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Wyniki wyszukiwania dla: mixtures toxicity modelling
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Determination of API content in a pilot-scale blending by near-infrared spectroscopy as a first step method to process line implementation
PublikacjaNear infrared (NIR) spectroscopy was used for estimation of powder blend homogeneity and manufacturing control of a medicinal product powder mixture containing active pharmaceutical ingredient (API). Aiming at initiating a Process Analytical Technology (PAT) activity, the first step was a stationary mode atline evaluation. In this, the content of pharmaceutical active compound in the powder mixtures intended to the direct tabletting...
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Oil removal from polluted soil by washing with surfactants solutions in dynamic conditions
PublikacjaFor washing of the oil from polluted soil surfactants solutions were applied. In a research a nonionic synthetic surfactant - polyoxyethylene ether of synthetic fatty alcohol (Rokanol NL6), rhamnolipid biosurfactant JBR 425 (Jeneil Biosurfactant Co. LLC) and their mixtures were used. Results of oil removal from peat soil and sand with mixtures of surfactants solutions at concentration 0,5 g/dm...
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Determination of metals in water samples by atomic absorption spectrometry and flame emission spectrometry
PublikacjaMetal species in environmental waters are relevant to characterize the metal toxicity, the mobility between different environmental compartments, and for remediation purposes in case of contamination. The concentration of many trace metals in natural water samples are generally at µg/l level. The paper describes determination of metals in water samples based on flame atomic emission and flame atomic absorption spectrometry.
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The optimisation of analytical parameters for routine profiling of antioxidants in complex mixture by HPLC coupled post-column derivatisation
PublikacjaIntroduction: The wide application of natural and artificial antioxidants in food, cosmetic and pharmaceutical industry as well as the recognition of the importance of food antioxidants for supporting human health created demand for reliable and industrially applicable methods of determining antioxidative activity. This requirement can be fullfilled with the recently proposed HPLC-post-column derivatisation approach enabling the...
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The potential interaction of environmental pollutants and circadian rhythm regulations that may cause leukemia
PublikacjaTumor suppressor genes are highly affected during the development of leukemia, including circadian clock genes. Circadian rhythms constitute an evolutionary molecular machinery involving many genes, such as BMAL1, CLOCK, CRY1, CRY2, PER1, PER2, REV-ERBa, and RORA, for tracking time and optimizing daily life during day-night cycles and seasonal changes. For circulating blood cells many of these genes coordinate their proliferation,...
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A Review of Hyperelastic Constitutive Models for Dielectric Elastomers
PublikacjaDielectric elastomers are smart materials that are essential components in soft systems and structures. The core element of a dielectric elastomer is soft matter, which is mainly rubber-like and elastomeric. These soft materials show a nonlinear behaviour and have a nonlinear strain-stress curve. The best candidates for modelling the nonlinear behaviour of such materials are hyperelastic strain energy functions. Hyperelastic functions...
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Modelowanie podziału zadań przewozowych w obszarach zurbanizowanych
PublikacjaNiniejsza rozprawa doktorska dotyczy problematyki modelowania podziału zadań przewozowych w procesie modelowania podróży. Wykonane analizy wykazały zasadność zastosowania dodatkowych czynników w modelowaniu wyboru środka transportu z uwagi na ich istotny wpływ na jakość modelu dla wybranych motywacji podróży. W pracy zawarto przykładowe modele uwzględniające każdy z analizowanych czynników. Z wykorzystaniem badań heurystycznych...
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How green are ionic liquids? – A multicriteria decision analysis approach
PublikacjaDue to various desirable physicochemical properties, ionic liquids (ILs) are still gaining in popularity. ILs have been recurrently considered green solvents. However, environmental, health and safety assessments of ILs have raised certain doubts about their benignness, and their greenness status is currently unclear. To clarify the situation on their greenness, we perform a comprehensive assessment of more than 300 commercially...
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Synthesis and Cholinesterase Inhibitory Activity of N-Phosphorylated /N-Tiophosphorylated Tacrine
PublikacjaNovel phosphorus and thiophosphorus tacrine derivatives were designed, synthesized and their biological activity and molecular modeling was investigated as a new potential anti-Alzheimer's disease (AD) agents. All new synthesized compound exhibited lower toxicity against neuroblastoma cell line (SH-SY5Y) in comparison with tacrine. Two analogues in the series, 7 and 9, demonstrated lack of cytotoxicity against hepatocellular cells...
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The impact of the shape of deep drilled well screen openings on the filtration process in full saturation conditions
PublikacjaThe authors propose a supplementary method of modelling seepage flow around the deep drilled well screen. The study applies 3D numerical modelling (FEM) in order to provide an in-depth analysis of the seepage process. The analysis of filtration parameters (flow distribution q(x,t) and pressure distribution p) was conducted using the ZSoil.PC software system. The analysis indicates that the shape of perforation is of secondary importance...
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Reduced order model of 2d system
PublikacjaA new method of modelling is developed for static and dynamic analysis of two-dimensional elastic bodies. In the analysis, an elastic body is divided into strips. For each one-dimensional strip the reduced modal model is build up. The modal model contains appropriate number of inputs and outputs to connect lumped interaction that occur between strips. Proposed method of modelling enables to obtain more accurate and more simple...
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Applications of permeability, oedometer and direct shear tests to the sand mixed with waste tire crumb
PublikacjaThe amount of the used waste rubbers in the world has been increasing every year, and their utilization, become a major environmental problem worldwide. The present experimental work has been performed to investigate the influence of rubber inclusion on the behavior of a sand. Geotechnical properties of the sand, and sand with tire crumb at various ratios mixtures (0%, 2.5%, 7.5%, and 15%) were investigated through a series of...
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Spectroscopic Study of Plasma Polymerized a-C:H Films Deposited by a Dielectric Barrier Discharge
PublikacjaPlasma polymerized a-C:H thin films have been deposited on Si (100) and aluminum coated glass substrates by a dielectric barrier discharge (DBD) operated at medium pressure using C2Hm/Ar (m = 2, 4, 6) gas mixtures. The deposited films were characterized by Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS), Raman spectroscopy, and ellipsometry. FT-IRRAS revealed the presence of sp3 and sp2 C–H stretching and...
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Design of poroelastic wearing course with the use of direct shear test
PublikacjaPoroelastic Road Surfaces (PERS) are characterized by porous structure with at least 20% of air void content and stiffness almost 10 times lower than typical asphalt course. Such properties enable noise reduction up to 12 dB in comparison to SMA 11 mixture. However, the main disadvantage of previously used poroelastic mixtures, based on resin type binders, was their low durability, which resulted in raveling and delamination from...
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Simulation of the switched reluctance drive system
PublikacjaSwitched reluctance motors (SRM), unlike other types of motors, for their application require a control system and the supply from a power electronic converter. A method of modelling and mathematical model of an SRM in a switched reluctance drive (SRD) system is presented in the paper. Modelling is based on Lagrange's energy method. Coefficients of the Lagrange's equation have been calculated using the finite element method (FEM)....
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Research into the Movements of Surface Water Masses in the Basins Adjacent to the Port
PublikacjaThis paper presents the results of the practical and simulation research into determining the routes of movement of small objects moving together with surface water masses in basins adjacent to the port. The results of this research were referenced against the modelling of routes of small objects in port channel basins. The results of practical research concerning the movement of small objects in basins adjacent to the port were...
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An enhanced method in predicting tensile behaviour of corroded thick steel plate specimens by using random field approach
PublikacjaThe present work investigates the possibility of using random field techniques in modelling the mechanical behaviour of corroded thick steel plate specimens. The nonlinear Finite Element method, employing the explicit dynamic solver, is used to analyse the mechanical properties of typical specimens. A material model considering full nonlinearity is used to evaluate the stress-strain response. The influence of major governing parameters...
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Polynomial Chaos Expansion in Bio-and Structural Mechanics
PublikacjaThis monograph presents a probabilistic approach to modelling the mechanics of materials and structures where the modelled performance is influenced by uncertainty in the input parameters. The work is interdisciplinary and the methods described are applied to medical and civil engineering problems. The motivation for this work was the necessity of mechanics-based approaches in the modelling and simulation of implants used in the...
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Polynomial Chaos Expansion in Bio- and Structural Mechanics
PublikacjaThis thesis presents a probabilistic approach to modelling the mechanics of materials and structures where the modelled performance is influenced by uncertainty in the input parameters. The work is interdisciplinary and the methods described are applied to medical and civil engineering problems. The motivation for this work was the necessity of mechanics-based approaches in the modelling and simulation of implants used in the repair...
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Biocompatibility and potential functionality of lanthanum-substituted cobalt ferrite spinels
PublikacjaBulk and nanostructurized lanthanum-cobalt spinels have attracted a lot of interest from researchers, due to their unique physical and chemical properties as well as functionalities, which are interesting for biomedical and electronic industries. In this manuscript we show that introducing small lanthanum (La3+) content can tune magnetic, electronic and cytotoxic properties of the CoFe2− xLaxO4 system (x ≤ 0.1). The mechanisms...
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Review and evaluation of cold recycling with bitumen emulsion and cement for rehabilitation of old pavements
PublikacjaThe article presents Polish experience with cold recycling of asphalt pavements with theusage of bituminous emulsion and cement. In the 1990s numerous roads in Polandrequired immediate reinforcement due to their significant degradation. Implementation ofthe cold recycling technology was one of the solutions to this problem. Cold recycledmixtures containebeside the recycled asphalt pavement and aggregateetwo differenttypes of binding...
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Low-cost Adsorbents Derived from Agricultural By-products/Wastes for Enhancing Contaminant Uptakes from Wastewater: A Review
PublikacjaA major threat to the comfort of human life has been imposed by increased industrialization and urbanization. The generation and disposal of huge amounts of toxic materials and pollutants have heavily contaminated our environment. Some Organics such as synthetic dyes (SD) and heavy metals (HM) are becoming increasingly prevalent as the most dangerous pollutants in soil and surface water environments. They are...
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Składowiska odpadów komunalnych jako źródła emisji zanieczyszczeń do środowiska
PublikacjaCelem pracy było przeprowadzenie badań mających na celu określenie związków uwalnianych do powietrza ze składowisk odpadów komunalnych oraz charakterystyka ich właściwości zapachowych i toksycznych. Próbki powietrza analizowano za pomocą techniki TD-GC-MS. Przeprowadzone badania pozwoliły na zidentyfikowanie następujących związków: styren, benzen, ksylen, toluen, etylobenzen, disiarczek dimetylu, dekan, kwas butanowy i octowy....
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Novel Fault Identification for Electromechanical Systems via Spectral Technique and Electrical Data Processing
PublikacjaIt is proposed, developed, investigated, and validated by experiments and modelling for the first time in worldwide terms new data processing technologies, higher order spectral multiple correlation technologies for fault identification for electromechanical systems via electrical data processing. Investigation of the higher order spectral triple correlation technology via modelling has shown that the proposed data processing technology...
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On the influence of the acceleration recording time on the calculation of impact severity indexes
PublikacjaThe paper concerns with the analysis of normative requirements pertaining to experimental setup of a crash test and its numerical modelling. An overview of parameters describing the collision of a vehicle with a road restraining system is presented. A short description of a concrete road safety barrier is presented. A brief description of numerical modelling procedures for crash tests is given as well. The parametric influence...
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On Applications of Fractional Derivatives in Circuit Theory
PublikacjaIn this paper, concepts of fractional-order (FO) derivatives are discussed from the point of view of applications in the circuit theory. The properties of FO derivatives required for the circuit-level modelling are formulated. Potential problems related to the generalization of transmission line equations with the use of FO derivatives are presented. It is demonstrated that some of formulations of the FO derivatives have limited...
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Konzetrationslöschung durch Energieübertragung bei der Lumineszenz von Lösungen
PublikacjaThe absorption spectra and quantum yields of the fluorescence of rhodamine 6 G are investigated in two different water-glycerol mixtures as a function of the rhodamine concentration. The observed concentration quenching is attributed to the formation of rhodamine dimers and the decrease in quantum yield is compared with theoretical concepts about concentration quenching by energy transfer to the dimers.
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Usuwanie lotnych związków organicznych z fazy gazowej z zastosowaniem cieczy jonowych
PublikacjaUżycie cieczy jonowej do usuwania LZO jest limitowane przez rozpuszczalność usuwanych związków. Dane literaturowe sugerują, że ciecze jonowe jako faza membranowa mogą być z powodzeniem stosowane do selektywnej separacji węglowodorów aromatycznych z mieszanin węglowodorów aromatycznych i alifatycznych. Przedmiotem pracy było kompleksowe opisanie procesu separacji LZO z fazy gazowej z uwzględnieniem czynników wpływających na efektywność...
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Development of models for nitrogen-removal processes in subsurface flow constructed wetlands
PublikacjaThis paper summarizes recent progress in modelling approach of subsurface flow constructed wetlands (SSF CWs), focusing on nitrogen removal processes.
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A PAIR OF PERFECTLY CONDUCTING DISKS IN AN EXTERNAL FIELD
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A fast algorithm for computing the flux around non-overlapping disks on the plane
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Protection System Design of Induction Motor for Industries
PublikacjaThe fundamental and durable structures of induction motor, as well as their low manufacturing cost, make them popular components in a wide range of current applications. Providing a safety net for employees is a must-have for businesses. This project’s motivation for improvement is to provide industrial motors, lift motors, pumps, and so on with safety. An induction motor’s primary goal is to protect it from problems, such as...
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Study of free convective boundary layer of isothermal lateral surface of axisymmetrical horizontal body
PublikacjaPrzedstawiono rozwiązanie równań Naviera-Stokesa i Fouriera-Kirchhoffa we współrzędnych tau i sigma. Pierwsza jest styczną a druga normalną do konwekcyjnych linii prądu, wzdłuż jakich porusza się ogrzany od powierzchni płyn. Wynik w postaci równania na grubość warstwy przyściennej zweryfikowano dla granicznych przypadków ciała obrotowego o poziomej osi symetrii (stożka poziomego i kołowej pionowej płyty).
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Thermal self-action effects of acoustic beam in a vibrationally relaxing gas
PublikacjaThermal self-action of acoustic beam in a molecular gas with excited internal degrees of molecules’ freedom, is studied. This kind of thermal self-action differs from that in a Newtonian fluid. Heating or cooling of a medium takes place due to transfer of internal vibrational energy. Equilibrium and non-equilibrium gases, which may be acoustically active, are considered. A beam in an acoustically active gas is self-focusing unlike...
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Expedited constrained multi-objective aerodynamic shape optimization by means of physics-based surrogates
PublikacjaIn the paper, computationally efficient constrained multi-objective design optimization of transonic airfoil profiles is considered. Our methodology focuses on fixed-lift design aimed at finding the best possible trade-offs between the two objectives: minimization of the drag coefficient and maximization of the pitching moment. The algorithm presented here exploits the surrogate-based optimization principle, variable-fidelity computational...
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Torsional buckling and post-buckling of columns made of aluminium alloy
PublikacjaThe paper concerns torsional buckling and the initial post-buckling of axially compressed thin-walled aluminium alloy columns with bisymmetrical cross-section. It is assumed that the column material behaviour is described by the Ramberg–Osgood constitutive equation in non-linear elastic range. The stationary total energy principle is used to derive the governing non-linear differential equation. An approximate solution of the equation...
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Nuclear Power Plant Steam Turbine - Modeling for Model Based Control Purposes
PublikacjaThe nature of the processes taking place in a nuclear power plant (NPP) steam turbine is the reason why their modeling is very difficult, especially when the model is intended to be used for on-line optimal model based process control over a wide range of operating conditions, caused by changing electrical power demand e.g. when combined heat and power mode of work is utilized. The paper presents three nonlinear models of NPP steam...
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On the theory and numerical simulation of acoustic and heat modes interaction in a liquid with bubbles: acoustic quasi-solitons
PublikacjaTeoria rzutowania zaburzenia ogólnego na mody. Zastosowanie metody do badań układu równań typu Korteweg`a-de Vries`a. Rozwiązania analityczne i simulacje numeryczne.
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Extensions of Quasilinearization Method for Differential Equations with Integral Boundary Conditions
PublikacjaPraca dotyczy równań różniczkowych z warunkami brzegowymi typu całkowego. Podano warunki dostateczne na istnienie jedynego rozwiązania takiego zagadnienia i pokazano, że odpowiednio konstruowane ciągi monotoniczne są zbieżne do tego rozwiązania i jest to zbieżność kwadratowa. Te monotoniczne ciągi są przybliżonymi rozwiązaniami problemu wyjściowego i obustronnie szacują szukane rozwiązanie.
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Solving Boundary Value Problems for Second Order Singularly Perturbed Delay Differential Equations by ε-Approximate Fixed-Point Method
PublikacjaIn this paper, the boundary value problem for second order singularly perturbed delay differential equation is reduced to a fixed-point problem v = Av with a properly chosen (generally nonlinear) operator A. The unknown fixed-point v is approximated by cubic spline vh defined by its values vi = vh(ti) at grid points ti, i = 0, 1, ... ,N. The necessary for construction the cubic spline and missing the first derivatives at the boundary...
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Problem of proper decomposition and initialization of acoustic and entropy modes in a gas affected by the mass force
PublikacjaThe relations connecting perturbations specific for acoustic and entropy modes in an accelerated fluid or in a fluid affected by constant mass force, are derived. They allow to decompose the total vector of perturbations and the overall energy into acoustic and non-acoustic parts uniquely at any instant. In order to do this, three quantities are required, for example total perturbations in entropy, pressure and velocity. The evaluations...
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Modeling the impact of discretizing rotor angular position on computation of field-oriented current components in high speed electric drives
PublikacjaModern drives consist of alternating current electric motors, and the field-oriented control (FOC) of such motors enables fast, precise, and robust regulation of a drive's mechanical variables such as torque, speed, and position. The control algorithm, implemented in a microprocessor, requires feedback from motor currents, and the quality of this feedback is essential to a drive's control properties. Motor phase currents are sampled...
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Analysis of Interspike-Intervals for the General Class of Integrate-and-Fire Models with Periodic Drive
PublikacjaWe study one-dimensional integrate-and-fire models of the general type x˙=F (t, x) and analyze properties of the firing map which iterations recover consecutive spike timings. We impose very week constraints for the regularity of the function F (t, x), e.g. often it suffices to assume that F is continuous. If additionally F is periodic in t, using mathematical study of the displacement sequence of an orientation preserving circle...
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Electro-mechanical shear buckling of piezoelectric nanoplate using modified couple stress theory based on simplified first order shear deformation theory
PublikacjaThis paper studies the electro-mechanical shear buckling analysis of piezoelectric nanoplate using modified couple stress theory with various boundary conditions.In order to be taken electric effects into account, an external electric voltage is applied on the piezoelectric nanoplate. The simplified first order shear deformation theory (S-FSDT) has been employed and the governing differential equations have been obtained using...
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Dynamic analysis of lightweight structure of the Viaduct Millau in France subjected to the wind fluctuations described by Karman’s and Davenport’s spectrum
PublikacjaThe article presents numerical simulations for wind impact modelling on the Millau Viaduct structure in France performed with two independent spectrum generation methods. The viaduct's construction in affected by strong forces, as it is situated in the Tarn river's valley. Thus, the loading coming from the wind cannot be modelled, the way it is in case of simple structures as static loading, but as a loading in a form of a spectrum...
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NATURAL DEEP EUTECTIC SOLVENTS IN EXTRACTION PROCESS
PublikacjaDeveloping new, eco-friendly solvents which would meet technological and economic demands is perhaps the most popular aspects of Green Chemistry. Natural deep eutectic solvents (NADES) fully meet green chemistry principles. These solvents offer many advantages including biodegradability, low toxicity, sustainability, low costs and simple preparation. This paper provides an overview of knowledge regarding NADES with special emphasis...
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Damaged plasticity model - seismic analysis of structure of the Petronas Twin Towers (Kuala Lumpur) in Malaysia
PublikacjaThe article presents numerical simulations for the modelling of seismic impact on the structure of Petronas Twin Towers (Kuala Lumpur) in Malaysia with application of two methods. The Response Spectrum method, in which a spectrum of the structure's responses to an earthquake's impact is generated and the Acceletogram (BETA) method, in which we generate dynamic load in the form of a diagram of the connection between acceleration...
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Laboratory Determination of Burger's Model Parameters for Visco-elastic Analysis of Road Pavement Materials
PublikacjaBurger's Model is one of those models that describes performance of asphalt mixtures. Its parameters can be used in road construction analysis based on visco-elastic properties in wide variety of temperatures using dedicated programs (e.g. Veroad) or in Finite Element Method (FEM). Parameters of Burger's Model can be used for example in prediction of low temperature cracking in low winter temperatures or permanent deformation...
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Evaluation of Mechanical Properties of Two-Stage Concrete and Conventional Concrete Using Nondestructive Tests
PublikacjaDifferent types of concrete mixtures are used as building materials. The manufacturing process of two-stage concrete (TSC) differs from that of conventional concrete. This study investigated conventional mechanical properties derive empirical relations for estimation of the mechanical parameters of TSC and conventional concrete mixtures. TSC was used to prepare 216 specimens and conventional concrete was used to prepare 108 specimens...
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Variable Order Differential Models of Bone Remodelling * *This work was supported by FCT, through IDMEC, under LAETA, projects UID/EMS/50022/2013, BoneSys, joint Polish-Portuguese project Modelling and controlling cancer evolution using fractional calculus, PERSEIDS (PTDC/EMS-SIS/0642/2014) and IF/00653/2012
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