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Enhanced aging resistance of poly(ε-caprolactone)/brewers’ spent grain composites
PublikacjaThe presented paper investigated the influence of brewers’ spent grain (BSG) extrusion pa-rameters on the photo-oxidative resistance of poly(ε-caprolactone)-based wood polymer composites. Filler samples characterized by the higher melanoidin content were more efficient in hindering of poly-mer degradation, inhibiting the decomposition of the polymer amorphous phase. As aresult, deteriora-tion of mechanical performance was limited,...
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Efficient Extraction of Fermentation Inhibitors by Means of Green Hydrophobic Deep Eutectic Solvents
PublikacjaThe methods for hydrogen yield efficiency improvements, the gaseous stream purification in gaseous biofuels generation, and the biomass pretreatment are considered as the main trends in research devoted to gaseous biofuel production. The environmental aspect related to the liquid stream purification arises. Moreover, the management of post-fermentation broth with the application of various biorefining techniques gains importance....
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Uptake, tissue distribution, and metabolism of malachite green in the channel catfish (Ictalurus punctatus)
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Wheat Bread with Grape Seeds Micropowder: Impact on Dough Rheology and Bread Properties
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New Screening Protocol for Effective Green Solvents Selection of Benzamide, Salicylamide and Ethenzamide
PublikacjaNew protocol for screening efficient and environmentally friendly solvents was proposed and experimentally verified. The guidance for solvent selection comes from computed solubility via COSMO-RS approach. Furthermore, solute-solvent affinities computed using advanced quantum chemistry level were used as a rationale for observed solvents ranking. The screening protocol pointed out that 4-formylomorpholine (4FM) is an attractive...
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Green engineered biomaterials for bone repair and regeneration: Printing technologies and fracture analysis
PublikacjaDespite the exceptional self-regeneration properties of bone, severe injuries often require additional surgical intervention such as using artificial bone constructs. These structures need to meet a number of criteria regarding their structure, performance, alongside the rate and the mechanism of erosion and fracture when implanted, for stimulating the regeneration of defected bone and, more critically providing support in the...
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Green analytical chemistry introduction to chloropropanols determination at no economic and analytical performance costs?
PublikacjaIn this study we perform ranking of analytical procedures for 3-monochloropopane-1,2-diol determination in soy sauces with PROMETHEE method. Multicriteria decision analysis was performed for three different scenarios – metrological, economic and environmental, by application different weights to decision making criteria. All three scenarios indicate capillary electrophoresis – based procedure as the most preferable. Apart from...
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Grabe J.:Recommendations of the "Committee for Waterfront Structures Harbours and Waterways" EAU 2012
PublikacjaRecenzja - Grabe J.: Recommendations of the "Committee for Waterfront Structures Harbours and Waterways" EAU 2012. Ernst & Sohn, Berlin 2015
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Grafo-mania, czyli rzecz o grafach i algorytmach. Liczby Ramseya
PublikacjaZdefiniowano liczby Ramseya i wskazano na trudności obliczeniowe ich wyznaczania już przy niewielkich wartościach takich liczb.
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Grafo-ania, czyli rzecz o grafach i algorytmach. Drzewa Steinera
PublikacjaProblem: na płaszczyźnie leżą 3 punkty. Znajdź czwarty, taki że jego sumaryczna odległość od 3 pozostałych jest minimalna, Pokazujemy jak rozwiązać ten problem i jego uogólnienie.
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Effect of Sieve Unit Inclination Angle in a Rotary Cleaning Device for Barley Grain
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Application of multivariate statistics in assessment of green analytical chemistry parameters of analytical methodologies
PublikacjaThe study offers a multivariate statistical analysis of a dataset, including the major metrological, “greenness” and methodological parameters of 43 analytical methodologies applied for aldrin determination (a frequently analyzed organic compound) in water samples. The variables (parameters) chosen were as follows: metrological (LOD, recovery, RSD), describing the “greenness” (amount of the solvent used, amount of waste generated)...
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Research on flue gas flow measurement and modelling in the moving grate biomass boiler
PublikacjaThe aim of this research was to determine the nature of gas flow in a grate boiler model by the method of Particle Image Velocimetry (PIV) and CFD. The paper presents the comparison of the PIV results with numerical simulations made in the environment of ANSYS Fluent. The main goal of the experiment was to describe the phenomena occurring on the grate. Methodology of modelling solid fuel combustion on the moving grate was proposed...
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Spawalność tytanu Grade 2 na przykładzie płaszczowo-rurowego wymiennika ciepła
PublikacjaW artykule scharakteryzowano właściwości, obszary zastosowania i problemy związane ze spawalnością tytanu i jego stopów. Opracowano technologię spawania metodą TIG płaszczowo-rurowego wymiennika ciepła typu JAD B z tytanu Grade 2, zaprezentowano wyniki badań nieniszczących i niszczących złączy spawanych. Szczególną uwagę zwrócono na trudności związane z przygotowaniem krawędzi elementów do spawania i wynikające z nich niezgodności...
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Weldability of pipe grade polyethylenes as realized from thermal and mechanical properties assessments
PublikacjaSince polyethylene (PE) has been widely accepted for the production of high-pressure fluid conveying pipelines, studies devoted to weldability of PE connections were always of major importance. In this study, two industrial PE grades designed for pipe production, namely PE80 and PE100, were injection molded, cut, and then welded as PE100-PE100, PE100-PE80, and PE80-PE80. The heat-welded joints were assessed by differential scanning...
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A Green Chemistry "environmentally friendly" approach to the synthesis of chloro-intermediates of ephedrine/pseudoephedrine
PublikacjaMethylamphetamine is an addictive stimulant drug that strongly activates certain systems in the brain. It is closely related chemically to amphetamine, but the central nervous system effects of methamphetamine are greater. There is much interest in methylamphetamine among scientists and therefore the synthesizes of methylamphetamine and its metabolites are carried out on a large scale in chemical laboratories. Globally, ephedrine...
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Optimization of liquid chromatographic separation of pharmaceuticals within green analytical chemistry framework
PublikacjaThe contribution is aimed at the development of methodology that allows to consider green analytical chemistry criteria during optimization of liquid chromatographic separation with design of experiment. The objectives of the optimization are maximization of peak areas of five non-steroid anti-inflammatory drugs, maximization of resolution between peaks, with simultaneous shortening of chromatographic separation time and minimization...
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Planning of the green road system as an element of spatial management in suburbs and small towns
PublikacjaThe premise for the development of sustainable forms of road infrastructure in small towns is the appropriate plan at an early stage or modifi cation in the case of existing spaces. A multi-directional approach is extremely important, which takes into account the specifi city of the regional (country) road system, availability, and capacity of traffi c network, but also social and environmental factors. Effi cient management...
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Microstructure and Mechanical Properties of Carboxylated Nitrile Butadiene Rubber/Epoxy/XNBR-grafted Halloysite Nanotubes Nanocomposites
PublikacjaThe effect of various amounts of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the cure characteristics, mechanical and swelling behavior of XNBR/epoxy compounds was experimentally and theoretically investigated. The morphology of the prepared XNBR/epoxy/XHNTs nanocomposites was imaged using scanning electron microscopy (SEM). The effects of various XNBR-grafted nanotubes on the damping...
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Histological evaluation of age-related variations in saphenous vein grafts used for coronary artery bypass grafting
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Recent Achievements in Constitutive Equations of Laminates and Functionally Graded Structures Formulated in the Resultant Nonlinear Shell Theory
PublikacjaThe development of constitutive equations formulated in the resultant nonlinear shell theory is presented. The specific features of the present shell theory are drilling rotation naturally included in the formulation and asymmetric measures of strains and stress resultants. The special attention in the chapter is given to recent achievements: progressive failure analysis of laminated shells and elastoplastic constitutive relation...
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Anterior Cruciate Ligament Reconstruction Using a 4-Strand Semitendinosus Tendon Graft or a Doubled Semitendinosus and Gracilis Tendon Graft: A 4.5-Year Prospective, Randomized, Double-Blind, Parallel-Group Study
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Hydrological signals in polar motion excitation – Evidence after fifteen years of the GRACE mission
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Shear-Jamming in Two-Dimensional Granular Materials with Power-Law Grain-Size Distribution
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Algorytm budowy reprezentacji przedziałowej grafu jako heurystyka dla problemu mapowania DNA
PublikacjaW pracy dokonano analizy przydatności algorytmu Corneil'a budowy reprezentacji przedziałowej grafu jako heurystyki dla problemu tworzenia map fizycznych DNA. Prezentowana analiza dotyczy dwóch osobno rozpatrywanych przypadków, w których do danych wzorcowych wprowadzamy odpowiednio błędy negatywne (reprezentujące niedobór informacji) oraz błędy pozytywne (reprezentujące fałszywe informacje). Rozpatrywany algorytm zachowuje się znacznie...
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Microwave Assisted Liquefaction with Crude Glycerol as a Potential Method of Brewer’s Spent Grain Utilization
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The modulatory effect of green tea catechin on drug resistance in human ovarian cancer cells
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Starch‐graft copolymers of N‐vinylformamide and acrylamide modified with montmorillonite manufactured by reactive extrusion
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Green Synthesis of ZnO nanoparticles using Nigella sativa seed extract for antibacterial activities
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Green porous benzamide-like nanomembranes for hazardous cations detection, separation, and concentration adjustment
PublikacjaGreen biomaterials play a crucial role in the diagnosis and treatment of diseases as well as health-related problem-solving. Typically, biocompatibility, biodegradability, and mechanical strength are requirements centered on biomaterial engineering. However, in-hospital therapeutics require an elaborated synthesis of hybrid and complex nanomaterials capable of mimicking cellular behavior. Accumulation of hazardous cations like...
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System architecture of an INSPIRE-compliant green cadastre system for the EU Member State of Poland
PublikacjaIn response to the need for a sustainable agricultural policy, which would support activities such as decision making in precise agriculture and mitigation of crop threats, a concept agricultural information system was developed for the area of Poland. This innovative concept, called Green Cadastre (GC), proposes to create a uniform system designed for use on a national scale by both state administration as well as local farmers....
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Sustainable upcycling of brewers’ spent grain by thermo-mechanical treatment in twin-screw extruder
PublikacjaThermo-mechanical treatment of brewers’ spent grain (a by-product of beer manufacturing) was successfully performed via the extrusion process. The impact of temperature (from 30 to 180 °C), throughput (from 1 to 5 kg/h) and screw speed (from 75 to 375 rpm) on particle size, color, chemical structure, antioxidant activity and thermal stability of resulting material, as well as correlations between particular properties, were investigated....
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Insights into the Thermo-Mechanical Treatment of Brewers’ Spent Grain as a Potential Filler for Polymer Composites
PublikacjaThis paper investigated the impact of twin-screw extrusion parameters on the properties of brewers’ spent grain. The chemical structure, antioxidant activity, particle size, and color properties, as well as the emission of volatile organic compounds during extrusion, were investigated. The main compounds detected in the air during modifications were terpenes and terpenoids, such as α-pinene, camphene, 3-carene, limonene, or terpinene....
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Green TPUs from Prepolymer Mixtures Designed by Controlling the Chemical Structure of Flexible Segments
PublikacjaThis study concerns green thermoplastic polyurethanes (TPU) obtained by controlling the chemical structure of flexible segments. Two types of bio-based polyether polyols—poly(trimethylene glycol)s—with average molecular weights ca. 1000 and 2700 Da were used (PO3G1000 and PO3G2700, respectively). TPUs were prepared via a two-step method. Hard segments consisted of 4,4?- diphenylmethane diisocyanates and the bio-based 1,4-butanodiol...
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Participatory co-design approach for Greencoin educational tool shaping urban green behaviors.
PublikacjaOur main goal is to prepare assumptions of the Greencoin (GC) cybernetic system, implying pro-ecological attitudes and behavior of city residents. We used qualitative methods, including a literature review and action research -workshops attended by academics, representatives of private and business sectors, urban movements, municipal institutions’ partners, and residents. Our results defined functionalities of the GC, identified...
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Green monoterpenes based deep eutectic solvents for effective BTEX absorption from biogas
PublikacjaThe combustion of biogas which contains significant amounts of monoaromatic hydrocarbons, i.e. benzene, ethylbenzene, toluene, and xylene (BTEX) can cause many technological, environmental, and health problems. Therefore, in these studies, a new physical absorption method based on deep eutectic solvents (DES) consisting of monoterpenes and carboxylic acids was developed for BTEX removal. A total of 39 DES were synthesized, of which...
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Impact of steel grade on a ship colliding with an offshore wind turbine monopile supporting structure
PublikacjaOffshore wind power is experiencing rapid development around the world. The number of installations and their size is growing. Thousands of monopile support structures with diameters of 10 m and weights of 2000 tons will be installed in the coming years. Offshore wind power installations, often located close to the shore and shipping routes, pose a new challenge to ship safety. The study analyses the damages from an accidental...
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Numerical simulations of sand behavior using DEM with 2 different descriptions of grain roughness
PublikacjaW rozdziale przedstawiono wyniki dyskretnych symulacji jednorodnego trójosiowego ściskania piasku przy zastosowaniu metody elementów dyskretnych. Obliczenia wykonano stosując 2 różne opisy szorstkości ziaren: kule z uwzględnieniem momentów kontaktu oraz grona kul. Obliczono energię sprężystą i dysypację plastyczną. Wyniki symulacji numerycznych porównano z wynikami doświadczalnymi.
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Cellulose Nanofibers Isolated from the Cuscuta Reflexa Plant as a Green Reinforcement of Natural Rubber
PublikacjaIn the present work, we used the steam explosion method for the isolation of cellulose nanofiber (CNF) from Cuscuta reflexa, a parasitic plant commonly seen in Kerala and we evaluated its reinforcing efficiency in natural rubber (NR). Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and Thermogravimetric analysis (TGA) techniques...
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Engineering and Manufacturing Technology of Green Epoxy Resin Coatings Modified with Recycled Fine Aggregates
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Pier of the future- investigation of green and blue strategies as tools for modernization of Gdynia's public waterfront
PublikacjaBetween rising water levels and global migration to cities, architects and designers need to critically reimagine the relationship between coastal landscapes and public space. Cities are facing entirely new risks and environmental conditions. Resiliency, infrastructure, and ecology are increasingly common terms, reflecting the growing demand to address the spatial and formal challenges faced by cities worldwide. Rethinking boundaries...
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Likelihood of Transformation to Green Infrastructure Using Ensemble Machine Learning Techniques in Jinan, China
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Modalne grafy wiązań - podejście wykorzystujące metodę transmitancji układu o parametrach rozłożonych
PublikacjaCelem pracy jest zastosowanie metody transmitancji układu o parametrach rozłożonych do konstruowania modalnych grafów wiązań. Grafy takie wykorzystuje się w modelowaniu układów zawierających jednowymiarowe podukłady o parametrach rozłożonych. W wyniku zaproponowanego podejścia uzyskuje się dalsze zwiększenie dokładności otrzymywanych modeli.
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Lab-in-syringe as a practical technique for automatic microextraction: Evaluation by Blue Applicability Grade Index
PublikacjaLab-in-syringe (LIS) is a powerful automatic technique that is derived from sequential injection analysis. In LIS, a computer-controlled syringe pump is employed, and its syringe barrel serves as a mixing, reaction, and/or extraction chamber. Until now, the LIS concept has been efficiently employed for the automation of solid-phase microextraction and liquid-phase microextraction protocols as a front-end to a plethora of chromatographic...
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Analysis of the grain boundary conductivity for nanocrystalline doped ceria using the brick layer model.
PublikacjaW pracy przedstawiono wyniki badań elektrycznych i mikrostrukturalnych ceru domieszkowanego itrem. Gęste i nanokrystaliczne filmy przygotowane zostały z użyciem prekursorów polimerowych na szafirze. Konduktancja elektryczna była badana w funkcji temperatury syntezy, która jest skorelowana z wielkością ziaren. Otrzymano mniejszą konduktancję nanokrystalicznego filmu ceru w porównaniu z próbkami ceramicznymi.
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Blue applicability grade index (BAGI) and software: a new tool for the evaluation of method practicality
PublikacjaIn this work, blue applicability grade index (BAGI) is proposed as a new metric tool for evaluating the practicality of an analytical method. BAGI can be considered complementary to the well-established green metrics, and it is mainly focused on the practical aspects of White Analytical Chemistry. This tool evaluates ten main attributes including the type of analysis, the number of analytes that are simultaneously determined, the...
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Management Strategy for Seaports Aspiring to Green Logistical Goals of IMO: Technology and Policy Solutions
PublikacjaRecently, because of serious global challenges including the consumption of energy and climate change, there has been an increase in interest in the environmental effect of port operations and expansion. More interestingly, a strategic tendency in seaport advancement has been to manage the seaport system using a model which balances environmental volatility and economic development demands. An energy efficient management system...
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Do clusters help companies to "go green"? Experience of Polish National Key Clusters
PublikacjaThis study aims to explore cluster activity in the field of green transformation, taking into account the green, low-carbon and circular economy. Our intention was to identify the main green practices used by cluster organizations, which we showed through the lens of the attributes of both the cluster and the cluster organization. Through our study, we sought to answer the question: what is the role of cluster organizations in...
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Computational modeling of molecularly imprinted polymers as a green approach to the development of novel analytical sorbents
PublikacjaThe development of novel molecularly imprinted polymers (MIP) sorbents for specific chemical compounds require a lot of tedious and time-consuming laboratory work. Significant quantities of solvents and reagents are consumed in the course of the verification of appropriate configurations of polymerization reagents. Implementation of molecular modeling in the MIP sorbent development process appears to provide a solution to this...
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Carnivorous plants used for green synthesis of silver nanoparticles with broad-spectrum antimicrobial activity
PublikacjaIn this study, we exploit the anti-oxidative potential of four carnivorous plants to produce uniform and biologically active silver nanoparticles. The use of polyvinylpyrrolidone promoted syn-thesis of quasi-spherical nanoparticles characterized by stability and high uniformity. Their activity was tested against three human pathogens and three species of plant pathogenic bacteria. The study demonstrates the influence of synthesis...