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Chemoinformatic Approach to Assess Toxicity of Ionic Liquids
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Random height of thin layer of rheological liquids
PublicationPraca prezentuje nowe modele funkcji gęstości w rozkładach Gaussa, opisujących losowo zmieniającą się wysokość szczeliny w stawie biodrowym człowieka przy uwzględnieniu właściwości reologicznych synowialnej cieczy smarującej.
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Wykorzystanie lipaz do produkcji strukturyzowanych lipidów.
PublicationOmówiono metody otrzymywanie strukturyzowanych lipidów na drodze enzymatycznego przeestryfikowania oraz żywieniowe i funkcjonalne znaczenie tak uzyskanych produktów. Pokazano specyficzność lipaz i wykorzystanie ich jako biokatalizatorów w procesie przeestryfikowania. Omówiono także źródła substratów olejów i donorów acyli, używanych do produkcji strukturyzowanych lipidów.
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Rapid test for ionic liquids toxicity evaluation
PublicationW literaturze przedmiotu dostępne są dane na temat toksyczności cieczy jonowych, szczególności tych mających zastosowanie przemysłowe, gdzie toksyczność wyrażana jest jako EC50 mierzone względem konkretnego organizmu np. Vibrio fischeri, Daphnia magna itp. Z uwagi na taksonomiczne zróżnicowanie osadu czynnego nie jest możliwe bezpośrednie wnioskowanie na temat toksyczności cieczy jonowych w stosunku do osadu czynnego na podstawie...
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Ionic liquids - greener solvents or environmental threat?
PublicationZe względu na niemierzalnie niską prężność par ciecze jonowe były uważane za 'zielone rozpuszczalniki'. Ich zastosowanie w technologiach (bio)chemicznych przynosi korzyści nie tylko ekologiczne ale również ekonomiczne. Niemniej jednak zanieczyszczenie środowiska poprzez przedostanie się cieczy jonowych do gleb i wód gruntowych wraz ze ściekami/odciekami przemysłowymi lub w wyniku przypadkowych rozlewów stanowi realne zagrożenie....
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Application of Ionic Liquids in Amperometric Gas Sensors
PublicationThis article presents an analysis of available literature data on metrological parameters of the amperometric gas sensors containing ionic liquids as an electrolyte. Four mechanism types of signal generation in amperometric sensors with ionic liquid are described. Moreover, this article describes the influence of selected physico-chemical properties of the ionic liquids on the metrological parameters of these sensors. Some metrological...
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Application of ionic liquids for gas separation processes
PublicationNowym kierunkiem w procesach separacji dwutlenku węgla stało się w ostatnich latach zastosowanie cieczy jonowych. Niemierzalna prężność par i możliwość dostosowania ich właściwości czyni je idealnymi mediami zastępującymi lotne, korozyjne i toksyczne rozpuszczalniki. Ponadto ciecze jonowe wykazują niską współabsorpcję innych gazów. Dlatego też, możliwe jest selektywne odseparowanie dwutlenku węgla z mieszanin gazowych
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Review of ionic liquids applications in chemical processes
PublicationCiecze jonowe stały się obiektem zainteresowania naukowców. Składają się one z dużego organicznego kationu i małego anionu. Modyfikacje kationu i anionu pozwalają na dostosowanie ich właściwości do aktualnych potrzeb. Rozpuszczają one szerokie spektrum związków organicznych i nieorganicznych związków. Mogą zatem z powodzeniem zastąpić dotychczas stosowane tradycyjne rozpuszczalniki. Znajdują zastosowanie jako medium reakcyjne,...
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Aggregation of nonionic surfactants in imidazolium ionic liquids
PublicationMicellar aggregation of surfactants in aqueous solutions has been described in terms of the balance between dispersive interactions of the hydrocarbon part of the amphiphilic molecule, and the hydration and electrostatic repulsive effects of hydrophilic head group. Changing the interactions by replacing water with another polar solvent, such as amides or glycols, has been studied to a smaller extent (Singh, Saleem et al. 1980;...
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Application of ionic liquids in electronic nose instruments
PublicationAmong many applications in different fields of science and technology the ionic liquids (ILs) are also utilised in chemical sensors yielding improvement of their operation parameters (Buzzeo, 2004; Wei and Ivaska, 2008; Silvester, 2011; Gebicki et al., 2013). Some of these chemical sensors are the components of the devices, which resemble human sense of smell as far as their operation is concerned. These devices are named electronic...
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Investigation on the behaviour of imidazolium ionic liquids in the environment
PublicationCiecze jonowe są solami o niskiej temperaturze topnienia, które mogą zrewolucjonizować przemysł chemiczny ponieważ w wielu przypadkach oferują zarówno ekonomiczny jak i ekologiczny zysk w porównaniu z dotychczas stosowanymi technologiami. Imidazoliowe cieczejonowe należą do najczęściej stosowanych co sprawia, że mogą stanowić źródło zanieczyszczenia środowiska glebowego i wodnego. Niektóre parametry środowiskowe (np. biodegradowalność,...
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The Co-Culture of Staphylococcal Biofilm and Fibroblast Cell Line: The Correlation of Biological Phenomena with Metabolic NMR1 Footprint
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Frequency and phase analysis of daily reprocessed solutions from selected EPN stations relating to geological phenomena,
PublicationThe main assumption of this research was to check and verify the behaviour of a few EPN (European Permanent Network) stations on both sides of the Teisseyre-Tornquist zone (T-T zone), which is located on Polish territory and crosses Poland almost in half. The selected EPN stations’ time series were a subject of frequency and phase analysis. The main purpose of the research was to verify if there is any correspondence between stations...
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Deproteinated Potato Wastewater as a Sustainable Nitrogen Source in Trichosporon domesticum Yeast Lipids Biosynthesis—a Concept of Valorization of Wastewater from Starch Industry
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Interface analysis of compatibilized polymer blends
PublicationThis chapter seeks to address the interface location in the compatibilized polymer blends and paves the way for quantitative analysis of interface in terms of interfacial tension and interfacial adhesion to provide support for understanding the relationship between morphology and ultimate properties in the compatibilized polymer blends through the lens of interface. Since understanding and analysis of interfacial phenomena in the...
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Human UDP-Glucuronosyltransferases: Effects of altered expression in breast and pancreatic cancer cell lines.
PublicationIncreased aerobic glycolysis and de novo lipid biosynthesis are common characteristics of invasive cancers. UDP-glucuronosyltransferases (UGTs) are phase II drug metabolizing enzymes that in normal cells possess the ability to glucuronidate these lipids and speed their excretion; however, de-regulation of these enzymes in cancer cells can lead to an accumulation of bioactive lipids, which further fuels cancer progression. We hypothesize...
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Lipid mediators involved in the oxidative stress and antioxidant defence of human lung cancer cells
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Effect of intensive lipid-lowering therapies on cholinesterase activity in patients with coronary artery disease
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The lipid composition of Legionella dumoffii membrane modulates the interaction with Galleria mellonella apolipophorin III
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In vitro photodynamic activity of lipid vesicles with zinc phthalocyanine derivative against Enterococcus faecalis
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Serum lipid profile discriminates patients with early lung cancer from healthy controls
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Simvastatin Coadministration Modulates the Electrostatically Driven Incorporation of Doxorubicin into Model Lipid and Cell Membranes
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Influence of a lipid bilayer on the conformational behavior of amphotericin B derivatives - A molecular dynamics study.
PublicationAmphotericin B (AmB) is an effective but very toxic antifungal antibiotic. In our laboratory a series of AmB derivatives of improved selectivity of action was synthesized and tested. To understand molecular basis of this improvement, comparative conformational studies of amphotericin B and its two more selectivederivatives were carried out in an aqueous solution and in a lipid membrane. These molecular simulation studies revealed...
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Blood plasma protein and lipid profile changes in calves during the first week of life
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Longitudinal study of vitamins A, E and lipid oxidative damage in human milk throughout lactation
PublicationCelem pracy było zbadanie zmian wartości całkowitego potencjału antyoksydacyjnego (TAS), stężeń witamin antyoksydacyjnych i izoprostanów (markery stresu oksydacyjnego) w siarze i mleku dojrzałym. Badaniami objęto 49 kobiet po pełno terminowej ciąży i naturalnym porodzie. Kryteria wyłączenia to czynne i bierne palenie tytoniu, ostre i przewlekłe schorzeniach oraz farmakoterapia inna niż suplementacja witamin. Próbki siary pobierano...
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Electron attachment to representative cations composing ionic liquids
PublicationUsing ab initio electronic structure methods with flexible atomic orbital basis sets, we investigated the electronic structure and stability of reduction products of selected representative cations (C+) constituting ionic liquids. We found that an electron attachment to such cations leads to the neutral radicals, whereas a subsequent attachment of another (i.e., excess) electron leads to adiabatically stable anions only in two...
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Free silanols and ionic liquids as their suppressors in liquid chromatography
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Micelle formation of imidazolium ionic liquids in aqueous solution
PublicationCiecze jonowe (ILs) stanowią nową klasę związków o szerokich możliwościach przemysłowego zastosowania. Z przeglądu dostępnej literatury wynika, że niektóre ciecze jonowe tworzą agregaty w roztworach wodnych. W celu określenia jak tworzenie agregatów może wpływać na przebieg procesów technologicznych, dystrybucję w środowisku oraz toksyczność konieczne jest przeprowadzenie systematycznych badań dotyczących właściwości powierzchniowych...
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Hydrogen degradation of structural steels in technical hydrocarbon liquids
PublicationDla stali stopowych przeprowadzono badania absorpcji wodoru, mechaniczno-korozyjne przy stałej małej prędkości odkształcania, przy stałym obciążeniu i przy obciążeniu cyklicznie-zmiennym. Środowiskiem było paliwo kotłowe, przepracowany olej mineralny oraz gliceryna. Stwierdzono, iż pochłonięty wodór nie powoduje przedwczesnego zniszczenia stali poddanych działaniu stałego obciążenia ponizej granicy plastyczności oraz, że zaabsorbowany...
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Self-organization of imidazolium ionic liquids in aqueous solution
PublicationW pracy przeanalizowano i podsumowano wyniki badań nad samoorganizacją oraz tworzeniem micel cieczy jonowych w roztworach wodnych otrzymane przez wiele zespołów badawczych. Średnio i długołańcuchowe imidazoliowe ciecze jonowe wykazują aktywność powierzchniową zależną od długości łańcucha alkilowego w kationie, analogicznie do kationowych surfaktantów. Wskazano na liczne zagadnienia, które wymagają dalszych systematycznych badań
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Aggregate formation of imidazolium ionic liquids in aqueous solution
PublicationCiecze jonowe (ILs) stanowią nową klasę związków o szerokich możliwościach przemysłowego zastosowania. Z przeglądu dostępnej literatury wynika, że niektóre ciecze jonowe tworzą agregaty w roztworach wodnych. Zrozumienie oddziaływań międzycząsteczkowych cieczy jonowych w środowisku wodnym jest niezbędne dla prawidłowego projektowania, przewidywania i kontroli ich właściwości jako współ-rozpuszczalników, a w konsekwencji procesów...
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Interaction of imidazolium type ionic liquids with the solid phase
PublicationNiektóre ciecze jonowe, w szczególności te posiadające kation organiczny podstawiony długim łańcuchem alkilowym, wykazują strukturalne podobieństwo do surfaktantów. Samoczynne formowanie się agregatów cieczy jonowych może wpływać na procesy przenoszenia masy w wielu operacjach jednostkowych jak: ekstrakcja, nanofiltracja lub kataliza oraz transport i rozmieszczenie tych związków w środowisku naturalnym. W niniejszej publikacji...
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Thermodynamics of micellization of imidazolium ionic liquids in aqueous solutions
PublicationPodobieństwo pomiędzy strukturami niektórych cieczy jonowych, a surfaktamtami jonowymi wskazuje na możliwość wykazywania, przez te związki, tendencji do agregacji i adsorpcji na powierzchniach międzyfazowych. Mierząc w różnych temperaturach przewodnictwo elektryczne w funkcji stężenia oznaczono temperaturę Kraffta i zależność temperaturową krytycznego stężenia micelizacji (CMC) dla czterech, różniących się długościami łańcucha,...
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Estimation of flow for tissue perfusion of nutrient liquids in bioreactor.
PublicationPrzedstawione zostały problemy związane z wyznaczaniem pola prędkości w warstwie przyściennej opływanej tkanki miękkiej w bioreaktorze. Warunki brzegowe na powierzchni miękkiej tkanki o właściwościach porowatych zostały w niniejszej pracy sformułowane.
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THE ROLE OF NATURE IN PLACEMAKING WITHIN THE LIMITS OF HISTORIC CITIES
PublicationThis paper focuses on the role of nature in placemaking within historic cities. There are two different approaches to placemaking – The first is a more traditional approach, i.e. complete building process which entails significant investments. The second is “Lighter, Quicker, Cheaper” approach proposed by the Project for Public Spaces organization. This article discusses the role, importance and place of nature in both approaches....
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Study of Icosahedral Clusters in Close-packed Simple Liquids
PublicationThe local structure of liquid copper was determined using Steinhardt order parameters, with particular attention paid to icosahedral clusters. The positions of atoms were obtained from three sets of molecular dynamics simulations, with the forces obtained from: the Sutton-Chen (SC) potential, the Naval Research Laboratory total energy tight-binding (NRL-TB) method and the divide-and-conquer learn-on-the-fly (DCLOTF) method, respectively....
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Studies on micellar aggregation of nonionic surfactants in imidazolium liquids
PublicationA number of imidazolium ionic liquids, with 2-8 carbon atoms in cation alkyl chains, and tetrafluoroborate, hexafluorophosphate, bis(trifluoromethylsulfony)imide and trifluoromethanesulfonate anions, were characterized for their ability to support micellar aggregation of nonionic surfactants in binary solutions.
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Opportunities and shortcomings of ionic liquids in single-drop microextraction
PublicationThe synergistic combination of ionic liquids (ILs) and single-drop microextraction (SDME) involves a powerful coupling toward the development of sustainable analytical methodologies. This overview provides a survey of the literature regarding the IL-SDME, including a database on relevant physicochemical properties of ILs for their application in SDME, the strategies implemented to combine IL-based SDME methods efficiently with...
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Structural changes of a simple peptide—Trpzip-1—in aqueous solutions and the corresponding hydration phenomena under the influence of temperature
PublicationTrpzip-1, a simple β-hairpin, is a rare example of peptide with stable secondary structure and can be a convenient model to study temperature-related processes that potential prion or amyloid proteins undergo. Although its sequence is simple, the exact processes which the peptide undergoes in aqueous solutions are quite complex and not well understood. The selection of well-established experimental (DSC, FTIR) and theoretical methods...
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Volterra series usefulness in modelling of the time-domain cross-talk phenomena in coupled microstrip lines with nonlinear termination
PublicationW pracy przedyskutowano możliwość wykorzystania szeregów Volterry do analizy zjawiska przesłuchu w sprzężonych liniach mikropaskowych z nieliniowym obciążeniem. Apracowano algorytm metody, zaś uzyskane wyniki numeryczne zweryfikowano poprzez porównania z wynikami badań eksperymentalnych linii obciążonych w torze transmisyjnym diodą Schottky'ego.
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Vivedenna dosovih vod u grunt = The rain - water management solutions basedon the seepage phenomena cz.2
PublicationWprowadzanie wód opadowych do gruntu. Rozwiązania o dużej przepustowości, do użycia w odwadnianiu dużych powierzchni.
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Chemometric determination of solute-affected solvent vibrational spectra as a superior way of information extraction on solute solvation phenomena
PublicationW pracy zaprezentowano dwie chemometryczne metody wyznaczania widm zaburzonych rozpuszczalnika oraz liczby cząsteczek zaburzonych, na podstawie zmierzonych serii wibracyjnych widm FT-IR roztworów substancji. Pierwsza z metod została stworzona na podstawie Namiarowej Analizy Faktorowej (ang. Target Factor Analysis). Druga z nich wykorzystuje algorytm izolacji widm czystych składników z serii widm mieszanin. Działanie obu metod zostało...
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The role of bile salts in digestion
PublicationBile salts (BS) are bio-surfactants present in the gastrointestinal tract (GIT) that play a crucial role in the digestion and absorption of nutrients. The importance of BS for controlled release and transport of lipid soluble nutrients and drugs has recently stimulated scientific interest in these physiological compounds. BS are so-called facial amphiphiles showing a molecular structure that is very distinct from classical surfactants....
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Untargeted Lipidomics Analysis of the Cyanobacterium Synechocystis sp. PCC 6803: Lipid Composition Variation in Response to Alternative Cultivation Setups and to Gene Deletion
PublicationCyanobacteria play an important role in several ecological environments, and they are widely accepted to be the ancestors of chloroplasts in modern plants and green algae. Cyanobacteria have become attractive models for metabolic engineering, with the goal of exploring them as microbial cell factories. However, the study of cyanobacterial lipids’ composition and variation, and the assessment of the lipids’ functional and structural...
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Dynamic Behavior of Aluminum Alloy Aw 5005 Undergoing Interfacial Friction and Specimen Configuration in Split Hopkinson Pressure Bar System at High Strain Rates and Temperatures
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An inter-laboratory validation of methods of lipid peroxidation measurement in UVA-treated human plasma samples
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Cardiovascular risk and response to lipid lowering therapy in patients with HIV infection according to different recommendations
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Photodynamic inactivation of Enterococcus faecalis by non-peripherally substituted magnesium phthalocyanines entrapped in lipid vesicles
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EFFECT OF CHITOSAN AND LIPID LAYERS DEPOSITED ONTO POLYETHYLENE TEREPHTHALATE (PET) ON ITS WETTING PROPERTIES
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The Effect of Sterols on Amphotericin B Self-Aggregation in a Lipid Bilayer as Revealed by Free Energy Simulations
PublicationAmphotericin B (AmB) is an effective but toxic antifungal drug, known to increase the permeability of the cell membrane, presumably by assembling into transmembrane pores in a sterol-dependent manner. The aggregation of AmB molecules in a phospholipid bilayer is, thus, crucial for the drug’s activity. To provide an insight into the molecular nature of this process, here, we report an atomistic molecular dynamics simulation study...
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Modeling of Electrodynamic Phenomena in an Ultra-Rapid Inductive–Dynamic Actuator as Applied to Hybrid Short-Circuit Breakers - A Review Study
PublicationThis article is a study of the research development of electrodynamic phenomena occurring in ultra-fast electrodynamic drives. These types of linear drives are among the fastest, not only because of the huge accelerations achieved, but, above all, because of the extremely short reaction time. For this reason, electrodynamic drives are used in hybrid short-circuit breakers. The phenomena occurring in this type of drive are actually...
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Local Conformation and Cocrystallization Phenomena in Renewable Diaminoisoidide-Based Polyamides Studied by FT-IR, Solid State NMR, and WAXD
PublicationBiobased polyamides synthesized from diaminoisoidide (DAII), 1,4-diaminobutane, and sebacic acid are investigated by FT-IR, 13C{1H} magic-angle spinning/cross-polarization (CP/MAS) NMR spectroscopy, and WAXD. Their molecular conformation and mobility undergo distinct changes as a function of temperature and diaminoisoidide content in the compositions. The presence of randomly distributed diaminoisoidide (DAII) in the polyamides...
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Other lipid storage disorders - Male, 4 - Tissue image [507073002620451]
Open Research DataThis is the histopathological image of CONNECTIVE, SUBCUTANEOUS AND OTHER SOFT TISSUES tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Other lipid storage disorders - Male, 4 - Tissue image [5070730026203971]
Open Research DataThis is the histopathological image of CONNECTIVE, SUBCUTANEOUS AND OTHER SOFT TISSUES tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Other lipid storage disorders - Male, 4 - Tissue image [507073002620181]
Open Research DataThis is the histopathological image of CONNECTIVE, SUBCUTANEOUS AND OTHER SOFT TISSUES tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Other lipid storage disorders - Male, 4 - Tissue image [5070730026207451]
Open Research DataThis is the histopathological image of CONNECTIVE, SUBCUTANEOUS AND OTHER SOFT TISSUES tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Other lipid storage disorders - Male, 4 - Tissue image [5070730026204441]
Open Research DataThis is the histopathological image of CONNECTIVE, SUBCUTANEOUS AND OTHER SOFT TISSUES tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Other lipid storage disorders - Male, 4 - Tissue image [5070730026202761]
Open Research DataThis is the histopathological image of CONNECTIVE, SUBCUTANEOUS AND OTHER SOFT TISSUES tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Octanoic Acid—An Insecticidal Metabolite of Conidiobolus coronatus (Entomopthorales) That Affects Two Majors Antifungal Protection Systems in Galleria mellonella (Lepidoptera): Cuticular Lipids and Hemocytes
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Effects of black cohosh extract on body weight gain, intra-abdominal fat accumulation, plasma lipids and glucose tolerance in ovariectomized Sprague–Dawley rats
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Genes encoding proteins regulating fatty acid metabolism and cellular response to lipids are differentially expressed in porcine luminal epithelium during long-term culture
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Effect of ionic liquids on surface and photocatalytic properties of selected semiconducttors
PublicationThe main aim of this doctoral dissertation was to explain the role of ionic liquids in shaping the morphology of selected semiconductors, thereby enhancing the photocatalytic activity. In order to achieve this goal, the following research steps were taken: (i) developing synthesis methods of selected semiconductors, with particular emphasis on the electrochemical oxidation method; (ii) understanding the influence of the selected...
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Electrochemical investigations on corosivity of de-icing liquids for railway infrastructure
PublicationThe paper presents the results of electrochemical tests of the de-icing fluid for railway infrastructure. DC and AC electrochemical tests were performed to determine the corrosion rates of structural steel, cast iron and aluminium in the newly produced fluid. The results were compared with the corrosion rates of the same materials in the fluid without corrosion inhibitors. The obtained test results indicate a low corrosion risk...
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Experimental Study of the Resistance to Influence of Aggressive Liquids on Lightweight Concrete
PublicationIn light of the scientific research, the corrosion of concrete structures is one of the main problems that may reduce their durability due to the negative impact of the natural environment. The paper analyzes the influence of the type of component on the selected properties of lightweight concrete subjected to the influence of aggressive liquids. Four concrete mixes were prepared with a granular aggregate made of foamed glass (GEGA)...
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Deep eutectic solvents vs ionic liquids: Similarities and differences
PublicationDeep eutectic solvents (DES) were introduced as an alternative to ionic liquids (IL) to overcome the drawbacks of IL solvents. However, some authors consider them to be a subclass of ILs. In contrast, other authors emphasize that these are by their nature independent, different groups of substances. Thus, the question arises: Which solvent group should DESs belong to? Maybe a new class should be added to the existing ones. The...
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Capillary electrophoretic separation of cationic constituents of imidazolium ionic liquids
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The Relationship between the Structure and Properties of Amino Acid Ionic Liquids
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Recovery of ibuprofen from pharmaceutical wastes using ionic liquids
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Exploiting isohexide scaffolds for the preparation of chiral ionic liquids tweezers
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Chapter 23. Fate assessment of ionic liquids in porous media
PublicationW ostatnich latach obserwowany jest wzrost zainteresowania zastąpieniem tradycyjnych lubrykantów cieczami jonowymi z uwagi na ich szczególne właściwości fizykochemiczne zwłaszcza brak lotności -istotny z punktu bezpieczeństwa stosowania. Ciecze jonowe, choć nielotne, są związkami stosunkowo toksycznymi w stosunku do mikroorganizmów i bezkręgowców. Z tego względu ich zachowanie się w środowisku oraz parametry transportu powinny...
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Study of the Resistance to Influence of Aggressive Liquids on Concrete with Lightweight Aggregate
PublicationThe corrosion of the structure of concrete caused by the aggressive external environment is one of the main problems that can reduce the durability of buildings. The paper analyzes the influence of the type of component on selected properties of lightweight concrete (LWC) exposed to aggressive liquids. When lightweight concrete containing porous aggregates is used, the influence of an aggressive environment may be of particular...
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Experimental study of the variations of the freezing points of ionic liquids in water
PublicationTemperatura zamarzania czystych soli alkiloimidazoliowych zawiera się w przedziale od - 70ºC do - 90ºC zależnie od długości podstawinika alkilowego oraz od rodzaju anionu. Celem niniejszej pracy jest znalezienie odpowiedniej metody pomiaru zmian temperatury zamarzania chlorku 1-metylo-3-oktyloimidazolu w wodzie. Wynik przeprowadzonych badań pozwolił na sporządzenie fragmentu diagramu fazowego dla wodnego roztworu chlorku...
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How green are ionic liquids? – A multicriteria decision analysis approach
PublicationDue to various desirable physicochemical properties, ionic liquids (ILs) are still gaining in popularity. ILs have been recurrently considered green solvents. However, environmental, health and safety assessments of ILs have raised certain doubts about their benignness, and their greenness status is currently unclear. To clarify the situation on their greenness, we perform a comprehensive assessment of more than 300 commercially...
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Ionic liquids in the microextraction techniques: the influence of ILs structure and properties
PublicationIonic liquids (ILs) are composed entirely of ions thus they possess unique properties, including negligible volatility, a liquid state in a broad range of temperatures and ability to change them depending on the chosen type of anion and cation, which make ILs unique and useful for many applications in sample preparation techniques. A deeper understanding of the nature of ILs and the impact of their structure on their parameters...
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Prospects of ionic liquids application in electronic and bioelectronic nose instruments
PublicationThis paper addresses the problem of application of ionic liquids to chemical sensors and biosensors being an integral part of the electronic and bioelectronic-type instruments. The design and principle of operation of the electronic and bioelectronic noses are compared. Both the benefits and shortcomings of the application of ionic liquids in these type of instruments are described. The prospects of the development and application...
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Ionic liquids as an example of lubricating oils used in a field of tribology
PublicationPodczas prezentacji ustnej pokazano przykłady cieczy jonowych, ich możliwości w wykorzystaniu jako zastąpienie tradycyjnie używanych dziś smarów. Ponadto dokonano porównania kilku właściwości "tribologicznych" między cieczami jonowymi a obecnie wykorzystywanymi smarami
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Wetting of supports by ionic liquids used in gas separation processes
PublicationCiecze jonowe są stosowane w procesach separacji gazów jako selektywne rozpuszczalniki. Są szeroko stosowane w technologii immobilizowanych membran ciekłych, głównie w procesach oczyszczania strumieni gazowych. Praca ta charakteryzuje komercyjnie dostępne membrany porowate używane we wspomnianych procesach. Określenie właściwości nośników i fazy membranowej ma na celu wyznaczenie czynników mających wpływ na stabilności takich układów...
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Effect of oxygenation time on signal of a sensor based on ionic liquids
PublicationThe paper presents an oxygen sensor based on ionic liquids and solid electrodes. The following ionic liquids have been employed: [BMIM][BF4], [HMIM][Cl], [BMIM][N(CN2)]. Minimum time of the sensor exposure to analyte, after which the signal (current intensity) was stable, has been evaluated. An impact of volumetric flow rate of analyte on the sensor exposure time and signal has been determined. A product of permeability coefficient...
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Temperature-dependent structure-property modeling of viscosity for ionic liquids
PublicationIn this paper we present the methodology for assessing the ionic liquids' viscosity at six temperature points (25, 35, 45, 50, 60 and 70 [C]), which utilizes only the in silico approach. The main idea of such assessment is based on the "correction equation" describing the correlation between experimentally measured viscosity and theoretically derived density (calculated with use of molecular mechanics), given at 6 different temperature...
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Imaging of morphological and physicochemical changes occuring in the structure of austenitic steel due to the thermal sensitization
Open Research DataIn polycrystalline materials, grain boundaries are always where phenomena such as surface diffusion, sedimentation and corrosion occur. They have a significant impact on the macroscopic properties of the construction material [1]. In addition to inhomogeneities such as manganese sulphide inclusions formed during the metallurgical process, interfacial...
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Rapid Characterization of the Human Breast Milk Lipidome Using a Solid-Phase Microextraction and Liquid Chromatography-Mass Spectrometry-Based Approach.
PublicationHuman breast milk (HBM) is a biofluid consisting of various biomolecules such as proteins, lipids, carbohydrates, minerals and bioactive substances. Due to its unique and complex composition, HBM provides not only nutritional components required for the growth of the infant, but also additional protection against infections. Global insight into the composition of HBM is crucial to understanding the health benefits infants receive...
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Ocular irritation and cyclosporine A distribution in the eye tissues after administration of Solid Lipid Microparticles in the rabbit model
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Methotrexate Decreases the Level of PCSK9—A Novel Indicator of the Risk of Proatherogenic Lipid Profile in Psoriasis. The Preliminary Data
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Photodynamic inactivation of Enterococcus faecalis by conjugates of zinc(II) phthalocyanines with thymol and carvacrol loaded into lipid vesicles
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Zinc and the Innovative Zinc-α2-Glycoprotein Adipokine Play an Important Role in Lipid Metabolism: A Critical Review
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Lipid membranes exposed to dispersions of phytantriol and monoolein cubosomes: Langmuir monolayer and HeLa cell membrane studies
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Six Weeks of Calorie Restriction Improves Body Composition and Lipid Profile in Obese and Overweight Former Athletes
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Molecular dynamics study of a gelsolin-derived peptide binding to a lipid bilayer containing phosphatidylinositol 4,5-bisphosphate
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Rapana venosa consumption improves the lipid profiles and antioxidant capacities in serum of rats fed an atherogenic diet
PublicationIn the recent years, the consumption of seafood has increased. There are no results on the studies of Rapana venosa (Rv) as a supplementation to the diets. We hypothesized that Rv would increase antioxidant capacity and reduce blood lipids, based on the composition of bioactive compounds and fatty acids. Therefore, the aim of this investigation was to evaluate in vitro and in vivo actions of Rv from contaminated (C) and non-C (NC)...
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Membrane Sterols Modulate the Binding Mode of Amphotericin B without Affecting Its Affinity for a Lipid Bilayer
PublicationMembrane-active antibiotics are known to selectively target certain pathogens based on cell membrane properties, such as fluidity, lipid ordering, and phase behavior. These are in turn modulated by the composition of a lipid bilayer and in particular by the presence and type of membrane sterols. Amphotericin B (AmB), the golden standard of antifungal treatment, exhibits higher activity toward ergosterol-rich fungal membranes, which...
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Investigation of some magnetospheric phenomena of geomagnetic storm on March 17, 2013 based on observations from GNSS and NOAA-15 satellite
PublicationSubstantial variations of magnetospheric electron fluxes of low and intermediate energies at an altitude of ~ 800 km at different phases of the geomagnetic storm were investigated. The ionosphere and plasmasphere response was analyzed using TEC variation maps over the Central Europe. A concept of the connection of TEC variations above the Central Europe and spatially inhomogeneous fluxes of energetic particles is being proposed.
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Changes in the EPA and DHA content and lipids quality parameters of rainbow trout (Oncorhynchus mykiss, Walbaum) and carp (Cyprinus carpio, L.) at individual stages of hot smoking
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A comprehensive lipidomic analysis of oilseeds using LC-Q-TOF-MS and dispersive micro-solid phase (D-μ-SPE) extraction techniques
PublicationGrowing public health awareness increased the demand for natural products with positive health benefits. Vegetable oils containing omega-3 fatty acids (FA) such as alpha-linolenic acid (ALA) has been proposed as a possible source of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). In this work, a comprehensive lipidome analysis and comparison of seven oilseeds, including flaxseed, chia, hemp, black cumin, white sesame,...
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Comprehensive methodology for Staphylococcus aureus lipidomics by liquid chromatography and quadrupole time-of-flight mass spectrometry
PublicationStaphylococcus aureus is a common pathogen known to cause relatively minor infections as well as severe disorders in humans. Although there is fair amount of published data concerning various aspects of its biology, epidemiology, genetics, etc., there is still a scarce amount of data presenting reliable and thorough investigations regarding high-throughput analysis of total S. aureus lipid content. Therefore, the aim of this study...
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Ionic liquids in extraction techniques: Determination of pesticides in food and environmental samples
PublicationThe intensive use of pesticides in agricultural practices has promoted the appearance of environmentaland public health problems. Due to that, scientists face challenges with developing simple, fast, sensitive,selective, and low-cost methods dedicated to determining pesticide residues in food and environmentalsamples. Following thefifth principle of Green Analytical Chemistry, chemists are searching for greeneralternatives for...
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Ketoprofen-Based Ionic Liquids: Synthesis and Interactions with Bovine Serum Albumin
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Potential application of ionic liquids in aluminium production - economical and ecological assessment
PublicationTechnologia wytwarzania aluminium stosowana na skale przemysłową oparta jest na elektrodepozycji w ciekłym kriolicie i nosi nazwę procesu Hall-Heroult'a. Technologia ta wymaga wysokich nakładów energii elektrycznej, charakteryzuje się ponadto, szeroko udokumentowanym, negatywnym wpływem na środowisko naturalne. Produkcja aluminium możliwa jest również metodą alternatywną poprzez elektrodepozycję a mieszaniny cieczy jonowych w temperaturze...
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Composite Bioelectrodes Based on Lipidic Cubic Phase with Carbon Nanotube Network
PublicationElektrody z węgla szklistego modyfikowane fazą kubiczną z siecią nanorurek zastosowano do enzymatycznej redukcji tlenu katalizowanej przez lakazę. Zastosowanie nanorurek obniżyło nadpotencjał redukcji tlenu o 0,5 V. W celu zwiększenia gęstości prądu redukcji tlenu zastosowano znany mediator przeniesienia elektronów - ABTS. Mediator adsorbowano na nanorurkach lub wiązano kowalencyjnie z końcami nanorurek. Kowalencyjne związanie...
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Characterization of PVC-based polymer inclusion membranes with phosphonium ionic liquids
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Electrochemical oxidation of ionic liquids at highly boron doped diamond electrodes
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