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Search results for: ARENE RUTHENIUM COMPLEX
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A memory efficient and fast sparse matrix vector product on a Gpu
PublicationThis paper proposes a new sparse matrix storage format which allows an efficient implementation of a sparse matrix vector product on a Fermi Graphics Processing Unit (GPU). Unlike previous formats it has both low memory footprint and good throughput. The new format, which we call Sliced ELLR-T has been designed specifically for accelerating the iterative solution of a large sparse and complex-valued system of linear equations arising...
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Kompleksowa analiza symulacyjna układu napędowego zespołu trakcyjnego
PublicationThe paper describes an approach to comprehensive analysis of traction electric drive. The drivetrain of ED-74 electric unit equipped with four inverter-fed induction motors was modeled in Matlab/Simulink. The model consists of functional blocks as: motors, inverters, drive controllers, filters. Structure and operation of the model was described. Chosen simulation results were presented and discussed. Two methods of modeling the...
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Comparative Greenness Evaluation
PublicationGreenness of analytical procedure is multivariable aspect as many greenness criteria should be taken into consideration. On the other hand, modern analytical chemistry offers dozens of analytical procedures, based on different sample preparation and final determination techniques that are used for the determination of a given analyte in a given matrix. For such complex decision-making processes, multi-criteria decision analysis...
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Interference aware bluetooth scatternet (re)configuration algorithm IBLUERA
PublicationThis paper presents a new algorithm IBLUEREA, which enables reconfiguration of Bluetooth scatternet to reduce interference. IBLUEREA makes use of the complex model comparing ISM environment efficiency. The mechanism envisages the use of the assessment of the probability of successful (unsuccessful) frame transmission in order to take a decision concerning co-existence of technologies which make use of the same ISM band (here Bluetooth...
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Compact antenna array comprising fractal-shaped microstripradiators
PublicationA design method of antenna array consisting of eight microstrip patches modified with Sierpinski fractal curves has been presented andexperimentally validated in this paper. Method proposed has enabled the achievement of considerable miniaturization of array length (26%),together with multi-band behavior of the antenna, which proves the attractiveness of presented design methodology and its ability to be implemented in more complex...
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Free-surface elevation in open vortex flow controls
PublicationRotational form of fluid motion is complex, but very important in science and technology. The paper is devoted to the hydraulic mechanism of flow in open vortex flow controls, or regulators. The velocity field was described by the kinematic model, and intensity of rotation - by means of the energy balance between the input and dissipation. In consequence some algebraic expresions were obtained, which can be useful in approximated...
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Anticancer Study on IrIII and RhIII Half-Sandwich Complexes with the Bipyridylsulfonamide Ligand
PublicationTwo non-platinum compounds, organometallic half-sandwich complexes [(η 5 -Cp)IrCl(L)]PF 6 (1) and [(η 5 -Cp)RhCl(L)]PF 6 (2) were prepared by treating pentamethylcyclopentadienyl chloride dimers of iridium(III) or rhodium(III) with the obtained 4-amino-N-(2,2'-bipyridin-5- yl)benzenesulfonamide ligand (L) and ammonium hexafluorophosphate. The crystal structures of ligand (L) and complexes 1 and 2 were obtained and then analyzed. Coordination...
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DBpedia and YAGO as Knowledge Base for Natural Language Based Question Answering—The Evaluation
PublicationThe idea of automatic question answering system has a very long history. Despite constant improvement of the systems asking questions in the natural language requires very complex solutions. In this paper the DBpedia and YAGO are evaluated as a knowledge bases for simple class 1 and 2 question answering system. For this purpose a question answering system was designed and implemented. The proposed solution and the knowledge bases...
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Fatigue behaviour of SLM maraging steel under variable-amplitude loading
PublicationOne of the most challenging issues for additive manufactured materials is fatigue endurance. Engineering components often operate under complex, variable amplitude loadings, in which existing technological imperfections promote fatigue cracks growth and damage of elements eventually. In this study the effects of different variable-amplitude strain levels on fatigue life, 18Ni300 steel was tested. The work presents various behaviours...
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Rational method of grit chamber efficiency determination
PublicationAlthough grot chambers are designed with utmost care, they still remain difficuly to control. As concentration of grit is non-uniform, representative measurements of the sand concentration is a very complex issue. In the paper the results of measure,ents performed at WTP in Gdańsk and Gdynia were analyzed. The proposed method to determine grit chambers efficiency is based on comparison of suspension flow in the inlet and flux of...
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Applying Generative Modelling Tools to Explore Architectural Forms
PublicationThe digital generative methods open up new areas for exploration of formal and tectonic features, accentuate form’s ability to emerge and perform. They allow for automatic generation of variations of solutions, and digital production of “difficult” components of architectural forms using CNC technology.The paper deals with contemporary architectural explorations of complex , curvilinear surfaces in the context of generative...
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Engineering Analysis with ANSYS Software Second Edition
PublicationThe best way to learn complex systems is by means of hands-on experience. With an innovative and clear tutorial based approach, this powerful book provides a comprehensive introduction to the fundamental areas of engineering analysis needed on research or commercial engineering projects. With its detailed step-by-step explanations and sample problems, this book will develop the reader's understanding of FEA and their ability to...
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Defining a novel domain that provides an essential contribution to site-specific interaction of Rep protein with DNA
PublicationAn essential feature of replication initiation proteins is their ability to bind to DNA. In this work, we describe a new domain that contributes to a replication initiator sequence-specific interaction with DNA. Applying biochemical assays and structure prediction methods coupled with DNA–protein crosslinking, mass spectrometry, and construction and analysis of mutant proteins, we identified that the replication initiator of the...
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Closer look into the structures of tetrabutylammonium bromide–glycerol-based deep eutectic solvents and their mixtures with water
PublicationIn recent years, deep eutectic solvents (DES) and it’s mixture with water have become more and more attention as green solvents used in chemistry. However, there are only a few theoretical studies on the mechanisms of pure DES and DES-water complex formation. Therefore, the structural properties of tetrabutylammonium bromide–glycerol-based deep eutectic solvents and their mixtures with water have been investigated by means of Molecular...
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Diagnostics and monitoring of the longest span extradosed bridge in Europe
PublicationThe article presents complex diagnostic procedures applied for the purpose of behavior analysis of the extradosed bridge with the longest span in Europe that was built in 2018 in Poland. The system of health monitoring was used to: register internal forces in temporary supports, monitor concrete bonding, perform in situ diagnostics and operation tests. The bridge is a continuous four-span structure with spans theoretical lengths...
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Tailoring optical constants of few-layer black phosphorus coatings: Spectroscopic ellipsometry approach supported by ab-initio simulation
Publication2D black phosphorus (BP) has attracted extensive attention as an anisotropic platform for novel optoelectronic and polarizing optics applications. Insight into the factors that tune the optical and polarizing properties of 2D BP reveals their essential influence on BP-based photonic and optoelectronic devices. In this work, studies of the optical constants of few-layer black phosphorus coatings are studied and discussed, with particular...
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An Efficient PEEC-Based Method for Full-Wave Analysis of Microstrip Structures
PublicationThis article introduces an efficient method for the equivalent circuit characterization and full-wave analysis of microstrip structures, leveraging the full-wave partial element equivalent circuit (PEEC). In particular, the multilayered Green's function is evaluated using the discrete complex-image method (DCIM) and employed to establish the mixed potential integral equations. The proposed strategy considers time delays for the...
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Testing Situation Awareness Network for the Electrical Power Infrastructure
PublicationThe contemporary electrical power infrastructure is exposed to new types of threats. The cause of such threats is related to the large number of new vulnerabilities and architectural weaknesses introduced by the extensive use of Information and Communication Technologies (ICT) in such complex critical systems. The power grid interconnection with the Internet exposes the grid to new types of attacks, such as Advanced Persistent...
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A new approach to determination of the two-mass model parameters of railway current collector
PublicationThe paper presents two mathematical models of railway current collectors both with two degrees of freedom. The first one, hereinafter Pantograph Articulated Model (PAM), has one degree of freedom in rotational motion and the second degree of freedom in translational motion. The second model, called henceforth as Pantograph Reference Model (PRM), has both degrees of freedom in translational motion. Differential equations of the...
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A new approach to determination of the two-mass model parameters of railway current collector
PublicationThe paper presents two mathematical models of railway current collectors both with two degrees of freedom. The first one, hereinafter Pantograph Articulated Model (PAM), has one degree of freedom in rotational motion and the second degree of freedom in translational motion. The second model, called henceforth as Pantograph Reference Model (PRM), has both degrees of freedom in translational motion. Differential equations of the...
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New bis(azobenzocrown)s with dodecylmethylmalonyl linkers as ionophores for sodium selective potentiometric sensors
PublicationNovel biscrowns 1 and 2 were synthesized from 13-membered azobenzocrown ethers containing bromoalkylenoxy chains in para position relative to the azo group. The synthesized diester molecules are dodecylmethylmalonic acid derivatives differing by the linker length. The synthesized compounds have the potential of being used as sodium ionophores in ion-selective electrodes. They were characterized and used as ionophores in classic...
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Ipertrofan Revisited—The Proposal of the Complete Stereochemistry of Mepartricin A and B
PublicationBeing a methyl ester of partricin, the mepartricin complex is the active substance of a drug called Ipertrofan (Tricandil), which was proven to be useful in treatment of benign prostatic hyperplasia and chronic nonbacterial prostatitis/chronic pelvic pain syndrome. Nevertheless, no direct structural evidence on the stereochemistry of its components has been presented to date. In this contribution, we have conducted detailed, NMR-driven...
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In Vitro Biological Characterization of Silver-Doped Anodic Oxide Coating on Titanium
PublicationDespite the high biocompatibility and clinical effectiveness of Ti-based implants, surface functionalization (with complex osteointegrative/antibacterial strategies) is still required. To enhance the dental implant surface and to provide additional osteoinductive and antibacterial properties, plasma electrolytic oxidation of a pure Ti was performed using a nitrilotriacetic acid (NTA)-based Ag nanoparticles (AgNP)-loaded calcium–phosphate...
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Studying the Behaviour of Pedestrians and Drivers Within Pedestrian Crossings
PublicationEvery third road accident in Poland involves a pedestrian as a participant or, most of the time, a casualty. Pedestrian accidents are usually the result of complex situations and the outcome of a number of factors related to driver and pedestrian behaviour and road infrastructure. Safety depends largely on how well the traffic condition is perceived and on visibility in traffic. The re-lations between pedestrians and motorists...
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A New Approach to Stability Evaluation of Digital Filters
PublicationIn this paper, a new numerical method of evaluating digital filter stability is presented. This approach is based on novel root-finding algorithms at the complex plane using the Delaunay triangulation and Cauchy's Argument Principle. The presented algorithm locates unstable zeros of the characteristic equation with their multiplicities. The proposed method is generic and can be applied to a vast range of systems. Verification of...
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Hybrid approach to ontology specification and development
PublicationIn this chapter a first draft of a hybrid ontology development approach is presented. The context of this method encompasses the multi-agent system equipped with knowledge bases and inferring engine. The process of ontology engineering appears as a complex issue, as it addresses different point-views of both, a client and a modeler with a requirements/system analyst. Regarding this, an approach based on the knowledge preprocessing...
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Quaternion Encryption Method for Image and Video Transmission
PublicationQuaternions are hyper-complex numbers of rank 4. They are often applied to mechanics in 3D space and are considered to be one of the best ways of representing rotations. In this paper a quaternion encryption method, based on algorithm by Nagase et al. (2004) has been proposed. According to a computer-based simulation the results of the performed research yield a high level of security, which is additionally strengthened by the...
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Hybrid Approach to Networked Control System
PublicationEffcient control of Networked Control System (NCS) is a challenge, as the control methods need to deal with non-deterministic variable delays and data loss. This paper presents a novel hybrid approach to NCS where Model Predictive Control (MPC) is applied as a main controller and implicit switching MPC is used for data transmission control in event-driven shared communication medium, leading to complex control system with active...
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An Analysis of Elliptical-Rectangular Patch Structure on Multilayer Elliptic Cylinders
PublicationThe resonance frequency problem of an ellipticalrectangular patch mounted on multilayered dielectric coated elliptic conducting cylinder, is investigated in this paper. A fullwave analysis and a moment-method calculation are employed. The analysis is carried out considering the expansion of the field as a series of Mathieu functions. An additional theorem for Mathieu functions is utilized to investigate the non-confocal ellipse...
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Curlicues generated by circle homeomorphisms
PublicationWe investigate the curves in the complex plane which are generated by sequences of real numbers being the lifts of the points on the orbit of an orientation preserving circle homeomorphism. Geometrical properties of these curves such as boundedness, superficiality, local discrete radius of curvature are linked with dynamical properties of the circle homeomorphism which generates them: rotation number and its continued fraction...
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CHANGES TAKING PLACE IN THE KINETIC ARCHITECTURE OVER THE 20TH AND 21ST CENTURIES
PublicationKinematics has accompanied architecture from its beginning and is strongly associated with its evolution. Over the centuries, it has changed form and function. However, its rank grew at the beginning of the 20th century. Along with the widespread change of the design method in the early 90s of the twentieth century, its forms have become more complex. The study showed that with the development of design techniques, this time should be...
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Mobile devices and computing cloud resources allocation for interactive applications
PublicationUsing mobile devices such as smartphones or iPads for various interactive applications is currently very common. In the case of complex applications, e.g. chess games, the capabilities of these devices are insufficient to run the application in real time. One of the solutions is to use cloud computing. However, there is an optimization problem of mobile device and cloud resources allocation. An iterative heuristic algorithm for...
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INFLUENCE OF INLET GEOMETRY ON THE EFFICIENCY OF 1MW STEAM TURBINE
PublicationThe process of the design of the 1MW steam turbine includes designing the stator and rotor blades, the steam turbine inlet and exit, the casing and the rotor. A turbine that operates at rotation speeds other than 3000 rpm requires a gear box and generator with complex electronic software. This paper analyses the efficiency of eight turbine variants, including seven inlet geometries and three stages of stator as well as an eight...
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The relationship between architectural detail and light in contemporary architecture
PublicationThe paper deals with the influence of modern artificial and natural lighting technology on contemporary architecture, especially in relation to architectural detail. Advanced complex lighting systems have an increasing importance in contemporary design solutions. Light itself, and the effect of its actions, and characteristic parts of the sophisticated lighting systems, play an essential role as independent architectural elements,...
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Arch footbridge over Warta river in Wronki - design and construction
PublicationThe paper presents the concept of dynamic redesign of lively footbridge. The goal was to reduce probable dynamic excitation and change detailed structural concept. After the complex study the new design was created. In effect completely new static and dynamic properties were reached. Static and dynamic assumptions are explainde. General information, photos and drawings are presented. The final price of the project amounted to 1.25...
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Mashup Approaches for Improving Service Oriented Business Scenarios
PublicationTwo kinds of business scenarios are considered: application- and service-oriented. It is shown that the former are more flexible and easier reconfigurable for both traditional (human-oriented) and IT services. Moreover, complex IT services can be created by simple IT services using the modern mashup technology. It is the reason why such business scenarios can be modeled by BPMN in much easier ways. A simple example of a supply...
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Collaborative urban studios in Poland. Teaching collective problem solving via live projects
PublicationThe requirements of contemporary architectural and urban design practice places a growing importance on the ability to generate new solutions to complex design challenges. Such an approach is particularly relevant in the context of contemporary urban projects in need of urban innovation and socially engaged practice, i.e. urban regeneration or street quality improvement projects. Meaningful involvement in such topics requires a...
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Method-Dependent Epidemiological Cutoff Values for Detection of Triazole Resistance in Candida and Aspergillus Species for the Sensititre YeastOne Colorimetric Broth and Etest Agar Diffusion Methods
PublicationAlthough the Sensititre Yeast-One (SYO) and Etest methods are widely utilized, interpretive criteria are not available for triazole susceptibility testing of Candida or Aspergillus species. We collected fluconazole, itraconazole, posaconazole, and voriconazole SYO and Etest MICs from 39 laboratories representing all continents for (method/agent-dependent) 11,171 Candida albicans, 215 C. dubliniensis, 4,418 C. glabrata species complex,...
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Structural and dynamic insights on the EmrE protein with TPP+ and related substrates through molecular dynamics simulations
PublicationEmrE is a bacterial transporter protein that forms an anti-parallel homodimer with four transmembrane helices in each monomer. EmrE transports positively charged aromatic compounds, such as TPP+ and its derivatives. We performed molecular dynamics (MD) simulations of EmrE in complex with TPP+, MeTPP+, and MBTPP+ embedded in a membrane. The detailed molecular properties and interactions were analysed for all EmrE-ligand complexes....
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Metals and metal-binding ligands in wine: Analytical challenges in identification.
PublicationBackground Due to important role of metals in the vinification process as well as their impact on the human health, their content in this alcoholic beverage has been extensively studied by many researchers. It is already known that speciation of metals determines their toxicity and bioavailability as well as influences their activity. Understanding the chemistry and knowing the structures of metal complexes could have relevant...
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Urban scene semantic segmentation using the U-Net model
PublicationVision-based semantic segmentation of complex urban street scenes is a very important function during autonomous driving (AD), which will become an important technology in industrialized countries in the near future. Today, advanced driver assistance systems (ADAS) improve traffic safety thanks to the application of solutions that enable detecting objects, recognising road signs, segmenting the road, etc. The basis for these functionalities...
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A study on the interaction of rhodamine B with methylthioadenosine phosphorylase protein sourced from an Antarctic soil metagenomic library.
PublicationThe presented study examines the phenomenon of the fluorescence under UV light excitation (312 nm) of E. coli cells expressing a novel metagenomic-derived putative methylthioadenosine phosphorylase gene, called rsfp, grown on LB agar supplemented with a fluorescent dye rhodamine B. For this purpose, an rsfp gene was cloned and expressed in an LMG194 E. coli strain using an arabinose promoter. The resulting RSFP protein was purified...
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A high-accuracy method of computation of x-ray waves propagation through an optical system consisting of many lenses
PublicationThe propagation of X-ray waves through an optical system consisting of many X-ray refractive lenses is considered. Two differential equations are contemplated for solving the problem for electromagnetic wave propagation: first – an equation for the electric field, second – an equation derived for a complex phase of an electric field. Both equations are solved by the use of a finite-difference method. The simulation error is estimated...
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Colloidal transport of lipid digesta in human and porcine small intestinal mucus
PublicationSmall intestinal mucus transport of food-derived particulates has not been extensively studied, despite mucus being a barrier nutrients need to cross before absorption. We used complex dispersions of digesta obtained from simulated, dynamic gastrointestinal digestion of yogurt to examine the penetrability of human and porcine mucus to the particles formed of lipolysis products. Quantitative, time-lapse confocal microscopy revealed...
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Assessment of dynamic characteristics of thin cylindrical sandwich panels with magnetorheological core
PublicationBased on the equivalent single-layer linear theory for laminated shells, free and forced vibrations of thin cylindrical sandwich panels with magnetorheological core are studied. Five variants of available magnetorheological elastomers differing in their composition and physical properties are considered for smart viscoelastic core. Coupled differential equations in terms of displacements based on the generalized kinematic hypotheses...
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Time domain model of the resonance-based electromagnetic pulses emission system
PublicationIn the literature, the emission properties of the electromagnetic field pulse systems based on high voltage antennas (HVR) have been widely described. In order to increase the emission efficiency by extending duration and increasing amplitude of the impulse it is possible to use a resonance system tuned to the parameters of the signal shaped in the pulse forming circuit. The synthesis of a time-domain simulation model of a complex...
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Price Diversification
PublicationThe price diversification is a complex phenomenon. We show that price discrimination can have both positive and negative effects. The final result depends whether it makes competition more intense. As far as legal procedure is cocerned it is recommended to focus on the effects of compan's actions rather than on the form that these actions may take. There is a need to understand and distinguish between price discrimination as the...
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Propagation in the Open Cylindrical Guide of Arbitrary Cross Section With the Use of Field Matching Method
PublicationA simple solution to propagation problem in open waveguides and dielectric fibers of arbitrary convex cross section is presented. The idea of the analysis is based on the direct field matching technique involving the usage of the field projection at the boundary on a fixed set of orthogonal basis functions. A complex root tracing algorithm is utilized to find the propagation coefficients of the investigated guides. Different convex...
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Understanding Knowledge-Intensive Business Services. Identification, Systematization, and Characterization of Knowledge Flows
PublicationThis book contributes to an improved understanding of knowledge-intensive business services and knowledge management issues. It offers a complex overview of literature devoted to these topics and introduces the concept of ‘knowledge flows’, which constitutes a missing link in the previous knowledge management theories. The book provides a detailed analysis of knowledge flows, with their types, relations and factors influencing...
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Numerical Model of Surface and Quasi-Spherical Sea Noise and Its Application to Analysis of DIFAR Systems
PublicationVarious types of passive sonar systems are used to detect submarines. These activities are complex and demanding. Therefore, computer simulations are most often used at the design stage of these systems. For this reason, it is also necessary to simulate the acoustic ambient noise of the sea. The article proposes a new numerical model of surface and quasi-spherical sea noise and presents its statistical parameters. The results of...