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Search results for: electrodes
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 16. Synthesis of 25, 26, 27, 28-tetrakis(piperidinethiocarbonylmethylene)-p-tert-butylcalix[4]arene and its interaction with metal ions
PublicationThe synthesis, characterisation and X-ray crystal structures of p-tert-butyl-calix[4]arenethioamide L and its complex with lead L-Pb2+ is reported. The cation-binding properties in solution have been assessed by liquid-liquid extraction of the metal picrates from water into dichloromethane and by stability constants determination in acetonitrile using UV-absorption spectrophotometry or potentiometry. The compound was used as active...
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Is the Solid Electrolyte Interphase an Extra-Charge Reservoir in Li-Ion Batteries?
PublicationAdvanced metal oxide electrodes in Li-ion batteries usually show reversible capacities exceeding the theoretically expected ones. Despite many studies and tentative interpretations, the origin of this extra-capacity is not assessed yet. Lithium storage can be increased through different chemical processes developing in the electrodes during charging cycles. The solid electrolyte interface (SEI), formed already during the first...
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Selection of Electrode Material for Inconel 617/P92 Steel SMAW Dissimilar Welds
PublicationThe present work aimed to investigate the microstructure and mechanical properties of the dissimilar shielded metal arc welded (SMAW) joint of Alloy 617 and P92 steel for advanced ultrasupercritical boilers. The SMAW joint was produced using three different types of electrodes, namely, ENiCrFe-3, ENiCrMo-3, and ENiCrCoMo-1. During microstructural observation of the welded joints, no possible cracking was detected in the weldments....
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Wpływ rodzaju zanieczyszczenia powierzchni odlewu ze staliwa LH14 na jakość napoin wykonanych elektrodą otuloną
PublicationNapawanie jest szeroko stosowaną metodą naprawiania powierzchni. Pozwala między innymi na uzupełnienie miejsc, w których uprzednio wystąpiły wżery korozyjne. Techniki napawania wykorzystywane są również do przywracania pierwotnego kształtu zużytych części. W pracy wykonano badania napoin wykonanych elektrodami otulonymi na czołowych powierzchniach cylindrycznych próbek ze staliwa LH14. Proces wykonywano dwoma rodzajami elektrod:...
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Multi-DBD actuator with floating interelectrode for aerodynamic control
PublicationIn this paper the use of a floating inter-electrode in a multi-DBD (dielectric barrier discharge) plasma actuator is described. The multi-DBD plasma actuators with floating inter-electrodes were investigated to get a longer DBD on a dielectric surface and to maximise generated net airflow. Our actuator was used to control the boundary layer flow separation around NACA0012 airfoil model. The results of our investigations suggests...
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Weldability of S460ML High Strength Low Alloy Steel in Underwater Conditions
PublicationThe paper presents experimental evaluation of susceptibility of the high strength S460ML steel to cold cracking in the conditions of wet welding with the use of covered electrodes. From the results of Tekken tests it was found out that the investigated steel was characterised, in the conditions of the carried out experiments (underwater wet welding and air welding with rutile electrodes), of high susceptibility to cold cracking....
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A Comprehensive Analysis of Impedance of the Electrochemical Cell
PublicationA comprehensive impedance characteristics of two electrodes electrochemical cell has been pre sented. In this method a multisinusoidal current excitation signal is used. The change of potential of both the electrodes are all registered as a function of time. The proposed method gives the possibility of determining the impedance of both electrodes individually as well as the impedance of a twoelectrode system. Additional application...
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Simultaneous determination of Na+, K+, Ca2+, Mg2+ and Cl- in unstimulated and stimulated human saliva using all solid state multisensor platform
PublicationHuman saliva is one of the body fluids which collection method is relatively simple and non-invasive. The article is dedicated to assess concentration (activity) of Na+, K+, Ca2+, Mg2+ and Cl- in fresh, unstimulated or stimulated human saliva samples using single solid contact ion-selective electrodes with conventional reference electrode and self-made multisensor platform (MP) equipped with ion-selective membranes for Na+, K+,...
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Chromogenic derivatives of new bis(phenylhydrazono-1H-tetrazol-5-yl-acetonitriles) - synthesis and properties
PublicationDerivatives of bis(phenylhydrazono-1H-tetrazol-5-yl-acetonitriles) with oxygen and sulphur atoms in the structure of aliphatic chains were successfully synthesised. The correlation between the ligand structure and its complexation properties was investigated by absorption spectroscopy. The formation of complexes of presented compounds with metal cations (Cu2+, Ni2+, Zn2+, Co2+, Fe2+ and Pb2+) was studied. Ligands 5-8 were additionally...
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Wybrane aspekty oceny jakości produktów żywnościowych
PublicationPrzedstawiono wybrane aspekty oceny jakości produk tów żywnościo- wych: pojęcie jakości, wybrane metody oceny jakości ze szczególnym uwzględ- nieniem sztucznych potencjometrycznych sensorów sma ku składających się z szeregu elektrod typu ISE (Ion Selective Electrodes ) oraz ASSE (All Solid State Electrodes). Omówiono działanie sztucznych sensorów smaku. Przedstawiono 10 potencjometryczny sensor wprowadzony do obrotu hand lowego....
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Electrochemical characterization of a composite comprising PEDOT/PSS and N doped TiO2 performed in aqueous and non-aqueous electrolytes
PublicationNitrogen doped titania (N-TiO2) was used as an inorganic component of composite electrodes containing poly(3,4-ethylenedioxythiophene) with poly(4-styrenesulphonate) PEDOT/PSS/N-TiO2. The composite materials were obtained by direct electrodeposition from an N-TiO2 suspension containing polyelectrolyte (NaPSS) and monomer EDOT. The electrodes were electrochemically tested in aqueous and non-aqueous electrolytes using cyclic voltammetry...
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Lower rim substituted p-tert-butyl-calix[4]arene. Part 17. synthesis, extractive and ionophoric properties of p-tert-butylcalix[4]arene appended with hydroxamix acid moieties
PublicationThe synthesis and characterization of four p-tert-butylcalix[4]arene-hydroxamic acidc are reported. The dependence of the metal ion binding, assessed by liquid extraction of the metal nitrates from water into dichloromethane in individual and competitive experiments, on the ligand structure, is presented. The results showed that those ligands could be successfully used in separation process of trnasition and heavy metals often...
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Synthesis and properties of new 'N,'N-phenyltetrazole podand
PublicationThe synthesis of a new chromogenic N,N-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity...
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Electric transport in organic system with planar DBP/F16ZnPc junction on the basis of direct current and small signal admittance spectra analysis
PublicationThe objective of this work was to determine electric transport in the organic device based on a planar junction of electron donor and electron acceptor materials, namely ITO/MoO3/DBP/F16ZnPc/BCP/Ag. The analysis reported herein was based on direct current-voltage measurements and small-signal admittance spectra in the dark and under illumination. Such analysis may provide information on potential barriers, parasitic resistances...
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Diffusible hydrogen content in deposited metal of multilayer welded joints
PublicationThe article describes manufacturing technology of multilayer joints in terms of control the diffusible hydrogen content. Diffusible hydrogen content in deposited metal for multilayer welded joints made of covered rutile electrodes or covered cellulosic and basic electrodes was determined. It was found that after four beads, the diffusible hydrogen content decreases in the case of the first technology from 36 ml/100 g to 18 ml/100...
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Electrohydrodynamic secondary flow and particle collection efficiency in spike-plate multi-electrode electrostatic precipitator
PublicationIn this work the results of electrohydrodynamic (EHD) secondary flow measurements in a spike-plate type electrostatic precipitator (ESP) are presented. In the investigated ESP two-sided and one-sided spike electrodes were used as a discharge electrodes. The results of 2D PIV measurements showed that flow pattern obtained for a different spike tips positions in respect to the primary flow direction significantly changing the flow...
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Electrohydrodynamic Secondary Flow and Particle Collection Efficiency in Spike-Plate Multi-Electrode Electrostatic Precipitator
PublicationIn this work the results of electrohydrodynamic (EHD) secondary flowmeasurements in a spike-plate type electrostatic precipitator (ESP) are presented. In the investigated ESP two-sided and one-sided spike electrodes were used as a discharge electrodes. The results of 2D PIVmeasurements showed that flow pattern obtained for a different spike tips positions in respect to the primary flow direction significantly changing the flow...
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Particle Image Velocimetry Measurements of Airflow in Electrohydrodynamic Device for Dust Particle Collection
PublicationIn this paper the pumping effect of air in the electrohydrodynamic (EHD) device for dust particle collection is presented. To induce an airflow in this EHD device corona discharge was used. The discharge was generated between the one-sided spike electrodes and the plate electrodes. The asymmetric electric field and generated discharge resulted in a unidirectional airflow through the EHD device. The current-voltage characteristics...
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Particle Image Velocimetry Measurements of Airflow in Electrohydrodynamic Device for Dust Particle Collection
PublicationIn this paper the electrohydrodynamic (EHD)device for gas pumping and cleaning is presented. To induce an airflow in this EHD device corona discharge was used. The discharge was generated between the one-sided spike electrodes and the plate electrodes. An asymmetric electric field and generated discharge result in unidirectional gas flow through the EHD device. The current-voltage characteristics were measured and the corona discharge...
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Respiratory signals derived from capacitive electrocardiogram on the smart chair
PublicationCapacitive electrocardiogram (CECG) tends to deliver basic cardiac signals without need to use traditional glued electrodes. In the paper analysis of possibility if the ECG derived respiratory waveforms out of the CECG.
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Development of iron doped strontium titanates as oxygen electrode for solid oxide fuel cells
PublicationProducing efficient solid oxide fuel cells (SOFC) without the use of harmful elements is one of the current challenges. Increasing the safety of people and reducing production costs is possible, among others, thanks to the use of iron doped strontium titanates as porous oxygen electrodes. In this thesis, the results of research on iron doped strontium titanates as potential oxygen electrodes for SOFC are presented. The research...
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Comparison of the paracetamol electrochemical determination using boron-doped diamond electrode and boron-doped carbon nanowalls
PublicationTwo different type of electrodes, boron-doped diamond electrode (BDD) and boron-doped carbon nanowalls (B:CNW) electrode, were used for the electrochemical determination of paracetamol using the cyclic voltammetry and the differential pulse voltammetry in phosphate buffered saline, pH = 7.0. The main advantage of these electrodes is their utilization without any additional modification of the electrode surface. The peak current...
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Potentiometric Solid-Contact Multisensor System for Simultaneous Measurement of Several Ions
PublicationThe design and performance of potentiometric multisensor system made in solid-contact technology is described. Both, the measuring electrodes as well as the reference electrode are in a compact cell. The system allows for simultaneous measurement of various ions. The characteristics of the electrodes for Na+, K+ and Ca2+ ions were determined using the designed system and compared with ISEs of the same membrane composition in classical...
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A complete impedance analysis of electrochemical cells used as energy sources
PublicationA comprehensive description of impedance ofelectrochemical systems has been presented, along withthe assumptions of the method used. In this method, amultisinusoidal current excitation signal is used. Thechanges of potential of both the electrodes and thepotential difference between these electrodes are allregistered simultaneously as a function of time. Theproposed method offers the possibility of separatelydetermining the instantaneous...
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Optimal ECG lead for deriving respiratory signal
PublicationEDR is an interesting measuring technique that allows an indirect assessment of respiratory activity. This is an alternative solution to direct methods that are based on the measurement of air flow, which require a specialized sensor or even a system. However, due to inter-personal anatomical differences, the optimal ECG lead (placement of the electrodes) ensuring the best EDR signal quality is not fixed. An influence of ECG lead...
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Enhancement of lift and drag performances of a NACA0012 airfoil by multi-DBD plasma actuator with additional floating interelectrodes
PublicationIt is clear that the improvement of aircraft aerodynamic performances is currently and will continue to be a significant area of research for the aeronautical industry. The current study is focused on theenhancement of aerodynamic airfoil performances by using a multi-DBD plasma actuator mounted around the model leading-edge. Experiments have been conducted at the University of Orleans, in the 2 m x 2 m test section of a large...
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Effect of oxygenation time on signal of a sensor based on ionic liquids
PublicationThe paper presents an oxygen sensor based on ionic liquids and solid electrodes. The following ionic liquids have been employed: [BMIM][BF4], [HMIM][Cl], [BMIM][N(CN2)]. Minimum time of the sensor exposure to analyte, after which the signal (current intensity) was stable, has been evaluated. An impact of volumetric flow rate of analyte on the sensor exposure time and signal has been determined. A product of permeability coefficient...
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Improvement of Oxygen Electrode Performance of Intermediate Temperature Solid Oxide Cells by Spray Pyrolysis Deposited Active Layers
PublicationIntermediate temperature solid oxide fuel cells oxygen electrodes are modified by active interfacial layers. Spray pyrolysis is used to produce thin (≈500 nm) layers of mixed ionic and electronic conductors: Sm0.5Sr0.5CoO3−δ (SSC), La0.6Sr0.4CoO3−δ (LSC), La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF), and Pr6O11 (PrOx) on the electrode–electrolyte interface. The influence of the annealing temperature on the electrode polarization (area specific...
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Closing the loop: Upcycling secondary waste materials into nanoarchitectured carbon composites for the electrochemical degradation of pharmaceuticals
PublicationIn this study, we demonstrated the application of electrochemical oxidation as a safer and cleaner technology for minimizing the impact of pharmaceuticals in wastewaters, simultaneously mediated by upcycled secondary waste materials (SWMs)-derived electrodes, to further reduce their environmental impact. The modularity, scalability, ease of operation and reliability make electrochemical oxidation an ideal process for the destruction...
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Investigation of electrocatalytic gas sensor properties in presence of chlorine
PublicationProperties of sensor based on Nasicon with two round shaped platinum electrodes are investigated. Influence of different chlorine concentrations on the sensor response is presented. Measurements in different temperatures have been performed in order to determine optimal sensor working temperature.
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Electrohydrodynamic Flow Patterns in a Narrow Electrostatic Precipitator with Longitudinal Wire Electrode for Various Electrode Geometries
PublicationRecently narrow electrostatic precipitators (ESPs) have become a subject of interest because of their possible application in diesel engines. In this paper results of 2-dimensional (2D) Particle Image Velocimetry (PIV) measurements of the flow patterns in a narrow ESP for a various electrode geometries are presented. The PIV measurements were carried out in the observation plane that is perpendicular to the ESP duct. The ESP was...
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Analysis of thoracic regional impedance changes using PCA approach
PublicationA multichannel impedance and one lead electrocardiographic recording system has been developed. The impedance measurement unit is built using a four-electrode technique. It consists of a sinusoidal, 40 kHz, current source and five measurement channels. Circumferential current electrodes have been located at a neck and an abdomen. Voltagemeasurement disk electrodes formed five two-electrode measurement ports. The impedance change...
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Pumping effect measured by PIV method in a multilayer spike electrode EHD device for air cleaning
PublicationDust particles can be harmful for human health when inhaled. Particularly dangerous are submicrometer dust particles, which can contain traces of toxic elements and can easily penetrate into the human respiratory system. Thus, efficient devices for the air cleaning from submicrometer dust particles are needed. Recently, Katatani and Mizuno have proposed an electrohydrody- namic (EHD) device for air cleaning for submicrometer particles....
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Effect of electrode waterproof coating on quality of underwater wet welded joints
PublicationIn this paper, the effects of different hydrophobic coatings on the surface of covered electrodes on the quality of wet welded carbon steel joints were discussed. Commonly available hydrophobic substances used in industrial applications were selected for the research. The aim of using waterproof coatings was to check the possibility to decreasing the susceptibility of highstrength low-alloy S460N steel to cold cracking. During...
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Electrochemistry from first-principles in the grand canonical ensemble
PublicationProgress in electrochemical technologies, such as automotive batteries, supercapacitors, and fuel cells, depends greatly on developing improved charged interfaces between electrodes and electrolytes. The rational development of such interfaces can benefit from the atomistic understanding of the materials involved by first-principles quantum mechanical simulations with Density Functional Theory (DFT). However, such simulations are...
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Simple synthesis route for fabrication of protective photo‐crosslinked poly(zwitterionic) membranes for application in non‐enzymatic glucose sensing
PublicationThis work focuses on the fabrication of non-enzymatic glucose sensing materials based on laser-formed Au nanoparticles embedded in Ti-textured substrates. Those materials possess good catalytic activity toward glucose oxidation in 0.1 × phosphate buffered saline as well as resistance to some interferants, such as ascorbic acid, urea, and glycine. The electrodes are further coated with three different polymers, that is, Nafion,...
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The abrasive wear resistance of coatings manufactured on high-strength low-alloy (HSLA) offshore steel in wet welding conditions
PublicationSome marine and offshore structure elements exploited in the water cannot be brought to the surface of the water as this will generate high costs, and for this reason, they require in-situ repairs. One of the repair techniques used in underwater pad welding conditions is a wet welding method. This paper presents an investigation of the abrasive wear resistance of coatings made in wet welding conditions with the use of two grades...
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Electrochemical impedance spectroscopy spectra measured at 800 °C, 750 °C and 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrode sintered at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at 800 °C. EIS spectra were measured at 800 °C; 750°C and 700 °C (synthetic air). Results converted to electrode surfaces area and dived by two electrodes.
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Microscale microbial fuel cell (MFC) batch experiment results
Open Research DataThis dataset provides the results of six different scenarios meant to assess the efficiency COD, TN, TP removal and voltage generation in microbial fuel cells (MFC).
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Collection Efficiency in Narrow Electrostatic Precipitators with a Longitudinal or Transverse Wire Electrode
PublicationRecently narrow electrostatic precipitators (ESPs) have become a subject of interest because of their possible application in diesel engine exhaust systems. In this work, results of particle collection efficiency measurements in narrow electrostatic precipitators for negative and positive dc voltage polarity are presented. The ESP usedin this work was a parallelepiped equipped with wire discharge electrode and two collecting plate-electrodes....
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ECG measurement in the bathtub - getting into the bathtub- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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Influence of sintering temperature of porous SrTi0.50Fe0.50O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.65Fe0.35O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Influence of sintering temperature of porous SrTi0.30Fe0.70O3-d oxygen electrode on electrochemical impedance spectroscopy spectra measured at 800 °C
Open Research DataThis dataset contains results electrochemica impedance spectroscopy (EIS) of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures (800 °C; 900 °C and 1000 °C). Measure temperature was 800 °C (syntetic air, 40 ml min-1). Results converted to electrode surfaces area and dived by two electrodes.
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Investigation of electrocatalytic gas sensor properties in presence of chlorine
PublicationIn this paper performance of an electrocatalytic sensor in presence of chlorine is investigated. Presented studies concern sensor prepared in ceramic technology based on NASICON as a solid electrolyte with two round shaped platinum electrodes. Measurements in different temperatures have been performed in order to determine optimal sensor working temperature.
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ECG measurement in the bathtub - drl on the outside of the bathtub on one side- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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ECG measurement in the bathtub - one side of the bathtub is grounded, drl outside the bathtub - men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...
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ECG measurement in the bathtub - drl on one side of the bath mass on the other - the person is moving- men
Open Research DataThe measurement data shows the measurement of the ECG signal in water in the bathtub. The data includes the measurement time, the reference ECG signal from the chest, and the ECG signal measured by electrodes placed in the bathtub without contact with the human body. Using the presented data, it is possible to estimate the optimal arrangement of measuring...