaThe Pr and Sm co-doped ceria (with up to 20 mol.% of dopants) compounds were examined as catalytic layers on the surface of SOFC anode directly fed by biogas to increase a lifetime and the efficiency of commercially available DIR-SOFC without the usage of an external reformer. The XRD, SEM and EDX methods were used to investigate the structural properties and the composition of fabricated materials. Furthermore, the electrical...
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Recurrent Neural Network Based Adaptive Variable-Order Fractional PID Controller for Small Modular Reactor Thermal Power Control
PublikacjaThis paper presents the synthesis of an adaptive PID type controller in which the variable-order fractional operators are used. Due to the implementation difficulties of fractional order operators, both with a fixed and variable order, on digital control platforms caused by the requirement of infinite memory resources, the fractional operators that are part of the discussed controller were approximated by recurrent neural networks...
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Influence of metallic porous microlayer on pressure drop and heat transfer of stainless steel plate heat exchanger
PublikacjaThe experimental analysis of passive heat transfer intensification in the case of plate heat exchanger has been carried out. The metallic porous layer was created on the heat transfer surface of analyzed unit. The experiment was accomplished in two stages. In the first stage the commercial stainless steel gasketed plate heat exchanger was investigated, while in the second one – the identical heat exchanger but with the modified...
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Perspectives on the replacement of harmful organic solvents in analytical methodologies: a framework toward the implementation of a generation of eco-friendly alternatives
PublikacjaVolatile organic solvents derived from non-renewable fossil feedstocks are commonplace in analytical laboratories. In spite of their convenient performance in countless unit operations, their environmental, health and safety issues represent a major area of concern. The progressive replacement of organic solvents obtained from fossil resources by eco-friendly alternatives would involve remarkable advances within the framework of...
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Wyznaczenie obciążeń na poszycie okrętu wywołanych uderzeniem fal i uderzeniem w lód i ich wpływ na bezpieczeństwo okrętu
PublikacjaThe main problem is the vessels rather accurate determination of the hydrodynamic loads so-called hydroelasticity outside . This can be done by theoretical analysis , computer simulation or by experiment. This gives the hydrodynamic pressure distribution on the walls of the ship's hull and also on the walls of marine vessels .The most dangerous are the impact of extreme storm waves , the impact of the wharf and the impact zone...
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Analysis of unsteady flow forces on the thermowell of steam temperature sensor
PublikacjaIn this paper, 3D numerical analysis of unsteady flow forces acting on the measuring sheath of steam temperature is presented. According to that purpose, the CFD (Computation Fluid Dynamic [1]) approach has been used. The nonstationary of fluid acting on the measuring sheath such as: Strouhal frequency, amplitude of pressure, structure of vortex, peak of pressure, field of pressure, field of velocity etc. are studied analytically...
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Technology Concept of TLP Platform Towing and Installation in Waters with Depth of 60 m
PublikacjaThe article is part of the design and research work conducted at the Gdansk University of Technology, Faculty of Ocean Engineering and Ship Technology, in cooperation with a number of other research centres, which concerns offshore wind farms planned to be built in the Polish zone of the Baltic sea in the next years. One of most difficult tasks in this project is building suitable foundations for each power unit consisting of a...
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Synthesis and antimicrobial activity of amino acid and peptide derivatives of mycophenolic acid
PublikacjaThe series of 16 novel amino acid and peptide mycophenolic acid (MPA) derivatives was obtained as potential antibacterial agents. Coupling of MPA with respective amines was optimized with condensing reagents such as EDCI/DMAP and T3P/TEA. Amino acid analogs were received both as methyl esters and also with the free carboxylic group. The biological activity of the products was tested on five references bacterial strains: Klebsiella...
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Application of linear buckling sensitivity analysis to economic design of cylindrical steel silos composed of corrugated sheets and columns
PublikacjaThe paper deals with global stability of steel cylindrical silos composed of corrugated walls and vertical columns with loads imposed by a bulk solid following Eurocode 1. The optimum silo design with respect to the steel weight was based on a sensitivity analysis method. The changes of silo column profiles at each design step were performed by means of influence lines for the buckling load factor due to the unit column bending...
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Management of Urban Waters with Nature-Based Solutions in Circular Cities—Exemplified through Seven Urban Circularity Challenges
PublikacjaNature-Based Solutions (NBS) have been proven to effectively mitigate and solve resource depletion and climate-related challenges in urban areas. The COST (Cooperation in Science and Technology) Action CA17133 entitled “Implementing nature-based solutions (NBS) for building a resourceful circular city” has established seven urban circularity challenges (UCC) that can be addressed effectively with NBS. This paper presents the outcomes...
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Spatial differentiation of road safety in Europe based on NUTS-2 regions
PublikacjaRoad safety varies significantly across the regions in Europe. To understand the factors behind this differentiation and the effects they have, data covering 263 NUTS-2 (Nomenclature of Territorial Units for Statistics) regions across Europe (European Union and Norway) have been analysed. The assessment was made using Geographically Weighted Regression (GWR). As a dependent variable the Road Fatality Rate (RFR – number of fatalities...
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Investigating an Optimal Computational Strategy to Retrofit Buildings with Implementing Viscous Dampers
PublikacjaCivil engineering structures may seriously suffer from different damage states re-sult of earthquakes. Nowadays, retrofitting the existing buildings is a serious need among designers. Two important factors of required performance level and cost of retrofitting play a crucial role in the retrofitting approach. In this study, a new optimal computational strategy to retrofit structures by implementing linear Viscous Dampers (VDs)...
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IMPROVING STUDENT SKILLS WITH ENGAGING IN HERITAGE PROTECTION PROJECTS. CASE STUDY OF ARCHITECTURAL INVENTORY WORKS AT WISŁOUJŚCIE FORTRESS, POLAND (2017)
PublikacjaToday's educational offer at universities contains a lot of theoretical and general knowledge, which becomes less understandable and less suitable for students of the new generation. Student's educational needs aimed at increasing the practical experience necessary for future professional life. Heritage conservation projects are a good opportunity to implement project-based learning methods. Such projects can be scientific and...