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Search results for: chemical hydrogen storage
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Synthesis, physical and chemical properties of polyetherurethanes modified by natural antioxidant
PublicationOtrzymano nowe polieterouretany modyfikowane witaminą E. Ten naturalny przeciwutleniacz związany został z makrocząsteczkami w postaci bocznych odgałęzień poprzez wiązanie eterowe lub uretanowe, zależnie od użytego w syntezie jednego z dwóch rodzajów otrzymanych uprzednio monomerów. Polimery scharakteryzowano mierząc wytrzymałość na rozciąganie i twardość oraz absorpcję wody i oleju słonecznikowego. Odporność chemiczną badano oznaczając...
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Concept of the mobile monitoring system for chemical agents control in the air
PublicationW artykule przedstawiono koncepcję mobilnego systemu monitoringu związków chemicznych zanieczyszczających powietrze. Nowością w przedstawionej koncepcji monitoringu jest pomiar zanieczyszczeń powietrza wzdłuż ciągów komunikacyjnych, co do tej pory nie jest realizowane. W tym celu przedstawiono propozycję rozwiązania stosunkowo małego, bezobsługowego modułu do pomiarów związków chemicznych, który z łatwością będzie montowany na...
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Fog water chemical composition in different geographic regions of Poland
PublicationPróbki wody z mgły pobierane były w latach 2005-2006 na terenie Szrenicy, Zakopanego i Borucina. Analiza statystyczna ujawniła znaczące różnice w składzie chemicznym próbek wody z mgły w zależności od regionu geograficznego, wysokości pobierania próbek, ale także od momentu pobierania próbki. Stwierdzono również różnice składu chemicznego pomiędzy mgłą radiacyjna a orograficzną.
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Chapter 14. Physical and chemical interaction of componenets in food systems
PublicationBiałka, lipidy, sacharydy, składniki mineralne, woda i inne związki występują w żywności w postaci roztworów i różnych mikrostruktur - kropelek, globulek, kryształów, włókienek i błon. Reaktywne grupy funkcyjne tych składników wchodzą w warunkach przechowywania i obróbki, szczególnie po zniszczeniu oryginalnych struktur, w interakcje wpływające na barwę, zapach, smak i reologiczne właściwości żywności. W technologii żywności wykorzystuje...
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State of the art and prospects of methods for determination of lipophilicity of chemical compounds
PublicationLipophilicity of the compounds is useful to (i) explain their distribution in biological systems, which is different in plant and in animal organisms, (ii) predict the possible pathways of pollutant transport in the environment, and (iii) support drug discovery process and select optimal composition in terms of bioactivity and bioavailability. The lipophilic properties can be determined by two main approaches, experimental, which...
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Chemical modifications of graphene and their influence on properties of polyurethane composites: a review
PublicationPolyurethane composites are materials of great interest nowadays due to their wide range of available forms and applications in industry. Controlling and achieving unique properties via matrix modifications and addition of various specific nanofillers seems be one of the key elements to success. The purpose of this work is to briefly present some examples of graphene nanoderivatives, their syntheses, properties and influence on...
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Chemical Theory of Machines, basic principles of strength with examples of calculations
PublicationThis book encompasses the essential range of information on technical aspects of mechanical design. It was written primarily for the students and staff of chemistry faculties of technical universities, yet it may also be utilized by everyone, who ether would like to try or already enjoys designing, but cannot take advantage of typical stress & machine construction handbooks. These handbooks often require familiarity with the concepts...
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Water and chemical properties of hydrometeors over central european mountains
PublicationAtmospheric pollutants are transferred to the groundby the contribution of various types of hydrometeors. Because ofthe different techniques of measurement, comparative analysesbetween them are often neglected. Hence, the main goal is tocompare water volume and chemistry of different types ofhydrometeors and their role in both: water balance and pollutantsdeposition. The results of water input and atmospheric depositschemistry...
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JOURNAL OF THE CHILEAN CHEMICAL SOCIETY
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Mobility and bioavailability of mercury in sediments of the southern Baltic sea in relation to the chemical fractions of iron: Spatial and temporal patterns
PublicationMarine sediments play a significant role as reservoirs for mercury (Hg), a bioaccumulative toxic pollutant that poses risks to human and ecosystem health. Iron (Fe) has been recognized as an influential factor in the complexation and bioavailability of Hg in sediments. However, limited studies have investigated the interactions between the chemical fractions of these elements in natural settings. This study aims to examine the...
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Linear antenna microwave chemical vapour deposition of diamond films on long-period fiber gratings for bio-sensing applications
PublicationThe growth processes of nanocrystalline diamond (NCD) thin films on fused silica optical fibers with UV-induced long-period gratings (LPGs) were investigated with regard to biosensing applications. The films were deposited using a linear antenna microwave plasma enhanced chemical vapor deposition system, which allows for the growth of diamond at temperatures below 350°C. The films exhibited a high refractive index n = 2.32, as...
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Experimental and DFT insights into an eco-friendly photocatalytic system toward environmental remediation and hydrogen generation based on AgInS2 quantum dots embedded on Bi2WO6
PublicationBismuth tungstate (Bi2WO6) can work as a photocatalyst but suffers from rapid recombination of photogenerated charge carriers. Herein, density functional theory (DFT) simulations revealed that the formation of a thermodynamically stable AgInS2(112)/Bi2WO6(010) heterojunction could promote charge separation and enhance the photoactivity of Bi2WO6. To confirm these theoretical predictions, a new type of photocatalysts in the form...
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Superconducting lead granular layer prepared by reducting in hydrogen lead of germanate glass
PublicationCienka warstwa granul Pb została wytworzona poprzez wygrzewanie w wodorze, w wysokiej temperaturze. Struktura i nadprzewodzące właściwości warstwy ołowiu zależą od temperatury i czasu redukcji. Artykuł analizuje wpływ warunków redukcji na wytworzoną warstwę granul Pb.
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Shape-controllable synthesis of GdVO4 photocatalysts and their tunable properties in photocatalytic hydrogen generation
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Hydrogen-Containing Na3HTi1–xMnxF8 Narrow-Band Phosphor for Light-Emitting Diodes
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Descriptors to Predict Dye‐Sensitized Semiconductor Based Photocatalyst for Hydrogen Evolution Reaction
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Boosting of photocatalytic hydrogen evolution via chlorine doping of polymeric carbon nitride
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The use of nitriding as a prevention method against hydrogen degradation of high-strength steels
PublicationPrzedstawiono badania wpływu warstw azotowanych jarzeniowo na stali 34CrAlNi7-10 na jej podatność na niszczenie wodorowe. Wytworzono warstwy azotowane w atmosferach technologicznych o różnym udziale wodoru. Próbki materiału rodzimego i z warstwami azotowanymi poddano próbie rozciągania z małą prędkością odkształcania w środowisku 0,01 N kwasu siarkowego przy polaryzcaji katodowej. Względny spadek plastyczności i charakter przełomu...
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Conformers and hydrogen bond transformations in N-methylpiperidine betaine 2,4-dinitrophenolate crystals
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Numerical Simulations of DDT Limits in Hydrogen-Air Mixtures in Obstacle Laden Channel
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Municipal wastewater reclamation: Reclaimed water for hydrogen production by electrolysis – A case study
PublicationThis paper presents an analysis of a treatment system selection for municipal wastewater stream based on the DuPont Water Solutions WAVE software. The results obtained based on an analysis of 7 different processing cases studies (ultrafiltration and reverse osmosis) confirmed that the application of 2-pass membrane systems enables the reclamation of water from municipal wastewater that fulfills the requirements concerning the...
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Superconducting state in the atomic metallic hydrogen just above the pressure of the molecular dissociation
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Non-parametric application of Tsallis statistics to systems consisting of M hydrogen molecules
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State selective electron capture in the collision of S3+ ions in atomic hydrogen and helium.
PublicationZostało zaprezentowane teoretyczne podejście, uwzględniające obliczenia krytycznych adiabatycznych energii potencjalnych i dynamicznych sprzężeń pomiędzy nimi, do opisu procesu przechwytu elektronu przez jony siarki w zderzeniach z atomami wodoru i helu.
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The new analyzer based on single pellistor sensor for determination of hydrogen and methane in air
PublicationW artykule przedstawiono rezultaty niedawnych badań nad konstrukcją prostego i selektywnego analizatora do monitoringu stężenia gazów wybuchowych w powietrzu. Opisano konstrukcję takiego urządzenia i wyniki prób laboratoryjnych dla gazowych mieszanin wzorcowych.
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Strength deterioration of 26H2MF and 34HNM steels used in ship engines: hydrogen factor
PublicationBadano podatność stali 26H2MF i 34HNM poddanych różnej obróbce cieplnej na niszczenie wodorowe. Badania wykonano metodą powolnego rozciągania z szybkością 10-6 s-1. Określano wytrzymałość, wydłużenie, przewężenie i energię zniszczenia. Stwierdzono znaczna degradację w 0,01 M kwasie siarkowym z dodatkiem arszeniku. Wykazano istnienie korelacji między obróbką cieplną i stopniem degradacji. Efekty przypisano pułapkowaniu wodoru.
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Structural and electrical transport studies of reduced in hydrogen surfaceof bismuth germanate glass
PublicationOtrzymano nanostruktury krystalicznego bizmutu w matrycy szkła germanowegooraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanegow atmosferze wodoru szkła Bi0.33Ge0.67O1.83. Zaproponowano prosty model bu-dowy zredukowanych szkieł bizmutowo-germanowych potwierdzony wynikami badańAFM i XRD. Zbadano wpływ czasu i temperatury redukcji oraz topnienia bizmu-tu na własności elektryczne badanych szkieł. Przeanalizowano...
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Structure and morphology of hydrogen reduced surface of bismuth germanateand bismuth silicate glasses.
PublicationOtrzymano nanostruktury krystalicznego bizmutu w matrycy XO2(X=Si,Ge) oraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanych w atmosferze wodoru szkieł Bi0.33Ge0.67O1. i Bi0.57Si0.43O1.72. Zaproponowano prosty model budowy zredukowanych szkieł bizmutowo-germanowych potwierdzony wynikami badań AFM i XRD. Obserwowane zmiany przewodnictwa elektrycznego redukowanych szkieł wyjaśniono na podstawie modelu.
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Neutral Dissociation of Pyridine Evoked by Irradiation of Ionized Atomic and Molecular Hydrogen Beams
PublicationThe interactions of ions with molecules and the determination of their dissociation patterns are challenging endeavors of fundamental importance for theoretical and experimental science. In particular, the investigations on bond-breaking and new bond-forming processes triggered by the ionic impact may shed light on the stellar wind interaction with interstellar media, ionic beam irradiations of the living cells, ion-track nanotechnology,...
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Effect of plasma nitrided layers on low-alloy steel on its hydrogen degradation
PublicationPrzedstawiono badania wpływu warstw azotowanych jarzeniowo na stali 34CrAlNi7-10 na jej podatność na niszczenie wodorowe. Wytworzono warstwy azotowane w atmosferach technologicznych o różnym udziale wodoru. Próbki materiału rodzimego i z warstwami azotowanymi poddano próbie rozciągania z małą prędkością odkształcania w środowisku 0,01 N kwasu siarkowego przy polaryzcaji katodowej. Względny spadek plastyczności i charakter przełomu...
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Hydrogen migration in formation of NH(A3Π) radicals in photodissociations of isoxazole and pyridine molecules
PublicationIn the present study, the H atom migration was observed in the photodissociation processes of the isoxazole and pyridine molecules in the gas-phase, applying the photon-induced fluorescence spectroscopy (PIFS).
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Does the chemical modification of Nystatin A1 affect the drug's ability to overcome the multidrug resistance of fungi?
PublicationAlthough the contemporary medicine keeps moving forward, disseminated infections caused by fungal pathogens are an emerging challenge. The dramatic rise of fungal diseases, especially the most life-threatening systemic mycoses is associated with a permanently growing number of immunodeficient patients. Undoubted difficulties in the treatment of fungal infections are caused by lack of highly effective and selective antifungal drugs,...
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Seashore sediment and water chemistry at the Admiralty Bay (King George Island, Maritime Antarctica) – geochemical analysis and correlations between the concentrations of chemical species
PublicationThis study covers water and sediment chemical characteristics by the western shore of Admiralty Bay (King George Island, Antarctica) in 2016. Chemical processes between sediment and water have been described based on the determination of ions, metals, non-metals, and TOC concentrations. Rock weathering is an important source of Fe, Ni, Co, Al in the seashore area. The PCA shows the impact of acidification in the release metals...
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In silico study on the effects of carbonyl groups on chemical equilibrium of reactions with a polar product occurring under confinement in pores of activated carbons
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The XRD diffraction patterns of (La0.3Sr0.6Ce0.1)0.9FexTi(1-x)O3-δ (x=0.1, 0.2 and 0.3) materials after reduction at 900 deg.C in hydrogen
Open Research DataThe (La0.3Sr0.6Ce0.1)0.9FexTi(1-x)O3-δ (x=0.1, 0.2 and 0.3) materials were synthesized via the Pechini method. First, the reagents in the form of nitrates were weighed and dissolved in DI water. In another beaker, a stoichiometric amount of titanium (IV) butoxide (Ti(OBu)4) was mixed together with reagent-grade ethylene glycol (EG), and citric acid...
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Application of dispersive liquid - liquid microextraction for determination of pesticides from various chemical groups in water samples
PublicationPesticides are a global risk because they move with the wind, rain and sea currents from other regions, which makes getting to places which were never used before. Their presence was detected in all types of water circulating in the ecosystem, which is an easy source of exposure to life and health of all living organisms. Currently, it is considered one of the most dangerous and toxic pollutants, which fate and function is still...
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Synthesis, Chemical Characterization and Multiscale Biological Evaluation of a dimericcRGD Peptide for Targeted Imaging of αVβ3 Integrin Activity
PublicationCyclic peptides containing the Arg-Gly-Asp (RGD) sequence have been shown to specifically bind the angiogenesis biomarker α V β3 integrin. We report the synthesis, chemical characterization, and biological evaluation of two novel dimeric cyclic RGD-based molecular probes for the targeted imaging of α V β3 activity (a radiolabeled version, 64Cu-NOTA-PEG4-cRGD2, for PET imaging, and a fluorescent version, FITC-PEG4-cRGD2, for in...
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Oxidative and microbiological stability of raw ground pork during chilled storage as affected by Plant extracts
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Highly efficient conversion of waste plastic into thin carbon nanosheets for superior capacitive energy storage
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Symmetric Supercapacitors Based on MnOOH‐Coated Nanoporous Carbon toward High Energy‐Storage Performance
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The impackt of polish pumped-storage plants on operation of the national power system on working days and holidays
PublicationPrzedstawiono wpływ polskich elektrowni szczytowo-pompowych na pracę krajowego systemu elektroenergetycznego w cyklu dobowym na przykładzie dni charakterystycznych roboczych i dni wolnych od pracy. Analizę przeprowadzono w oparciu o obliczenia wykonane w dwóch wariantach: system pracuje z istniejącymi elektrowniami pompowymi i system pracuje bez elektrowni pompowych.
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New insights on lithium storage in silicon oxycarbide/carbon composites: Impact of microstructure on electrochemical properties
PublicationIn this work, we study the impact of the preceramic precursor vinyltriethoxysilane (VTES) on the electrochemical performance of silicon oxycarbide (SiOC) glass/graphite composites. We apply an innovative approach based on high-power ultrasounds in order to obtain highly homogenous composites with a uniform distribution of small graphitic flakes. This procedure enhances gelation and drying of VTES-based preceramic polymer/graphite...
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Studies on the utilization of post-distillation liquid from Solvay process to carbon dioxide capture and storage
PublicationIn this work, a method of precipitated calcium carbonate production from the post-distillation liquid created in the Solvay process and waste carbon dioxide was proposed and investigated. Precipitation was carried out in a model solution of calcium chloride containing ammonia at various molar ratios in relation to Ca2+ ions, while gaseous carbon dioxide was supplied to the reactor as a pure gas or as a mixture with air. It was...
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The role of tungsten in formation of active sites for no SCR on the V-W-O catalyst surface — quantum chemical modeling (DFT)
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Chemical analysis of the Au-Ag nanoaloys
Open Research DataThe nanostructures of AuAg nanoalloys were prepared by sequential sputtering of gold and silver thin films. Single layer thickness was usually 2.8 nm were deosted by magnetron sputtering method in a Ar plasma. As deposited layers were annealed in Ar atmosphere at 550 degress for 15 minutes. For XPS measurements five samples were selected: pure gold...
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Imaging and chemical investigation of silver coating
Open Research DataThe recovery of silver from materials such as plates, still used in clinical radiography [1], or scrap jewelery is still very popular. The subject of the research, part of which was microscopic imaging, was to recreate the behavior of an electrochemically deposited silver coating. The copper electrodes were covered with a layer of silver obtained from...
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Depth chemical profile in a CeIr3 sample
Open Research DataThe polycrystalline sample of CeIr3 used in the present studies was synthesized by arc-melting cerium (4N) and iridium (3N5) in an arc furnace on a water-cooled copper hearth using a tungsten electrode under a high purity argon atmosphere. A piece of zirconium was used as an oxygen getter. First, a button of Ir was prepared by arc-melting the iridium...
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Interactions between polyphenolic antioxidants quercetin and naringenin dictate the distinctive redox-related chemical and biological behaviour of their mixtures
PublicationFood synergy concept is suggested to explain observations that isolated antioxidants are less bioactive than real foods containing them. However, mechanisms behind this discrepancy were hardly studied. Here, we demonstrate the profound impact of interactions between two common food flavonoids (individual: aglycones quercetin—Q and naringenin—N− or their glycosides rutin—R and naringin—N+ vs. mixed: QN− and RN+) on their electrochemical...
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The impact of thermomechanical and chemical treatment of waste Brewers’ spent grain and soil biodegradation of sustainable Mater-Bi-Based biocomposites
PublicationDue to the massive plastic pollution, development of sustainable and biodegradable polymer materials is crucial to reduce environmental burdens and support climate neutrality. Application of lignocellulosic wastes as fillers for polymer composites was broadly reported, but analysis of biodegradation behavior of resulting biocomposites was rarely examined. Herein, sustainable Mater-Bi-based biocomposites filled with thermomechanically-...
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Tribological Properties of Ni-P/Si3N4 Nanocomposite Layers Deposited by Chemical Reduction Method on Aluminum Alloy AW-7075
PublicationThe article presents the results of tribological tests of Ni-P/Si3N4 nanocomposite and Ni-P nickel layers deposited on the AW-7075 aluminum alloy by chemical reduction method, and the AW-7075 alloy without coating. Nanocomposite layers were produced using Si3N4 siliconnitride in the form of a polydisperse powder whose particle sizes ranged from 20 to 25 nm. The influence of the content of the dispersion phase layer material on...