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Greening procedures and analytical parameters. The polychlorinated naphthalenes analysis in complex matrices as proof of concept
PublikacjaDue to the complexity of analytical procedures employed for the determination of wide spectrum of persistent organic pollutants (POPs), it is important to consider the green character of the applied protocols and propose the greenest solutions. In this review, the green aspects of several analytical procedures used for the determination of polychlorinated naphthalenes (PCNs) (as a representatives of POPs) in different types of...
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Application of deep eutectic solvents in bioanalysis
PublikacjaThe application of deep eutectic solvents (DESs) is sharply surging as a green alternative to conventional solvents due to their unique properties in terms of simplicity of preparation, designability and low cost. A great deal of attention has been paid to the application of these green solvents in analytical chemistry in recent years, and a lot of interesting work has been reported. This review summarizes the most relevant applications...
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The Influence of PEG on Morphology of Polyurethane Tissue Scaffold
PublikacjaIn this study, polyurethanes (PU) were synthesized from oligomeric dihydroxy(etylene-butylene adipate), poly(ethylene glycol) (PEG), hexamethylene diisocyanate (HDI), 1,4-butanediol (BDO) as chain extender and stannous octoate as catalyst. PEG due to its hydrophilic character influences physical and chemical properties of PU. For testing were used PU having the following weigh contents of PEG: 0%, 7%, and 14%. Porous scaffolds...
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Sewage sludge pretreatment by low thermal disintegration for better efficacy of sludge digestion process
PublikacjaThe wastewater water treatment plant (WWTP) sector and it is developing technologies strive to be implement circular economy. The methane production from the sludge digestion process constitute promising source of the renewable energy for WWTP and approaching circular economy assumptions. For this reason, the objective of the study was to examine the modification of sludge characteristics due to the low temperature pretreatment....
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Application of the X-ray micro computed tomography to the analysis of the structure of polymeric materials
PublikacjaIn this paper the application of X-ray micro-computed tomography (micro-CT) as a non-destructive testing method of polymeric materials is presented. Increasing applicability of polymers in variedend-use industries such as automotive, building and construction, consumer goods, and packaging is propelling the growth of the global polymer processing market. However, controlling of the polymer structure is one of the most important...
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Application of Barycentric Coordinates in Space Vector PWM Computations
PublikacjaThis paper proposes the use of barycentric coordinates in the development and implementationof space-vector pulse-width modulation (SVPWM) methods, especially for inverters with deformed space-vector diagrams. The proposed approach is capable of explicit calculation of vector duty cycles, independentof whether they assume ideal positions or are displaced due to the DC-link voltage imbalance. The use ofbarycentric coordinates also...
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Stabilization of the pyrochlore phase of Mn2Sb2O7 by double substitution
PublikacjaPolycrystalline samples of (Ce4+Mn2+3)(Ga3+Sb5+3)O14 were synthesized by a high-temperature solid-state reaction. In contrast with the parent Mn2Sb2O7 compound that adopts a rhombohedral or monoclinic structure at T > 600 °C, the pyrochlore structure of CeMn3GaSb3O14 is retained up to at least T = 1070°C. High-resolution synchrotron x-ray diffraction measurements show no sign of a superstructure or distortion from cubic symmetry...
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Social perception of technological innovations at sports facilities: justification for financing ‘white elephants’ from public sources? The case of Euro 2012 Stadiums in Poland
PublikacjaThe main purpose of the paper is to provide a monetary valuation of social benefits in connection with the hypothetical implementation of technological innovations at four Euro 2012 stadiums in Poland. Not only the construction of the sport’s arenas, but also the ongoing maintenance drain the pockets of Polish taxpayers. At the same time Euro 2012 stadiums remain underused, which familiarize the host cities with the concept of ‘white...
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Functionalization of graphene oxide coatings with phosphorus atoms and their corrosion resistance in sodium chloride environment
PublikacjaIn this work, we compared corrosion resistance of graphene oxide, and phosphorus functionalized reduced graphene oxide coatings obtained as a result of electrophoretic deposition on the copper substrate. Doping graphene oxide with phosphorus atoms was performed by a hydrothermal method in the presence of different amounts of phosphoric acid. Structural studies confirmed the insertion of phosphorus atoms into the graphene oxide...
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Katalizatory wykorzystywane w syntezie biodiesla
PublikacjaRising prices of electricity, conventional fuels and heating require decisive steps in the further development of technologies based on renewable energy sources. These include geothermal-; hydrothermal-; aerothermal-; and solar energy. Due to the fact that the petrochemical industry is one of the fastest growing branches of the economy, we would like to expand on the topic related to biofuels. Biodiesel is an alternative fuel similar...
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The SARS‐CoV ‐2 specific IgG antibodies biophotonic sensor
PublikacjaIn this paper, we present the design and the principle of operation of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) specific immunoglobulin G (IgG) biophotonic sensor, which is based on the single-mode telecommunication fiber. We fabricated the sensor head at the face of the single mode fiber-28. Due to the process of bio-functionalization, our sensor has the ability to selectively detect the SARS-CoV-2 specific...
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Power efficient thrust allocation algorithms in design of dynamically positioned ships
PublikacjaAssessment of power consumption on a Dynamically Positioned (DP) ship in the early design stage can assist crucial design choices. The study presents a comparison between two algorithms of optimal thrust allocation in a propulsion system for an over-actuated DP ship. Applied algorithms were Quadratic Programming (QP) and Non- dominated Sorting Genetic Algorithm II (NSGAII). Based on both approaches, tools were developed for ship...
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Stirling engines - the state of technology development and computational models
PublikacjaStirling engines represent a technologically important solution in combined heat and power systems. Their use enables the achievement of over 90 percent efficiency in the management of the primary energy source with a very high durability of the device, mainly due to the lack of contact of the working gas with external factors and a very small number of mechanical components. The use of a Stirling engine may be equally important...
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Occurrence and Levels of Biogenic Amines in Beers Produced by Different Methods
PublikacjaThe concentration of biogenic amines (BAs) in beer depends, among other factors, on the activity of microorganisms, in particular lactic acid bacteria. In this work an analytical method based on derivatization with tosyl chloride and high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was used to determine 17 BAs in samples of commercially available beers, and to monitor the changes in concentration of...
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Does one currency mean one price?
PublikacjaEuropean Monetary Union was expected to have many consequences for the economies of participant countries. Theory suggested that through a higher volume of trade and stronger competition in the Eurozone, a single currency would lead to a reduction in price dispersion. As far as prices are concerned, two effects were expected: an immediate effect due to the technical characteristics of the changeover process, and a long-term one...
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Heteroleptic tri-tert-butoxysilanethiolate complexes of manganese(II) - thermal studies
PublikacjaThe thermal behavior of Mn(II) silanethiolate series [Mn(SR)2L(MeOH)n], where R=SSi(OBut)3, L=heterocyclic nitrogen base and n=0, 1 or 2 has been comparatively investigated using differential scanning calorimetry (DSC), thermogravimetry (TG) and TG-infrared spectoscopy (IR) techniques. The TG curves indicate the differences in the thermal decomposition due to presence of distinct N-donor ligands and labile MeOH molecules coordinated...
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Once in a season – the pragmatic function of fuck in “BoJack Horseman” TV Show
PublikacjaThis article investigates the use and pragmatic functions of the swear word fuck in the “BoJack Horseman” produced by Netflix and bridges the gap in the linguistic research on this particular TVshow. Incorporating corpus linguistics tools, the BoJack Horseman Corpus was compiled and thelemma fuck has been investigated and analysed from the multimodal perspective....
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Analogue GPS repeater
PublikacjaThis article concerns the problem of difficulty in correct indoor Global Positioning System (GPS) signals reception due to attenuation. Radio signal repeaters are proposed as means to solve this problem. Firstly, the GPS signal characteristics are described, emphasizing their low power in the point of reception. In the second part, various applications of GPS signal repeater, where indoor GPS signals reception is required, are...
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Grade of service determination methodology in IP networks with SIP protocol
PublikacjaAlthough Grade of Service is very important in VoIP providers evaluation, We wasn't able to find any paper regarding the topic of measuring GoS variables for IP networks utilizing SIP, which are defined like for PSTN/ISDN/GSM networks (post-selection delay, answering delay, release delay, or probability of end-to-end blocking). Due to the lack of research in this field, it was necessary to start from defining measures and cover...
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The efficiency of pollutants removal and concepts on improvement for single-family TWs
PublikacjaIn the rural areas building of sewerage systems and central wastewater treatment plants (WWTPs) often brings too high costs, due to high distances from one farm to another and terrain configuration. Individual treatment systems for each farm are a good solution. Theteratment wetlands for nine individual farms were constructed in Kaszubian Lake District in summer and autumn 2009. Three configurations of hydrophyte beds were chosen....
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Detection of some volatile degradation products released during photoexposition of ranitidine in a solid state
PublikacjaRanitidine (RAN) is on top of the list of prescribed drugs, due to its popularity as a selective H2-receptor antagonist, which efficiently decreases the amount of acid produced in the stomach. RAN is not stable both in a solid state and in a solution, which creates manufacturing problems, requires appropriate storage conditions, and results in a short drug shelf-life. The aim of this work was to study the emission of volatile...
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Programmed metalloporphyrins for self-assembly within light-harvesting stacks: 5,15-dicyano-10,20-bis(3,5-di-tert-butylphenyl)-porphyrinato zinc(II) and its push-pull 15-N,N-dialkylamino-5-cyano congeners obtained by a facile direct amination.
PublikacjaThe title dicyano compound was synthesized via cyanation and it self-assembles in nonpolar solvents giving red-shifted and broad absorption maxima just as the bacteriochlorophylls which are encountered in the light-harvesting organelles of early photosynthetic bacteria. In the crystal, stacks are formed through a hierarchic combination of π-stacking and a CNZn electrostatic interaction. Push−pull 15-N,N-dialkylamino-5-cyano congeners...
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Ultrasonic spectroscopy of silicon single crystal
PublikacjaSpecimens of Si single crystals with different crystal orientation [100] and [110] were studied by the electro-ultrasonic spectroscopy (EUS) and Resonant Ultrasonic Spectroscopy (RUS). A silicon single crystal is an anisotropic crystal, so its properties are different in different directions in the material relative to the crystal orientation. EUS is based on interaction of two signals: electric AC signal and ultrasonic signal,...
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The use of weight in motion data to heavy vehicles - pavement interaction analysis
PublikacjaWeight in motion (WIM) is the element of modern intelligent transport systems created to control commercial vehicles and to detect overloaded items. Because all of the vehicles crossing the WIM station are weighed and recognized, given data can be used to vehicle-pavement interaction analysis. The paper presents the results of analysis based on data from seven WIM stations localized in Motorway and National Roads in Poland. The...
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Innovative method for utilization of wastewater for security and safety in rural areas
PublikacjaIn the rural areas building of sewerage systems and central wastewater treatment plants (WWTPs) often brings too high costs, due to high distances from one farm to another and terrain configuration. Individual treatment systems for each farm are a good solution. The teratment wetlands for nine individual farms were constructed in Kaszubian Lake District in summer and autumn 2009. Three configurations of reed beds were chosen. In...
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Non-linear FEM analysis of pounding-involved response of buildings under non-uniform earthquake excitation
PublikacjaThe aim of the paper is to show the results of the study investigating the influence of non-uniform earthquake excitation, due to spatial seismic effects connected with the propagation of seismic wave, on the pounding-involved response of two buildings. The three-dimensional non-linear FEM analysis has been conducted using the detailed models of colliding structures. Acceleration records for different structural supports have been...
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Beta-Galactosidases of Pseudoalteromonas sp. – Characteristics and application for lactose hydrolysis and galactopyranosides synthesis
PublikacjaBeta-galactosidase [EC 3.2.1.23] is an enzyme that catalyzes the hydrolysis of O-glycosidic linkages in galactosides. It has biotechnological applications in the dairy industry for the production of milk with a low content of lactose and galactooligosacharides for use in healthy food. The transgalactosylation activity of beta-galactosidase can be used in the synthesis of alkyl galactopyranosides. Due to the fact that conditions of...
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On the necessity of experimental verification of numerical results in biomedical applications
PublikacjaPorous structures made of metal or biopolymers with a structure similar in shape and mechanical properties to human bone can be easily produced by stereolitography techniques, e.g. selective laser melting (SLM). Numerical techniques, like finite element method (FEM) have great potential in testing new, even the most sophisticated designs, according to their mechanical properties, i.e. strength or stiffness. However, due to different...
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Mathematical modelling of implant in an operated hernia for estimation of the repair persistence
PublikacjaThis paper presents mathematical modelling of an implanted surgical mesh used in the repair process of the abdominal hernia. The synthetic implant is simulated by a membrane structure. The author provides a material modelling of the implant based on the dense net model appropriate for technical fabrics. The accuracy of the proposed solution is evaluated by comparing the simulations of the dynamic behaviour of the system with the...
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Numerical analysis of a temporary steel grandstand
PublikacjaThe purpose of this paper is to present the results of the numerical analysis focused on the response of the temporary steel scaffolding grandstand subjected to human-induced vibrations due to jumping. Shell as well as beam elements have been used in the numerical model. Its first stage has involved conducting modal analysis in order to determine the modes of free vibrations and the corresponding natural frequencies for the empty...
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Cell-penetrating peptides – mechanism of transduction and synthesis – short review
PublikacjaPotential antimicrobial agents may be effective if they are delivered efficiently to their site of action. In many cases, lack of permeability through the cell membrane is the main problem. One of the possible solutions could be a novel intracellular delivery system involving cell-penetrating peptides (CPPs), which may improve the efficiency of many new biophar-maceuticals. Among other things, CPPs are capable of trans-porting...
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Response of a steel tank during earthquakes and mining tremors - experimental investigation
PublikacjaCylindrical steel tanks are very popular shell structures used to store the products of chemical and petroleum industries. Any failure might have disastrous consequences, therefore their safety and reliability is essential. Earthquakes are the most dangerous and also the most unpredictable dynamic loads acting on such structures. On the other hand, mining tremors are usually considered to be less severe due to lower acceleration...
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High temperature corrosion resistance of porous hastelloy alloy
PublikacjaTo further understand the suitability of Ni-Cr-base alloy for solid oxide fuel cell (SOFC), a commercial Ni-Cr-Fe-Mo alloy, Hastelloy X was selected and evaluated for oxidation behaviour under high temperature conditions. HastelloyX was chosen due to its unusual resistance to oxidizing, reducing and neutral atmospheres. For long term stability of metal supported fuel cell, the corrosion resistance plays a vital role and must be...
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Higher harmonics of the intensity modulated Photocurrent/Photovoltage spectroscopy response - a tool for studying photoelectrochemical nonlinearities
PublikacjaIn this work, a higher harmonic analysis (HHA) of the intensity modulated photocurrent/photovoltage (IMPS/IMVS) spectroscopy data is proposed as a potent tool for studying nonlinear phenomena in photoelectrochemical and photovoltaic systems. Analytical solutions of kinetic equations were constructed for cases of single and double resonance accounting for various sources of higher harmonics. These sources correspond to the physical...
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A method to synthesise groove cam Geneva mechanisms with increased dwell period
PublikacjaThe present study develops a method to synthesise the groove cam Geneva mechanism with increased dwell period. The main condition of the synthesis is to provide the desired law of motion of the wheel. Additional synthesis conditions are the limitation of the maximum pressure angle and the limitation of the minimum curvature radius of the cam profile. Unlike the conventional Geneva mechanisms, the synthesised groove cam Geneva mechanisms...
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Hybrid use of the building as a method supporting epidemic safety
PublikacjaThe COVID-19 pandemic has resulted in changing organisational and technical requirements in the operation of treatment facilities. This paper summarises the available knowledge on the principles of hybrid design of the architecture of treatment units to ensure that different levels of sanitary and hygienic safeguards can be implemented. The basis of this narrative overview is an analysis of the existing Polish legislation on required...
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MXene-based materials for removal of antibiotics and heavy metals from wastewater– a review
PublikacjaAs a novel family of 2D materials, MXenes provide an extensive variety of applications in water and effluent treatment due to their distinctive properties and attractive applicability, including superior electrical conductivity, higher thermal stability, hydrophilicity, and high sorption-reduction capacity. Their excellent sorption selectivity makes them perfect for removing hazardous contaminants. Currently, MXene-based materials...
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Fibrillar aggregates in powdered milk
PublikacjaThis research paper addresses the hypothesis that powdered milk may contain amyloid fibrils. Amyloids are fibrillar aggregates of proteins. Up to this time, research on the presence of amyloids in food products are scarce. To check the hypothesis we performed thioflavin T fluorescence assay, X-ray powder diffraction, atomic force microscopy and fluorescence microscopy imaging. Our preliminary results show that commercially available...
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Buckling Analysis of a Micro Composite Plate with Nano Coating Based on the Modified Couple Stress Theory
PublikacjaThe present study investigates the buckling of a thick sandwich plate under the biaxial non-uniform compression using the modified couple stress theory with various boundary conditions. For this purpose, the top and bottom faces are orthotropic graphene sheets and for the central core the isotropic soft materials are investigated. The simplified first order shear deformation theory (S-FSDT) is employed and the governing differential...
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Low-frequency noise in ZrS3 van der Waals semiconductor nanoribbons
PublikacjaWe report the results of the investigation of low-frequency electronic noise in ZrS3 van der Waals semiconductor nanoribbons. The test structures were of the back-gated field-effect-transistor type with a normally off n-channel and an on-to-off ratio of up to four orders of magnitude. The current–voltage transfer characteristics revealed significant hysteresis owing to the presence of deep levels. The noise in ZrS3 nanoribbons...
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Leveraging Generative AI Tools for UX Design in Lean and Agile Projects
PublikacjaRecent advancements in Generative AI (GenAI) open new opportunities to improve User Experience (UX) practitioners’ efficiency in their projects. Due to intensive teamwork caused by time pressure and readiness for rapid changes, Lean and Agile project management seems particularly predestined for easy adoption of GenAI-supported UX design methods. However, precipitate and spontaneous leveraging of GenAI tools to UX design bears...
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Experimental and numerical studies on the mechanical response of a piezoelectric nanocomposite-based functionally graded materials
PublikacjaThis work presents an experimental study of piezoelectric structures reinforced by graphene platelets, based on the concept of the functionally graded materials (FGMs). The assumed model is a rectangular beam/plate and the composition is due to the Halpin-Tsai rule. The model is also simulated in the Abaqus software which is the first time that such a structure has been modelled in an FEM package. In addition, a mathematical model...
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Dc Leakage Current in Isolated Grid-Connected dc Nanogrid - Origins and Elimination Methods
PublikacjaThe LV dc system is a relatively new trend in the distribution sector, which seems to grow widely in the near future due to its promising advantages. In this context, LV dc protection and grounding are challenging issues. Although the galvanically isolated connection mode of dc nanogrid to the ac grid has high reliability, the leakage current can still be injected into the ac grid through the interwinding capacitors and the insulation...
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Accurate Post-processing of Spatially-Separated Antenna Measurements Realized in Non-Anechoic Environments
PublikacjaAntenna far-field performance is normally evaluated in expensive laboratories that maintain strict control over the propagation environment. Alternatively, the responses can be measured in non-anechoic conditions and then refined to extract the information on the structure field-related behavior. Here, a framework for correction of antenna measurements performed in non-anechoic test site has been proposed. The method involves automatic...
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Management of low-temperature heat source by ORC aided by additional heat source
PublikacjaIn the paper presented is a concept to utilize waste heat from the power plant with the aid of the low-temperature ORC cycle. The ORC system is heated from two heat sources, the first one being the flow rate of waste heat obtained from the exhaust gases. Subsequently, the working fluid in the cycle is additionally heated by the condensing steam from the low pressure turbine extraction points increasing in such way the level of...
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Operational algae bloom detection in the Baltic Sea using GIS and AVHRR data
PublikacjaDuring the blooming season, algal colonies can, in extreme cases, cover up to 200 000 square kilometres of the Baltic Sea water surface. Because the position and shape of the blooms may significantly change in very short time due to the influence of wind and waves, regular monitoring of the blooms' development is necessary. Currently, the desired monitoring frequency may only be achieved by means of remote sensing. The article...
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Insights Into Hydrodynamics of Spinning Fluids Reactor
PublikacjaSpinning fluids reactor (SFR) is one of the most efficient gas-liquid contacting system with high potential of application in many fields. The unique solution of SFR is the contacting of two spinning fluids which generated centrifugal force. The aim of this study was to investigate the pressure field distribution on the inner surface of reactors dispersing element. Obtained results confirm the high heterogeneity of the field pressure...
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Adaptive Management Approach to an Infrastructure Project
PublikacjaThe paper presents an adaptive approach to project management, illustrated by the description of a case study, i.e., of a project whose aim was to develop the means and prepare the documentation for the revitalization of a railway line. The project itself was a major challenge for the implementers due to a novel and innovative subject thereof, including the construction of a railway line which takes place in a difficult terrain...
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Effect of culinary treatment on chnages in the contents of selected nutrients and non-nutrients in curly kale (Brassica oleracea var. acephala)
PublikacjaKale has a great nutritive value, very high antioxidant activity and pro-healthypotential. The level of phytochemicals and related bioactive compounds arestrongly dependent on pre and postharvest stages of production chain (domestic orindustrial). The study investigated changes in the levels of vitamin C, b-carotene,total polyphenols, antioxidant activity, degradation products of glucosinolates aswell as nitrates and nitrites in...
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Underwater Acoustic Communications in Time-Varying Dispersive Channels
PublikacjaUnderwater acoustic communication (UAC) system designers tend to transmit as much information as possible, per unit of time, at as low as possible error rate. However, the bit rate achieved in UAC systems is much lower than for wire or radio-communication systems. This is due to disadvantageous properties of the UAC channels, namely the sea and inland waters. Estimation of UAC channel transmission properties is possible within...