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Search results for: microextraction techniques
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Raman scattering measurements in monitoring of polymer synthesis process. Lightmetry 2002 : Metrology and Testing Techniques Using Light.
PublicationW artykule omówiono możliwości wykorzystania pomiarów ramanowskich do monitorowania w czasie rzeczywistym przebiegu procesów syntezy materiałów polimerowych. Wykorzystano sondy światłowodowe do sprzęgnięcia aparatury pomiarowej z typowym stanowiskiem technologicznym. Pomiary miały charakter zdalny, nieniszczący i niezakłócający przebieg reakcji.
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Silica-Based Ionogels: Nanoconfined Ionic Liquid-Rich Fibers for Headspace Solid-Phase Microextraction Coupled with Gas Chromatography–Barrier Discharge Ionization Detection
PublicationIn this work, hybrid silica-based materials with immobilized ionic liquids (ILs) were prepared by sol–gel technology and evaluated as solid-phase microextraction (SPME) fiber coatings. High loadings of the IL 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide ([C4MIM][TFSI]) were confined within the hybrid network. Coatings composition and morphology were evaluated using scanning electron microscopy and energy dispersive...
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Plant-based meat substitute analysis using microextraction with deep eutectic solvent followed by LC-MS/MS to determine acrylamide, 5-hydroxymethylfurfural and furaneol
PublicationFor the analysis of plant-based meat substitutes and the determination of Maillard reaction products such as acrylamide, 5-hydroxymethylfurfural and furaneol, a novel and effective procedure based on hydrophobic natural deep eutectic solvent and liquid chromatography coupled with tandem mass spectrometry was developed for the first time. The 49 compositions of the deep eutectic solvents were designed and screened to select the...
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Determination of mefenamic acid in urine and pharmaceutical samples by HPLC after pipette-tip solid phase microextraction using zinc sulfide modified carbon nanotubes
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An in situ derivatization – dispersive liquid–liquid microextraction combined with gas-chromatography – mass spectrometry for determining biogenic amines in home-made fermented alcoholic drinks
PublicationA novel dispersive liquid–liquid microextraction (DLLME) gas chromatography mass-spectrometry(GC–MS) method was developed for the determination of 13 biogenic amines in home-made wine sam-ples. The method allows to simultaneous extraction and derivatization of the amines providing a simpleand fast mode of extract enrichment. During the study, two different procedures were examined. Sta-tistical analysis was performed to choose...
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Application of dispersive liquid-liquid microextraction and gas chromatography with mass spectrometry for the determination of oxygenated volatile organic compounds in effluents from the production of petroleum bitumen
PublicationWepresent a new procedure for the determination of oxygenated volatile organic compounds in samples of postoxidative effluents from the production of petroleum bitumens using dispersive liquid–liquid microextraction and gas chromatography with mass spectrometry. The eight extraction parameters were optimized for 43 oxygenated volatile organic compounds. The detection limits obtained ranged from 0.07 to 0.82 g/mL for most of the...
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Solid phase microextraction–comprehensive twodimensional gas chromatography–time-of-flight mass spectrometry: a new tool for determining PAHs in airport runoff water samples
Publicationfundamental aspect of airport operations is the pollution caused by airport runoff waters. Polycyclic aromatic hydrocarbons (PAHs) are one of the most important groups of xenobiotics which are commonly found in runoff water originating from airports. Only very limited data on the analysis of airport runoff water have been published until now. Therefore, a reliable and accurate analytical method based on headspace solid-phase microextraction...
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Ultrasound assisted dispersive solid phase microextraction using polystyrene-polyoleic acid graft copolymer for determination of Sb(III) in various bottled beverages by HGAAS
PublicationA new polyoleic acid-polystyrene (PoleS) block/graft copolymer was synthesized and applied as adsorbent for ultrasound assisted dispersive solid phase microextraction (UA-DSPME) of Sb(III) in different bottled beverages and analysis using hydride generation atomic absorption spectrometry (HGAAS). Adsorption capacity of the PoleS was 150 mg g−1. Several sample preparation parameters such as sorbent amount, solvent type, pH, sample...
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Identification of the metabolic fingerprints in women with polycystic ovary syndrome using the multiplatform metabolomics technique
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Endogenous oxidative DNA base modifications analysed with repair enzymes and GC/MS technique
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A new approach for the extraction of tetracyclines from soil matrices: application of the microwave-extraction technique
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Novel Fault Identification for Electromechanical Systems via Spectral Technique and Electrical Data Processing
PublicationIt is proposed, developed, investigated, and validated by experiments and modelling for the first time in worldwide terms new data processing technologies, higher order spectral multiple correlation technologies for fault identification for electromechanical systems via electrical data processing. Investigation of the higher order spectral triple correlation technology via modelling has shown that the proposed data processing technology...
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Aqueous Mechanical Oxidation of Zn Dust: An Inventive Technique for Bulk Production of ZnO Nanorods
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Thermoluminescence and optically stimulated luminescence studies on LiMgPO4 crystallized by micro pulling down technique
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Damage Detection Using Cointegration Technique and Wavelet Analysis of the Post-Cointegrated Lamb Waves
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Hybrid Obfuscation Technique to Protect Source Code From Prohibited Software Reverse Engineering
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Neuro-wavelet damage detection technique in beam, plate and shell structures with experimental validation
PublicationNiniejsza praca poświęcona jest technice diagnostyki konstrukcji bazującej na transfor-macie falkowej oraz sztucznych sieciach neuronowych (tzw. system neuro-wavelet). Zastosowanie analizy falkowej pozwala na lokalizację uszkodzeń wymagającą mini-malnej ilości danych wejściowych. W tym celu niezbędna jest tylko odpowiedź kon-strukcji pomierzona w wielu punktach. Poprawę efektywności lokalizacji zniszczeń uzyskano poprzez użycie...
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Distal pancreatic resection via laparo-endoscopic single site surgery – development of the technique
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Photovoltaic Maximum Power Point Technique based on Incremental Conductance (INCON) control algorithm
PublicationMaximum output power status can significantly improve the deployment rate of solar energy system. In order to get the maximum power output, issue of tracking maximum power point (MPP), reduced harmonics around MPP and improve efficiency of the solar power energy system, this paper presents the improved maximum power point tracking (MPPT) control...
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Analysis of urinary nucleosides as potential cancer markers determined using LC–MS technique
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Overactive bladder treatment: application of methylene blue to improve the injection technique of onabotulinum toxin A
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A comparison of the spectrophotometric Winkler method and HPLC technique in the determination of 5-Hydroxymethylfurfural in natural honey
PublicationPorównano technikę HPLC i klasyczną metodę spektrofotometryczną Winklera pod względem odzysku, precyzji, wykrywalności i oznaczalności 5-hydroksymetylofurfuralu (HMF) w miodach naturalnych. Zawartości HMF obiema metodami oznaczono w 15 różnych miodach naturalnych. Sześć miodów pochodziło z trójmiejskich punktów handlowych, 9 miodów pozyskano bezpośrednio od pszczelarzy z sześciu pasiek. Testem t-Studenta oszacowano istotność różnic...
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Determination of the ionic conductivity of Sr-doped lanthanum manganite by modified Hebb–Wagner technique
PublicationThe Hebb–Wagne rpolarization method with the electron blocking electrode has been discussed in this paper in aim to determine a partial ionic conductivity of Sr-doped lanthanum manganite.The “limiting current” in the proposed system was measured using the two-point DC technique with additional Pt electrode between LSM and blocking electrode.The electrochemical model based on bulk diffusion processes and Boltzmann statistics has...
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Resonance Frequency Calculation of a Multilayer and Multipatch Spherical Microstrip Structure Using a Hybrid Technique
PublicationThis communication offers a rigorous analysis of the resonance frequency problem of a spherical microstrip structure mounted on a multilayer, dielectric-coated metallic sphere, with an electrically small radius. The structure consists of single or multiple metallic patches with arbitrary shapes. A full-wave analysis is employed with the use of proposed hybrid approach, combining the finite-difference technique with a spectral domain...
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Multiresidue Methods for Determination of Currently Used Pesticides in Fruits and Vegetables Using QuECHERS Technique
PublicationApplied all over the world, pesticides are some of the most common pollutants of the environment because of their stability, mobility, their consequent long-term adverse effects on living organisms in general and human health in particular. For these reasons it is essential to monitor and analyse pesticide residues in the fruits and vegetables. The analysis of food samples for the presence of pesticides causes a lot of difficulties...
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Nested Space Mapping Technique for Design and Optimization of Complex Microwave Structures with Enhanced Functionality
PublicationIn this work, we discuss a robust simulation-driven methodology for rapid and reliable design of complex microwave/RF circuits with enhanced functionality. Our approach exploits nested space mapping (NSM) technology, which is dedicated to expedite simulation-driven design optimization of computationally demanding microwave structures with complex topologies. The enhanced func-tionality of the developed circuits is achieved by means...
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Resonance microstrip structure with patch of arbitrary convex geometry with the use of field matching technique
PublicationAn analysis of the resonance frequency problem of planar microstrip structure with patch of arbitrary convex geometry is presented. A full-wave analysis is employed utilizing a combination of Galerkin’s moment method and field matching technique. In this approach, a field matching technique is adopted to calculate the patch surface current densities, and next the method of moments is utilized to calculate resonance frequencies...
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Customization of UWB 3D-RTLS Based on the New Uncertainty Model of the AoA Ranging Technique
PublicationThe increased potential and effectiveness of Real-time Locating Systems (RTLSs) substantially influence their application spectrum. They are widely used, inter alia, in the industrial sector, healthcare, home care, and in logistic and security applications. The research aims to develop an analytical method to customize UWB-based RTLS, in order to improve their localization performance in terms of accuracy and precision. The analytical...
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Fabrication of Composite Polyurethane/Hydroxyapatite Scaffolds Using Solvent-Casting Salt Leaching Technique
PublicationScaffolds are porous three-dimensional structures which are used to fill bone losses and make them possible to cells to grow. Many different structural and biological properties are required from them: porosity, mechanical strength and biocompability. The present research is aimed at development of composite polyurethane/hydroxyapatite scaffolds by using the solvent-casting salt leaching method. The SEM examinations were applied...
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Low cost real time UAV stereo photogrammetry modelling technique – accuracy considerations
PublicationThe paper presents accuracy considerations regarding three 3D modelling techniques. The tested new consumer type stereo camera (ZED 3D Stereolabs) has been implemented info an aerial mapping system, on board micro air vehicle MAV) and tested object has been mapped using a real-time photogrammetry with original real-time software application. The evaluated results has been compared with model gained with a state of art unmanned...
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Magnetic field gradient as the most useful signal for detection of flaws using MFL technique
PublicationThe magnetic flux leakage (MFL) technique is extensively used for detection of flaws as well as for evaluation of their dimensions in ferromagnetic materials. However, proper analysis of the MFL signal is hindered by the MFL sensor velocity causing distortions of this signal. Traditionally measured components of the MFL signal are particularly sensitive to the scanning velocity. In this paper, an another signal – the gradient of...
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Airstrip Ground Improvement Works by Blasting Charge Technique and Dredged-Ash Material Mixture
PublicationSoil improvement by blasting charge technique is known in geotechnics as one of the efficient and inexpensive method. It can be used in preparing of underground to found road construction and buildings as well. The technique proves usefulness especially when dynamic load is applied. It is because of non-stiff or rather resilient type soil after improvement. In noncohesive or organic soil, blasting charge...
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Fast frequency sweep based on the model order reduction technique for calculating scattering parametersjinjFDFDj
PublicationArtykuł prezentuje ulepszoną, efektywną metodę przemiatania częstotliwościowego dla metody FDFD. Liczba równań opisujących analizowaną strukturę jest redukowana za pomocą metody redukcjirzędu modeli, a następnie macierz wynikowa jest diagonalizowana. Kosztowne czasowo odwracanie dużych macierzy jest zastąpione prostym mnożeniem małej macierz diagonalnej przez wektor. Zaprezentowana metoda przemiatania częstotliwościowego może...
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Comprehensive two-dimensional gas chromatography - promising technique for analysis of complex food matrices
PublicationThe present paper is focused on brief description of operational principle of comprehensive two-dimensional gas chromatography (GC×GC) technique, instrumentation and data processing. Furthermore, the examples of application in the field of food analysis, performed also in the author's laboratory, are given. The detailed discussion of GC×GC characterization and comparison of the volatile composition of berries of different blue...
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Monitoring of lysozyme thermal denaturation by volumetric measurements and nanoDSF technique in the presence of N-butylurea
PublicationThe results of thermal studies of denaturation of hen egg white lysozyme (HEWL) in water and an aqueous solution of N-butylurea (BU) are presented. High-precision densimetric measurements were used to characterize and analyze the changes of the specific volume, v, during temperature elevation. The temperature of the midpoint of protein denaturation was also determined by nanoDSF technique (differential scanning fluorimetry). The...
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The computational methods in the development of a novel multianalyte calibration technique for potentiometric integrated sensors systems
PublicationIn recent years, integration and miniaturization of ion-selective electrodes (ISEs) have brought many benefits resulting in the possibility of simultaneous determination of the ions concentration in small volume samples. One of the key problems related to the preparation of potentiometric integrated sensors systems (PISSs) is a calibration procedure due to the necessity to calibrate each particular sensor separately. The main aim...
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Sensorless Rotor Position Estimation of Doubly-Fed Induction Generator Based on Backstepping Technique
PublicationThis paper proposes a speed observer algorithm for the sensorless control of a doubly-fed induction generator based on classical adaptive backstepping technique. The sensorless control is shown using classic stator field oriented control which is used to active and reactive power control. Performance of the proposed algorithm of a speed observer is validated by simulation and experimental results obtained using a small-rating generator...
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Submerged objects modeling and storing in a global reference context using multiresolution spline technique,
PublicationContemporary records from multibeam sonars or even elevations from 3D shuttle radar topography missions feature high resolution. On the other hand, bathymetric models of a different resolution from different sensors are available as well, beginning from very high resolution MBS records and low resolution records coming from regular scattered measurements. Approximating and eventually visualizing the high volume scattered 3D raster...
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A novel method for drop in drop edible oils encapsulation with chitosan using a coaxial technique
PublicationThe presented work concerns a novel one step method for oil encapsulation. In this coaxial system the oil constitutes the core of the capsule, while the chitosan solution is the polymer shell surrounding the core to provide separation of the core from the external environment. The paper contains a diagram of the encapsulation equipment and explains the principle of its operation. The experimental results showed the impact of the...
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Tensile failure study of 3D printed PLA using DIC technique and FEM analysis
PublicationThe paper presents the experimental and numerical study of the failure behaviour of Fused Filament Fabricated (FFF) Polylactic Acid (PLA) samples subjected to tensile load. The examined samples are printed in flat orientation with 0◦, 45◦ and 90◦ raster angles. During the experiments the deformation of the specimens is continuously scanned with the 3D Aramis measuring system utilizing the digital imaging correlation technique,...
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Micro‑ and nano‑ bentonite to improve the strength of clayey sand as a nano soil‑improvement technique
PublicationNano-additives results in the formation of nano-cementation (NC). This process is recently used to improve the durability of various building materials. NC used to improve the strength of untreated soil materials, also known as nano soil-improvement (NSI). In few years, the role of nano-additives in various types of soils were developed. In this research, the role of micro- and nano- size of bentonite as soil stabilizer was evaluated...
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Experimental and numerical analysis of the pyrolysis dynamics of a single wood particle: presentation of the radiographic technique
PublicationPyrolysis is an oxygen-free process for the thermal decomposition of raw materials. The heat conduction and flow of pyrolysis products (i.e., the gas fraction and liquid vapour generated during pyrolysis) influence the process and products. In this work, the influence of the orientation of wooden particle fibres with respect to the direction of the heat source on the dynamics of the process was investigated, where there were two...
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The Application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) Technique in Corrosion and Corrosion Inhibition Studies
Publicationorrosion studies have attracted considerable interest in the areas of materials chemistry and industrial chemistry, as it affects the direct and indirect costs of industry, leading to huge economic setbacks due to the need for repair, maintenance, and even shutdowns due corrosion damage. This new volume is a comprehensive resource that presents new and up-to-date, theoretical, and experimental corrosion inhibition studies.
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Experimental investigations of strain localization in concrete using Digital Image Correlation (DIC) technique
PublicationW artykule przedstawiono wyniki pomiarów tensora odkształceń w belkach betonowych podczas zginania. Pomiary stref pękania wykonano przy zastosowaniu techniki fotooptycznej DIC.
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Measurements of strain localization in granular and brittle specimens using a digital image correlation technique
PublicationW artykule przedstawiono wyniki pomiarów lokalizacji odkształceń w materiałach granulowanych i kruchych przy zastosowaniu cyfrowej techniki korelacji obrazu. Doświadczenia wykonano dla przepływu silosowego (materiały granulowane) i zginanych belek betonowych (materiały kruche).
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Krzysztof Wróblewski prof. dr art. mal.
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Deep eutectic solvents in analytical sample preconcentration Part B: Solid-phase (micro)extraction
PublicationOne of the key challenges of modern analytical chemistry is the monitoring of trace amounts of contaminants using sensitive and selective instrumental techniques. Due to the variety and complexity of some samples, it is often necessary to properly prepare a sample and to perform a preconcentration of trace amounts of analytes. In line with the principles of Green Analytical Chemistry (GAC), it is important for an analytical procedure...
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Sensitive method for determination of benzoic acid in beverages and food samples using air–assisted hydrophobic deep eutectic solvent-based dispersive liquid-liquid microextraction
PublicationA simple, reliable and rapid air–assisted hydrophobic deep eutectic solvent-based dispersive liquid–liquid microextraction (AA-HDES-DLLME) was developed for analysis of benzoic acid in various beverages and food samples. The final determination stage was performed via UV–visible spectrophotometry. The key parameters (extraction time, HDES type and volume, dispersant volume, pH and sample volume) of the AA-HDES-DLLME method were...
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Investigation of use of hydrophilic/hydrophobic NADESs for selective extraction of As(III) and Sb(III) ions in vegetable samples: Air assisted liquid phase microextraction and chemometric optimization
PublicationIn this paper, a green, cost-effective sample preparation method based on air assisted liquid phase microextraction (AA-LPME) was developed for the simultaneous extraction of As(III) and Sb(III) ions from vegetable samples using hydrophilic/hydrophobic natural deep eutectic solvents (NADESs). Central composite design was used for the optimization of extraction factors including NADES volume, extraction cycle, pH, and curcumin concentration....
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Comparison of Air-Assisted, Vortex-Assisted and Ultrasound-Assisted Dispersive Liquid–Liquid Microextraction for the Determination of BTEX Compounds in Water Samples Prior to GC-FID Analysis
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