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Search results for: charge density waves
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Rapid and Green Separation of Mono- and Diesters of Monochloropropanediols by Ultrahigh Performance Supercritical Fluid Chromatography–Mass Spectrometry Using Neat Carbon Dioxide as a Mobile Phase
PublicationThis study demonstrates the effect of column selectivity and density of supercritical carbon dioxide (SC-CO2) on the separation of monochloropropanediol (MCPD) esters, known as food toxicants, using SC-CO2 without addition of cosolvent in ultrahigh performance supercritical fluid chromatography–mass spectrometry (UHPSFC-MS). This study shows that over 20 2-monochloropropanediol (2-MCPD) and 3-monochloropropanediol (3-MCPD) mono-...
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Influence of friction stir welding technological parameters on the properties of the joints of selected aluminum alloys
PublicationThe purpose of this dissertation was to determine the effect of friction stir welding technological parameters on the properties of selected aluminum alloy joints, with consideration of the residual stresses and dislocation density in the joints. The goal of the present work was also to produce defect-free joints with high mechanical and electrochemical properties. In the dissertation, similar welds of AA6082 alloy and dissimilar...
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Power balance in hydraulic satellite motors supplied with oil and HFA-E emulsion
PublicationMineral oil and HFA-E emulsion are liquids which differ in viscosity, density and lubricant properties. Therefore, supplying hydraulic satellite motors with these liquids, differences between quantity of hydraulic, volumetric and mechanical losses are observed. These losses influence efficiency of conversion of hydraulic energy into mechanical energy and thereby power balance of motors.
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Production of singlet oxygen atoms by photodissociation of oxywater
PublicationQuantum chemical calculations are reported for the energies of the few lowest electronic singlet states of oxywater along dissociation of the oxygen-oxygen bond into water and singlet oxygen using multistate multireference second-order Møller–Plesset perturbation theory. We compute an energy of 21 kcal/mol to remove one oxygen atom in the lowest singlet state. The two lowest excited singlet states have vertical excitation energies...
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Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones
PublicationTriphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn’t be formed. The results of electrochemical,...
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Ammonium <i>O</i>,<i>O</i>'-diethyl dithiophosphate
PublicationIn the title compound, NH4+·(C2H5O)2PS2−, the ammonium cation is connected by four charge-assisted N−H···S hydrogen bonds to four tetrahedral O,O'-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Interlacing of the external ethyl groups...
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Red Algae – An Alternative Source of Carbon Material for Energy Storage Application
PublicationNew electrode material obtained by pyrolysis of aquatic biomass macro (red algae) soaked with glucose solution has been characterized by SEM, EDX and Raman spectroscopy. Graphitized carbon was identified by Raman spectroscopy. Galvanostatic cyclic polarization of the materials in contact with 1M LiPF6 electrolyte in EC:DMC (1:1 v/v) and Li as a counter electrode was performed. Specific capacity of the novel material was enhanced...
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Preload monitoring in a bolted joint using Lamb wave energy
PublicationThe knowledge of the load in prestressed bolted connections is essential for the proper operation and safety of engineering structures. Recently, bolted joints have become an area of intensive research associated with non-destructive diagnostics, in particular in the context of wave propagation techniques. In this paper, a novel procedure of bolt load estimation based on the energy of Lamb wave signals was proposed. Experimental...
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Magnetoacoustic Heating of Plasma Caused by Periodic MagnetosoundPerturbations with Discontinuities in a Quasi-Isentropic Magnetic Gas
PublicationThe magnetoacoustic heating of plasma by harmonic or periodic saw-tooth perturbations at a trans-ducer is theoretically studied. The planar fast and slow magnetosound waves are considered. The wavevector may form an arbitrary angleθwith the equilibrium straight magnetic field. In view of variableθand plasma-β, the description of magnetosound perturbations and appropriate magnetosound heatingis fairly difficult. The scenario of...
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Reference-free determination of debonding length in reinforced concrete beams using guided wave propagation
PublicationThis paper presents theoretical and experimental investigations of guided wave propagation in reinforced concrete beams, with pre-existing debonding between steel rebars and concrete blocks, for the purpose of damage detection. The primary aim of these investigations was a detailed analysis of the possible applications of wave propagation in single and multiple debonding detection in reinforced concrete structures and reference-free...
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Local buckling of thin-walled channel member flange made of aluminum alloy
PublicationThe paper deals with local stability of the thin-walled compressed flange of channel columns and beams made of aluminum alloy. The aim of paper is to find critical stress of local buckling of the flange member taking into account the web-flange interaction in linear and nonlinear elastic range of the member material. The governing differential equation of the problem is derived with aid of the principle of stationary total potential...
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Operational algae bloom detection in the Baltic Sea using GIS and AVHRR data
PublicationDuring the blooming season, algal colonies can, in extreme cases, cover up to 200 000 square kilometres of the Baltic Sea water surface. Because the position and shape of the blooms may significantly change in very short time due to the influence of wind and waves, regular monitoring of the blooms' development is necessary. Currently, the desired monitoring frequency may only be achieved by means of remote sensing. The article...
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Receiver of Doppler multistatic system for moving target detection and tracking
PublicationThe article presents a method for solving major structural problems that occur in the receiver used in the multistatic Doppler system, aimed at determination of the trajectory and velocity of a moving target. In the system two transmitters emit acoustic continuous sinusoidal waves at different frequencies. The signals, scattered from a moving target are received by four hydrophones. Beside of the echoes, much larger signals coming...
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A novel heterogeneous model of concrete for numerical modelling of ground penetrating radar
PublicationThe ground penetrating radar (GPR) method has increasingly been applied in the non-destructive testing of reinforced concrete structures. The most common approach to the modelling of radar waves is to consider concrete as a homogeneous material. This paper proposes a novel, heterogeneous, numerical model of concrete for exhaustive interpretation of GPR data. An algorithm for determining the substitute values of the material constants...
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Conditions for Multiple Acquisition of Echoes from Stationary Targets in Successive Transmissions of Active Sonars
PublicationIn echolocation, the highest possible number of contacts with a detected target is clearly decisive on the possibilities of echo processing to optimise the estimation of distinctive characteristics of the observed target. In hydrolocation, the slow propagation of acoustic waves in water reduces the number of contacts of echosounders and sonars with detected targets. The article considers model conditions for acquiring multiple...
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Characterization and properties of LDPE/(ground tire rubber)/crosslinked butyl rubber blends
PublicationIn recent years, interest in used rubber recycling, mainly focusing on the utilization of end-of-life tires, has heightened. This interest, is owing to the activities related to environmental protection and economic factors, which both stimulate companies to reuse the high-quality rubber present in ground rubber scrap. In this study, the application of crosslinked butyl rubber in thermoplastic compositions of low-density polyethylene...
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Micellar aggregation of Triton X-100 surfactant in imidazolium ionic liquids
PublicationIn this work we investigated aggregation behavior of a nonionic surfactant Triton X-100 in eighteen imidazolium ionic liquids (ILs) with two to eight carbon atoms in cations alkyl chain, namely 1-ethyl-3-methylimidazolium, [EMIM], 1-butyl-3-methylimidazolium, [PrMIM], 3-methyl-1-propylimidazolium, [BMIM], 1-hexyl-3-methylimidazolium, [PMIM], 3-methyl-1-pentyl-imidazolium, [HMIM], and 1-octyl-3-methylimidazolium, [OMIM], and with...
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The effect of pre-hydrogen charging on corrosion behaviour of superduplex stainless steel welded joints
PublicationThe paper presents results of research undertaken to determine the influence of hydrogen on passivity and corrosion resistance of 2507 super duplex stainless steel welded joints. Butt welded joints were made with low heat input using flux corded arc welding (FCAW) method. Coupons of 5.0 x 5.0 mm were cut from the welded joints containing weld metal (WM), heat affected zone (HAZ) and parent metal (PM). Hydrogen was introduced...
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Optimum Choice of Randomly Oriented Carbon Nanotube Networks for UV-Assisted Gas Sensing Applications
PublicationWe investigated the noise and photoresponse characteristics of various optical transparencies of nanotube networks to identify an optimal randomly oriented network of carbon nanotube (CNT)-based devices for UV-assisted gas sensing applications. Our investigation reveals that all of the studied devices demonstrate negative photoconductivity upon exposure to UV light. Our studies confirm the effect of UV irradiation on the electrical...
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Production of fuel briquette from solid waste biomass using natural resin as a binder
PublicationBackground: This research aimed to evaluate the use of natural resin as a binder for the production of fuel briquette from solid waste biomass.Methods: Proximate analyses were made for fuel briquette prepared from solid waste biomass using natural resin as a binder in comparison with using starch as a binder.Results: The results for density, percent content of moisture, percent content of volatile matter, percent...
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Electrochemical Production of Sodium Hypochlorite from Salty Wastewater Using a Flow-by Porous Graphite Electrode
PublicationThe production of sodium hypochlorite (NaOCl) from salty wastewater using an electrochemical cell has several advantages over other methods that often require hazardous chemicals and generate toxic waste, being more sustainable and environmentally friendly. However, the process of producing sodium hypochlorite using an electrochemical cell requires careful control of the operating conditions, such as the current density, flow rate,...
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Production of fuel briquette from solid waste biomass using natural resin as a binder
PublicationAbstract Background: This research aimed to evaluate the use of natural resin as a binder for the production of fuel briquette from solid waste biomass. Methods: Proximate analyses were made for fuel briquette prepared from solid waste biomass using natural resin as a binder in comparison with using starch as a binder. Results: The results for density, percent content of moisture, percent content of volatile matter, percent content...
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Chapter 4. Electricity generation from glucose microbial fuel cell
PublicationThe microbial fuel cell was constructed to generate electricity with simultaneous digestion of a glucose fuel by a bacterial biofilm. The decomposition of glucose resulted in releasing of electrons to an anode and to production of some by-products, e.g. metane or organic acids. It was found that maximum electric power density strongly depended on the proton transport through the proton exchange membrane seperating the anolyte and...
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Novel single-stage buck-boost inverter with unfolding circuit
PublicationA novel solution of a single-stage buck-boost inverter with unfolding circuit at the output stage is presented. The inverter has a wide range of input voltage regulation, minimum passive components and a very flexible control structure. It can be applied for renewable energy systems where high power density is required. Our simulation results confirmed all theoretical statements
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Study of Aliphatic Polyurethanes by the Low-Field 1H NMR Relaxometry Method with the Inversion of the Integral Transformation
PublicationIn this paper, the distributions of the 1H nuclear magnetic resonance (NMR) spin–lattice and spin–spin relaxation times are used to characterize the mobility of different sections of macromolecules of aliphatic polyurethanes and the cross-linking density of polymer chains. The NMR relaxometry method with inversion of integral transformation is applied to study the effect of poly (ethylene glycol) and glycerol phosphate calcium...
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OPTIMIZATION OF NASICON PREPARATION METHOD
PublicationNasicon is a solid conductor which has an ability to conduct Na+ ions and it is used in solid gas sensors. In this article a method of Nasicon preparation appropriate for gas sensing application by solgel technique is presented. Influence of the fabrication process parameters on properties of obtained samples was determined. Results of X-Ray diffraction, density, porosity, conductivity, and activation energies measurement are presented.
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Constructive entanglement test from triangle inequality
PublicationWe derive a simple lower bound on the geometric measure of entanglement for mixed quantum states in the case of a general multipartite system. The main ingredient of the presented derivation is the triangle inequality applied to the root infidelity distance in the space of density matrices. The obtained bound leads to entanglement criteria with a straightforward interpretation. The proposed criteria provide an experimentally accessible,...
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Impedance of cation-coupled electron transfer reaction: Theoretical description of one pathway process
PublicationIt has been assumed that cation electron coupled charge transfer can be conducted in accordance with two mutually coupled reactions. Using a differential method an expression was introduced which describes the impedance of a cation electron coupled transfer reaction. Also, an electrical equivalent circuit has been defined. The total faradaic impedance is the sum of electron transfer impedance and cation transfer impedance. Issues...
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Identification of diagnostic parameter sensitivity during dynamic processes of a marine engine
PublicationChanging some parameters of the engine structure alters the emission of harmful components in the exhaust gas. This applies in particular to the damage of charge exchange system as well as fuel system and engine supercharger. These changes are much greater during the dynamic states and their accompanying transitional processes. The different sensitivity of diagnostic parameters to the same force, coming from the engine structure, but...
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Dynamic Charging of Electric Buses as a Way to Reduce Investment Risks of Urban Transport System Electrification
PublicationNight charging and fast charging are currently the two most common systems for charging electric buses. Despite the fact that numerous trial installations were started, neither of these two systems has obtained unqualified approval of the users. The alternative is to charge vehicles in motion - dynamic charging which combines the advantages of trolleybus transport and of electric buses. One of the advantages is the reduction of...
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PUBLICZNE ŚRODKI TRANSPORTOWE A SAMOCHÓD ELEKTRYCZNY W OBSŁUDZE PODRÓŻY MIEJSKICH W METROPOLII TRÓJMIEJSKIEJ
PublicationMetropolia trójmiejska ma wyjątkowo negatywne uwarunkowania terenowe dla funkcjonowania i rozwoju sieci komunikacji publicWyznej. Dzielnice położone w tzw. dolnym tarasie są dobrze skomunikowane za pomocą linii SKM i tramwajowych. Jedynie te środki komunikacji szynowej, przy częstotliwości połączeń nie większej niż co 10 minut, są konkurencyjne dla indywidualnych dojazdów samochodami osobowymi. Natomiast autobusy i trolejbusy utykające...
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Diagnostyka ultradźwiękowa mostowej belki prefabrykowanej typu T metodą młoteczkową
PublicationZastosowanie prefabrykacji w budowie obiektów mostowych pozwala optymalizować zużycie energii i materiałów i tym samym redukować koszty budowanego obiektu. Prefabrykowane belki sprężone mogą występować jako elementy kablobetonowe wykonywane bezpośrednio na placu budowy lub powstawać w zakładzie prefabrykacji jako elementy strunobetonowe. Elementy prefabrykowane wytwarzane w warunkach przemysłowych muszą spełniać wymagania wysokiej trwałości,...
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Exploring the cocrystallization potential of urea and benzamide
PublicationThe cocrystallization landscape of benzamide and urea interacting with aliphatic and aromatic carboxylic acids was studied both experimentally and theoretically. Ten new cocrystals of benzamide were synthesized using an oriented samples approach via a fast dropped evaporation technique. Information about types of known bi-component cocrystals augmented with knowledge of simple binary eutectic mixtures was used for the analysis...
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On the mechanism of photocatalytic reactions on CuxO@TiO2 core–shell photocatalysts
PublicationTitania (titanium(IV) oxide) is a highly active, stable, cheap and abundant photocatalyst, and is thus commonly applied in various environmental applications. However, two main shortcomings of titania, i.e., charge carrier recombination and inactivity under visible-light (vis) irradiation, should be overcome for widespread commercialization. Accordingly, titania has been doped, surface modified and coupled with various ions/compounds,...
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Efficiency and proportions of waste tyre pyrolysis products depending on the reactor type—A review
PublicationThis article discusses the current use of different pyrolytic reactors, their constructions and operating principles regarding the yields of main products of waste tyre pyrolytic recycling. Whether one makes a larger or smaller profit, or even a loss due to a surcharge being levied on waste tyre recycling, depends on the sale of the pyrolysis products (gas, char, oil), the proportions and market prices of which differ. The cheapest...
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A Note on Reduced Strain Gradient Elasticity
PublicationWe discuss the particular class of strain-gradient elastic material models which we called the reduced or degenerated strain-gradient elasticity. For this class the strain energy density depends on functions which have different differential properties in different spatial directions. As an example of such media we consider the continual models of pantographic beam lattices and smectic and columnar liquid crystals.
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Detection of the Direct Sequence Spread Spectrum Signals with BPSK Modulation
PublicationThis paper presents a method of the DS CDMA signals with BPSK modulation detection through the examination of the enhanced signal spectrum density. On the base of experiments carried out on the real radio communication signals the impact of a narrowband emission occurring in the examined frequency band on the detection process effectiveness was shown. The results of the experiment aimed at the detection of the satellite navigation...
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Compensation of magnetic disturbances caused by sensors in a differential magnetometric system
PublicationStudy of low magnetic fields necessitates the use of precision magnetometers working in a differential system. Minimization of this error is a substantial issue in the case of magnetometers working in a differential system on a mobile platform. The compensation method of heading error consists in taking measurements of changes in magnetic induction with the use of the tested magnetometer for various locations of the sensor in relation...
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Fault Diagnostics in PEMFC Stacks by Evaluation of Local Performance and Cell Impedance Analysis
PublicationStarvation, flooding, and dry‐out phenomena occur in polymer electrolyte membrane fuel cells (PEMFCs), due to heterogeneous local conditions, material inhomogeneity, and uneven flow distribution across the single cell active area and in between the individual cells. The impact of the load level and air feed conditions on the performance was identified for individual single cells within a 10‐cell stack. Analysis of the current density...
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SrCe0.9In0.1O3-δ-based reversible symmetrical Protonic Ceramic Cell
PublicationIn-doped SrCe0.9In0.1O3-δ (SCI) perovskite-type oxide is utilized as the solid electrolyte, as well as a component, together with SrFe0.75Mo0.25O3-δ (SFM) compound, in the composite-type electrodes to construct symmetrical Protonic Ceramic Fuel Cells (PCFC). With good mutual stability of SCI and SFM at high temperatures in water vapor-containing reducing and oxidizing conditions, as well as sufficient ionic conductivity with high...
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Effects of Bromine Doping on the Structural Properties and Band Gap of CH3NH3Pb(I1–xBrx)3 Perovskite
PublicationAn experimental and theoretical study is reported to investigate the influence of bromine doping on CH3NH3Pb(I1−xBrx)3 perovskite for Br compositions ranging from x = 0 to x = 0.1, in which the material remains in the tetragonal phase. The experimental band gap is deduced from UV−vis absorption spectroscopy and displays a linear behavior as a function of bromine concentration. Density functional theory calculations are performed...
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The Design Development of the Sliding Table Saw Towards Improving Its Dynamic Properties
PublicationCutting wood with circular saws is a popular machining operation in the woodworking and furniture industries. In the latter sliding table saws (panel saws) are commonly used for cutting of medium density fiberboards (MDF), high density fiberboards (HDF), laminate veneer lumber (LVL), plywood and chipboards of different structures. The most demanded requirements for machine tools are accuracy and precision, which mainly depend on...
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On the crack front curvature in bonded joints
PublicationStandard tests of adhesively bonded specimens are likely to produce heterogeneous stress distribution along the crack front and its vicinity. High separation rate mode I dominated fracture test is performed.Observation of post mortem fractured surfaces with an optical microscope reveals characteristic features of mixed mode I/III fracture near the sides of the specimen but not in the middle. At first, finite elements calculations...
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Application of BDD thin film electrode for electrochemical decomposition of heterogeneous aromatic compounds
PublicationThe aim of the presented study is to investigate the applicability of electrochemical oxidation of aromatic compounds containing heteroatoms, e.g. waste from production of pesticides or pharmaceutics, at a borondoped diamond (BDD) electrode. The BDD electrodes were synthesized by microwave plasma enhanced chemical vapour deposition (MW PE CVD). Investigation of the electrode surface by optical microscopy and scanning electron microscopy...
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Gas Detection Using Resistive Gas Sensors And Radial Basis Function Neural Networks
PublicationWe present a use of Radial Basis Function (RBF) neural networks and Fluctuation Enhanced Sensing (FES) method in gas detection system utilizing a prototype resistive WO3 gas sensing layer with gold nanoparticles. We investigated accuracy of gas detection for three different preprocessing methods: no preprocessing, Principal Component Analysis (PCA) and wavelet transformation. Low frequency noise voltage observed in resistive gas...
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Thermomagnetic behavior of a semiconductor material heated by pulsed excitation based on the fourth-order MGT photothermal model
PublicationThis article proposes a photothermal model to reveal the thermo-magneto-mechanical properties of semiconductor materials, including coupled diffusion equations for thermal conductivity, elasticity, and excess carrier density. The proposed model is developed to account for the optical heating that occurs through the semiconductor medium. The Moore–Gibson–Thompson (MGT) equation of the fourth-order serves as the theoretical framework...
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Multi-objective optimization of tool wear, surface roughness, and material removal rate in finishing honing processes using adaptive neural fuzzy inference systems
PublicationHoning processes are usually employed to manufacture combustion engine cylinders and hydraulic cylinders. A crosshatch pattern is obtained that favors the oil flow. In this paper, Adaptive Neural Fuzzy Inference System (ANFIS) models were obtained for tool wear, average roughness Ra, cylindricity and material removal rate in finish honing processes. In addition, multi-objective optimization with the desirability function method...
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Cascaded Buck Hybrid Interlink Converter for Multiple-Input / Multiple-Output Operation
PublicationThe provision of isolated- and non-isolated DC output voltages by Power electronics power-conditioning devices in the recent ‘green-energy-revolution’ era is on course. In this paper, a structure for multi-input multi-output(MIMO) DC–DC buck converter is proposed to generate output voltages of varying levels with fewer component-count. The DC output voltage of each of the constituting buck converters can be used independently or...
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[ITiT] Transmission Channel in Radio Communication Systems - 2023/2024
e-Learning Courses{mlang pl} Dyscyplina: informatyka techniczna i telekomunikacja Zajęcia fakultatywne dla doktorantów II roku Prowadzący: dr hab. inż. Sławomir Ambroziak, prof. PG Liczba godzin: 15 Forma zajęć: wykład {mlang} {mlang en} Discipline: technical informatics and telecommunications Elective course for 2nd-year PhD students Academic teachers: dr hab. inż. Sławomir Ambroziak, prof. PG Total hours of training: 15 teaching hours Course...
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[ITiT] Transmission Channel in Radio Communication Systems
e-Learning Courses{mlang pl} Dyscyplina: informatyka techniczna i telekomunikacja Zajęcia fakultatywne dla doktorantów II roku Prowadzący: dr hab. inż. Sławomir Ambroziak, prof. PG Liczba godzin: 15 Forma zajęć: wykład {mlang} {mlang en} Discipline: technical informatics and telecommunications Elective course for 2nd-year PhD students Academic teachers: dr hab. inż. Sławomir Ambroziak, prof. PG Total hours of training: 15 teaching hours Course...