Search results for: ETHANOL UPGRADING
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Luminescence properties of TeOx-2%Eu1.5%Tb1.5%Tm thin films annealing under an oxidizing atmosphere
Open Research DataThe DataSet contains the emission and excitation spectra of TeOx-2%Eu1.5%Tb1.5%Tm thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of rare-earth ions were added, the nitrates were used as a source of rare-earth...
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Luminescence properties of TeOx-1%Eu1.5%Tb2.5%Dy thin films annealing under an oxidizing atmosphere
Open Research DataThe DataSet contains the emission and excitation spectra of TeOx-1%Eu1.5%Tb2.5%Dy thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of rare-earth ions were added, the nitrates were used as a source of rare-earth...
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A thermodynamic criterion for selection of working fluid for subcritical and supercritical domestic micro CHP
PublicationW pracy przedstawiono kryterium termodynamiczne doboru czynnika roboczego dla mikrosiłowni pracującej w warunkach podkrytycznych i nadkrytycznych. Przeanalizowano 20 płynów możliwych do wykorzystania w mikrosiłowni ORC. Z analizy wynika, że najlepszym płynem roboczym jest etanol, R123 oraz R141b.
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MoS2-containing composite membranes for separation of environmental energy-relevant liquid and gas mixtures: A comprehensive review
PublicationMolybdenum sulfide (MoS2) materials adapted into membranes have demonstrated potential for different areas dealing with molecular separations. For instance, MoS2-based membranes have been proposed for distinct environmental applications, such as water treatment, seawater desalination, gas separation, and solvent separation. Emergently, such membranes have been ultimately investigated for energy-relevant gas separation mixtures,...
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Evaluation of Connectivity Gaps Impact on TCP Transmissions in Maritime Communications
PublicationMany organizations and research working groups, including among others IEEE, ITU, ETSI and IMO are currently working towards improvements in communication of different types of vehicles (cars, trains, planes and vessels) and upgrading utilities and services offered to their crews and passengers travelling all over the world. The paper deals with selected aspects of the TCP protocol connectivity in maritime wireless networks. The...
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Fluctuation enhanced gas sensing with WO3-based nanoparticle gas sensors modulated by UV light at selected wavelengths
PublicationThe sensitivity and selectivity of WO3-based gas sensors can be enhanced by UV-irradiation-induced modulation, especially if different wavelengths are employed. We used fluctuation-enhanced gas sensing, based on measurements of resistance fluctuations in the gas sensor, to study the effects of such modulation on the noise intensity for ambient atmospheres of synthetic air without and with additions of small amounts of ethanol,...
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Hydroliza materiału lignocelulozowego w warunkach podwyższonego ciśnienia i temperatury połączona z gwałtownym rozprężaniem wody
PublicationWykorzystanie biomasy na cele energetyczne jako alternatywy dla paliw kopalnych jest atrakcyjne zarówno z powodów ekonomicznych jak i ekologicznych. Jedną z metod umożliwiających przygotowanie materiału lignocelulozowego do produkcji paliw takich jak etanol bądź metan, w procesie fermentacji, jest hydroliza.
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Thanos Of Titan
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GDP growth in Iran
Open Research DataThe economy of the Islamic Republic of Iran is one of the fastest growing in the Middle East. Iran should not only be associated with crude oil industry but also other areas of the economy. The sanctions that hindered oil exports from Iran meant that the authorities had to take measures to increase exports of other products. There was an increase in...
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Precipitation and Transformation of Vaterite Calcium Carbonate in the Presence of Some Organic Solvents
PublicationIn this paper, the production of CaCO3 particles via the carbonation route in the reaction of CaCl2 and CO2, using NH3 as a promoter of CO2 absorption, was studied. The solvents used as the reaction media for CaCO3 precipitation were aqueous solutions of methanol, isopropanol and dimethyl sulfoxide (DMSO), in a concentration range of 0–20% (v/v). It was found that the presence of an organic additive influenced the precipitation...
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Alkohol-społeczny problem XXI wieku. Zastosowanie biowskaźników spożywania alkoholu w diagnostyce medycznej.
PublicationAlkohol etylowy jest legalną i ogólnodostępną substancją o działaniu psychoaktywnym. Spożywany w niewielkich ilościach może pozytywnie wpływać na zdrowie, ale jego nadmierna konsumpcja powoduje silne uzależnienie. Może być to przyczyną agresywnych zachowań, przemocy w rodzinie, problemów w kontaktach z ludźmi, problemów z prawem, samobójstw, wypadków samochodowych oraz problemów finansowych. Dlatego też, szybka i jednoznaczna diagnostyka...
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Sterowanie procesem destylacji z wykorzystaniem regulatorów rozmytych
PublicationProces destylacji jest popularnym przemysłowym sposobem rozdziału ciekłych mieszanin wieloskładnikowych. W artykule rozważana jest mieszanina etanol-woda, będąca powszechnie destylowanym produktem. Celem artykułu jest zaprojektowanie i symulacyjna analiza działania trzech układów sterowania kolumną rektyfikacyjną z wykorzystaniem rozmytych regulatorów: P, PD i PI.
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Gas boiler as a heat source for the domestic micro-CHP
PublicationIn the presented analysis a commercially available domestic gas boiler as a heat source for domestic ORC is considered. The applicability of the gas boiler (De Dietrich with thermal power 25 kW) coupled with the laboratory prototype micro ORC setup has experimentally studied. The main aim of the study is to determine the working fluid temperature, attainable heat rates and efficiencies of the whole system. Preliminary investigations...
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Increase of power and efficiency of the 900 MW supercritical power plant through incorporation of the ORC
PublicationThe objective of the paper is to analyse thermodynamical and operational parameters of the supercritical power plant with reference conditions as well as following the introduction of the hybrid system incorporating ORC. In ORC the upper heat source is a stream of hot water from the system of heat recovery having temperature of 90 °C, which is additionally aided by heat from the bleeds of the steam turbine. Thermodynamical analysis...
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Gas boiler as a heat source for the domestic micro-CHP
PublicationThis analysis considers a commercially available domestic gas boiler as a heat source for a domestic organic Rankine cycle system. An experimental study was made into the applicability of the gas boiler (De Dietrich with thermal power 25 kW) coupled with the laboratory prototype micro ORC setup. The main aim of the study is to determine the working fluid temperature, attainable heat rates and effciencies of the whole system. Preliminary...
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Assessing Acute Toxicity and Endocrine Disruption Potential of Selected Packages Internal Layers Extracts
PublicationThe focus of the present study is migration of toxic substances from food contact materials and its actual influence on the health of the final consumer. Two food packagings (metal cans, TetraPack®) and five simulants medias (water, ethanol, acetic acid, DMSO, artificial saliva) were selected for simulation studies. For assessment of acute toxicity and endocrine disruption potential of extract samples, two biotests (Microtox® and...
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LC–MS/MS analysis, antioxidant and anticholinergic properties of galanga (Alpinia officinarum Hance) rhizomes
PublicationGalanga (Alpinia officinarum Hance) is a pungent and aromatic rhizome, which is a member of the ginger family (Zingiberaceae). The rhizomes of this plant have been used as a traditional medicine in far east countries for relieving stomach ache, invigorating the circulatory system, treating colds, and reducing swelling. The aim of this study was to investigate antioxidant and anticholinergic properties of galanga. For this purpose,...
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A new cold-adapted beta-D-galactosidase from the Antarctic Arthrobacter sp. 32c - gene cloning, overexpression, purification and properties
PublicationThe development of a new cold-active β-D-galactosidases and microorganisms that efficiently ferment lactose is of high biotechnological interest, particularly for lactose removal in milk and dairy products at low temperatures and for cheese whey bioremediation processes with simultaneous bio-ethanol production. In this article, we present a new β-D-galactosidase as a candidate to be applied in the above mentioned biotechnological...
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A Convenient Way to Methylated 2-Imidazolines. Syntheses of Fluorene and Triazine Cyclic Diamidines
PublicationOne N-methyl- and 4-substituted 2-imidazolines are described. Fluorene bisimidazolines were obtained in good yield (64-92%), starting from 2,7-dicyanofluorene and ammonium sulfide. In a two-step procedure the crude bisthioamide was reacted with excess diaminoalkane-ethanol (1:1 mixt.) in an oil bath. This new procedure is superior over std. methods. For the sake of comparison, a new triazine bisimidazoline (I) was prepd. by...
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Revalorization of the Szewalski binary vapour cycle
PublicationThe aim of the paper is to revalorizate of the Szewalski binary vapour cycle by analysing thermodynamical and operational parameters of this cycle. This was carried by accessible numerical CFM (Computational Flow Mechanics) codes type, by step-by-step modeling of separates apparatus. The binary vapour cycle is providing steam as the working fluid in the high temperature part of the cycle, while another fluid - a low boiling point...
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Experimental investigation of domestic gas boiler fitted with ORC module
PublicationIn the paper the prototype of innovative domestic cogenerative ORC system, consisting of a conventional gas boiler and a small size axial vapour microturbines (in-house designed for ORC and the commercially available for Rankine cycle (RC)), evaporator and condenser were scrutinised. In the course of study the fluid working temperatures, rates of heat, electricity generation and efficiency of the whole system were obtained. The...
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Measurements of the chemical composition of LTO:Cu powders
Open Research DataLithium titanate doped by copper was measured by X-ray photoemission spectroscopy (XPS). For sol-gel synthesis lithium acetate dehydrate and titanium (IV) butoxide 97% and copper (II) nitrate from Alfa Aesar were used as a reagents. Cu precursor was added in the proper weight to get an x index equal 0, 0.1 and 0.2. In the first step lithium acetate...
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XRD patterns of TeOx-BaO-BiO powder
Open Research DataThe DataSet contains the XRD patterns of the TeOx-BaO-BiO powder. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor), barium carbonate, and bismuth carbonate with thetraetylene glycol, water, ethanol, and acetic acid. (Samples molar concentration: 73TeO2-4BaO-3Bi2O3 and 73TeO2-3BaO-4Bi2O3)....
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Wewnętrzne i zewnętrzne źródła węgla organicznego dla wspomagania efektywności procesu denitryfikacji
PublicationCelem prezentowanych badań było określenie wpływu dozowania różnych zewnętrznych źródeł węgla organicznego na efektywność usuwania związków biogennych metodą osadu czynnego. W doświadczeniach zastosowano ścieki oczyszczone mechanicznie (bez podczyszczania, podczyszczone w procesie koagulacji/flokulacji) oraz "konwencjonalne" (kwas octowy, etanol) i "alternatywne" (odpady poprodukcyjne z gorzelni) źródła zewnętrznego węgla organicznego.
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REVITALIZATION PROJECT OF SLUM TRANSFORMATION: A CASE STUDY HAY-AL TANAK,BEIRUT,LEBANON
PublicationSlums are global phenomena that exist as a solution for those who couldn’t afford a house. This phenomenon is growing accompanying the rapid urbanization and the growth of the urban population, three-quarter of the world population anticipated to live in an urban environment by 2050 (Avis, 2016, p. 57). This paper reviews slum's evaluation of the revitalization project for one of the poorest slums in Beirut called Hay-Al Tanak....
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Determination of flavanols by liquid chromatography with fluorescence detection. Application to the characterization of cranberry-based pharmaceuticals through profiling and fingerprinting approaches
PublicationIn this work, a new method based on reversed-phase high-performance liquid chromatography (HPLC) with fluorescence detection (FLD) was established for the determination of catechins and related oligomeric proanthocyanidins (PACs) in cranberry-based pharmaceuticals. Compounds were recovered by liquid extraction using methanol/water/hydrochloric acid (60:39:1, v:v:v) as the extraction solvent. The chromatographic separation was carried...
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Size Exclusion Coupled to Reversed Phase Liquid Chromatography for the Characterization of Cranberry Products
PublicationA combination of solvent extraction, size exclusion purification, and reversed-phase liquid chromatography with UV absorption and fluorescence detection was here used for the determination of flavan-3-ols and related oligomeric compounds in cranberry products. The method relied on robust, simple, and inexpensive instrumental equipment present in most of routine analytical laboratories. Sample extracts in methanol/water/hydrochloric...
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eFRADIR: An Enhanced FRAmework for DIsaster Resilience
PublicationThis paper focuses on how to increase the availability of a backbone network with minimal cost. In particular, the new framework focuses on resilience against natural disasters and is an evolution of the FRADIR/FRADIR-II framework. It targets three different directions, namely: network planning, failure modeling, and survivable routing. The steady state network planning is tackled by upgrading a sub-network (a set of links termed...
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Alternative cogeneration thermodynamic cycles for domestic ORC
PublicationThe Organic Flash Cycle (OFC) is suggested as a vapor power cycle that could potentially improve the efficiency of utilization of the heat source. Low and medium temperature finite thermal sources are considered in the cycle. Additionally the OFC’s aim is to reduce temperature difference during heat addition. The study examines 2 different fluids. Comparisons are drawn between the OFC and an optimized basic Organic Rankine Cycle...
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High-temperature heat pumps – potential technology for heat recovery and production of process heat
PublicationIn the paper, the high temperature vapour compressor based heat pump with a selection of working fluids, both perspective and ecological ones, is considered. Such system is not yet commercially available on the market and in author’s opinion it has significant potential for various applications. In the presented analysis it was assumed that the heat source has a temperature of 50oC and the temperature lift is 60, 80 and 100K respectively....
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NUTRITIONAL AND PHARMACEUTICAL APPLICATIONS OF BIOACTIVE COMPOUNDS IN TROPICAL FRUITS
PublicationDuring the past two decades our international scientific group investigated in vitro the physicochemical and nutritional characteristics of some cultivars of durian at various stages of ripening, mangosteen and new cultivars of snake fruit in comparison with widely used avocado, kiwifruit and mango, and in vivo their influence on laboratory animals. The main objective of the present study was to screen and compare the properties...
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Flow distribution and heat transfer in minigap and minichannel heat exchangers during flow boiling
PublicationThe topic of boiling heat transfer in miniscale geometries has focused the ever increasing interest of researchers in recent years. However, most of the works are related to mini- and microchannels and much less to minigaps. Meanwhile, minigaps allow for more comprehensive experimental studies, i.e. flow visualisations due to the flat, two-dimensional configuration of the flow. The results of the experimental investigations of...
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A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties
PublicationMononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone...
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Optimal boiling temperature for ORC installation
PublicationW pracy przedstawiono oryinalne kryterium wyznaczania optymalnej temperatury odparowania czynnika w obiegu ORC w postaci równań analitycznych. Pokazano przykład obliczeniowy na bazie R134a, wody i etanolu.
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A Perspective on Missing Aspects in Ongoing Purification Research towards Melissa officinalis
PublicationMelissa officinalis L. is a medicinal plant used worldwide for ethno-medical purposes. Today, it is grown everywhere; while it is known to originate from Southern Europe, it is now found around the world, from North America to New Zealand. The biological properties of this medicinal plant are mainly related to its high content of phytochemical (bioactive) compounds, such as flavonoids, polyphenolic compounds, aldehydes, glycosides...
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Flexomagneticity in Functionally Graded Nanostructures
PublicationFunctionally graded structures have shown the perspective of materials in a higher efficient and consistent manner. This study reports a short investigation by concentrating on the flexomagnetic response of a functionally graded piezomagnetic nano-actuator, keeping in mind that the converse magnetic effect is only taken into evaluation. The rule of mixture assuming exponential composition of properties along with the thickness...
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Polyester-urethanes modified with gelatine for tissue scaffolds
PublicationNovel aliphatic PU foams, modified with gelatine, were obtained in a one-step polymerization process. Hard segments were obtained from 1,6-hexamethylene diisocyanate (HDI) and chain extenders 1,4-butanediol (BDO) or 2-(2-(2-hydroxyethoxy)ethoxy)ethanol (TG), soft segments were obtained from poly(ethylene-buthylene adipate) (EBO) polyol. We examined the PU foams for their sorption capability in canola oil, saline (0.9% NaCl water...
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A commercial gas boiler fitted with the ORC module as perspective solution for households
PublicationIn this paper the applicability of the commercial gas boiler (De Dietrich DTG X23N) coupled with the laboratory prototype micro ORC setup was experimentally studied. The main objective was to determine the working fluid capability to obtain required temperatures of vapour prior to the turbine, attainable heat rates and efficiencies of the whole system. The boiler thermal power was 25 kW. Tests were carried out with a single stage...
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Domestic ORC micro-CHP combined with a commercial gas boiler
PublicationThe chapter presents the results of experimental studies conducted during the launch of the first in Poland demonstration prototype of the micro ORC coupled to a domestic gas boiler. The accomplished studies indicated the possibility for the ORC module to work with such boiler (autonomous source of heat) with a prototype single-stage axial micro turbine as the expansion machine. Confirmation of that fact has been delineated in...
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Flow Boiling in Minigap in the Reversed Two-Phase Thermosiphon Loop
PublicationThe paper presents the results of experimental investigations of a model of a heat exchanger featuring a minigap, which is perceived as an evaporator for an inverted thermosiphon. The system works with a single component test fluid. The tested evaporator generates pumping power in the test loop in a way similar to the mammoth pump. The tests regarded a module of the heat exchanger, consisting of a hot leg and a cold leg with the...
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Phytoremediation—From Environment Cleaning to Energy Generation—Current Status and Future Perspectives
Publication:Phytoremediationis a technology based on the use of green plants to remove, relocate, deactivate, or destroy harmful environmental pollutants such as heavy metals, radionuclides, hydrocarbons, and pharmaceuticals. Under the general term of phytoremediation, several processes with distinctively different mechanisms of action are hidden. In this paper, the most popular modes of phytoremediation are described and discussed. A broad...
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Sol-gel derived lithium titanate powders measured by XPS method
Open Research DataFor sol-gel synthesis lithium acetate dehydrate from Alfa Aesar GmbH &Co and titanium (IV) butoxide 97% from Aldrich were used as reagents. Copper (II) nitrate from Alfa Aesar was used as a source of Cu dopant. It was added in the proper weight to get an x index equal 0, 0.1 and 0.2. In the first step lithium acetate and copper nitrate were dissolved...
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Investigation of Acoustic Properties of Poroelastic Asphalt Mixtures in Laboratory and Field Conditions
PublicationMeasures for the improvement of acoustic conditions in the vicinity of roads include the construction of pavement structures with low-noise surfaces with optimal macrotexture and the highest possible sound absorption coefficient. Laboratory evaluation of acoustic properties of a designed asphalt mixture before its placement in the pavement is a good solution. Currently, the most popular method for the determination of the sound...
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Rural Landscape Planning for Sustainable Development. The Case of Poland
PublicationThis text results from theoretical study on the possibilities of rural landscape renovation in Poland. The introduction marks new spatial phenomena and the scope of their influence. It indicates social and cultural reasons of the changes, and states the need of their renewed interpretation. The second part of the article contains a description of the degrading cultural landscape of the country and presents its features. It then...
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Ceramic composites for single-layer fuel cells
PublicationComposite materials consisting of acceptor doped lanthanum orthoniobate electrolyte phase (La0.98Ca0.02NbO4) and Li2O:NiO:ZnO semiconducting phase were synthesized. The precursor powder of La0.98Ca0.02NbO4 was prepared in nanocrystalline (mechanosynthesis) and microcrystalline (solid-state synthesis) form. The composite can be applied in a single-layer fuel cell, because of the presence of two phases acting as an anode and a cathode...
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Metody oczyszczania odcieków z procesów przeróbki osadów w komorach fermentacji
PublicationOdcieki z beztlenowych procesów przeróbki osadu w komorach fermentacji (tzw. wody poosadowe) są istotnym źródłem azotu dopływającego do części biologicznej oczyszczalni ścieków. Odpowiednie oczyszczanie tych wód może więc, w bardzo istotny sposób wpłynąć na warunki eksploatacji oczyszczalni. Konwencjonalny proces usuwania amoniaku za pomocą dwóch faz, tj. nitryfikacji i denitryfikacji, są coraz częściej zastępowane przez jednoetapowy...
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Experimental investigations on condensation in flow in small diameter channels
PublicationW pracy przedstawiono innowacyjne podejście do eksperymentalnych badań kondensacji w przepływie oraz omówiono wstępne wyniki badań eksperymentalnych kondensacji etanolu w pionowej rurce srebrnej o średnicy wewnętrznej 2.3 mm.
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Bending analysis of functionally graded nanoplates based on a higher-order shear deformation theory using dynamic relaxation method
PublicationIn this paper, bending analysis of rectangular functionally graded (FG) nanoplates under a uniform transverse load has been considered based on the modified couple stress theory. Using Hamilton’s principle, governing equations are derived based on a higher-order shear deformation theory (HSDT). The set of coupled equations are solved using the dynamic relaxation (DR) method combined with finite difference (FD) discretization technique...
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Sterowanie kolumną rektyfikacyjną z wykorzystaniem nieliniowego algorytmu predykcyjnego
PublicationPopularną metodą rozdziału ciekłych mieszanin wieloskładnikowych jest rektyfikacja, stosowana w różnych gałęziach przemysłu. W artykule rozważana jest mieszanina etanol-woda. Przedstawiono powszechnie stosowany nieliniowy model dwuskładnikowej kolumny rektyfikacyjnej, dokonano jego dyskretyzacji i zaimplementowano w środowisku MATLAB/Simulink. Następnie zaprojektowano układ sterowania wykorzystując nieliniowy algorytm predykcyjny....
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Reduction of CO2 Emissions from Offshore Combined Cycle Diesel Engine-Steam Turbine Power Plant Powered by Alternative Fuels
PublicationDiverse forms of environmental pollution arise with the introduction of materials or energy that exert adverse effects on human health, climate patterns, ecosystems, and beyond. Rigorous emission regulations for gases resulting from fuel combustion are being enforced by the European Union and the International Maritime Organization (IMO), directed at maritime sectors to mitigate emissions of SOx, NOx, and CO2. The IMO envisions...