Search results for: DUAL HYDROLYSIS
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Extractive detoxification of feedstocks for the production of biofuels using new hydrophobic deep eutectic solvents – Experimental and theoretical studies
PublicationThe paper presents a synthesis of novel hydrophobic deep eutectic solvents (DESs) composed of natural components, which were used for removal of furfural (FF) and 5-hydroxymethylfurfural (HMF) from lignocellulosic hydrolysates. The main physicochemical properties of DESs were determined, followed by explanation of the DES formation mechanism, using 1H NMR, 13C NMR and FT-IR analysis and density functional theory (DFT). The most...
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Advantageous conditions of saccharification of lignocellulosic biomass for biofuels generation via fermentation processes
PublicationProcessing of lignocellulosic biomass includes four major unit operations: pre-treatment, hydrolysis, fermentation and product purifcation prior to biofuel generation via anaerobic digestion. The microorganisms involved in the fermentation metabolize only simple molecules, i.e., monosugars which can be obtained by carrying out the degradation of complex polymers, the main component of lignocellulosic biomass. The object of this...
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Influence of hydrochloric acid concentration and type of nitrogen source on the electrochemical performance of TiO2/N-MoS2 for energy storage applications
PublicationIn this work, nitrogen-doped molybdenum sulfide was directly deposited on titanium dioxide nanotubes substrate (TiO2/N-MoS2) during hydrothermal synthesis. The study focuses on the influence of hydrochloric acid concentration used for the synthesis, with the results indicating its essential role in thioacetamide hydrolysis and thus in the effectiveness of the N-MoS2 deposition. The electrode material itself is characterized by...
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Novel Functionalization of Boron-Doped Diamond by Microwave Pulsed-Plasma Polymerized Allylamine Film
PublicationWe report the novel modification of a hydrogen-terminated polycrystalline boron-doped electrode with a microwave pulsed-plasma polymerized allylamine. Boron-doped diamond (BDD) was coated with a very thin layer of adherent cross-linked, pinhole- and additive-free allylamine plasma polymer (PPAAm) resistant to hydrolysis and delamination and characterized by a high density of positively charged amino groups. The pulsed microwave...
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Effect of Hydroxypropylation and Beta-Amylase Treatment on Complexation of Debranched Starch With Naringenin
PublicationNaringenin exhibits many health benefits but it has limited water solubility and consequently low bioavailability. The objective of this study is to investigate the effect of hydroxypropylation and enzymatic treatments on starch complexation with naringenin. Potato starch and Hylon VII are hydroxypropylated to two substitution degrees and then debranched or debranched/β‐amylase treated prior to complexing with naringenin. Both...
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Which casein in sodium caseinate is most resistant to in vitro digestion? Effect of emulsification and enzymatic structuring
PublicationWe investigated the resistance of individual constituent casein epitopes (αS1-, αS2-, β- and κ-CN) in food-grademilk protein sodium caseinate (NaCN) to simulated human gastro-duodenal digestion. The influence of NaCNadsorption to the surface of oil-in-water emulsion droplets and the effect of crosslinking of the protein withenzyme transglutaminase (TG) on the proteolysis were studied by indirect ELISA. TG crosslinking renderedfragments...
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Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups
PublicationRe(L1)–Re(L3), a series of rhenium(I) tricarbonyl chloride complexes with bpy-R2 derivatives L1–L3 (bpy = 2,2′-bipyridine, R represents the substitution at the 4- and 4′-positions), and their corresponding trishomoleptic Ru(L1)3–Ru(L3)3 as well as heteroleptic ruthenium(II) complexes Ru(tbbpy)2(L1) and Ru(tbbpy)2(L2) have been synthesized and characterized. Their applicability as immobilizable metal–organic chromophores in solar...
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Red Algae – An Alternative Source of Carbon Material for Energy Storage Application
PublicationNew electrode material obtained by pyrolysis of aquatic biomass macro (red algae) soaked with glucose solution has been characterized by SEM, EDX and Raman spectroscopy. Graphitized carbon was identified by Raman spectroscopy. Galvanostatic cyclic polarization of the materials in contact with 1M LiPF6 electrolyte in EC:DMC (1:1 v/v) and Li as a counter electrode was performed. Specific capacity of the novel material was enhanced...
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Znaczenie różnorodności w wirtualnej współpracy
PublicationRóżnorodność jest jedną z podstawowych cech zespołów wirtualnych. Odnosi się ona do geograficznego rozproszenia członków zespołu, różnic stref czasowych, w których pracują, zróżnicowania narodowogo i kulturowego, ale również do pracy dla różnych organizacji, pełnienia różnych ról zespołowych o odpowiedzialności za różne części realizowanego projektu. Artykuł dotyczy najważniejszych wymiarów różnorodności istotnych dla wirtualnej...
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Medium voltage drives - challenges and requirements
PublicationThe design and application of medium voltage (MV) drives are associated with different requirements related to the line side and motor side of the drive. This paper presents a brief review of the existing challenges and requirements for employing medium voltage drives in various industries. Line side, motor side, and converterproblems and requirements are described. The aim of the paper is to review the existing problems to allow...
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KOMPUTER W LABORATORIUM VS LABORATORIUM W KOMPUTERZE
PublicationAbstract. In March 2020, all of the sudden, university teachers have been made to run all the classes remotely. But, how to deal with lab classes for future engineers? Different aspects of teaching labs on Moodle, that should be taken in consideration, are not only connected with the content of the class, but also with transferring the knowledge and materials to the students in a way that would avoid distractions and help students...
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The application of a photopolymer material for the manufacture of machine elements using rapid prototyping techniques
PublicationThe paper discusses the application of polymer resin for 3D printing. The first section focuses on rapid prototyping technique and properties of the photopolymer, used as input material in the manufacture of machine components. Second part of the article was devoted to exemplary 3-D-printed elements for incorporation in machines. The article also contains detailed description of problems encountered in implementation of the selected...
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Specification-Oriented Automatic Design of Topologically Agnostic Antenna Structure
PublicationDesign of antennas for modern applications is a challenging task that combines cognition-driven development of topology intertwined with tuning of its parameters using rigorous numerical optimization. However, the process can be streamlined by neglecting the engineering insight in favor of automatic de-termination of structure geometry. In this work, a specification-oriented design of topologically agnostic antenna is considered....
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Enhancing electrochemical properties of an ITO-coated lossy-mode resonance optical fiber sensor by electrodeposition of PEDOT:PSS
PublicationA sensor working in multiple domains may offer enhanced information about the properties of an investigated analyte, including those containing biological species. It has already been shown that a dual-domain sensing capability, i.e., in optical and electrochemical domains, can be offered by lossy-mode resonance (LMR) sensors based on indium-tin-oxide (ITO) thin film. The spectral response of the LMR sensors depends on the refractive...
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TIME-AND-SPACE STRUCTURE OF FORCE-DRIVEN RIGID SPHEREWAVEFIELD
PublicationThis paper introduces a time-domain, causality-inspired description of a vector-source acoustic wavefield of arbitrary time evolution, where a sphere is a practical realisation of quasi-point contact surface without which a point force would not be able to exert an impact onto non-viscous fluid. At every space location, the resulting acoustic field is described by a pair of physical variables characterising the time evolution of...
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Suppression of distortions in signals received from Doppler sensor for vehicle speed measurement
PublicationDoppler sensors are commonly used for movement detection and speed measurement. However, electromagnetic interference and imperfections in sensor construction result in degradation of the signal to noise ratio. As a result, detection of signals reflected from moving objects becomes problematic. The paper proposes an algorithm for reduction of distortions and noise in the signal received from a simple, dual-channel type of a Doppler...
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Reliable Multi-Stage Optimization of Antennas for Multiple Performance Figures in Highly-Dimensional Parameter Spaces
PublicationDesign of modern antenna structures needs to account for multiple performance figures and geometrical constraints. Fulfillment of these calls for the development of complex topologies described by a large number of parameters. EM-driven tuning of such designs is mandatory yet immensely challenging. In this letter, a new framework for multi-stage design optimization of multi-dimensional antennas with respect to several performance...
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Wykonanie czujnika LPR oraz dobór materiałów konstrukcyjnych w instalacji wody morskiej
PublicationWykonano analizę pracy systemu monitorowania korozji, dokonano wymiany czujnika. Zamontowano nowy czujnik z opcją pomiaru kuponowego w celu doboru materiałów konstrukcyjnych do instalacji wody morskiej.
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BADANIA SKŁADU ORAZ OCENY DOBORU STALI I KOROZJI KANAŁU WENTYLACYJNEGO NA PŁYWALNI AQUA CENTRUM W KOŚCIERZYNIE
PublicationW ramach zlecenia dokonano badania oraz oceny składu doboru stali i korozji kanału wentylacyjnego na pływalni Aqua Centrum w Kościerzynie.
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Monitorowanie szybkości korozji oraz dobór materiałów konstrukcyjnych w instalacji wody morskiej platformy Baltic Beta
PublicationWykonano analizę szybkości korozji systemu monitorowania korozji z okresu od 25.11.2016 do 12.07.2017. Zdemontowano czujnik korozyjny w instalacji wody morskiej, Zainstalowani nowy czujnik z opcją pomiaru szybkości korozji metodą kuponową. Monitoringiem poddano następujące materiały: 1.7362, 1.5415, 1.0038
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Evaluation of Praseodymium and Gadolinium Doped Ceria as a Possible Barrier Layer Material for Solid Oxide Cells
PublicationIn this work, nanocrystalline layers based on the Pr, Gd co-doped CeO2 were investigated. For the preparation of thin layers, lowtemperature spray pyrolysis technique was used. Different stoichiometries of the layers were produced for comparison on polished sapphire substrates. The microstructure of the prepared thin layers was studied by scanning electron microscopy (SEM), energydispersive X-ray spectroscopy (EDS) and X-ray diffractometry (XRD)....
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Effects of Basalt and Carbon Fillers on Fire Hazard, Thermal, and Mechanical Properties of EPDM Rubber Composites
PublicationDue to growing restrictions on the use of halogenated flame retardant compounds, there is great research interest in the development of fillers that do not emit toxic compounds during thermal decomposition. Polymeric composite materials with reduced flammability are increasingly in demand. Here, we demonstrate that unmodified graphene and carbon nanotubes as well as basalt fibers or flakes can act as effective flame retardants...
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A Test-Bed Analysis of Simultaneous PMIPv6 Handover in 802.11 WLANs Environment
PublicationProviding mobility in access networks is a challenge that we have to deal with. Due to networks’ convergence and migration to all-IP networks, mobility management at the network layer is required. However, there is a need for cooperation mechanisms between the network layer and lower layers to support multimedia services and make handover more efficient. This paper presents experimental research on simultaneous handover performance...
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Radar and Sonar Imaging and Processing (2nd Edition)
PublicationThe 14 papers (from 29 submitted) published in the Special Issue “Radar and Sonar Imaging Processing (2nd Edition)” highlight a variety of topics related to remote sensing with radar and sonar sensors. The sequence of articles included in the SI deal with a broad profile of aspects of the use of radar and sonar images in line with the latest scientific trends, in which the latest developments in science, including artificial intelligence,...
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Kazimierz Market Place. Akwarela 38x56cm
PublicationL'acquerello in Alessandria, la mostra internazionale patrocinata dal Comune e dalle Provincia di Alessandria, dalla Regione Piemonte e dal Comune di Vignale e organizzata dall'Associazione italiana acquerellisti. L'esposizione, circa 150 acquerelli dei socie Aia e di artisti provenienti da Australia, Belgio, Brasile Polonia e Spagna per presentare le principali tecniche dell'acquerelli e le diverse concezioni artistiche e stilistiche...
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Characterization of immobilized Escherichia coli cells transformed by β-galactosidase gene from Pyrococcus woesei
PublicationThermostable β-galactosidase from Escherichia coli transformant containing theenzyme gene from Pyrococcus woesei was immobilized on alginate gel.The benefits of using whole bacterial cells not only exclude expensive, laborious proteinisolation and purification but also stabilize enzymes by cytosol components. Increase inproductivity of enzyme can be achieved by cells permeabilization. To increase permeability ofcytoplasmic membrane...
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Characterization of glucoamylase immobilized on magnetic nanoparticles
PublicationMagnetic support was prepared by precipitation from an alkaline solution of divalent and trivalent iron ions and subsequently was modified with 3-aminopropyltriethoxysilane. FTIR analysis showed existence of a new Si-O-Fe bond in obtained particles. Scanning electronic microscopy images shows that the nanoparticles of all samples have particle size below 30 nm. Glucoamylase AMG 300L was immobilized onto the modified magnetic support...
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Pre-treatment of bio fraction waste prior to fermentation processes
PublicationCurrent efforts are taken to increase resource efficiency, close material loops, and improve sustainable waste and by-products management. Thus, networking agro-food by-products and converting them into valuable products completely exhausting the potential of the raw material becomes significant. Model lignocellulosic and starch based biomass were subjected to pre-treatment with the application of acidic compounds, i.e. sulphuric...
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Extractive detoxification of hydrolysates with simultaneous formation of deep eutectic solvents
PublicationThe hydrolysis of lignocellulosic biomass results in the production of so-called fermentation inhibitors, which reduce the efficiency of biohydrogen production. To increase the efficiency of hydrogen production, inhibitors should be removed from aqueous hydrolysate solutions before the fermentation process. This paper presents a new approach to the detoxification of hydrolysates with the simultaneous formation of in-situ deep eutectic...
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Analysis of the Factors Affecting Static In Vitro Pepsinolysis of Food Proteins
PublicationIn this meta-analysis, we collected 58 publications spanning the last seven decades that reported static in vitro protein gastric digestion results. A number of descriptors of the pepsinolysis process were extracted, including protein type; pepsin activity and concentration; protein concentration; pH; additives; protein form (e.g., ‘native’, ‘emulsion’, ‘gel’, etc.); molecular weight of the protein; treatment; temperature; and...
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Prediction of Bioactive Peptides From Chicken Feather and Pig Hair Keratins Using In Silico Analysis Based on Fragmentomic Approach
PublicationBackground: Keratin is among the most abundant structural proteins of animal origin, however it remains broadly underutilized. Objective: Bioinformatic investigation was performed to evaluate selected keratins originating from mass-produced waste products, i.e., chicken feathers and pig hair, as potential sources of bioactive peptides. Methods: Pepsin, trypsin, chymotrypsin, papain, and subtilisin were used for in silico keratinolysis...
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The impact of slowly biodegradable organic compounds on the oxygen uptake rate in activated sludge systems
PublicationThe hydrolysis process of slowly biodegradable substrate (Xs) have impact on the efficiencies of nutrient removal in activated sludge systems. Measurement of OUR and corresponding COD is accepted as a very useful tool to reflect the consumption of biodegradable substrates. The influence of the readily biodegradable substrate (Ss) in biological wastewater treatment systems has been extensively investigated, but little is known about...
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The impact of slowly biodegradable organic compounds on the oxygen uptake rate in activated sludge systems
PublicationThe hydrolysis process of slowly biodegradable substrate (Xs) have impact on the efficiencies of nutrient removal in activated sludge systems. Measurement of OUR and corresponding COD is accepted as a very useful tool to reflect the consumption of biodegradable substrates. The influence of the readily biodegradable substrate (Ss) in biological wastewater treatment systems has been extensively investigated, but little is known about...
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Tuning of the Electrochemical Properties of Transparent Fluorine-doped Tin Oxide Electrodes by Microwave Pulsed-plasma Polymerized Allylamine
PublicationWe report here the dry, one-step, and low-temperature modification of FTO surfaces using pulsed plasma polymerization of allylamine (PPAAm). PPAAm/FTO surfaces were characterized by X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and contact angles to understand the morphological, structural, and optical properties. FTO were coated with a very thin layer of adherent cross-linked, pinhole-, and additive-free allylamine...
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Hybrid Approach to Networked Control System
PublicationEffcient control of Networked Control System (NCS) is a challenge, as the control methods need to deal with non-deterministic variable delays and data loss. This paper presents a novel hybrid approach to NCS where Model Predictive Control (MPC) is applied as a main controller and implicit switching MPC is used for data transmission control in event-driven shared communication medium, leading to complex control system with active...
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Work–life balance: Does age matter?
PublicationWork-life balance is a priority of EU policies but at the same time demographic change affects the labour market. Employers have to deal with the ageing of their employees and adjust human resource management to maintain their competitiveness. The purpose of the article is to answer research questions: whether the age of workers determines their assessment of the work-life balance, and whether there is a relationship between the...
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Tin oxide nanoparticles from laser ablation encapsulated in a carbonaceous matrix – a negative electrode in lithium-ion battery applications
PublicationThis report concerns carbonaceous electrodes doped with tin(II) oxide nanoparticles. Tin nanoparticles are obtained by pulsed laser ablation in water. Crystalline nanoparticles have been encapsulated in a carbonaceous matrix formed after pyrolysis of a mixture consisting of tin/tin(IV) oxide nanoparticles and gelatine. The obtained material is characterized by means of X-ray diffraction, selected area diffraction, scanning electron...
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Hard carbon derived from rice husk as low cost negative electrodes in Na-ion batteries
PublicationHere, we report the synthesis of hard carbon materials (RH) made from natural rice husk through a single pyrolysis process and their application as an anode in sodium-ion batteries. The studies show that the electrochemical properties of RHs are affected by the treatment temperatures, which determine the materials morphology, in particular, their degree of graphitization and extent of continuous channels (nanovoids). The latter...
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A note on the Morse homology for a class of functionals in Banach spaces involving the 2p-area functional
PublicationIn this paper we show how to construct Morse homology for an explicit class of functionals involving the 2p-area functional. The natural domain of definition of such functionals is the Banach space W_0^{1,2p}(\Omega), where p > n/2 and \Omega \subet R^n is a bounded domain with sufficiently smooth boundary. As W_0^{1,2p}(\Omega) is not isomorphic to its dual space,critical points of such functionals cannot be non-degenerate...
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Development of the New Polish Method for Capacity Analysis of Motorways and Expressways
PublicationThe paper presents development of the new Polish method for performing capacity analysis of basic segments of dual carriageway roads (motorways and expressways). The method is based on field traffic surveys conducted at 30 motorway and expressway sites (class A and S roads) in Poland. Traffic flows, composition and travel times were observed in 15-min intervals at each site using ANPR filming method. These data were used to calibrate...
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A Model-Order Reduction Approach for Electromagnetic Problems With Nonaffine Frequency Dependence
PublicationThe aim of this paper is to present a novel model-order reduction (MOR) technique for the efcient frequency-domain nite-element method (FEM) simulation of microwave components. It is based on the standard reduced-basis method, but the subsequent expansion frequency points are selected following the so-called sparsied greedy strategy. This feature makes it especially useful to perform a fast-frequency sweep of problems that lead...
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Circularly Polarized Metalens Antenna Design for 5G NR Sub-6 GHz Communication Systems
Publication5G NR (new radio) FR1 range refers to as Sub-6GHz band (410MHz to 7125MHz and 3.4GHz to 6GHz). In this paper, the frequency range of interest is from 3.4 to 6GHz, as many cellular companies are focusing on this Sub-6GHz band. A wideband circularly polarized (CP) antenna radiator is designed with diamond shape patches, fed by a microstrip line at the bottom through a rectangular shape wide slot on a ground plane. The proposed CP...
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Macrocyclic derivatives of imidazole as chromoionophores for bismuth(III)/lead(II) pair
Publication18-membered diazomacrocycles with imidazole or 4-methylimidazole residue as a part of macrocycle were used as chromoionophores in bismuth(III) and lead(II) dual selective optodes for the first time. Cellulose triacetate membranes doped with macrocyclic chromoionophores are bismuth(III) and lead(II) selective with color change from orange/red to different shades of blue and violet, respectively. Results obtained for model and real...
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Rapid redesign of multiband antennas with respect to operating conditions and material parameters of substrate
PublicationThis work addresses geometry parameter scaling of multi-band antennas for Internet of Things applications. The presented approach is comprehensive and permits re-design of the structure with respect to both the operating frequencies and material parameters of the dielectric substrate. A two-step procedure is developed with the initial design obtained from an inverse surrogate model constructed using a set of appropriately prepared...
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TiO2-C nanocomposite synthesized via facile surfactant-assisted method as a part of less energy-consuming LED-based photocatalytic system for environmental applications
PublicationA novel facile method was used to incorporate carbon into the titania structure. An alternative synthesis method of carbon-doped TiO2 has been proposed by using a widely used and cheap surfactant. During the process, cetyltrimethylammonium bromide plays a dual role, as a morphology modifier and as a carbon source. The presented approach allows obtained TiO2-C nanostructures to be anatase nanocrystals with carbon being deposited...
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Design-Oriented Constrained Modeling of Antenna Structures
PublicationFast surrogate models are crucially important to reduce the cost of design process of antenna structures. Due to curse of dimensionality, standard (data-driven) modeling methods exhibit serious limitations concerning the number of independent geometry parameters that can be handled but also (and even more importantly) their parameter ranges. In this work, a design-oriented modeling framework is proposed in which the surrogate is...
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Interactions of positrons with atoms and molecules
PublicationThe positron is the antiparticle of the electron. It has the same mass as the electron, but opposite charge. The understanding of the interactions of positrons with normal matter, like atoms and molecules, is of interest in various scientific fields, like nuclear medicine, plasma physics and astronomy. In this talk we will give a short introduction to some theoretical methods to describe the interactions of positrons with atoms...
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Nitrogen transformations and mass balances in anaerobic/anoxic/aerobic batch experiments with full-scale biomasses from BNR activated sludge systems.
PublicationThe aim of this study was to investigate nitrogen mass balances occurring inside full-scale BNR activated sludge systems, with special attention to colloidal and dissolved organic nitrogen (CON and DON) transformations. For this purpose, laboratory experiments were carried out using process biomass from two large BNR plants in northern Poland. Two parallel batch reactors were operated in a 3-phase (anaerobic/anoxic/aerobic) cycle....
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Nitrogen transformations and mass balances in anaerobic/anoxic/aerobic batch experiments with full-scale biomasses from BNR activated sludge systems.
PublicationThe aim of this study was to investigate nitrogen mass balances occurring inside full-scale BNR activated sludge systems, with special attention to colloidal and dissolved organic nitrogen (CON and DON) transformations. For this purpose, laboratory experiments were carried out using process biomass from two large BNR plants in northern Poland. Two parallel batch reactors were operated in a 3-phase (anaerobic/anoxic/aerobic) cycle....
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The influence of cultivation conditions on the myrosinase activity and glucosinolate content in white cabbage
PublicationIn the process of biofumigation typically natural compounds present in Brassicaceae family are used to combat pests and protect crops. Glucosinolates, sulfur-containing secondary metabolites found in Brassica plants, are hydrolized by the enzyme myrosinase (β-thioglucosidase, EC 3.2.3.1) with the liberation of degradation products such as isothiocyanates, nitriles, thiocyanates and epithionitriles. Isothiocyanates are the most...