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Search results for: PHOTOCATALYTIC%20PROPERTIES
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Thermodynamic and electrostatic properties of ternary Oxytricha nova TEBP-DNA complex
PublicationZa pomocą metod chemi obliczeniowej badano właściwości molekularne kompleksu telomerowego białka TEBP z Oxytricha nova w kompleksie trójskkładnikowym z DNA o sekwencji telomerowej. Wyliczone wartości energii kompleksowania wskazują specyficznie na jedną z dróg tworzenia kompleksu, gdzie wpierw podjednostka alfa łaczy się z DNA a następnie podjednostka beta dołącza się do takiego dwuskładnikowego kompleksu. Policzone rozkłady molekularnego...
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Properties of a lithium solid electrolyte gas sensor based on reaction kinetics
PublicationW artykule przedstawiono zasadę działania, budowę i właściwości czujnika gazu na bazie elektrolitu stałego z mobilnymi jonami litu. Czujnik został przygotowany w technologii grubowarstwowej. Przedstawiono wyniki badań czujnika w mieszaninach gazów toksycznych.
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Properties of a polyethyleneimine-based sensor for measuring medium and high relative humidity
PublicationW artykule przedstawiono metodę przygotowania filmów polimerowych o zwiększonej odporności na działanie wody. Polietylenoimina została usieciowana w podwyższonej temperaturze. Określono optymalną kompozycję polimeru oraz temperaturę sieciowania. Czujniki rezystancyjne przygotowano metodą ''dip-coating''. Otrzymane czujniki charakteryzują się doskonałą trwałością w wysokich wilgotnościach. Elektryczne parametry czujników określono...
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Relation between steel microstructure and its properties in inert and aggressive environments
PublicationBadano stale 26H2MF i 34HNM poddane różnej obróbce cieplnej. Mikrostruktury stali zmieniały sie od martenzytu i bainitu do odpuszczonego martenzytu i sorbitu. Obserwowano spadek energii zniszczenia, wydłużenia i przewżenia w próbie rozciągania z małą prędkością i równoczesnej polaryzacji katodowej do 100 mA/cm2. Degradacji towarzyszyła zmiana przełomu z ciągliwego na kruchy łupliwy i quasiłupliwy.
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Structural and electronic properties of some intriguing (rare-earth)Ba2Cu3O7 compounds.
PublicationW rozdziale przedstawiono przegląd wyników eksperymentalnych i teoretycznych dotyczących wybranych związków o wzorze (lantanowiec)Ba2Cu3O7 wykazujących całkowicie odmienne właściwości w porównaniu z całą klasą nadprzewodzących związków tlenkowych o stechiometrii 1:2:3. Szczególny nacisk położono na analizę procesu wzrostu kryształów i powstawania defektów punktowych determinujących późniejsze własności fizyczne tych materiałów....
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Influence of microstructure on properties of 18Cr-10Ni-Ti stainless steel products.
PublicationBadano wpływ mikrostruktury na właściwości mechaniczne i odporność korozyjną wyrobów ze stali austenitycznej 18Cr-10Ni-Ti po przesycaniu z temperatury 1050 C. Wykazano, że węgliki TiC w ziarnach i na granicach ziaren/bliźniaków powodują znaczne obniżenie wydłużenia stali. Węgliki TiC na granicach ziaren/bliźniaków obniżają odporność na korozję międzykrystaliczną i sprzyjają powstawaniu uszkodzeń korozyjnych podczas hutniczej operacji...
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Fabrication, microstructure and properties of Al-Si -Fe-Cu in situ composites.
PublicationW poszukiwaniu tanich kompozytów na bazie stopów Al powstała koncepcja otrzymywania kompozytów in situ o osnowie stopu Al-Si w reakcji ciekłego stopu Al-Si (Al-Si11, Al-Si25) z proszkiem Fe. Powstałe wydzielenia np. iglastego AlFe4Si w stopie AlSi25 o niezbyt wysokiej twardości (rys.2) stanowią skuteczne wzmocnienie stopu pod względem twardości, sztywności i wytrzymałości na ściskanie jak też obniżonej ścieralności. Jednak znaczny...
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Influence of deformation velocity on mechanical properties of high strength structural steels.
PublicationW referacie przedstawiono wyniki badań własności mechanicznych stali wysokiej wytrzymałości przeznaczonych na spawane konstrukcje okrętowe w zależności od prędkości odkształcenia. Badania były prowadzone w Akademii Marynarki Wojennej oraz w Politechnice Gdańskiej przy współudziale Uniwersytetu Technicznego w Rostocku podczas opracowywania charakterystyk tych stali dla potrzeb polskiego przemysłu okrętowego. Uwzględnienie obciążeń...
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Modelling of mechanical properties of cooper alloys sand cast ship propellers.
PublicationBadania właściwości mechanicznych (Rm ,A5) stopów miedzi, stosowanych na pędniki okrętowe, w zależności od ich składu chemicznego i grubości odlewów piaskowych pozwalają na wyznaczenie równań regresji mających zastosowanie do prognozowania wytrzymałości statycznej na rozciąganie (Rm) i wydłużenia plastycznego (A5).Obliczenia wartości Rm i A5 dla wybranych odlewów piaskowych (mosiądz MM55, brązy BA93, BA2 i CMA1) wykazały, że opracowane...
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Influence of zinc and magnesium carboxylates on properties of emulsions stabilized with acylglycerol emulsifiers.
PublicationOkreślono właściwości emulsji stabilizowanych emulgatorami acyloglicerolowymi modyfikowanymi karboksylanami cynku i magnezu. Zbadano wpływ kompozycji emulgatorów na HLB i efektywność w modelowych układach emulsyjnych.
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The effects of growth conditions on superconducting properties of Nd1Ba2Cu3O7-ë single crystals.
PublicationW pracy przedstawiono rezultaty badan wpływu warunków wzrostu kryształów Nd1Ba2Cu3O7-d na ich własności nadprzewodzące. Kryształy hodowano metodą spontanicznego wzrostu z fazy ciekłej. Mikrostruktura kryształów została zbadana skaningowym mikroskopem elektronowym oraz skaningowym mikroskopem tunelowym. Własności nadprzewodzące badano przeprowadzając pomiary momentu magnetycznego w funkcji temperatury.W przypadku badanych kryształów...
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Analysis of material properties of technical fabric for hanging roofs andpneumatic shells.
PublicationPrzedyskutowano zastosowanie w metodzie elementów skończonych specjalnego modelu elementu do analizy tkanin technicznych. Przedstawiono specjalne postępowanie z typowym elementem w płaskim w stanie naprężenia, tak aby uwzględnić można było zjawiska charakterystyczne dla tkanin technicznych. Zaproponowany model pozwala na zastosowanie niesprężystych związków konstytutywnych a w szczególności związków lepkoplastycznych. Opisano doświadczenia...
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Magnetoelectric, spectroscopic, optical and elastic properties of Co-doped BaTiO3 ceramics
Publicationhe BaTiO3 perovskite is widely used in the electronic technology due to its dielectric, piezoelectric and ferroelectric properties and is a well-known base for obtaining a promising multifunctional material. In this paper we report the extensive studies on the Co-doped BaTiO3 ceramics for the wide range cobalt content. Full structural characterization of studied samples in a 20–450 K range was provided. The results of research...
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Reinforcing and plasticizing effects of reclaimed rubber on the vulcanization and properties of natural rubber
PublicationThe production of high-added value reclaimed rubber (RR) is of great signifi-cance for the sustainability of rubber industries. To green recycle waste rub-bers and broaden the application of RR, a RR material with potentialreinforcing and plasticizing effects on nature rubber (NR) composites are pre-pared by a thermo-oxidative reclamation process. The reclamation degree ofRR is controlled by adjusting the content of soybean oil....
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Classification of Sea Going Vessels Properties Using SAR Satellite Images
PublicationThe aim of the project was to analyze the possibility of using machine learning and computer vision to identify (indicate the location) of all sea-going vessels located in the selected area of the open sea and to classify the main attributes of the vessel. The key elements of the project were to download data from the Sentinel-1 satellite [1], download data on the sea vessels [2], then automatically tag data and develop a detection...
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Influence of the Addition of Recycled Aggregates and Polymer Fibers on the Properties of Pervious Concrete
PublicationThe aim of the study was to check the possibility of reusing aggregate from recycled concrete waste and rubber granules from car tires as partial substitution of natural aggregate. The main objective was to investigate the effects of recycled waste aggregate modified with polymer fibers on the compressive and flexural strength, modulus of elasticity and permeability of pervious concrete. Fibers with a multifilament structure and...
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Preparation and properties of composite coatings, based on carbon nanotubes, for medical applications
PublicationThe coatings based on carbon nanotubes (CNTs) are increasingly developed for their applications, among others, in medicine, in particular for implants in implantology, cardiology, and neurology. The present review paper aims at a detailed demonstration of diferent preparation methods for such coatings, their performance, and relationships between deposition parameters and microstructure and material, mechanical, physical, chemical,...
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Structural properties of hydration shell around various conformations of simple polypeptides
PublicationIn this paper we investigate structural properties of water within the solvation shell around the peptide core created by a well-defined conformation of polypeptide chain. The following secondary structures are investigated: linear (straight chain), and three helices PII (polyproline-like), 310, and α. We propose using the two-particle contribution to entropy as a rational measure of the water structural ordering within the solvation...
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Properties of nanocrystalline TiO2:V thin films as a transparent semiconducting oxides
Publicationw pracy zaprezentowano wyniki badań cienkich warstw tlenku tytanu domieszkowanego wanadem. badany materiał charakteryzowano pod kątem wykorzystania, jako przezroczysty tlenek półprzewodnikowy (tos). warstwy zostały naniesione metodą rozpylania magnetronowego na szklane podłoża.
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Optimal Features of Porosity of Ti Alloys Considering their Bioactivity and Mechanical Properties
PublicationW artykule przedstawiono wpływ porowatości i rozmiaru porów tytanu i jego stopów, użytych, jako materiały ortopedyczne, na bioaktywność i własności mechaniczne struktur porowatych. Optymalne cechy porowatych rusztowań tytanowych umożliwiają rekonstrukcję i regenerację tkanki kostnej w zastosowaniach przenoszących obciażenie.
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Effects of the Origin and Deacetylation Degree of Chitosan on Properties of Its Coatings on Titanium
PublicationThe properties of chitosan coatings on titanium surfaces may be influenced by a variety of factors, including their chemical characteristics and the deposition method. The aim of this research was to determine the influence of a chitosan’s origin (a type of shrimp) and deacetylation degree (DD), when deposited on a very smooth titanium surface, on adhesion and biological behavior. The tests were performed using chitosan of a degree...
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Copolymerization of Styrene and Pentadecylphenylmethacrylate (PDPMA): Synthesis, Characterization, Thermomechanical and Adhesion Properties
PublicationThe copolymerization of styrene (St) with a bioderived monomer, pentadecylphenylmethacrylate (PDPMA), via atom transfer radical polymerization (ATRP) was studied in this work.The copolymerization reactivity ratio was calculated using the composition data obtained from1HNMR spectroscopy, applying Kelen-Tudos and Finemann-Ross methods. The reactivity ratio of styrene (r1=0.93) and PDPMA (r2=0.05) suggested random copolymerization...
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Comprehensive Evaluation of the Biological Properties of Surface-Modified Titanium Alloy Implants
PublicationAn increasing interest in the fabrication of implants made of titanium and its alloys results from their capacity to be integrated into the bone system. This integration is facilitated by different modifications of the implant surface. Here, we assessed the bioactivity of amorphous titania nanoporous and nanotubular coatings (TNTs), produced by electrochemical oxidation of Ti6Al4V orthopedic implants’ surface. The chemical composition...
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Structural Properties and Water Uptake of SrTi1−xFexO3−x/2−δ
PublicationIn this work, Fe-doped strontium titanate SrTi1−xFexO3−x/2−δ, for x = 0–1 (STFx), has been fabricated and studied. The structure and microstructure analysis showed that the Fe amount in SrTi1−xFexO3−x/2−δ has a great influence on the lattice parameter and microstructure, including the porosity and grain size. Oxygen nonstoichiometry studies performed by thermogravimetry at different atmospheres showed that the Fe-rich compositions...
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Experimental and predicted physicochemical properties of monopropanolamine-based deep eutectic solvents
PublicationIn this work, the novel deep eutectic solvents (DESs) based on 3-amino-1-propanol (AP) as hydrogen bond donor (HBD) and tetrabutylammonium bromide (TBAB) or tetrabutylammonium chloride (TBAC) or tetraethylammonium chloride (TEAC) as hydrogen bond acceptors (HBAs) were synthesized with different molar ratios of 1:4, 1:6 and 1:8 salt to AP. Fourier Transform Infrared Spectroscopy measurements were performed to provide an evidence...
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Methodology for determination of the selected mechanical properties of wood based on cutting tests
PublicationFrom kiln-dried spruce wood (with steam) as well as in natural conditions were randomly selected 8 samples. After determining the average dimensions, moisture content and density of the samples they have been cut on the frame sawing machine PRW15M for measurement of cutting power. Based on those results from a linear rela-tionship of cutting power versus feed per toot mechanical properties of wood such as facture toughness and...
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The external walls of a passive building: A classification anddescription of their thermal and optical properties
PublicationThis paper attempts a new classification of insulating materials from the perspective of their utility in thepro-ecological passive construction industry. The main criterion is the conductivity of thermal and solarenergy. Based on their ability to conduct or block fluxes of thermal and solar energy, six types of insulatingwalls are proposed. On the basis of this criterion there are traditional dividing walls (typical walls, wallinsulating...
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MECHANICAL PROPERTIES OF BOTTOM ASH – DREDGED MATERIAL MIXTURES IN LABORATORY TESTS
PublicationBottom ash from EC Gdańsk and dredged material taken from the mouth of The Vistula were mixed to form an engineering material used for dike construction. Mixtures with different bottom ash content were tested in laboratory to determine its basic physical and mechanical properties. The optimum bottom ash–dredged material mixture, built in the corps of the test dike, contains 70% of ash. The optimum bottom ash content in the mixture...
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Effect of Coating Material Properties on Tilting-pad Thrust Bearing Performance
PublicationPolymer lined tilting-pad bearings demonstrate many advantages over traditional bearing systems. Bearings with a polymer layer in comparison with a babbitted layer show, for example: lower value of friction coefficient (important during start/stops), higher fatigue strength of the coating, better distribution of the load on individual pads due to lower elasticity of the polymers, wider range of operational temperatures or the ability...
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Mechanical properties of polyvinyl chloride-coated fabric under cyclic tests
PublicationThe aim of the present paper is to propose a method of laboratory tests necessary for the identification of mechanical properties of the coated fabric. The material parameters of the coated fabric AF 9032 are specified on the basis of the uniaxial and biaxial tensile tests. For the identification process, the techniques based on the least squares methods are used. Additionally, the uniaxial and biaxial cyclic tests are performed...
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Influence of the internal electrolyte composition on amperometric sulphur dioxide sensor properties
PublicationIn this work investigation of an amperometric sulphur dioxide sensor with a liquid electrolyte, a mercury sulphate reference electrode and solid polymer electrolyte (Nafion) covered with gold as a working electrode properties is presented. The main goal of this research is to determine the influence of internal electrolyte composition on the sensor properties. Sensor filled with 1M and 5M sulphuric acid has been studied.
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Preparation, composition and properties of fish silage produced with post-coagulation sludge
PublicationPost-coagulation sludge was added to fish fydrolyzates (silage). Silage was prepared using whole sprats. Technology of the process has been modified and sulphuric acid was replaced with phosphoric acid. The objective was to evaleuate the quality of produced silage during storage, particulary the changes of peroxide value and amount of free acids in silage fat.
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Electrical properties of Y0.08Sr0.92Ti0.92Nb0.08O3-δ after reduction in different reducing conditions
PublicationElectrical properties of perovskite Y0.08Sr0.92Ti0.92Nb0.08O3−ı after reduction in different conditions were studied. Relatively high electrical conductivity in samples reduced in ammonia was observed. The conductivity of Y0.08Sr0.92Ti0.92Nb0.08O3−ı reduced in ammonia at 1500 ◦C was of about 600 S/cm at 200 ◦C. Conductivity after reduction in ammonia at 1500 ◦C was stable both in hydrogen and oxygen atmosphere up to 600 ◦C. Reduction...
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A COMPARISON OF WEAR PROPERTIES OF WATER LUBRICATED NBR AND PTFE SLIDING BEARINGS
PublicationThe excessive wear of a journal shaft can be caused by many factors, for example, working conditions (e.g., temperaturę, slip speed, the type of lubricant), pressure, the type of material used on the bearings and shafts and their roughness, as well as contamination remaining in the system. This paper presents the roughness profiles co-operating with a rubber (NBR) and polytetrafluoroethylene (PTFE) bushes. The conditions of cooperation...
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Aggregation properties of some zirconium phosphate loaded with dirhenium(III) complexes
PublicationOne of the important areas of modern science is the selection of the right forms of drug delivery. Layered inorganic nanoparticles, such as zirconium phosphate, have proven themselves well in this area. The study of the properties of these systems and methods of their preparation makes it possible to determine a rational technology of their manufacture, storage conditions as well as suggest a possible mechanism of therapeutic action....
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Effects of Na+, K+ and B3+ Substitutions on the Electrical Properties of La10Si6O27 Ceramics
PublicationDoping of Na and K at La sites and of B at Si site in La10Si6O27 with oxyapatite structure and fabrication of their ceramics were made by the solid-state reaction method. It was found that partial substitution of Na+ and K+ on La sites decreased the sinterability of the La10Si6O27 based ceramics, whereas partial substitution of B3+ on the Si site improved the sinterability. Na+ and K+ substitutions in La10−xNaxSi6O27−x and La10−xKxSi6O27−x...
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Study of nanomechanical properties of (1-y)BST-yMgO thin films
PublicationIn the present study thin films of MgO – modified Ba0.6Sr0.4TiO3 (BST60/40) solid solution were prepared by the sol-gel-type chemical solution deposition method on stainless steel substrates. A multilayer spin-coating approach was utilized for the Ba0.6Sr0.4TiO3-MgO thin film deposition with subsequent thermal annealing at T=650-750C. Dried BST60/40-MgO gel powders were studied with thermogravimetric and differential thermal analysis...
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Effects of Na+, K+ and B3+ Substitutions on the Electrical Properties of La10Si6O27 Ceramics
PublicationDoping of Na and K at La sites and of B at Si site in La10Si6O27 with oxyapatite structure and fabrication of their ceramics were made by solid-state reaction method. It was found that partial substitution of Na+ and K+ on La sites decreased the sinterability of the La10Si6O27 based ceramics, whereas partial substitution of B3+ on Si site imporved the sinterability. Na+ and K+ substitutions in La10-xNaxSi6O27-x and La10-xKxSi6O27-x...
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Comparison of Properties of the Hybrid and Bilayer MWCNTs—Hydroxyapatite Coatings on Ti Alloy
PublicationCarbon nanotubes are proposed for reinforcement of the hydroxyapatite coatings to improve their adhesion, resistance to mechanical loads, biocompatibility, bioactivity, corrosion resistance, and antibacterial protection. So far, research has shown that all these properties are highly susceptible to the composition and microstructure of coatings. The present research is aimed at studies of multi-wall carbon nanotubes in three different...
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Influence of Sn and Pb Ions Substitutions on Dielectric Properties of Barium Titanate
PublicationThe results of the microstructural and dielectric measurements of (Ba1-xPbx)(Ti1-xSnx)O3 (BPTSx) (x = 0, 0.05, 0.10, 0.30) polycrystalline samples are presented. The samples were obtained by means of a high temperature synthesis and their expected stoichiometry was confirmed by energy dispersive spectroscopy (EDS) measurements. The dielectric properties of BPTSx were studied with the use of broadband dielectric spectroscopy. The...
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Microstructural and electrical properties of Y0:07Sr0:93−xTiO3− perovskite ceramics
PublicationIn order to find a relationship between electrical and microstructural properties, yttrium-doped strontium titanate (7 mol%) with various values of strontium nonstoichiometry was investigated and shown in this work. It has been observed that yttrium doping can affect the electrical properties of SrTiO3 to a great extent. Moreover, the microstructural and electrical properties can be influenced by strontium nonstoichiometry. The...
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Electrical properties and structure of lead-borate glass containing iron ions.
PublicationThe ac and dc conductivity in iron–lead-borate glass samples was investigated in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by the means of atomic force microscopy (AFM) and the crystalline phases (if present) were identified by the means of X-ray diffractometry. Two types of ac electrical behaviour were observed. The first group of glass samples which...
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Numerical analysis of mechanical properties of an infill structure used in 3D printings
PublicationThe paper presents results of a numerical analysis focused on an identification of mechanical properties of an element created by using Fused Deposition Modelling additive manufacturing technique (FDM). There is presented a description of technology of the 3D printing, numerical model created by using the finite element method (FEM), as well as some problems referred to estimation of the mechanical properties of the printout. The...
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Effect of Semiconductor Element Substitution on the Electric Properties of Barium Titanate Ceramics
PublicationThe investigated ceramics were prepared by a solid-state reaction from simple oxides and carbonates with the use of a mixed oxide method (MOM). The morphology of BaTi0.96Si0.04O3 (BTSi04) ceramics was characterised by means of a scanning electron microscopy (SEM). It was found that Si+4 ion substitution supported the grain growth process in BT-based ceramics. The EDS results confirmed the high purity and expected quantitative composition...
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Structural and electrical properties of Cr-doped SrTiO 3 porous materials
PublicationSeries of single-phase materials with assumed formula SrTi1−xCrxO3 (where x = 0, 1, 4, 6 mol.%) were obtained by sol-gel method. The structure and microstructure of materials were characterised by X-ray diffraction and scanning electron microscopy methods. Moreover, the study of electrical properties and evaluation of chemical stability in CO2/H2O atmosphere was performed by electrochemical impedance spectroscopy and thermogravimery...
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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
PublicationSodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between...
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Properties of surface layers of duplex stainless steel after burnishing processes
PublicationStress corrosion cracking resistance of cold worked layers of 25 Cr duplex stainless steel grade UR52N+ has been investigated. The surface layers were performed through burnishing treatment. The residual stresses at surface layers were determined using grazing angle incidence X-ray diffraction method (g-sin2 Ψ). Corrosion tests were performed with the use of Slow Strain Rate Test technique in boiling 35% MgCl2 solution. It has...
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Study of structures and properties of the laser cladding exhaust valve after service
PublicationPrzylgnie zaworów wydechowych silnie obciążonego silnika okrętowego zostały pokryte warstwą wykonana ze stopu kobaltu za pomocą techniki napawania laserowego. Tak przygotowane zawory były eksploatowane przez 3000 godzin w silniku Daru Młodzieży. Po tym czasie zostały zdemontowane i poddane szczegółowej analizie. Warunki pracy spowodowały powstanie na powierzchni przylgni warstwy tlenków o różnej grubości, wykazującej skłonność...
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Influence of laser melting on surface layer properties of titanium alloy Ti6Al4V
PublicationIn time of rapid technology and medicine progress, implants are becoming more widely used in the human body, ranging from dental implants, stabilizing plates, screws, orthopaedic prostheses. For example, there are many types of hip prostheses used for hip replacement as well as various types of materials used for these orthopaedic prostheses. Properties of titanium alloys used in hip prostheses combined with good strength properties,...
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Barkhausen noise properties measured by different methods for deformed Armco samples
PublicationPorównano właściwości sygnału napięciowego efektu Barkhausena (BN) uzyskanego za pomocą 'sondy punktowej' (użytecznej dla badań przemysłowych) oraz cewki otaczającej badany materiał. W pierwszej metodzie mierzono trzy wielkości: V1 - napięcie skuteczne, Nc - liczba impulsów, V2 - napięcie kontrolne z cewki. W drugiej metodzie z napięcia indukowanego w cewce wyznaczano pętlę histerezy B(H), obwiednie z napięcia skutecznego a także...