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Search results for: SOFC · SOEC ELECTRODES · DOPED-STRONTIUM TITANATE · ELECTRICAL CONDUCTIVITY · PEROVSKITES · REDOX CYCLES · EX-SOLUTION · NICKEL NANOPARTICLES
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Magnetic study of Fe3O4/Ag nanoparticles
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Deposition of gold nanoparticles on titanium nanopits
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Functionalization of carbon encapsulated iron nanoparticles
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Nanoparticles Preparation Using Microemulsion Systems
PublicationW rozdziale opisano otrzymywanie nanocząstek za pomocą metody mikroemulsyjnej oraz wpływ parametrów reakcji na powstawanie nanocząstek. Omówiono różne rodzaje struktur bimetalicznych - rdzeń-otoczka i stopowe.
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INFLUENCE OF NANOPARTICLE CONCENTRATION ON THERMAL PROPERTIES OF THERMAL OIL-MWCNT NANOFLUID
PublicationThis paper deals with measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of thermal oil-MWCNT (TO-MWCNT) nanofluid. Nanoparticles were tested at the concentration of 0.001%, 0.005%, 0.01%, 0.05%, and 0,1% by weight. Ultrasonic vibration was used in order to stabilize the dispersion of the nanoparticles. Thermal oil (TO) was selected as a base liquid, because of possible application in ORC systems...
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Change of reaction quotients for SOFC fueled by biogas mixture at 750 C
Open Research DataThe dataset contains the Change of reaction quotients for SOFC fueled by biogas mixture at 750 C (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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Inverse heat transfer problem solution of sounding rocket using moving window optimization
PublicationAn Inverse Heat Transfer Problem is solved for a sounding rocket module given its geometry and measured temperature profile. The solution is obtained via moving window optimization, a technique for solving inverse dynamics. An analysis is performed to modify the method to avoid oscillatory behavior of the resulting heat flux profile. The method parameters are tuned in relation to characteristic phases of the flight. Results are...
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Materials for energy storage and conversion devices 2022/2023
e-Learning CoursesElectrodes: Metals as electrodes in aqueous and non-aqueous systems, metal nanoparticles. Collectors current. 3D, 2D, 1 D carbons, carbon nanomaterials. Organic semiconductors "Synthetic metals" - p-type, n-type. Inorganic semiconductors: oxides, selenides, sulfides, others. Intercalated electrodes. Mixed conductors (MIEC). Photo-active semiconductor materials. Electrolytes. Water electrolytes in commercial products. Electroactive...
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Influence of Annealing Atmospheres on Photoelectrochemical Activity of TiO2 Nanotubes Modified with AuCu Nanoparticles
PublicationIn this article, we studied the annealing process of AuCu layers deposited on TiO2 nanotubes (NTs) conducted in various atmospheres such as air, vacuum, argon, and hydrogen in order to obtain materials active in both visible and UV–vis ranges. The material fabrication route covers the electrochemical anodization of a Ti plate, followed by thin AuCu film magnetron sputtering and further thermal treatment. Scanning electron microscopy...
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Elucidating photoluminescent properties of Eu‐doped Ca–Al–Si–O(–N) glasses and the local structures of Eu ions
PublicationEuropium (Eu) ion–doped luminescent materials have attracted considerable attention for their numerous optical applications. Eu-doped Ca–Al–Si–O(–N) glasses were synthesized from a mixture of oxynitride glasses and Eu2O3 powder using a standard melt-quenching technique in a radiofrequency furnace. The source Eu trivalent ions primarily changed to Eu2+ during melting, and the ratio of Eu2+ ions increased with an increase in Eu content...
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Rare earth ions doped K 2 Ta 2 O 6 photocatalysts with enhanced UV–vis light activity
PublicationNew rare earth-doped K2Ta2O6 photocatalysts were successfully synthesized by hydrothermal method. The effect of dopant type (Y,Yb,Ho,Pr,Er) and amount of rare earth precursor (2,4,8 and 10 mol%) on the physicochemical and photocatalytic properties of RE-K2Ta2O6 have been investigated. All as-prepared materials were characterized by UV–vis diffuse reflectance spectroscopy, Brunauer-Emmett-Teller specific surface area measurement,...
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Computer modeling of the solution conformation of cyclic enkephalins
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Optical switching technologies: problems and proposed solution
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Adsorption of 1,2-dichloropropane from aqueous solution
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The photosensitized oxidation of mixture of parabens in aqueous solution
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GIS Solution for Weather Forecast Data Analysis
PublicationIn this paper authors present the GIS system for the analysis of the numerical weather prediction data. This kind of data has multidimensional character (three dimensions and time) and its analysis should consider all the available factors. Proposed GIS system consists of RASDAMAN application with implemented OLAP cube mechanism, which enables the user to process data in the spatial-time domain. It also simplifies the meteorological...
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Hydrogen charging of nitrided steel in acid solution
PublicationKonstrukcyjną stal, azotowaną w wyładowaniu jarzeniowym w mieszaninie gazów o różnej zawartości N2, H2 i Ar, poddawano katodowemu nawodorowaniu w kwaśnym roztworze, imitującym przepracowany olej maszynowy. W pomiarach szybkości przenikania wodoru i ekstrakcji próżniowej określano wpływ azotowanych warstw, odpowiednio, na transport wodoru i na jego nieodwracalne pułapkowanie. W obecności niezdefektowanej warstwy kompaktowych azotków...
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Two dimensional inverse solution for diagonal pumps
PublicationW pracy przedstawiono rozwiązanie zadania odwrotnego dla wirnika i kierownicy pompy diagonalnej. Dla założonego kształtu powierzchni prądu wyznaczono kształt łopatek obu palisad. Geometria kanałów łopatkowych została wyznaczona w wyniku rozwiązania układu równań zapisanych w krzywoliniowym układzie współrzędnych. W pracy przedstawiono fotografie wirnika wykonanego techniką Rapid Prototyping.
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Space-Time Conservation Method applied to numerical solution of water hammer equations
PublicationArtykuł poświęcony jest metodzie czasoprzestrzennych objętości skończonych (STC) zastosowanej do przypadku uderzenia hydraulicznego w stalowym przewodzie pracującym pod ciśnieniem. Metoda STC ze względu na swoje własności numeryczne - m.in. wysoką dokładność - może być interesującą alternatywą dla tradycyjnych metod numerycznych, szczególnie w przypadku, gdy efekty numeryczne mają bardzo silny wpływ na rozwiązanie, tym samym utrudniając...
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A Solution to Image Processing with Parallel MPI I/O and Distributed NVRAM Cache
PublicationThe paper presents a new approach to parallel image processing using byte addressable, non-volatile memory (NVRAM). We show that our custom built MPI I/O implementation of selected functions that use a distributed cache that incorporates NVRAMs located in cluster nodes can be used for efficient processing of large images. We demonstrate performance benefits of such a solution compared to a traditional implementation without NVRAM...
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The ex‐post impact of agricultural technology adoption on poverty: Evidence from north Shewa zone of Amhara region, Ethiopia
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Electrochemical Evaluation of the Compact and Nanotubular Oxide Layer Destruction under Ex Vivo Ti6Al4V ELI Transpedicular Screw Implantation
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A solution of the integrated µBIST for functional and diagnostic testing in mixed-signal electronic embedded systems
PublicationMain problem of the paper is testing of analog circuits and blocks in mixed-signal electronic embedded systems (EESs), using the built-in self-test (BIST) technique. The integrated mBIST based on reusing signal blocks already present in an EES, such as processors, memories, ADCs, is presented. The novelty of the solution is the extended functionality of the mBIST. It can perform 2 testing functions: functional testing and fault...
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Redox State Sensitive Spectroscopy of the Model Compound [(H-dcbpy)(2)Ru-II(NCS)(2)](2-) (dcbpy=2,2 '-Bipyridine-4,4 '-dicarboxylato)
PublicationThe charge transfer reaction mechanism in a ruthenium polypyridine model complex with isothiocyanato ligands, i.e., [(H-dcbpy)(2)Ru(NCS)(2)](2-) 2Bu(4)N(+) (Ru2H) (dcbpy = 2,2'-bipyridine-4,4'-dicarboxylato), has been investigated by combining UV-vis absorption, resonance Raman spectroscopy, and electrochemical methods. Understanding the photophysics of light-harvesting complexes of this class is an indispensable prerequisite to...
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Mixed electronic-ionic conductivity in vanadate oxide glasses containing alkaline ions
PublicationZbadano mieszane przewodnictwo polaronowo-jonowe w szkłach wanadanowych zawierających jony metali alkalicznych.
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Comparison of conductivity averaging methods for one-dimensional unsaturated flow in layered soils
PublicationW artykule przedstawiono numeryczne rozwiązania równania Richardsa, opisującego nieustalony przepływ wody w uwarstwionym gruncie nienasyconym. Przeanalizowano różne metody obliczania średniej przewodności hydraulicznej między węzłami siatki numerycznej oraz różne możliwości położenia węzłów względem granic warstw gruntu. Najlepsze wyniki otrzymano stosując metodę uśredniania stanowiącą adaptację wcześniejszej propozycji jednego...
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Copper defects and conductivity in Bi-Pb-Sr-Ca-Cu-O glasses.
Publication(Bi0.8Pb0.2) 4Sr3Ca3Cu4Ox częściowo skrystalizowane próbki otrzymano poprzez wygrzewanie szkła w wysokiej temperaturze. Badano je metodą EPR w zakresie temperatur od 4K do 300K. Koncentracja paramagnetycznych centrów Cu2+ zmniejsza się wraz ze wzrostem przewodnictwa elektrycznego i znika po skrystalizowaniu faz nadprzewodzących.
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Flavoenzyme-catalyzed redox cycling of hydroxylamino- and amino metabolites of 2,4,6-trinitrotoluene: implications for their cytotoxicity
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Tailoring diamondised nanocarbon-loaded poly(lactic acid) composites for highly electroactive surfaces: extrusion and characterisation of filaments for improved 3D-printed surfaces
PublicationA new 3D-printable composite has been developed dedicated to electroanalytical applications. Two types of diamondised nanocarbons - detonation nanodiamonds (DNDs) and boron-doped carbon nanowalls (BCNWs) - were added as fillers in poly(lactic acid) (PLA)-based composites to extrude 3D filaments. Carbon black served as a primary filler to reach high composite conductivity at low diamondised nanocarbon concentrations (0.01 to 0.2...
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Structural Properties and Water Uptake of SrTi1−xFexO3−x/2−δ
PublicationIn this work, Fe-doped strontium titanate SrTi1−xFexO3−x/2−δ, for x = 0–1 (STFx), has been fabricated and studied. The structure and microstructure analysis showed that the Fe amount in SrTi1−xFexO3−x/2−δ has a great influence on the lattice parameter and microstructure, including the porosity and grain size. Oxygen nonstoichiometry studies performed by thermogravimetry at different atmospheres showed that the Fe-rich compositions...
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Physicochemical and Mechanical Performance of Freestanding Boron-Doped Diamond Nanosheets Coated with C:H:N:O Plasma Polymer
PublicationThe physicochemical and mechanical properties of thin and freestanding heavy boron-doped diamond (BDD) nanosheets coated with a thin C:H:N:O plasma polymer were studied. First, diamond nanosheets were grown and doped with boron on a Ta substrate using the microwave plasma-enhanced chemical vapor deposition technique (MPECVD). Next, the BDD/Ta samples were covered with nylon 6.6 to improve their stability in harsh environments and...
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Interaction of SrTi0.65Fe0.35O3-δ with LaNi0.6Fe0.4O3-δ, La0.6Sr0.4Co0.2Fe0.8O3-δ and Ce0.8Gd0.2O2-δ
PublicationIron doped strontium titanates SrTi1-xFexO3-δ are perovskites of versatile properties. They can be used in solid oxide fuel cells or high temperature oxygen sensors. Their reactivity with electrolyte materials, cathode buffer layer materials, other cathode materials or current collector layers has not been fully tested. In this study we use X-ray diffraction to check SrTi0.65Fe0.35O3-δ compatibility with Ce0.8Gd0.2O2-δ (used as...
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Cu-Content La1−XSrxNi1−YCuyO3−Δ Perovskites As Cobalt-Free Cathode Materials for High-Performance It-SOFCs
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Coking Study in Anode Materials for SOFCs: Physicochemical Properties and Behavior of Mo-Containing Perovskites in CO and CH4 Fuels
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Influence of controlled crystallization and SrF2 content on the structure and properties of Eu3+ doped phosphate glasses
PublicationNew phosphate glasses and glass-ceramics P2O5–Bi2O3–K2O–Nb2O5-SrF2 doped with Eu were synthesized and studied in this work. The influence of the SrF2 content (0–15 mol%) and the parameters of the heat treatment on their structural and optical properties were investigated. For the above purpose, the structural characterization by FTIR spectroscopy and XRD measurements was carried out, which showed a significant effect of SrF2 on...
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Fractional neutron point kinetics equations for nuclear reactor dynamics – Numerical solution investigations
PublicationThis paper presents results concerning numerical solutions to a fractional neutron point kinetics model for a nuclear reactor. The paper discusses and expands on results presented in (Espinosa-Paredes et al., 2011). The fractional neutron point kinetics model with six groups of delayed neutron precursors was developed and a numerical solution using the Edwards’ method was proposed (Edwards et al., 2002). The mathematical model...
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Properties of Nanohydroxyapatite Coatings Doped with Nanocopper, Obtained by Electrophoretic Deposition on Ti13Zr13Nb Alloy
PublicationNowadays, hydroxyapatite coatings are the most common surface modification of long-term implants. These coatings are characterized by high thickness and poor adhesion to the metallic substrate. The present research is aimed at characterizing the properties of nanohydroxyapatite (nanoHAp) with the addition of copper nanoparticle (nanoCu) coatings deposited on the Ti13Zr13Nb alloy by an electrophoresis process. The deposition of...
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Photoactivity of decahedral TiO2 loaded with bimetallic nanoparticles: Degradation pathway of phenol-1- 13 C and hydroxyl radical formation
PublicationDecahedral TiO2decorated with bimetallic nanoparticles were synthesized via radiolysis and photode-position method. The effect of bimetallic surface composition (Ag Pt, Ag Au, Au Pd, Au Pt) as well asdeposition technique (simultaneous or sequential) on the photocatalytic activity in phenol degradationand efficiency of hydroxyl radicals generation under UV–vis light irradiation were investigated. Modifiedand pristine decahedral...
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Tomasz Zubowicz dr inż.
PeopleTomasz Zubowicz has received his M.Sc. Eng. degree in Control Engineering from the Faculty of Electrical and Control Engineering at the Gda{\'n}sk University of Technology (GUT) in $2008$. He received his Ph.D. Eng. (Hons.) in the field of Control Engineering from the same faculty in $2019$. In $2012$ he became a permanent staff member at the Department of Intelligent Control and Decision Support Systems at GUT and a member of...
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Electrospun Nanofiber Electrodes with in situ Exsolved Nanocatalysts for Symmetrical SOCs
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Electrospun Nanofiber Electrodes with in situ Exsolved Nanocatalysts for Symmetrical SOCs
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Pitting corrosion characterization by electrochemical noise measurements on asymmetric electrodes
PublicationKorozja wżerowa stali nierdzewnych może być wykryta za pomocą obserwacji charakterystycznych sygnałów prądowych, jakie płyną między dwiema elektrodami metalowymi. W artykule proponuje się wyznaczanie funkcji bispektrum dla układu dwóch elektrod o istotnie różnej powierzchni narażonej na występowanie korozji. Proponowana metoda została zastosowana do analizy korozji wżerowej stali 0H18N9 powstającej pod wpływem 1M roztworu FeCl3...
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Thermal and Chemical Expansion in Proton Ceramic Electrolytes and Compatible Electrodes
PublicationThis review paper focuses on the phenomenon of thermochemical expansion of two specific categories of conducting ceramics: Proton Conducting Ceramics (PCC) and Mixed Ionic-Electronic Conductors (MIEC). The theory of thermal expansion of ceramics is underlined from microscopic to macroscopic points of view while the chemical expansion is explained based on crystallography and defect chemistry. Modelling methods are used to predict...
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Nano-engineered diamond-based materials for supercapacitor electrodes: A review
PublicationOwing to the popularity of carbon-based supercapacitors, diamond has also been examined as a potential candidate with unique advantages such as a wide electrochemical potential window and stable capacitive behavior in both aqueous and non-aqueous electrolytes. Moreover, its chemical stability in harsh environments at extreme applied potential and current provides rare opportunities for designing new supercapacitors. Owing to the...
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Portable reactor with LTCC electrodes for production of plasma activated water
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Lead(II)-selective ionophores for ion-selective electrodes: A review
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Electro-chemo-mechanical properties in nanostructured Ca-doped ceria (CDC) by field assisted sintering
PublicationRecent investigations have shown that highly oxygen defective cerium oxides generate non-classical electrostriction that is superior to lead-based ferroelectrics. In this work, we report the effect of field-assisted spark plasma sintering (SPS) on electro-chemo-mechanical properties of calcium doped ceria (CDC). Nanometric powders of Ca.10 nm are rapidly consolidated to form polycrystalline nanostructures with a high degree of...
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General solution of quantum mechanical equations of motion with time-dependent Hamiltonians: A Lie algebraic approach
PublicationThe unitary operators U(t), describing the quantum time evolution of systems with a time-dependent Hamiltonian, can be constructed in an explicit manner using the method of time-dependent invariants. We clarify the role of Lie-algebraic techniques in this context and elaborate the theory for SU(2) and SU(1,1). In these cases we give explicit formulae for obtaining general solutions from special ones. We show that the constructions...
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Chlorido(1-pyrrolidinecarbodithioato-k2S,S')(triphenylphosphine)nickel(II)chloroform hemisolvate
PublicationTytułowy kompleks chloro(1-pirolidynoditiokarbaminiano-S,S')(trifenylofosfina)-nikiel(II), będący hemisolwatem chloroformu zawiera płaski rdzeń o składzie NiClS2P. Molekuły chloroformu oddziałują z kompleksem poprzez słabe wiązania C-H...S.
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Enhanced Degradation of Ethylene in Thermo-Photocatalytic Process Using TiO2/Nickel Foam
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