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wszystkich: 1995
wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: ammonium iodide
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The domination of ionic conductivity in tetragonal phase of the organometal halide perovskite CH3NH3PbI3-xClx
PublikacjaOrganometal trihalide perovskites have recently gained extreme attention due to their high solar energy conversion in photovoltaic cells. Here, we investigate the contribution of iodide ions to a total conductivity of the mixed lead halide perovskite CH3NH3PbI3−xClx with a use of the modified DC Hebb–Wagner polarization method. It has been identified that an ionic conductivity dominates in tetragonal phase which is associated with room...
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The advanced monitoring as a key factor for appropriate optimization and control of full-scale activated sludge systems – case study Debogorze WWTP.
PublikacjaComputer simulation has become a helpful tool in wastewater treatment systems performance and effectiveness analysis. Advanced monitoring, by using appropriate software, enables to create a mathematical model of a real wastewater treatment plant (WWTP), run a simulation and subsequently interpret results under various conditions. An operation of WWTP is usually controlled by global parameters such as flow, solids retention time,...
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XPS analysis of the GO based materials
Dane BadawczeGraphene oxides samples were measured by XPS method. The X-ray photoemission spectroscopy measurements were carried out with Omicron NanoTechnology UHV equipment. The hemispherical spectrophotometer was equipped with a 128-channel collector. The XPS measurements were performed at room temperature at a pressure below 1.1 × 10−8 mBar. The photoelectrons...
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Thin layer of ordered boron-doped TiO2 nanotubes fabricated in a novel type of electrolyte and characterized by remarkably improved photoactivity
PublikacjaThis paper reports a novel method of boron doped titania nanotube arrays preparation by electrochemical anodization in electrolyte containing boron precursor – boron trifluoride diethyl etherate (BF3 C4H10O), simultaneously acting as an anodizing agent. A pure, ordered TiO2 nanotubes array, as a reference sample, was also prepared in solution containing a standard etching compound: ammonium fluoride. The doped and pure titania...
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Design and synthesis of TiO2/Ti3C2 composites for highly efficient photocatalytic removal of acetaminophen: The relationships between synthesis parameters, physicochemical properties, and photocatalytic activity
PublikacjaIn this study, we report the potential of TiO2/Ti3C2 composite fabricated by oxidation of MXene for degradation of persistent organic pollutants. The effect of the synthesis conditions (time, temperature, and reaction environment) on the morphology, physicochemical properties, and photocatalytic activity was investigated. It was found that acetaminophen degradation was positively correlated with TiO2 content in the composite structure. Furthermore,...
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Evaluation of Partial Nitritation/Anammox (PN/A) Process Performance and Microorganisms Community Composition under Different C/N Ratio
PublikacjaA one-stage partial nitritation/anammox (PN/A) process with intermittent aeration is possible under sidestream conditions, but implementation in a mainstream is a challenge due to increased Carbon/Nitrogen (C/N) ratios in domestic wastewater. This study investigated the effect of C/N ratios on process efficiency and the effect of narrowing non-aeration time on process improvement at high chemical oxygen demand (COD) load. An increase...
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ANALIZA ROZKŁADU POLA MAGNETYCZNEGO WEWNĄTRZ OBIEKTU FERROMAGNETYCZNEGO
PublikacjaW artykule przedstawione zostały wyniki analizy rozkładu natężenia pola magnetycznego wewnątrz obiektu ferromagnetycznego. Obiekt ferromagnetyczny znajdujący się w zewnętrznym polu magnetycznym wywołuje jego zaburzenie, które może być podstawą do wykrycia tego obiektu. Pożądanym zatem jest, aby kompensować to zaburzenie przez zastosowanie cewek kompensujących umieszczonych wewnątrz obiektu. Analiza rozkładu natężenia pola magnetycznego...
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Enhanced visible light photocatalytic activity of Pt/I-TiO2 in a slurry system and supported on glass packing
PublikacjaHighly photoactive I/TiO2, Pt/I-TiO2 nanocomposites were obtained using a hydrothermal and wet impregnation method. The incorporation of iodine and modification with 0.05 mol% of platinum leads to enhanced photocatalytic activity as compared to singly doped TiO2 due to the presence of impurity energy level in the structure of TiO2. X-ray diffraction, TEM microscopy, UV–Vis spectroscopy, X-ray photoelectron spectroscopy and BET...
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Exercise bike powered electric generator for fitness club appliances
PublikacjaA generator powered by a stationary bicycle for the purposes of generating electricity for fitness club appliances is considered. A generator is connected to a stationary bicycle in such a way as the circular rotation of the front wheel rotates the coils of wires inside the generator between the poles of the magnets inside the generator. The resulting Direct Current is channeled to the attached battery bank and converted into different...
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Excitation energy migration in uniaxially oriented polymer films.
PublikacjaPrzedstawiono wyniki pomiarów i symulacji Monte Carlo anizotropii emisji dla procesu bezpromienistego transportu energii w orientowanych osiowo foliach polimerowych. Badany układ stanowiły molekuły DTCI (3,3´-diethylthiacarbocyamine iodine) umieszczony w folii PVA (poliwinyl). Za przestrzenny rozkład orientacji dipoli emisji molekuł w symulacjach Monte Carlo przyjęto rozkład Tanizaki.
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Powder x-ray diffraction pattern of polycrystalline Cu(IO3)2*xH2O
Dane BadawczeHydrated copper(II) iodate sample was prepared in water solution by reacting copper(II) sulfate and potassium iodate, following the method described by Peterson (J. Chem. Educ. 1957, 34, 12, 612). The sample was subsequently dried at various temperatures in order to produce an anhydrous Cu(IO3)2:
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Influence of selected submicron inorganic particles on mechanical and thermo-mechanical properties of unsaturated polyester/glass composites
PublikacjaIn this paper, the influence of different submicron-scaled particles (zinc oxide, titanium dioxide, or silica) on mechanical and thermo-mechanical properties of unsaturated polyester matrix composites reinforced with glass fabric was investigated. Surface morphology of obtained composites was also examined. At first inorganic particles were mechanically dispersed into unsaturated polyester resin system as per the calculated weight...
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Linking optical and electronic properties to photoresponse of heterojunctions based on titania nanotubes and chromium, molybdenum, and tungsten oxides
PublikacjaThe development of photosensitization strategies for titanium dioxide is necessary for the enhancement of its optical and electronic properties towards its application potential in solar photoelectrochemistry. In this work, significant differences in the photosensitizing capability of the 6th group transition metal oxides applied on the surface of titania nanotubes are reported. For the first time, correlations between the experimentally...
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ADAPTATION OF THE ACTIVATED SLUDGE TO THE DIGESTATE LIQUORS DURING THE NITRIFICATION AND DENITRIFICATION PROCESSES
PublikacjaThe activated sludge process of the digestate liquors after chemical separation was conducted using a 10 L lab-scale sequencing batch reactor (SBR) and a 0.50 m3 pilotscale SBR independently (with pH control). Due to the relatively high concentration of free ammonia (FA), clear inhibitory effects of the digestate liquors on the nitrifying bacteria were observed. The adaptation of the activated sludge to the toxicity was evaluated...
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Galvanostatic cycling with potential limitation (GCPL) of WS2/userGOx (composites of tungsten disulfide and ultrafast self-expanded and reduced graphene oxide) and ex-WS2 (exfoliated tungsten disulfide)
Dane BadawczeThese data contain results of galvanostatic cycling with potential limitation (GCPL) of WS2/userGOx (composites of tungsten disulfide and ultrafast self-expanded and reduced graphene oxide) and ex-WS2 (exfoliated tungsten disulfide). The data were collected for samples obtained from three ex-WS2:GO dispersions - with 1:1, 1:2, and 2:1 weight ratios.
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TEM data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Dane BadawczeThis Dataset include presentation of summarized TEM investigation of (Mn,Co,Fe,Ni,Cr)3O4 high-entropy spinel oxide prepared in the form of a ~ 500 nm thin film utilising a facile spray pyrolysis technique. The structural and electrical properties of the layers were characterised after exposure to temperatures in the range of 400–900 ◦C. The as-deposited...
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X-Ray Computer Tomography Study of Degradation of the Zircaloy-2 Tubes Oxidized at High Temperatures
PublikacjaThe investigations of high-temperature oxidation of zirconium alloys, applied for fuel pellets in nuclear power plants, are usually limited to oxidation kinetics, phase transformations and microstructural characterization. The purpose of this research was to characterize the degradation phenomena occurring within oxide layer and at the interface oxide/metal, on internal and external Zircaloy-2 tube...
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Optimization of Hydrogen - Evolving Photochemical Molecular Devices
PublikacjaA molecular photocatalyst consisting of a RuII photocenter, a tetrapyridophenazine bridging ligand, and a PtX2 (X=Cl or I) moiety as the catalytic center functions as a stable system for light-driven hydrogen production. The catalytic activity of this photochemical molecular device (PMD) is significantly enhanced by exchanging the terminal chlorides at the Pt center for iodide ligands. Ultrafast transient absorption spectroscopy...
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Sławomir Milewski prof. dr hab. inż.
OsobySławomir Milewski, urodzony w 1955 r. w Pucku (woj. pomorskie), ukończył w 1979 r. studia magisterskie na kierunku Chemia, w specjalności Chemia i Technologia Organiczna, na Wydziale Chemicznym PG. Po ukończeniu Studium Doktoranckiego w 1984 r., został zatrudniony na macierzystym wydziale w Katedrze Technologii Leków i Biochemii, początkowo na stanowisku naukowo-technicznym, a od r. 1986 jako nauczyciel akademicki. W 1985 r. uzyskał...
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Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile
PublikacjaDensities of some acetonitrile solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octylmorpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide were measured at T = (298.15− 318.15) K and at atmospheric pressure....
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Electrolytic deposition of reactive element thin films on Crofer 22 APU and evaluation of the resulting high-temperature corrosion protection properties at 700 °C–900 °C
PublikacjaThis article presents electrolytic deposition of thin Rare Earth (RE) coatings on Crofer 22 APU stainless steel substrates for high temperature applications, such as interconnects in solid oxide cell stacks. The deposition of coatings based on yttrium-, gadolinium-, lanthanum-, and cerium nitrates is discussed. The high temperature corrosion properties of surface-modified steels were examined using thermogravimetry and electrical...
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Reactivity of Phosphanylphosphinidene Complex of Tungsten(VI) toward Phosphines: A New Method of Synthesis of catena-Polyphosphorus Ligands
PublikacjaThe reactivity of an anionic phosphanylphosphinidene complex of tungsten(VI), [(2,6-i-Pr2C6H3N)2(Cl)- W(η2-t-Bu2P=P)]Li·3DME toward PMe3, halogenophosphines, and iodine was investigated. Reaction of the starting complex with Me3P led to formation of a new neutral phosphanylphosphinidene complex, [( 2,6-i-Pr2C6H3N)2(Me3P)W(η2-t-Bu2P=P)]. Reactions with halogenophosphines yielded new catena-phosphorus complexes. From reaction with...
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Potentiometric Oxygen Sensor with Solid State Reference Electrode
PublikacjaThe concentration or the partial pressure of oxygen in an environment can be determined using different measuring principles. For high temperature measurements of oxygen, ceramic-based sensors are the most practical. They are simple in construction, exploration and maintenance. A typical oxygen potentiometric sensor consists of an oxygen ion conducting solid electrolyte and two electrodes deposited...
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Dependence between Ionic Liquid Structure and Mechanism of Visible-Light-Induced Activity of TiO2 Obtained by Ionic-Liquid-Assisted Solvothermal Synthesis
PublikacjaBecause of the tremendous structural diversityof ionic liquids (ILs), simple transfer of observations performed for one IL used for IL-TiO2 preparation on different samples is not possible. Therefore, four ionic liquids, all containing distinct nitrogen-bearing organic cations (pyridinium, pyrrolidinium, ammonium, imidazolium), were used for the first time for the preparation of IL-TiO2 composites. The role of the individual IL...
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Phosphorus and nitrogen forms in liquid fraction of digestates from agricultural biogas plants
PublikacjaThe novelty of the presented research is the determination of the nitrogen and phosphorus fraction in the liquid fraction of digestate from agricultural biogas plants. This information is important because it can help in proposing possible further liquid fraction management or developing of new technologies for their purification. The research covered digestates from agricultural biogas plants, obtained from the fermentation of...
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Modeling nutrient removal and energy consumption in an advanced activated sludge system under uncertainty
PublikacjaActivated sludge models are widely used to simulate, optimize and control performance of wastewater treatment plants (WWTP). For simulation of nutrient removal and energy consumption, kinetic parameters would need to be estimated, which requires an extensive measurement campaign. In this study, a novel methodology is proposed for modeling the performance and energy consumption of a biological nutrient removal activated sludge system...
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Case study of water vapour transmission properties of EPDM façade membranes
PublikacjaThis research aimed to investigate the water vapour transmission properties of chosen EPDM membranes applied in façade and window systems under laboratory tests. The applied procedure included in national and international standards utilized for the laboratory tests of water vapour transmission properties of EPDM membrane is described. Two main types (outside and inside types) of EPDM membranes are laboratory tested. The authors...
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Efficient Selenenylation of Malonates Using Bis(phosphorothioyl) Diselenide
PublikacjaBis(O,O-diisopropoxyphosphinothioyl) diselenide reacts readily and quickly with the sodium salt of malonates to give quantitatively stable sodium 2-(O,O-diisopropyl phosphorothioselenenyl)propanedioates. No traces of the corresponding C,C-diselenenylation products were detected. A standard aqueous workup procedure affords the products, albeit in poor yield (about 45%). It was proved that the reaction is reversible due to the presence...
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SEM/EDX data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Dane BadawczeThis Data set include SEM and EDX results of (Mn,Co,Fe,Ni,Cr)3O4 high-entropy spinel oxide prepared in the form of a ~ 500 nm thin film utilising a facile spray pyrolysis technique. The structural and electrical properties of the layers were characterised after exposure to temperatures in the range of 400–900 ◦C. The as-deposited layers were amorphous,...
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Curing behavior of epoxy/Fe 3 O 4 nanocomposites: A comparison between the effects of bare Fe 3 O 4 , Fe 3 O 4 /SiO 2 /chitosan and Fe 3 O 4 /SiO 2 /chitosan/imide/phenylalanine-modified nanofillers
PublikacjaIn this study, Fe3O4 magnetic nanoparticles (MNPs) were synthesized (B-MNP) and then modified with SiO2 to form Fe3O4/SiO2 core/shell MNPs. The Fe3O4/SiO2 MNPs were chemically functionalized with chitosan so as to gain Fe3O4/SiO2/Chitosan (CH-MNP). The CH-MNP was functionalized with a macromolecule containing imide and phenylalanine precursors to gain Fe3O4/SiO2/Chitosan/imide/phenylalanine based MNPs (CH-IM-MNP). The differences...
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Fast Fading Characterization for Body Area Networks in Circular Metallic Indoor Environments
PublikacjaWith the increasing development of 5G and Body Area Network based systems being implemented in unusual environments, propagation inside metallic structures is a key aspect to characterize propagation effects inside ships and other similar environments, mostly composed of metallic walls. In this paper, indoor propagation inside circular metallic structures is addressed and fast fading statistical distributions parameters are obtained...
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New insights into modeling two-step nitrification in activated sludge systems – The effects of initial biomass concentrations, comammox and heterotrophic activities
PublikacjaIn this study, the conventional two-step nitrification model was extended with complete ammonia oxidation (comammox) and heterotrophic denitrification on soluble microbial products. The data for model calibration/validation were collected at four long-term washout experiments when the solid retention time (SRT) and hydraulic retention time (HRT) were progressively reduced from 4 d to 1 d, with mixed liquor suspended solids (MLSS)...
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Solvation of ionic liquids based on N -methyl- N -alkylmorpholinium cations in N,N -dimethylformamide and N,N -dimethylacetamide – Volumetric and compressibility studies
PublikacjaDensity and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl- morpholinium cations: N-ethyl- -methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-Nmethylmorpholinium bis(trifluoromethanesulfonyl)imide, N-octyl-N-methyl -morpholinium bis(trifluor omethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in N, N-dimethylformamide and N,N-dimethylacetamide were...
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High-temperature kinetics study of 430L steel powder oxidized in air at 600–850 °C
PublikacjaThe 430L stainless steel powder with a mean particle size of 95 μm was studied to determine its high-temperature oxidation properties. Continuous thermogravimetric measurements were carried out for 100 h in air at temperatures in the range of 600–850 °C. Even though a considerable amount of Cr (up to ˜5 wt.% Cr) inside the grains was depleted – especially inside small grains – no breakaway oxidation was observed. This indicates...
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Revalorization of the Szewalski binary vapour cycle
PublikacjaThe aim of the paper is to revalorizate of the Szewalski binary vapour cycle by analysing thermodynamical and operational parameters of this cycle. This was carried by accessible numerical CFM (Computational Flow Mechanics) codes type, by step-by-step modeling of separates apparatus. The binary vapour cycle is providing steam as the working fluid in the high temperature part of the cycle, while another fluid - a low boiling point...
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Analytical fluctuation enhanced sensing by resistive gas sensors
PublikacjaResistance fluctuations across polarised resistive gas sensors were studied in detail to evaluate sensor working conditions for detecting methane and ammonia at various concentrations. The 1/f noise component typically dominates other noise sources up to a few kHz and can be utilised to improve gas selectivity when compared with measurements of the sensor DC resistance. The Arrhenius plot was created and the activation energy for...
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Low-Coherence Interferometric Fiber-Optic Sensors with Potential Applications as Biosensors
PublikacjaFiber-optic Fabry-Pérot interferometers (FPI) can be applied as optical sensors, and excellent measurement sensitivity can be obtained by fine-tuning the interferometer design. In this work, we evaluate the ability of selected dielectric thin films to optimize the reflectivity of the Fabry-Pérot cavity. The spectral reflectance and transmittance of dielectric films made of titanium dioxide (TiO2) and aluminum oxide (Al2O3) with...
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Low-Coherence Interferometric Fiber-Optic Sensors with Potential Applications as Biosensors
PublikacjaFiber-optic Fabry-Pérot interferometers (FPI) can be applied as optical sensors, and excellent measurement sensitivity can be obtained by fine-tuning the interferometer design. In this work, we evaluate the ability of selected dielectric thin films to optimize the reflectivity of the Fabry-Pérot cavity. The spectral reflectance and transmittance of dielectric films made of titanium dioxide (TiO2) and aluminum oxide (Al2O3) with...
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Influence of titanium layer on counter electrode on electrical parameters of DSSC
PublikacjaIn this paper the influence of the Ti layer thickness at counter-electrode on electrical parameters of DSSCs was examined. The transparent conductive oxide – less (TCO-less) counter electrodes (CE) with titanium layers and platinum as catalyst on Bk7 glass were prepared. Thin metallic films were deposited by means of magnetron sputtering (titanium) and Pulsed Laser Deposition (platinum). The counter electrode with Pt layer on Fluorine...
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Total electrical conductivity data of (Cr,Fe,Mn,Co,Ni)3O4 High-entropy spinel oxide thin films deposited on amorphous SiO2 substrate by spray pyrolysis techniqe
Dane BadawczeThis dataset includes electrical conductivity measurements results measured by van der pauw technique up to 900oC.
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Evaluation of Immobilization of Selected Peat-Isolated Yeast Strains of the Species Candida albicans and Candida subhashii on the Surface of Artificial Support Materials Used for Biotrickling Filtration
PublikacjaThe paper describes the process of n-butanol abatement by unicellular fungi, able to deplete n-butanol content in gas, by using n-butanol as source of carbon. Isolated and identified fungi species Candida albicans and Candida subhashii were subjected to a viability process via assimilation of carbon from hydrophilic and hydrophobic compounds. The isolates, which exhibited the ability to assimilate carbon, were immobilized on four...
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Surprising Radiolytic Stability of 8‑Thiomethyladenine in an Aqueous Solution
Publikacja8-Thiomethyladenine (ASCH3), a potentially radiosensitizing modified nucleobase, has been synthesized in a reaction between 8-thioadenine and methyl iodide. Despite favorable dissociative electron attachment (DEA) characteristics, the radiolysis of an aqueous solution of ASCH3 with a dose of X-ray amounting to as much as 300 Gy leads to no effects. Nevertheless, crossed electron-molecule beam experiments in the gas phase on ASCH3...
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IOSiE sem II ćw. - Matematyka 2023/2024 (D.Żarek)
Kursy Online -
Krzysztof Szarf dr inż.
Osoby -
XPS measurement of the Fe-Ti based materials
Dane BadawczeThe mono‐ and bimetal‐modified (Pd, Cu) titanium(IV) oxide and iron oxide (III) photocatalysts were prepared by chemical reduction method and characterized using XPS method. The composition of elements incorporated in the surface layer of mono- and bimetallic photocatalysts was determined by XPS analysis, as well as the valence state of elements. Measurements...
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Application of vertical flow constructed wetlands for highly contaminated wastewater treatment: preliminary results
PublikacjaBasing on quantitative and qualitative characteristics of reject waters (RWC) generated during dewatering of digested sewage sludge on centrifuges in conventional WWTP and municipal landfill leachate (LL), the pilot constructed wetlands for treatment of both types wastewater were designed and built. In the paper the conception, design and assumed treatment efficiencies of the pilot plants are presented. The water balance of the...
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How thermal stability of ionic liquids leads to more efficient TiO2-based nanophotocatalysts: Theoretical and experimental studies
PublikacjaIonic liquids (ILs) containing distinct nitrogen-bearing organic cations (pyridinium, pyrrolidinium, imidazolium, ammonium, morpholinium) were first used for the preparation of 23 IL-TiO2 types of composites by ionic liquid assisted solvothermal synthesis. These 23 optimal ILs structures (i.e. compounds exhibiting an optimal combination of specific properties, functionality, and safety) for synthesis and experimental validation...
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The dispersive micro-solid phase extraction method for MS-based lipidomics of human breast milk*
PublikacjaA simple and rapid microextraction method ensuring high lipidome coverage was developed for liquid chromatography mass spectrometry (LC-MS)-based lipidomics of human breast milk. The dispersive microsolid phase extraction (D-µ-SPE) technique, coupled with the design of experiment (DoE) method, enabled the study of the influence of several conditions (desorption solvent, stationary phase ratio, and sorption and desorption time)...
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Denitrifcation rate in the mainstream deammonification
PublikacjaThe conventional processes of biological nitrogen removal based on nitrification and denitrification does not fit properly into the concept of the circular economy. As the alternative one should consider the deammonification process, which is a combination of partial nitrification (nitritation) and Anammox processes. It consists of removing ammonium nitrogen from wastewater under anaerobic conditions by a group of autotrophic microorganisms....
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The Use of Sensory Analysis Techniques to Assess the Quality of Indoor Air
PublikacjaThe quality of indoor air is one of the significant elements that influences people's well-being and health inside buildings. Emissions of pollutants, which may cause odor nuisance, are the main reason for people's complaints regarding the quality of indoor air. As a result, it is necessary to perform tests aimed at identifying the sources of odors inside buildings. The article contains basic information on the characteristics...