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Novel decahedral TiO2 photocatalysts modified with Ru or Rh NPs: Insight into the mechanism
PublicationNovel decahedral TiO2 modified with Ru or Rh NPs were successfully synthesized by hydrothermal method. The effect of metal type as well as amount of noble metal precursor (0.05, 0.1, 0.2, 0.3 and 0.5 wt.%) on the photocatalytic activity were investigated. Decahedral TiO2 decorated by Ru and Rh nanoparticles was prepared by photodeposition method, whereas Rh doped TiO2 was obtained by onestep hydrothermal method with introduction...
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Radiative lifetime of a BODIPY dye as calculated by TDDFT and EOM-CCSD methods: solvent and vibronic effects
PublicationThe radiative emission lifetime and associated S1 excited state properties of a BODIPY dye are investigated with TDDFT and EOM-CCSD calculations. The effects of a solvent are described with the polarizable continuum model using the linear response (LR) approach as well as state-specific methods. The Franck–Condon (FC), Herzberg–Teller (HT) and Duschinsky vibronic effects are evaluated for the absorption and emission spectra, and...
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Small-scale passive emission chamber for screening studies on monoterpene emission flux from the surface of wood-based indoor elements
PublicationAnalysis of literature data published in the last fewyears leads to the conclusion that in the process of assessment of emission flux of organic compounds emitted from different types of equipment and finishing materials, new types of devices, among which small-scale passive emission chambers for the performance of in-situ research are designed and applied on a larger scale. These devices can be successfully used for the assessment...
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Modelling long-term technological transition of Polish power system using MARKAL: Emission trade impact
PublicationThe need for technological transition of electricity production becomes a global problem. However, in coal-dominated Polish power system this need is even more crucial than anywhere, since technical lifetime of the most domestic power plants is ending. In this paper, the impact of the EU Emission Trading Scheme (EU ETS) for CO2 combined with sulfur dioxide (SO2) and nitrogen oxides (NOx) emission trading mechanism on power technology...
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Monoterpenes emissions from different samples of wood-based materials – laminated chipboards and medium-density fiberboards (MDF)
PublicationThe paper presents the results of studies on emission rates of monoterpenes, carried out with the use of a new type of device - Markes’ Micro-Chamber/Thermal Extractor™ (μ-CTE250). Subject of studies were different types of wood-based materials such as: laminated chipboards and medium-density fiberboards (MDF). Based on the results obtained one can conclude that the laminated chipboards may affect the indoor air quality in much...
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Real-time monitoring of volatiles and particles emitted from thermoplastic filaments during 3D printing
PublicationThe proliferation of consumer-grade three-dimensional (3D) printers using fused deposition, also known as fused filament fabrication, has given rise to concerns over the exposure of users to potentially harmful substances. Thermoplastic filaments made of different polymers are extruded through a heated printer nozzle and deposited layer by layer on a build platform to form the printed object. This process leads to the emission...
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PHOTON LUMINESCENCE STUDIES OF TETRAHYDROFURAN FOLLOWING TRIHYDROGEN CATIONS IMPACT IN THE 20–1000 EV ENERGY RANGE
PublicationPhoton emission arising during tetrahydrofuran (C4H8O, THF) fragmentation initiated by H3 + ion impact has been studied experimentally. Luminescence fragmentation spectra and the relative emission cross-sections of the excited fragments have been measured using collision-induced emission spectroscopy in the 20–1000 eV energy range. The main features in the spectra are the H Balmer series lines, whose intensities decrease with increasing...
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Clean gas technologies - towards zero-emission repowering of Pomerania.
PublicationThe main aim this work is to show the different thermodynamic cycles which improve efficiency and/or decrease emission like: Cheng cycle, Szewalski cycle, LOTHECO cycle, hybrid pSOFC/GT cycle, inverse Brayton cycle, low-emission cycle and zero-emission cycle. For that purpose, cycles and results of analysis are first studied and, secondly, new concept is presented. The role of coupled analysis 0D and 3D in cycle’s devices is also...
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Time domain model of the resonance-based electromagnetic pulses emission system
PublicationIn the literature, the emission properties of the electromagnetic field pulse systems based on high voltage antennas (HVR) have been widely described. In order to increase the emission efficiency by extending duration and increasing amplitude of the impulse it is possible to use a resonance system tuned to the parameters of the signal shaped in the pulse forming circuit. The synthesis of a time-domain simulation model of a complex...
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Emission and properties of airborne wear particles from train brake friction materials based on novolac phenolic resins and butadiene rubbers
PublicationThe emission of airborne particulate matter from a train brake depends on the formulation of its friction material. This study investigates the emission and properties of wear particles from train brake friction materials based on straight or resorcinol-modified novolac phenolic resin and nitrile or styrene butadiene rubber used as binding ingredients. The wear particles are generated by a pin-on-disc tribomachine inside an aerodynamic...
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Does the carbon emissions trading system reduce carbon emissions by promoting two-way FDI in developing countries? Evidence from Chinese listed companies and cities
PublicationHow developing countries can effectively promote cities’ carbon emission reduction through the carbon emission trading system (ETS) is a topic worthy of attention in the global carbon reduction campaign. Policy changes in China's ETS provide a unique opportunity to measure whether ETS impacts carbon emissions through two-way FDI. Hence, this paper employs difference-in-differences (DID) method to test the causal impact of ETS...
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Emission Profiles of Volatiles during 3D Printing with ABS, ASA, Nylon, and PETG Polymer Filaments
PublicationIn this short communication we characterize the emission of volatile organic compounds (VOCs) from fused filament fabrication (FFF) 3D printing using four polymer materials, namely polyethylene terephthalate glycol-modified (PETG), acrylonitrile styrene acrylate (ASA), Nylon, and acrylonitrile butadiene styrene (ABS). Detailed emission profiles are obtained during thermal degradation of the polymers as a function of temperature...
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Determination of Mechanical Properties of P91 Steel by Means of Magnetic Barkhausen Emission
PublicationIn this work, an attempt at determination of mechanical properties by means of a method based on magnetic Barkhausen emission measurements was proposed. The specimens made of P91 steel were subjected to creep or plastic flow which were interrupted after a range of selected time periods in order to achieve specimens with an increasing level of strain. Subsequently, measurements of magnetic Barkhausen emission were carried out, and...
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High Frequency Conducted Emission in AC Motor Drives Fed By Frequency Converters: Sources and Propagation Paths
PublicationProvides a concise and thorough reference for designing electrical and electronic systems that employ adjustable speed drives Electrical and electronic systems that employ adjustable speed drives are being increasingly used in present-day automation applications. They are considered by many application engineers as one of the most interfering components, especially in a contemporarily faced industrial environment. This book fills...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublicationEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Estimation of the effectiveness of nbpt for limiting ammonia emission from urea based on the field experiments
PublicationThe efectiveness of the ammonia emission reduction from NBPT-stabilized urea was investigating in 2011 during a field experiment on a grassland plot fertilized with a one-time dose of 60 kgN/ha. The obtained reduction coefficient of ammonia emission equaled 73% and 39-51% relative to erea without the inhibitor and ammonium nitrate, respectively.
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Boron doped Nanocrystalline Diamond-Carbon Nanospike Hybrid Electron Emission Source
PublicationElectron emission signifies an important mechanism facilitating the enlargement of devices that have modernized large parts of science and technology. Today, the search for innovative electron emission devices for imaging, sensing, electronics, and high-energy physics continues. Integrating two materials with dissimilar electronic properties into a hybrid material is an extremely sought-after synergistic approach envisioning a...
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Structural and luminescent study of TeO2-BaO-Bi2O3-Ag glass system doped with Eu3+ and Dy3+ for possible color-tunable phosphor application
PublicationTellurite glass systems of 73TeO2-4BaO-3Bi2O3-1Ag:xEu2O3-(2-x)Dy2O3 (where x = 0.5, 1, 1.5, 2 in molar ratio) composition have been successfully synthesized. In order to acquire Ag nanoparticles, materials have been heat treated at 350 °C in the air atmosphere. Structural properties of obtained samples were evaluated with various techniques. X-Ray Diffraction (XRD) measurements indicated that obtained materials are amorphous in...
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Low Frequency Conducted Emissions of Grid Connected Static Converters
PublicationPulse-width modulated rectifiers are nowadays commonly used for AC to DC power conversion. PWM rectification technology is very effective and allows for bidirectional power flow with the possibility of power factor improvement and low-order harmonic emission limitation. Unfortunately, employed PWM boost topology results with generation of input current harmonic distortions in a frequency range tightly correlated to modulation frequency....
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High Frequency Harmonics Emission in Smart Grids
PublicationPulse-width modulated rectifiers are nowadays commonly used for AC to DC power conversion. PWM rectification technology is very effective and allows for bidirectional power flow with the possibility of power factor improvement and low-order harmonic emission limitation. Unfortunately, employed PWM boost topology results with generation of input current harmonic distortions in a frequency range tightly correlated to modulation frequency....
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Analysis and assessment of the acoustic emission suitability for determination of the energy states of a tribological system in the form of a four-ball tester friction node
PublicationThe present operating safety and cost reduction requirements of the compression ignition engines make it necessary to search for new methods of detecting their defects, e.g. by the analysis of acoustic emission signals coming from the slide bearings. The paper presents non-destructive measurements of acoustic emission (AE) in order to obtain information on the processes taking place in a tribological system under the continuously...
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Extraction of antenna pattern from near field antenna measurements distorted by undesired emission
PublicationIn this paper authors present experimental correction of antenna pattern obtained from near field measurements when they are distorted by determined electromagnetic emission. Such situation may be met e.g. when feeding or supply subsystem interacts with antenna radiation pattern due to self-emission. Presented results of experiments show effectiveness of extraction of antenna pattern utilizing near field antenna measurements.
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Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex
PublicationTwo dinuclear complexes of zinc and cadmium with silanethiolate and bridging biimidazole ligands are characterized by X-ray diffraction, FT-IR, UV–Vis and emission spectroscopies. The complexes 1 (Zn) and 2 (Cd) are isostructural but exhibit different electronic structures and different character of frontier HOMO orbitals as indicated by DFT calculations. Lluminescence studies prove strong emission properties of zinc complex.
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Polychlorinated biphenyls (PCBs) in bottom sediments: Identification of sources
PublicationPolychlorinated biphenyls (PCBs) can enter the environment from various sources. They are synthetic chemicals and as such are present in the environment mainly as mixtures containing various amounts of PCB congeners. It is therefore difficult to pinpoint the source of PCB emissions into the environment and the pathways along which they migrate there. The situation is different where locating the emission sources of polycyclic aromatic...
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COMPARISON OF NOISE EMISSION OF HCT AND CLASSIC VEHICLE COMBINATIONS FOR TIMBER TRANSPORTATION IN SWEDEN
PublicationBy means of a special simulation tool, the noise emission of a high-capacity heavy vehicle (11 axles) was compared to that of a classic heavy vehicle (a truck-dolly-semitrailer with 8 axles). The two cases are designated “Extended vehicle” versus “Classic vehicle” in this study, having total lengths of 34 and 25 m, respectively. The Classic vehicle represents the most common articulated heavy vehicle configuration for transport...
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Reverberation chamber in emc tests of naval systems
PublicationPaper covers the techniques of emission and immunity testing to the electromagnetic field in reverberation chamber. The procedure of he chamber calibration and field homogeneity assessment were covered. The naval forces' product as selected as an example for discussing the testing procedure in the chamber. The paper's summary gives the assortment of methodology in radiation emission testing and immunity to the electromagnetic field...
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Recent progress in ultra-low formaldehyde emitting adhesive systems and formaldehyde scavengers in wood-based panels: a review
PublicationTraditional wood-based panels are produced with synthetic, formaldehyde-based adhesives, commonly made from fossil-derived constituents, such as urea, phenol, melamine, etc. Along with their numerous advantages, such as chemical versatility, high reactivity and excellent adhesive performance, these adhesives are characterized by certain problems, connected with the hazardous volatile organic compounds (VOCs), mostly free formaldehyde...
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Automatic Analysis System of TV Commercial Emission Level
PublicationThe purpose of the study was to determine whether the commercial emission level is higher than the emission level of a regular program and to check if the commercials broadcasters follow the recommended levels of loudness. The paper shortly reviews some chosen methods of volume measurements specified in the ITU and EBU recommendations. Then, it describes a prototype of a system implemented in Embarcadero C++ Builder 2010 which...
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A study on microcrack monitoring in concrete: discrete element method simulations of acoustic emission for non-destructive diagnostics
PublicationThe research is focused on the monitoring of fracture evolution in concrete beams under three-point bending using the acoustic emission technique and the discrete element method. The main objective of the study was to numerically and experimentally investigate the mechanism behind the generation of elastic waves during acoustic emission events and their interaction with micro- and macro-cracking in concrete beams under monotonic...
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High Frequency Harmonics Emission of Modern Power Electronic AC-DC Converters
PublicationModern AC/DC converters with bidirectional power flow employing PWM boost topology generate harmonic distortions of input current in relatively high frequency range tightly related to modulation carrier frequency. These frequencies and its multiples in typical applications are usually located in frequency range from single up to several of kHz. Increased harmonic emission in this frequency range can easily and harmfully influence...
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Real-time monitoring of volatiles and particles emitted from thermoplastic filaments during 3D printing
PublicationPresentation on the use of instrumental analytical techniques for the assessment of emission of volatiles and particulates during fdm 3d printing.
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The Emission and Combustion Characteristics of Marine Diesel Engine with Extreme Throttled of Air or Exhaust Ducts
PublicationPresented paper shows the results of the laboratory tests on the relationship between the extreme throttling of both air intake duct and exhaust gas duct and gaseous emission from the marine engine. The object of research is a laboratory, 4-stroke, DI diesel engine, operated at loads from 50 kW to 250 kW at a constant speed equal to 750 rpm. During the laboratory tests the thermodynamic and exhaust gas emission characteristics...
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A Noded Carbon Emission Tool (NCET) to Measure Embodied Carbon (EC) in Compositional Cementitious Materials
PublicationThe ever evolving modern construction industry is now producing the highest levels of carbon content adversely affecting the construction associated environment. Although, the impact of carbon induced emission is quite large, but still not enough measurable standards and tools to scale these emission are available. This study contributes to the body of knowledge by providing a Grasshopper based definition to calculate the embodied...
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Surface Plasmon-Coupled Emission of Rhodamine 110 Aggregates in a Silica Nanolayer
PublicationFirst analysis of strong directional surface plasmon-coupled emission(SPCE) of ground-state formed intermolecular aggregates of Rhodamine 110 (R110) insilica nanofilms deposited on silver nanolayers is reported. Until now, the processes ofenergy transport and its trapping due to aggregate formation have not been studied in the presence of SPCE. A new approach to multicomponent systems with weakly and strongly fluorescent centers...
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BODIPY‐Perylene Charge Transfer Compounds; Sensitizers for Triplet‐Triplet Annihilation Up‐conversion
PublicationBODIPY heterochromophores, asymmetrically substituted with perylene and/or iodine at the 2 and 6 positions were prepared and investigated as sensitizers for triplet-triplet annihilation up conversion (TTA-UC). Single-crystal X-ray crystallographic analyses show that the torsion angle between BODIPY and perylene units lie between 73.54 and 74.51, though they are not orthogonal. Both compounds show intense, charge transfer absorption...
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From structure to luminescence investigation of oxyfluoride transparent glasses and glass-ceramics doped with Eu3+/Dy3+ ions
PublicationGlasses and glass-ceramics with nominal composition 73 TeO2– 4BaO– 3Bi2O3–18SrF2-2RE2O3 (where RE = Eu, Dy) have been synthesized by conventional melt-quenching technique and subsequent heat treatment at 370 °C for 24 h in air atmosphere. Various Eu3+ to Dy3+ molar ratio have been applied to investigate luminescence properties in both glass and glass-ceramic matrices. Especially, white light emission through simultaneous excitation...
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Secondary emission influenced fluorescence decay of a homogeneous fluorophore solution
PublicationAn analytical expression is found allowing the calculation of the secondary emission influenced fluorescence decay of a homogeneous fluorophore solution. Before starting the calculation one has to know the shape of the primary fluorescence decay of the fluorophore and the value of the parameter kappa denoting the ratio of the secondary to primary steady-state fluorescence intensities. The method elaborated by Budo and Ketskemety...
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Release Kinetics Studies of Early-Stage Volatile Secondary Oxidation Products of Rapeseed Oil Emitted during the Deep-Frying Process
PublicationThe research concerns the use of proton transfer reaction mass spectrometer to track real-time emissions of volatile secondary oxidation products released from rapeseed oil as a result of deep-frying of potato cubes. Therefore, it was possible to observe a sudden increase of volatile organic compound (VOC) emissions caused by immersion of the food, accompanied by a sudden release of steam from a potato cube and a decrease of the...
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Clean energy in the European Union: Transition or evolution?
PublicationIn this paper, we analyse two phenomena. First, the relationship between greenhouse gases emission and effectiveness of the European Union energy policies and second the transition from the fossil fuels to renewable energy sources. We run two-step data analysis concerning 25 European Union member states in the period from 1990 to 2018. We use information on greenhouse gases emission, introduction of new energy policies, source...
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Noise emitted by SKM Trains in Gdansk
PublicationHigh intensity traffic of SKM trains in Gdansk carries a significant level of noise emission. SKM line runs through the central part of the city and therefore in the vicinity of residential areas and recreational facilities. This research was planned and performed to find out what was the real noise emission of SKM trains and to determine whether the measurement noise values are within allowed limits. Individual acoustic events...
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MARKAL LONG-TERM POWER GENERATION SCENARIOS FOR POLAND: INCREASING THE SHARE OF RENEWABLE ENERGY SOURCES BY 2040
PublicationIn this paper, renewable energy sources (RES) support mechanisms in Poland was presented with perspectives of proposed support system modifications, discussed in the project of Renewable Energy Act. In addition, MARKAL model of RES support mechanism was presented, taking into account technology-specific multiplication factors. Two model runs with emission trading system in place and two additional runs without emission trade were...
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Monitoring of underdeck corrosion by using acoustic emission method
PublicationThis paper presents first short characteristics of underdeck corrosion process as well as a problem of its monitoring. Next is described an acoustic emission (AE) method elaborated by Department of Ship Technology , Quality Systems and Material Engineering, Gdańsk University of Technology in cooperation with partners of CORFAT project realized within 7th EU Frame Program . Further are presented short characteristics of the emission...
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Airborne wear particle emission from train brake friction materials with different contents of steel and copper fibres
PublicationThis study investigated the influence of the amount of steel and copper fibres in a train brake friction material on the tribological performance, emission intensity and characteristics of airborne wear particles. The particles were generated on a pin-on-disc tribometer under controlled friction and environmental conditions. It was found that the steel fibre results in a more intensive emission of 0.3–10 μm particles compared to...
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An adaptive approach to non-destructive evaluation (NDE) of cast irons containing precipitated graphite particles with the help of magnetoacoustic emission
PublicationPhysical properties of cast irons strongly depend on both their microstructure and the presence of casting defects. The paper analyses the possibility of application of magnetoacoustic emission (MAE) for nondestructive detection of flawed cast iron components. The investigated samples containing dross, chunky graphite and lamellar graphite were compared with the reference, flawless, spheroidal cast iron sample. The optimisation...
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Investigations of the Working Process in a Dual-Fuel Low-Emission Combustion Chamber for an FPSO Gas Turbine Engine
PublicationThis investigation is devoted to an analysis of the working process in a dual-fuel low-emission combustion chamber for a floating vessel’s gas turbine. The low-emission gas turbine combustion chamber with partial pre-mixing of fuel and air inside the outer and inner radial-axial swirlers was chosen as the object of research. When modelling processes in a dual-flow low-emission gas turbine combustion chamber, a generalized method...
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Optical Spectroscopic Studies of Tetrahydrofuran Fragmentation Induced by Collisions with Dihydrogen Cations
PublicationCollisions of dihydrogen cations with tetrahydrofuran molecules have been studied. Luminescence spectra and the emission functions of the excited products at projectile energies ranging from 8 to 1000 eV have been measured using collision-induced emission spectroscopy. The recorded spectra are dominated by the atomic lines of the hydrogen Balmer series, whose intensities decrease more quickly than derived by the quantum-theoretical...
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MARKAL long-term power generation scenarios for Poland: Increasing the share of renewable energy sources by 2040
PublicationIn this paper, renewable energy sources (RES) support mechanisms in Poland was presented with perspec-tives of proposed support system modifications, discussed in the project of Renewable Energy Act. In ad-dition, MARKAL model of RES support mechanism was presented, taking into account technology-specific multiplication factors. Two model runs with emission trading system in place and two additional runs without emission trade...
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Correlations between the wear of car brake friction materials and airborne wear particle emissions
PublicationAirborne wear particles emitted from transport vehicle brakes are one of the main sources of toxic metals in inhalable particulate matter. Prediction of wear particle emissions may become more accurate if the relationship between the wear and particle emission characteristics is known. An experimental study was performed to investigate proportional correlations between the mass wear, 0.01–0.42 μm particle emission measured by a NanoScan...
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O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission
PublicationOxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon-photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core-valence double excitations, while shape resonances are suppressed. In contrast,...
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ROSANNE Project: New Procedure for Noise Characterisation of Road Surfaces in Europe
PublicationROSANNE is a collaborative project in the 7th EU Framework Programme which aims at harmonising measurement methods for skid resistance, noise emission and rolling resistance of road pavements as a preparation for standardization. The project started in November 2013 and is developing and improving standards in the field of working group CEN/TC 227/WG 5. Regarding the influence of the pavement on the road traffic noise emission,...