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Search results for: PHI DARMSTADT
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Study of pH and temperature effect on lipophilicity of catechol-containing antioxidants by reversed phase liquid chromatography
PublicationLipophilicity of selected antioxidant phytochemicals, including flavonoids, phenolic acids and xanthonoids, was determined by reversed phase high performance liquid chromatography with UV detection (RP-HPLC-UV). The analyses run at different temperature and pH conditions in isocratic mode suggested that lipophilicity as distribution coefficient (logD) between aqueous and organic phase decreases with increasing temperature. For...
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pH-Responsive Drug Delivery Nanoplatforms as Smart Carriers of Unsymmetrical Bisacridines for Targeted Cancer Therapy
PublicationSelective therapy and controlled drug release at an intracellular level remain key challenges for effective cancer treatment. Here, we employed folic acid (FA) as a self-navigating molecule in nanoconjugates containing quantum dots (QDs) and β-cyclodextrin (β-CD) for the delivery of antitumor unsymmetrical bisacridine compound (C-2028) to lung and prostate cancers as well as normal cells. The bisacridine derivative can form the...
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The Prognostic Value of PI-RADS Score in CyberKnife Ultra-Hypofractionated Radiotherapy for Localized Prostate Cancer
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Wieloobszarowy miękkoprzełączalny regulator PI w sterowaniu stężeniem tlenu w biologicznej oczyszczalni ścieków
PublicationNapowietrzanie jest podstawowym procesem decydującym o jakości oczyszczania ścieków. Prawidłowy przebieg procesów biologicznych wymaga dostarczenia odpowiedniej ilości tlenu. Zapewnia to optymalne warunki oczyszczania ścieków, dostateczne wymieszanie ścieków z osadem czynnym i zmniejsza główny koszt eksploatacji oczyszczalni ścieków, czyli koszt pompowania powietrza. W artykule zaproponowano sterowanie stężeniem tlenu (Dissolved...
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<title>Search for optical flashes accompanying gamma ray bursts Pi of the Sky collaboration</title>
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Wieloobszarowy układ regulacji PI do sterowania prędkością obrotową samochodu z silnikiem spalinowym
PublicationSterowanie pojazdami stanowi istotny obszar działalności koncernów samochodowych. W pracy przedstawiono nieliniowy model matematyczny układu napędowego samochodu osobowego z silnikiem spalinowym. Następnie zaproponowano strukturę systemu sterowania i zaprojektowano nieliniowy wieloobszarowy układ regulacji PI. Przeprowadzono testy symulacyjne zaproponowanego rozwiązania i dokonano krytycznej analizy uzyskanych wyników.
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Myrosinase activity in different plant samples; optimisation of measurement conditions for spectrophotometric and pH-stat methods
PublicationMyrosinase found in Brassicaceae plants, is the enzyme responsible for hydrolysis of glucosinolates. As a result a variety of biologically active metabolites are liberated, whose importance in crop protection and especially in cancer chemoprevention is rapidly gaining recognition. The growing practical application of glucosinolate degradation products requires that sensitive and reliable methods of myrosinase activity determination...
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Studies on Treatment of Bitumen Effluents by Means of Advanced Oxidation Processes (AOPs) in Basic pH Conditions
PublicationThe paper presents the results of studies on chemical treatment of effluents from production of bitumen of petroleum origin. Due to the presence of sulfide ions, the pH of these effluents is strongly alkaline. Several Advanced Oxidation Processes (AOPs) were studied, including the use of hydroxyl and sulfate radicals oxidants, the hydrodynamic cavitation as well as sonocavitation. The best processes allow to obtain 45% reduction...
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Studies on treatment of bitumen effluents by means of Advanced Oxidation Processes (AOPs) in basic pH conditions
PublicationThe paper presents the results of studies on chemical treatment of effluents from production of bitumen of petroleum origin. Due to the presence of sulfide ions, the pH of these effluents is strongly alkaline. Several Advanced Oxidation Processes (AOPs) were studied, including the use of hydroxyl and sulfate radicals oxidants, the hydrodynamic cavitation as well as sonocavitation. The best processes allow to obtain 45% reduction...
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Impact of inorganic ions and pH variations on toxicity and endocrine potential of selected environmentally relevant pharmaceuticals
PublicationAssessment of the impact of pharmaceutical residues on living organisms is a very complex subject. Apart from taking into account the toxicity of individual compounds, environmental factors should also be taken into account. In this paper, attempts were made to assess the impact of coexisting inorganic ions and changes in pH on the toxicity of ten selected pharmaceuticals. Two bioassays were used to measure the estrogenic and androgenic...
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Release of selected chemical elements from shale drill cuttings to aqueous solutions of different pH
PublicationThe effect of pH changes on leachability of light and heavy metals from shale drill cuttings generated from unconventional shale gas production was investigated. Cuttings, being the primary byproduct generated from drilling operations, belong to the potentially hazardous type of wastes due to presence of heavy and radioactive elements and remains of drilling fluid. In this regard, assessment of potentially dangerous components...
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Photosensitive and pH-dependent activity of pyrazine-functionalized carbazole derivative as promising antifungal and imaging agent
PublicationCarbazole skeleton plays a significant role as a structural scaffold of many pharmacologically active compounds. Pyrazine-functionalized carbazole derivative was constructed by coupling 2-amino-5-bromo-3-methylaminepyrazine (ABMAP) into 3 and 6 positions of the carbazole ring. Multi-experimental methods were used, e.g., potentiometric, spectroscopic (ATR, UV, XRD powder,1H and13C NMR), electrochemical (cyclic voltammetry), and...
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pH-Induced modification to stratum corneum lipids investigated using thermal, spectroscopic, and chromatographic techniques
PublicationZbadano jakim zmianom jakościowym i ilościowym ulegają indywidualne klasy lipidów w Stratum Corneum (tkanka rogowa skóry) pod wpływem środowiska o zmiennym pH.
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Niemetryczne zdjęcia cyfowe w fotogrametrii bliskiego zasięgu w systemie Topcon PI - 3000
PublicationReferat jest opisem możliwośći opracowania obiektu architektonicznego w systemie Topcon Image Surveying Station PI - 3000. Prezentuje możliwości współczesnej fotogrametrii cyfrowej opartej na niemetrycznych obrazach pozyskanych z amatorskich aparatów cyfrowych.
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Komunikacja on-line [on-line]. lipiec 2002 [dostęp 13 grudnia 2002]. Dostę-pny wWorld wide web:<http://www.swiatmarketingu.pl/pages/i/1/5020.php>.
PublicationW wielu opracowaniach mówiących o roli Internetu w działalności organizacjigospodarczych można spotkać się ze stwierdzeniem, że Internet stwarza fir- mom ogromne możliwości rozwoju. Artykuł prezentuje podejście, w którym na- cisk jest położony na nawiązanie relacji z klientami, warunkującymi wytwo- rzenie silnych więzów pomiędzy nimi a organizacją.
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Study of Different Advanced Oxidation Processes for Wastewater Treatment from Petroleum Bitumen Production at Basic pH
PublicationEffluents from production of petroleum bitumens were submitted to treatment by three different AOPs at basic pH (i.e., O3, H2O2 and the combination of O3 and H2O2, a so-called peroxone). The paper presents studies on the identification and monitoring of the volatile organic compounds (VOCs) degradation present in the effluents and formation of byproducts, COD, BOD5, sulfide ions, biotoxicity, and biodegradability changes during...
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Soil pH effects on the comparative toxicity of dissolved zinc, non-nano and nano ZnO to the earthwormEisenia fetida
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Molecular dynamics simulations of the affinity of chitin and chitosan for collagen: the effect of pH and the presence of sodium and calcium cations
PublicationChitosan and chitin are promising biopolymers used in many areas including biomedical applications, such as tissue engineering and viscosupplementation. Chitosan shares similar properties with hyaluronan, a natural component of synovial fluid, making it a good candidate for joint disease treatment. The structural and energetic consequences of intermolecular interactions are crucial for understanding the biolubrication phenomenon...
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Retention time and peak width in the combined pH/organic modifier gradient high performance liquid chromatography
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Inhibition of amyloid fibril formation of hen egg white lysozyme by trimethylamine N-oxide at low pH
PublicationIn vitro inhibition of the formation of fibrous aggregates of proteins (amyloids) has gained increasing attention due to the number of diseases associated with protein misfolding and fibrillation. An interesting group of compounds for which pronounced activity against this phenomenon can be expected consists of low molecular weight substances (osmolytes) which have the ability to change protein stability. Here we investigate the...
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Multiregional PI control strategy for dissolved oxygen and aeration system control at biological wastewater treatment plant
PublicationThe dissolved oxygen is a key parameter for biological processes at wastewater treatment plant. The dissolved oxygen tracking problem is one of the most complex and fundamental issue of biological processes. The paper proposes a new multiregional control strategy for dissolved oxygen tracking problem. The aeration system is included in overall control structure. The control mechanism within the operating point area is based on...
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Importance of the combined effects of dissolved oxygen and pH on optimization of nitrogen removal in anammox-enriched granular sludge
PublicationThe combined effects of dissolved oxygen (DO) and pH on nitrogen removal were investigated in a laboratory-scale sequencing batch reactor (SBR) with anammox-enriched granular sludge obtained from a nitritation/anammox system. The highest specific nitrogen removal rate (SNRR) (1.1 gN gVSS−1 d−1) was observed under non-aerated conditions, resulting in the nitrogen removal efficiency of 81.6%. Although nitrogen removal was readily...
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Mapping the Structural and Dynamic Determinants of pH-Sensitive Heparin Binding to Granulocyte Macrophage Colony Stimulating Factor
PublicationGranulocyte macrophage colony stimulating factor (GMCSF) is an immunomodulatory cytokine that is harnessed as a therapeutic. GMCSF is known to interact with other clinically important molecules, such as heparin, suggesting that endogenous and administered GMCSF has the potential to modulate orthogonal treatment outcomes. Thus, molecular level characterization of GMCSF and its interactions with biologically active compounds is critical...
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Effects of different omeprazole dosing on gastric pH in non-variceal upper gastrointestinal bleeding: A randomized prospective study
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Highly effective degradation of selected groups of organic compounds by cavitation based AOPs under basic pH conditions
PublicationCavitation has become on the most often applied methods in a number of industrial technologies. In the case of oxidation of organic pollutants occurring in the aqueous medium, cavitation forms the basis of numerous advanced oxidation processes (AOPs). This paper presents the results of investigations on the efficiency of oxidation of the following groups of organic compounds: organosulfur, nitro derivatives of benzene, BTEX, and...
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16-kanałowy moduł LED do systemu wspomagającego rozwój roślin sterowany za pomocą Raspberry PI
PublicationOpracowywane są nowe rozkłady widma światła, które wpływają na poprawę zarówno ilości plonów i jakości dokonywanych zbiorów. W celu uproszczenia wprowadzania zmian widma w procesach badawczych oraz w celu przyspieszenia i zrównoleglenia badań w tym zakresie został opracowany niedrogi programowalny moduł LED pozwalający sterować 16 niezależnymi stałoprądowymi kanałami. Niska cena proponowanego rozwiązania oraz jeden sterownik obsługujący...
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Structural analogues of reactive intermediates as inhibitors of glucosamine-6-phosphate synthase and phosphoglucose isomerase
PublicationCentra aktywne izomerazy fosfoglukozowej (PGI) oraz domeny izomerazowej (HPI) syntazy glukozamino-6-fosforanu (GlcN-6-P), wykazują podobieństwo ułożenia przestrzennego kluczowych reszt aminokwasowych, z wyjątkiem reszty Arg272 PGI i reszt Lys603 i Lys485 HPI. Dziesięć pochodnych D-heksitolo-6-P, kwasu 5-fosfoarabonowego i kwasu 6-fosfoglukonowego, strukturalnych analogów cis-enolaminy lub cis-enolanu, przypuszczalnych stanów przejściowych...
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Poly-L-Lysine-functionalized fluorescent diamond particles: pH triggered fluorescence enhancement via surface charge modulation
PublicationRecently, the interest in applying fluorescent diamond particles (FDPs) containing nitrogen-vacancy (NV) centers for enhancing the mechanical and chemical properties of some materials, biological imaging, and sensing has been expanding rapidly. The unique properties of NV centers such as intensive, time-stable fluorescence, and an electron spin, which exhibits long coherence time and may be manipulated using external stimuli, such...
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Application of Wavelet Transform and Fractal Analysis for Esophageal pH-Metry to Determine a New Method to Diagnose Gastroesophageal Reflux Disease
PublicationIn this paper, a new method for analysing gastroesophageal reflux disease (GERD) is shown. This novel method uses wavelet transform (WT) and wavelet-based fractal analysis (WBFA) on esophageal pH-metry measurements. The esophageal pH-metry is an important diagnostic tool supporting the physician’s work in diagnosing some forms of reflux diseases. Interpreting the results of 24-h pH-metry monitoring is time-consuming, and the conclusions...
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Laboratoryjny bioreaktor z systemem kontroli pH do badań nad wytwarzaniem wodoru w procesie ciemnej fermentacji
PublicationW pracy przedstawiono konstrukcję niskokosztowego bioreaktora badawczego wyposażonego w sys-tem kontroli i regulacji pH. Zaprezentowano jego wykorzystanie do badania produkcji wodoru w pro-cesie fermentacji ciemnej z zastosowaniem Enterobacter aerogenes ATCC 13048. W pracy porównano wyniki uzyskane przy prowadzeniu procesu bez i z regulacją pH dla różnych materiałów wsadowych: glukozy, hydrolizatów topoli energetycznej, serwatki...
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Solid-Contact pH Sensor without CO2Interference with a Superhydrophobic PEDOT-C14as Solid Contact: The Ultimate “Water Layer” Test
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Influence of pH of sol-gel solution on phase composition and photocatalytic activity of TiO 2 under UV and visible light
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Picomolar analysis of flavins in biological samples by dynamic pH junction-sweeping capillary electrophoresis with laser-induced fluorescence detection
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Real-time working gas recognition system based on the array of semiconductor gas sensors and portable computer Raspberry PI
PublicationThe gas-analyzing systems based on the array of partially selective gas sensors and pattern-recognition techniques are potentially fast and low-cost alternative for other devices, like gas analysers. They give the possibility of recognition the type and the concentration of measured volatile compounds in their working environment. In this work we present the implementation of gas recognition system, in which the signals from an...
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Modernizacja eksperymentalnego pojazdu hybrydowego PH-MAK. Pojazd a Środowisko. Jedlnia-Letnisko, 12-13 czerwca 2003 r.
PublicationPrzedstawiono opis eksperymentalnego pojazdu z szeregowym napędem hybrydowym, który został zbudowany w Politechnice Gdańskiej w celu prowadzenia badań różnych sposobów sterowania. Krótko opisano możliwe do zastosowania strategie sterowania. Podano przykład wyników badań sterowania hybrydowym układem napędowym. Uzasadniono konieczność modernizacji pojazdu, opisano jej zakres i scharakteryzowano nowy silnik spalinowy oraz dodatkowy...
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Capping ligand initiated CuInS2 quantum dots decoration on, ZnIn2S4 microspheres surface under different alkalinity levels resulting in different hydrogen evolution performance
PublicationSurface distribution of quantum dots (QDs) at the semiconductor matrix caused by synthesis condition (e.g. pH of solution during coupling) could lead to different photocatalytic activity. Thus, achieving an optimal covering of semiconductor matrix by QDs has been challenging. Herein, the influence of the alkalinity level of aqueous decoration medium for the coupling of mercaptoundecanoic acid (MUA) capped CuInS2 quantum dots (CIS)...
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Algorytm automatycznego strojenia regulatorów PI serwonapędów w maszynie frezującej CNC z wykorzystaniem metody optymalizacji rojem cząstek
PublicationPublikacja traktuje o zagadnieniu automatycznego strojenia przemysłowych regulatorów liniowych. Przedstawiono proces projektowania i implementacji systemu zarówno w środowisku symulacyjnym, jak i rzeczywistym. Przeanalizowano wyniki badań porównujących jakość działania układu sterowania przy zestawach parametrów regulatorów otrzymanych różnymi metodami. Jako metodę służącą poszukiwaniu odpowienich nastaw regulatorów wykorzystano...
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Aplikacja komputerowa wspomagająca proces diagnostyki chorób górnego odcinka przewodu pokarmowego na podstawie analizy przebiegu pH-metrii
PublicationW artykule przedstawiono propozycję pierwszego modułu opracowanej i wykonanej aplikacji komputerowej wspomagającej proces diagnostyki GERD i LPR poprzez automatyzacje procesu wyznaczania całkowitej liczby DeMeestera oraz liczby Ryana. Efektem działania aplikacji jest propozycja diagnozy (bazująca na autorskim algorytmie analizy przebiegu pH) metodą DeMeestera lub Rayana. Dodatkowym atutem aplikacji jest możliwość zapoznania użytkownika...
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Aplikacja komputerowa wspomagająca proces diagnostyki chorób górnego odcinka przewodu pokarmowego na podstawie analizy przebiegu pH-metrii
PublicationW artykule przedstawiono propozycję pierwszego modułu opracowanej i wykonanej aplikacji komputerowej wspomagającej proces diagnostyki choroby refluksowej przełyku (GERD) lub refluksu gardłowo-krtaniowego (LPR) poprzez automatyzacje procesu wyznaczania całkowitej liczby DeMeestera oraz liczby Ryana. Efektem działania aplikacji jest propozycja diagnozy (bazująca na autorskim algorytmie analizy przebiegu pH) metodą DeMeestera lub...
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Reactions of tBu2P-PLi-P(tBu)2 with [(Et3P)2MCl2] (M = Ni, Pd, Pt). Synthesis and properties of [(1,2-h-tBu2P=P-P(tBu)2)M(PEt3)Cl] (M=Ni, Pd)
PublicationtBu2P-PLi-P(tBu)2*2THF reaguje z [(Et3P)2MCl2] (M = Ni, Pd) dając odpowiednio [(1,2-h-tBu2P=P-P(tBu)2)Ni(PEt3)Cl] i [(1,2-h-tBu2P=P-P(tBu)2)Pd(PEt3)Cl]. Związek tBu2P-PLi-P(tBu)2 utlenia się i ligand tBu2P-P-P(tBu)2 przyjmuje w produktach strukturę bocznie związanego kationu z krótkim wiązaniem P-P. Reakcja ze związkami platyny nie dała oczekiwanych produktów.
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Inhibitor kinazy Brutona u chorych z nawrotowym lub opornym na leczenie chłoniakiem z komórek płaszcza – wyniki międzynarodowego, wieloośrodkowego, badania II fazy z ibrutynibem (PCI-32765) – EHA Encore
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Effective method of treatment of effluents from production of bitumens under basic pH conditions using hydrodynamic cavitation aided by external oxidants
PublicationUtilization of cavitation in advanced oxidation processes (AOPs) is a promising trend in research on treatment of industrial effluents. The paper presents the results of investigations on the use of hydrodynamic cavitation aided by additional oxidation processes (O3/H2O2/Peroxone) to reduce the total pollution load in the effluent from the production of bitumens. A detailed analysis of changes in content of volatile organic compounds...
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A new pH/organic modifier gradient RP HPLC method for convenient determination of lipophilicity and acidity of drugs as applied to established imidazoline agents
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Maximum Power Point Technique (MPPT) for PV System Based on Improved Pert and Observe (P&O) Method with PI Controller
PublicationPhotovoltaic power generation system has key rule in electricity production. Although, it is clean renewable energy with unlimited resources but it has some drawbacks in efficiency. In order to maximize the efficiency, PV array must drive at maximum power point. For the reason so, several algorithms are used in PV system to track MPP and reduce the...
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Improvement of derivatized amino acid detection sensitivity in micellar electrokinetic capillary chromatography by means of acid-induced pH-mediated stacking technique
PublicationDerivatization is a frequently used sample prepara-tion procedure applicable to the enhancement of analyte de-tection sensitivity. Amino acids mostly require derivatization prior to electrophoretic or chromatographic analysis, especial-ly if spectrophotometric detection is used. This study presents an on-line preconcentration technique for derivatized amino acids. The sensitivity of the method was improved by the utilization of...
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Pracujący w czasie rzeczywistym system detekcji gazów wykorzystujący przenośny komputer Raspberry PI oraz matrycę półprzewodnikowych czujników gazu
PublicationThe gas-analyzing systems based on the array of partially selective gas sensors and pattern-recognition techniques are potentially fast and lowcost alternative for other devices, like gas‑analysers. They give the possibility of recognition the type and the concentration of measured volatile compounds in their working environment. In this work we present the implementation of gas recognition system, in which the signals from an...
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Effective method of treatment of industrial effluents under basic pH conditions using acoustic cavitation – a comprehensive comparison with hydrodynamic cavitation processes
PublicationThe use of acoustic cavitation in advanced oxidation processes (AOPs) is a promising trend in research for treatment of industrial effluents. The paper presents the results of investigations on the use of acoustic cavitation aided by additional oxidation processes (ozonation/H2O2 oxidation/Peroxone/UV-C) for the treatment of effluents from the production of bitumens. Under these conditions, the total contaminant load, expressed...
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Treatment of bitumen post oxidative effluents by sulfate radicals based advanced oxidation processes (S-AOPs) under alkaline pH conditions
PublicationSulfate radicals based Advanced Oxidation Processes (S-AOPs), namely Persulfate and peroxymonosulfate, were used for the treatment of post oxidative effluents from a production of petroleum bitumens under alkaline pH. Studies on the identification and monitoring of the volatile organic compounds (VOCs) along with COD, BOD and sulfide ions reduction were performed. Persulfate with a ratio between the oxygen from the oxidant and...
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Non-Typical Fluorescence Effects and Biological Activity in Selected 1,3,4-thiadiazole Derivatives: Spectroscopic and Theoretical Studies on Substituent, Molecular Aggregation, and pH Effects
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An Excess Electron Bound to Magnesium Halides and Basic Grignard Compounds (RMgX and RMgR, R = Me, Et, Ph; X = F, Cl, Br)
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