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Search results for: thin layer chromatography
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Analysis of serum homocysteine in the laboratory practice - comparison of the direct chemiluminescence immunoassay and high performance liquid chromatography coupled with fluorescent detection
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Steroid profiles as potential biomarkers in patients with urogenital tract cancer for diagnostic investigations analyzed by liquid chromatography coupled to mass spectrometry
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Determination of trace levels of eleven bisphenol A analogues in human blood serum by high performance liquid chromatography–tandem mass spectrometry
PublicationChemicals showing structural or functional similarity to bisphenol A (BPA), commonly called BPA analogues, have recently drawn scientific attention due to their common industrial and commercial application as a substitute for BPA. In the European Union, the use of BPA has been severely restricted by law due to its endocrine disrupting properties. Unfortunately, it seems that all BPA analogues show comparable biological activity,...
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Complementary Use of Multi-dimensional Gas Chromatography and Proton Transfer Reaction Mass Spectrometry for Identification of Rapeseed Oil Quality Indicators
PublicationThe change of concentration of various volatiles generated during frying may be an indicator of oil quality. Chemical compounds such as aldehydes, ketones, alcohols and carboxyl acids are the products of oxidation during thermal degradation of edible oils. Shown in this work is a complementary use of GC×GC-TOFMS and PTR-MS for the detection and determination of quality indicators of rapeseed oil. The former technique was used for...
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Analysis of chiral pharmaceutical residues in influent and effluent samples at racemic and enantiomeric level using liquid chromatography-tandem mass spectrometry
PublicationIn this work, two different chromatographic methods for seasonal monitoring of pharmaceutical residue in wastewater samples were developed. In the case of enantiomeric separation of selected compounds, LC-MS technique combining with vancomycin based chiral stationary phase was used. The performance of chiral analysis enabled to monitor the pharmaceutical contamination at the enantiomeric level. The d-SPE procedure was developed...
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Application of gas chromatography to the study of the kinetics of reactionsin solution. Ring opening reactions for á-lactams studied using internal standard
PublicationW pracy przedstawiono metodę badania kinetyki reakcji otwarcia pierścienia á-laktamu, wykorzystującą technikę chromatografii gazowej. Na podstawie badań kinetyki reakcji w różnych temperaturach wyznaczono wartości energii aktywacji dwóch badanych reakcji. Podstawowym celem pracy było pokazanie możliwości wykorzystania GC w badaniach kinetyki reakcji prowadzonych w mikroskali.
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Thermal decomposition of surface compounds for the generation of small quantities of acetaldehyde. Calibration of a thermal desorption gas chromatography flame ionization detection.
PublicationW pracy opisano sposób wytwarzania niewielkich ilości acetaldehydu w procesie termicznego rozkładu związku powierzchniowego uzyskanego w wyniku chemicznej modyfikacji żelu krzemionkowego.Proces rozkładu prowadzony jest w temperaturze 130-190 stopni Celsjusza.Przedstawiono również sposób syntezy prowadzący do uzyskania odpowiedniego związku powierzchniowego.
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Determination of robenidine in animal feeds by liquid chromatography coupled with diode-array detection and mass spectrometry after accelerated solvent extraction
PublicationRobenidyna (chlorowodorek 1,3-bis[(4-chlorobenzylideno)amino]guanidyny) jest stosowana w celu zapobiegania i leczenia kokcydiozy - pasożytniczej choroby układu pokarmowego wielu zwierząt hodowlanych (kozy, owce, króliki, drób) wywoływanej przez pierwotniaki należące do rzędu Eimeria tenella, E. Necatrix, E. Acervulina, E. Maxima, E. Brunetti, and E. Mivati. Robenidyna wykazuje stosunkowo wysoką skuteczność terapeutyczną, przy niewielkiej...
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Scanning with Laser Beam over the TiO2 Nanotubes Covered with Thin Chromium Layers towards the Activation of the Material under the Visible Light
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Ocean mixed layer dynamics: high-resolution simulations of wind, wave and convective effects
Open Research DataThis dataset contains results of high-resolution numerical simulations of the ocean mixed layer (OML) forced by wind, waves and cooling from the atmosphere, i.e., under strongly turbulent, convective conditions. The goal is to provide detailed, three-dimensional information about OML circulation, turbulent kinetic energy, and temperature and salinity...
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Reaction quotients of reforming reactions for SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C - longterm
Open Research DataThe dataset contains the calculated reaction quotients of reforming reactions for the SOFC and SOFC with LSCNT layer (La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s) fueled by synthetic biogas mixture (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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The low coherence Fabry-Pérot interferometer with diamond and ZnO layers
PublicationThe authors present a fiber-optic Fabry-Pérot interferometer built with the application of diamond and zinc oxide (ZnO) thin layers. Thin ZnO films were deposited on the tip of a standard telecommunication single-mode optical fiber (SMF- 28) while the diamond layer was grown on the plate of silicon substrate. Investigated ZnO layers were fabricated by atomic layer deposition (ALD) and the diamond films were deposited using Microwave...
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FTIR spectra of SOFC with LSCNT layer fueled by H2 and 20ppm H2S/biogas mixture at 750 C - cyclic measurements (12h per cycle)
Open Research DataThe dataset contains the FTIR spectra collected during the cyclic measurements of H2S poisoning in DIR-SOFC with LSCNT layer. The H2S poisoning and H2 regenrating cycles were 12 h each. The spectra were collected every 10 min.
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Experimental research on water lubricated three layer sliding bearing with lubrication grooves in the upper part of the bush and its comparison with a rubber bearing
Publicationcomposite. Eachofitslayershasanimportantfunction.Speciallypreparedslidingsurfaceensures minimum resistance.Followingrunning-initssmoothnessbecomesveryhighandthebearingmay continue workingunder fluid lubricationregime.NBRlayerensuresbearingelasticity,goodvibration damping propertiesandinsusceptibilitytoshaftaxismisalignment.Theexternalbrasslayermakes fitting thebearingeasier. Experiment resultsoftheconductedresearchwerecomparedwiththoseforarubberbearingof similar...
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Determination of amikacin and ciprofloxacin by liquid chromatography with pre-column derivatization to evaluate sustained delivery of antibiotics from Drug-Eluting Biopsy Needle
PublicationDetermination of chosen antibacterial antibiotics: amikacin and ciprofloxacin was carried out by HPLC-UV after derivatization with 9-fluorenylmethyl chloroformate and in their native form by HPLC-MS/MS. Developed methods have been applied to control the kinetics of antibiotic release from polymer-based controlled drug delivery system.
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Improvement of derivatized amino acid detection sensitivity in micellar electrokinetic capillary chromatography by means of acid-induced pH-mediated stacking technique
PublicationDerivatization is a frequently used sample prepara-tion procedure applicable to the enhancement of analyte de-tection sensitivity. Amino acids mostly require derivatization prior to electrophoretic or chromatographic analysis, especial-ly if spectrophotometric detection is used. This study presents an on-line preconcentration technique for derivatized amino acids. The sensitivity of the method was improved by the utilization of...
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Quantification of unconjugated and total ibuprofen and its metabolites in equine urine samples by gas chromatography–tandem mass spectrometry: Application to the excretion study
PublicationIbuprofen (IBU) is a widely used nonsteroidal anti-inflammatory drug (NSAID) in human and also veterinary medicine. NSAIDs are usually highly metabolized compounds in horses; they are often present in equine urine, mostly in their conjugated forms (glucuronides). Thus, hydrolysis to cleave the glucuronide linkage prior to anti-doping analysis is often necessary for improving detection. In this study, unconjugated and total IBU...
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Oznaczanie lotnych kwasów tłuszczowych w ściekach metodą chromatografii gazowej =Determination of volatile fatty acids in wastewater using gas chromatography.
PublicationPrzedstawiono metody oznaczania lotnych kwasów tłuszczowych (LKT) w ściekachze szczególnym uwzględnieniem chromatografii gazowej. Omówiono rolę LKT wprocesie biologicznego oczyszczania ścieków. Scharakteryzowano poszczególneetapy procedury analitycznej, począwszy od pobrania próbek rzeczywistych askończywszy na sposobie detekcji. Ze względu na znaczną złożoność matrycyjaką stanowią ścieki, główny nacisk położono na techniki...
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Some Aspects of Measuring Nonlinear Optical Features of Advanced Vertically Aligned Mesoporous Silica Thin Films Activated by Silver and Copper Ions
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X-ray photoelectron spectroscopy, Raman and photoluminescence studies on formation of defects in Cu:ZnO thin films and its role in nonlinear optical features
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Multi-step functionalization procedure for fabrication of vertically aligned mesoporous silica thin films with metal-containing molecules localized at the pores bottom
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In Situ Micro-Observation of Surface Roughness and Fracture Mechanism in Metal Microforming of Thin Copper Sheets with Newly Developed Compact Testing Apparatus
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Chemical-Assisted Mechanical Lapping of Thin Boron-Doped Diamond Films: A Fast Route Toward High Electrochemical Performance for Sensing Devices
PublicationThere is an urgent need for an effective and economically viable increase in electrochemical performance of boron-doped diamond (BDD) electrodes that are used in sensing and electrocatalytic applications. Specifically, one must take into consideration the electrode heterogeneity due to nonhomogenous boron-dopant distribution and the removal of sp2 carbon impurities saturating the electrode, without interference in material integrity....
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Ellipsometric investigation of nitrogen doped diamond thin films grown in microwave CH4/H2/N2 plasma enhanced chemical vapor deposition
PublicationThe influence of N2 concentration (1%–8%) in CH4/H2/N2 plasma on structure and optical properties of nitrogen doped diamond (NDD) films was investigated. Thickness, roughness, and optical properties of the NDD films in the VIS–NIR range were investigated on the silicon substrates using spectroscopic ellipsometry. The samples exhibited relatively high refractive index (2.6 6 0.25 at 550 nm) and extinction coefficient (0.05 6 0.02...
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Analysis of electrochemical parameters in time domain during the passive layer cracking occurring on the 304L stainless steel in chlorides solution under tensile stresses
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Wpływ procesów utleniania na budowę warstwy napawanej ze stopu kobaltu = Oxidation process influence on the morphology the cobalt alloy clad layer
PublicationWarstwę napawaną laserowo ze stopu kobaltu poddano utlenianiu w różnych warunkach. Na powierzchni otrzymano różniące się warstwy tlenków o zróżnicowanej morfologii. Brak było widocznych zmian w mikrostrukturze napoiny. Zbadano także wpływ utleniania na twardość warstwy.
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Synergistic effect of nanoscale carbon black and ammonium polyphosphate on improving thermal stability and flame retardancy of polypropylene: A reactive network for strengthening carbon layer
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Areas of Updraft Air Motion in an Idealised Weather Research and Forecasting Model Simulation of Atmospheric Boundary Layer Response to Different Floe Size Distributions
PublicationPresented dataset is part of a numerical modelling study focusing on the analysis of the influence of sea ice floe size distribution (FSD) on the horizontal and vertical structure of convection in the atmosphere. The total area and spatial arrangement of the up-drafts indicates that the FSD affects the total moisture content and the values of area averaged turbulent fluxes in the model domain. In fact, while convective updrafts...
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Analysis of electrochemical parameters in time domain during the passive layer cracking occurring on the 304L stainless steel in chlorides solution under tensile stresses.
PublicationDynamiczna Elektrochemiczna Spektroskopia Impedancyjna została wykorzystana do szczegółowej analizy zakresu przejścia stan pasywny - stan aktywny podczas procesu pękania warstwy pasywnej. Wpływ potencjału oraz naprężeń mechanicznych na niszczenie warstwy ochronnej występującej na stali 304L w środowisku 0.5M NaCl w pokojowej temperaturze został przestudiowany. Praca prezentuje chwilowe widma impedancyjne uzyskane przy różnych warunkach...
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Application of gas chromatography-mass spectrometry preceded by solvent extraction to determine volatile fatty acids in wastewater of municipal, animal farm and ladfill origin
PublicationW ramach przeprowadzonych badań została opracowana metodyka oznaczania lotnych kwasów tłuszczowych (LKT) z próbek ścieków pochodzących z oczyszczalni ścieków komunalnych, farm zwierząt oraz ze składowiska odpadów organicznych, techniką ekstrakcji ciecz-ciecz (LLE) za pomocą eteru metylo-tert-butylowego (MTBE) jako ekstahenta. Dobrano optymalne warunki chromatograficznego rozdzielania i oznaczania LKT w próbkach środowiskowych,...
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Application of headspace-solid phase microextraction followed by gas chromatography-mass spectrometry to determine short-chain alkane monocarboxylic acids in aqueous samples
PublicationCelem prowadzonych badań było opracowanie metodyki oznaczania krótkołańcuchowych kwasów alkanomonokarboksylowych (KKA), opartej na ich izolowaniu i wzbogacaniu za pomocą techniki HS-SPME, a następnie oznaczaniu za pomocą chromatografii gazowej sprzężonej ze spektrometrią mas (GC-MS). Do ekstrakcji zastosowano włókno pokryte polarną fazą stacjonarną opartą na glikolu polietylenowym (PEG). Dla celów porównawczych zastosowano również...
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Studies on origin of Polish honeys by two-dimensional gas chromatography Ocena pochodzenia surowcowego polskich miodów przy użyciu dwuwymiarowej chromatografii gazowej
PublicationPolish acacia, linden, rapessed and buckwheat-derived honeys and a honydew were analysed for presence of hydrocarbons, alcs., ketones and esters by 2-dimensional gas chromatog. to establish the markers for the honey origin. PrOH was found characteristic for acacia honey, Me(CH2)11OH for linden honey, Me(CH2)6CHOMe for honeydew and Me(CH2)8COOEt for the rapeseed honey. Wykorzystano technikę dwuwymiarowej chromatografii gazowej sprzężonej...
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Determination of organotin compounds in biological samples using accelerated solvent extraction, sodium tetraethylborate ethylation, and multicapillary gas chromatography flame photometric detection.
PublicationPrzedstawiono metodę oznaczania związków cynoorganicznych w próbkach biologicznych. Procedura oparta jest na wykorzystaniu ekstrakcji pod zwiększoną temperaturą i ciśnieniem (ASE) do izolacji związków cynoorganicznych z próbek wątroby morświnów odłowionych w Morzu Bałtyckim. Walidacji metody dokonano na podstawie analizy materiału odniesienia NIES No 11.
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Electrical performance measurement of reference and SOFC with LSCNT layer fueled by H2 and 20ppm H2S/biogas mixture at 750 C - cyclic measurements (12h per cycle)
Open Research DataThe dataset contains the electrical IV measurements collected during the cyclic measurements of H2S poisoning in DIR-SOFC with/-out LSCNT layer. The H2S poisoning and H2 regenrating cycles were 12 h each. The spectra were collected every 10 min.
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Hydrophobic PVDF hollow fiber membranes with narrow pore size distribution and ultra-thin skin for the fresh water production through membrane distillation
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Organochlorine pesticides and polichlorinated biphenyls concentrations in fresh snowfall or top layer of snow from Hornsund region, Svalbard, in the spring 2019
Open Research DataThe dataset contains concentration of organochlorine persistent organic pollutants in snow samples collected from top layer of snow, which corresponded to fresh snowfall in most cases (except DS location, where these are 20 cm top layer sampled weekly). All snow samples have been collected within one month during spring 2019, in the vicinity of the...
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Improvement of the Water Resistance of a Narrow-Band Red-Emitting SrLiAl3N4:Eu2+Phosphor Synthesized under High Isostatic Pressure through Coating with an Organosilica Layer
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The effect of strain rate on the passive layer cracking of 304L stainless steel in chloride solutions based on the differential analysis of electrochemical parameters obtained by means of DEIS
PublicationOkreślono wpływ szybkości rozciągania w zakresie 10-5s-1 ÷ 16∙10-5s-1 na niestacjonarny proces elektrochemiczny pękania warstwy pasywnej. Badania przeprowadzono na stali wysokostopowej 304L w temperaturze pokojowej w środowisku chlorków za pomocą dynamicznej elektrochemicznej spektroskopii impedancyjnej (DEIS). W rezultacie uzyskano zestaw chwilowych widm impedancyjnych odzwierciedlających dynamikę badanego układu korozyjnego....
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Wide-field magnetometry using nitrogen-vacancy color centers with randomly oriented micro-diamonds
PublicationMagnetometry with nitrogen-vacancy (NV) color centers in diamond has gained significant interest among researchers in recent years. Absolute knowledge of the three-dimensional orientation of the magnetic field is necessary for many applications. Conventional magnetometry measurements are usually performed with NV ensembles in a bulk diamond with a thin NV layer or a scanning probe in the form of a diamond tip, which requires a...
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Optimal conditions of ramentaceone and plumbagin separation and isolation from carnivorous plants extracts using reverse phase-high performance liquid chromatography (RP-HPLC)
PublicationPreparatywna chromatografia cieczowa jest szczególnie przydatną techniką do rozdzielania i izolacji użytecznych ilości substancji z różnych skomplikowanych mieszanin. Praca prezentuje optymalne warunki rozdzielania i izolacji ramentaceonu i plumbaginy uwzględniając maksymalną selektywność rozdzielania naftochinonów od substancji balastowych z chloroformowych ekstraktów roślinnych D. aliciae i D. capensis z zastosowaniem techniki...
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Optimal conditions of ramentaceone and plumbagin separation and isolation from carnivorous plants extracts using normal phase-high performance liquid chromatography (NP-HPLC)
PublicationPraca prezentuje optymalne warunki rozdzielania i izolacji plumbaginy i ramentacenu z matrycy analitycznej, którą stanowią chloroformowe ekstrakty z roślin D.aliciae i D.capensis z wykorzystaiem techniki NP-HPLC. Skład eluentu dla żelu krzemionkowego jako fazy stacjonarnej był optymalizowany. Zostały przedstawione optymalne warunki powiększania skali procesu izolacji badanych metabolitów z ekstrakrów roślinnych. Określono również...
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DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS IN SOIL SAMPLES USING ULTRASONIC PROBE AND SALT-ASSISTED LIQUID-LIQUID EXTRACTION COUPLED WITH HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY
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Optimisation of pressurised liquid extraction for elimination of sulphur interferences during determination of organotin compounds in sulphur-rich sediments by gas chromatography with flame photometric detection
PublicationOpracowano metodę analizy osadów dennych na zawartość związków cynoorganicznych (MBT, DBT, TBT, MPhT, DPhT, TPhT) przy użyciu przyspieszonej ekstrakcji rozpuszczalnikiem i chromatografii gazowej z detektorem płomieniowo-fotometrycznym. Detektor ten pozwala selektywnie wykrywać niewielkie ilości pochodnych cynoorganicznych. Niestety, bardzo często spotykana w osadach siarka oraz jej pochodne zakłócają sygnał detektora. Z tego względu...
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Silica-Based Ionogels: Nanoconfined Ionic Liquid-Rich Fibers for Headspace Solid-Phase Microextraction Coupled with Gas Chromatography–Barrier Discharge Ionization Detection
PublicationIn this work, hybrid silica-based materials with immobilized ionic liquids (ILs) were prepared by sol–gel technology and evaluated as solid-phase microextraction (SPME) fiber coatings. High loadings of the IL 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide ([C4MIM][TFSI]) were confined within the hybrid network. Coatings composition and morphology were evaluated using scanning electron microscopy and energy dispersive...
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Analiza pola magnetycznego wewnątrz i na zewnątrz cienkościennego obiektu ferromagnetycznego = An analisis of magnetic field inside and outside thin-walled ferromagnetic object
PublicationAnomalia wnoszona przez obiekt ferromagnetyczny znajdujący się w ziemskim polu magnetycznym związana jest z jego namagnesowaniem stałym i indukowanym.W pracy przedstawiono wyniki badań symulacyjnych dotyczące rozkładu indukowanego pola magnetycznego wewnątrz i na zewnątrz obiektu ferromagnetycznego odpowiadającemu kadłubowi okrętu. Analizę numeryczną przeprowadzono w pakiecie OPERA 3d.
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A 3D-FEM mesh technique for fast analysis of waveguide problems containing rotatable tuning elements
PublicationIn this paper a meshing technique for 3D Finite Element Method is presented. It allows for fast analysis and optimization of the waveguide structures, which contain rotatable tuning elements. In the proposed procedure a thin layer of varying cylindrical mesh buffer is introduced in order to reuse unchanged mesh and FEM matrices in the rest of the domain.
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Nanolayers in Fiber-Optic Biosensing
PublicationIn this chapter, fiber-optic sensors based on nanolayers or thin films and their ability to perform biophotonic measurements is presented. In the last decade, fiber-optic sensors have gained popularity as biosensing devices. This has been made possible because of the design and the integration of new materials in fiber-optic technology. Nanolayers and thin films made from various materials such as nanodiamond (NCD), boron-doped...
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Preparation and Characterization of Microsphere ZnO ALD Coating Dedicated for the Fiber-Optic Refractive Index Sensor
PublicationWe report the fabrication of a novel fiber-optic sensor device, based on the use of a microsphere conformally coated with a thin layer of zinc oxide (ZnO) by atomic layer deposition (ALD), and its use as a refractive index sensor. The microsphere was prepared on the tip of a single-mode optical fiber, on which a conformal ZnO thin film of 200 nm was deposited using an ALD process based on diethyl zinc (DEZ) and water at 100 °C....
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In-situ monitoring of electropolymerization processes at boron-doped diamond electrodes by Mach-Zehnder interferometer
PublicationIn this work, the Mach-Zehnder interferometer was designed to monitor the electrochemical processes conducted at boron-doped diamond electrode surface. The diamond electrodes were synthesized via Microwave Plasma-Assisted Chemical Vapor Deposition on optical grade quartz glass. The achieved transmittance in working are of diamond electrodes reached 55 %. A cage system-based Mach-Zehnder interferometer was used which allowed the...
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Area-Averaged Surface Moisture Flux over Fragmented Sea Ice: Floe Size Distribution Effects and the Associated Convection Structure within the Atmospheric Boundary Layer
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