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Wyniki wyszukiwania dla: free volume
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Mathematical modelling: Lessons from composite indicators
PublikacjaWe discuss here composite indicators as mathematical models, which can be looked at through the lenses of the five rules discussed in this volume. Composite indicators sit between analysis and advocacy, and their use has social and political implications. For this reason, the lenses of the manifesto can be used to build them better, to make them more transparent, as well as to inspect incumbent indicators for methodological or...
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Pollutant deposition via dew in urban and rural environment, Cracow, Poland
PublikacjaThis study is a comparative analysis of dew in rural and urban environment. Dew samples were collected between May and October, 2009 in two reference stations in southern Poland: Cracow and Gaik-Brzezowa. The investigation included comparison of volume and chemistry of the collected samples. Due to its formation mechanisms, dew is a good indicator of air pollution. Following parameters were analyzed in 159 collected samples: pH,...
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Morphology changes in Fe-Cr porous alloys upon high-temperature oxidation quantified by X-ray tomographic microscopy
PublikacjaThe effect of high-temperature oxidation at 850 C (10 h, 30 h, 100 h) and 900 C (10 h) on porous (30 % porosity) ferritic stainless steel (Fe22Cr) has been investigated using synchrotron tomographic microscopy, which allowed for visualisation, separation and quantitative analysis of the metallic core, closed pores, open pores and oxide scale phase. The same regions within the samples were investigated before and after oxidation...
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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
PublikacjaDensities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate...
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Application of multivariate statistics in assessment of green analytical chemistry parameters of analytical methodologies
PublikacjaThe study offers a multivariate statistical analysis of a dataset, including the major metrological, “greenness” and methodological parameters of 43 analytical methodologies applied for aldrin determination (a frequently analyzed organic compound) in water samples. The variables (parameters) chosen were as follows: metrological (LOD, recovery, RSD), describing the “greenness” (amount of the solvent used, amount of waste generated)...
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Novel methods for diagnosis of pulmonary microangiopathy in diabetes mellitus
PublikacjaLung microangiopathy is a little known negative influence of diabetes mellitus on the functioning of the lungs. In current medical practice lung microangiopathy is diagnosed by comparing two measurements of lung diffusing capacity - one with the subject standing and one with the subject lying. The necessity to take two measurements is inconvenient. In lung microangiopathy we observe a reduction of diffusing capacity, lung flow...
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New procedure for the control of the treatment of industrial effluents to remove volatile organosulfur compounds
PublikacjaWe present a new procedure for the determination of volatile organosulfur compounds in samples of industrial effluents using dispersive liquid–liquid microextraction and gas chromatography with flame photometric detection. Initially, the extraction parameters were optimized. These included: type and volume of extraction solvent, volume of disperser solvent, salting out effect, pH, time and speed of centrifugation as well as extraction...
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Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples
PublikacjaThis manuscript presents a new method for selective extraction and determination of fosetyl-aluminum in fruits and vegetable samples based on ultrasonic-assisted dispersive liquid-liquid microextraction method using ionic liquids (IL-UA-DLLME). A UV-Visible spectrophotometer was used for detection and quantification. Plants used for sample collection were grown under controlled conditions in a greenhouse. Central composite design...
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Distributed representation of information on cyclic events
PublikacjaA representation of information on cyclic events has been proposed which is advantageous for computing environments where a distributed set of Receivers reacts to cyclic events generated by distributed sources. In such scenario no immanent central information repository exist on event timing or volume. Receivers are able to learn the event cycles without communicating with each other, merely on the basis of the fact that an event...
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Performance of the flat plate solar collector operated with water-Al2O3 nanofluid
PublikacjaThis paper shows the experimental results of the performance a flat plate solar collector with water-Al2O3 nanofluid as a working fluid. The weight fractions of nanoparticles were 0.1%, 0.2% and 0.4%. The volume flow rate of nanofluid varied from 60 l/h to 170 l/h. The results show that application of nanofluids instead of pure water resulted in higher efficiency of the tested flat plate solar collector for given range of thermal...
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Automatic Analysis System of TV Commercial Emission Level
PublikacjaThe purpose of the study was to determine whether the commercial emission level is higher than the emission level of a regular program and to check if the commercials broadcasters follow the recommended levels of loudness. The paper shortly reviews some chosen methods of volume measurements specified in the ITU and EBU recommendations. Then, it describes a prototype of a system implemented in Embarcadero C++ Builder 2010 which...
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New Design of Axial Piston Pump with Displaced Swash Plate Axis of Rotation for Hydro-Mechanical Transmissions
PublikacjaThis paper presents a prototype design of an axial piston pump with displaced swash plate axis of rotation in two directions of discharge with electronic control intended for installation on a hydraulic-mechanical gearbox dedicated to working machines. The effect of displacement of the swash plate rotation axis on dead space volume and volumetric efficiency is presented. The construction and principle of operation of the capacity...
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Multianalyte Calibration Methods for Potentiometric Integrated Sensors System for Determination of Ions Concentration in a Body Fluids
PublikacjaIn recent years, integration and miniaturization of ion-selective electrodes (ISEs) have brought many benefits resulting in the possibility of simultaneous determination of the ions concentration in a small sample volume. One of the key problems related to the preparation of integrated sensors systems (ISSs) is a calibration procedure due to the necessity to calibrate each particular sensor separately. The main aim of the research...
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Modeling Volunteer Based Systems
PublikacjaThere are two main approaches to processing tasks requiring high amounts of computational power. One approach is using clusters of mostly identical hardware, placed in dedicated locations [1, 2, 3]. The other approach is outsourcing computing resources from large numbers of volunteers connected to the Internet [7]. This chapter presents an application of a mathematical model of the volunteer computing presented in Volume 1 of this...
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Dew Formation and Chemistry Near a Motorway in Poland
PublikacjaIn this study, the influence of traffic intensity on dewformation efficiency and chemistry is presented. The measurementswere conducted near the A4 motorway in SW Poland in almost flatland relief with intense agricultural activity. The dew/hoarfrost wascollected by means of insulated plain passive radiative condensersat three sites: AN and AS located in the close vicinity of themotorway (30 m) on the opposite sides of the road,...
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An optimal designed experiment for the alkaline hydrolysis of feather keratin
PublikacjaFeathers, burdensome waste from the poultry industry, can be a cheap source of keratin, a protein with excellent physico- chemical, biological, and mechanical properties. Acid and alkaline hydrolyses are usually adopted for isolation of keratin from its natural resources. This study aimed at assessing the statistically significant effect of input variables in the alkaline hydrolysis of keratin from chicken feathers on the process...
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Role of quantitative chest perfusion computed tomography in detecting diabetic pulmonary microangiopathy
PublikacjaAims: Aimof the study was to determine the role of perfusion chest computed tomography(pCT) in evaluation of pulmonary diabetic angiopathy.Methods: 18 never-smoking patients (10 diabetic patients and 8 healthy controls) underwentchest high resolution CT (HRCT) and then pCT scanning. In both groups, blood tests,biochemical analysis, fibrinogen, HbA1c, spirometry, diffusion capacity for carbonmonoxide(DLCO) and body pletysmography...
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Solvation of ionic liquids based on N-methyl-N-alkyl morpholinium cations in dimethylsulfoxide – volumetric and compressibility studies
PublikacjaThe density and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octyl-morpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in dimethylsulfoxide were measured at T = (298.15 to 318.15)...
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Optimization of vortex-assisted hydrophobic magnetic deep eutectic solvent-based dispersive liquid phase microextraction for quantification of niclosamide in real samples
PublikacjaIn this manuscript, a green and fast vortex-assisted hydrophobic magnetic deep eutectic solvent-based dispersive liquid phase microextraction (VA-HMDES-DLPME) method was developed for the selective extraction and determination of niclosamide in read samples, including rice, medicine tablets, and water samples. Here, hydrophobic magnetic deep eutectic solvents were used as the extracting solvent without requiring any centrifugation...
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Evaluation of the Macro- and Micro-Economic Factors Affecting the Financial Energy of Households
PublikacjaThis paper is an evaluation of the common macro-economic, micro-economic, and social factors affecting households’ financial situations. Moreover, the author’s objective was to develop a fuzzy logic model for forecasting fluctuations in the number of nonperforming consumer loans in a country using the example of Poland. This study represents one of the first attempts in the global literature to develop such a forecasting model...
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On Dynamic Boundary Conditions Within the Linear Steigmann-Ogden Model of Surface Elasticity and Strain Gradient Elasticity
PublikacjaWithin the strain gradient elasticity we discuss the dynamic boundary conditions taking into account surface stresses described by the Steigmann–Ogden model. The variational approach is applied with the use of the least action functional. The functional is represented as a sum of surface and volume integrals. The surface strain and kinetic energy densities are introduced. The Toupin–Mindlin formulation of the strain gradient elasticity...
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Digitalization Process and Its Impact on Economic Growth A Panel Data Study for Developing Countries
PublikacjaThis book analyses the impact of Information and Communication Technologies (ICTs) on economic development. It contains theoretical and empirical studies, including panel studies on various issues facing developing countries, such as education, corruption, economic growth, government expenditure, financial inclusion, foreign direct investment, infrastructure, economic and social welfare, and inequality. Each chapter offers a well-conceived...
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Young’s modulus distribution in the FEM models of bone tissue
PublikacjaThis paper presents how differences of Young’s modulus in adjacent finite elements typical for organic materials such as bone tissue, influence stress calculating. Emphasizing high computational cost of variable Young’s modulus in parts of the model, where the number of finite elements has been raised, the authors wants to prove that new model of finite element which has variable Young’s modulus in its volume needs to be created....
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VOF-DEM-FEM combined model of the reef breakwater collapse
PublikacjaZespolony model numeryczny (metoda modelowania przepływu ze swobodną powierzchnią rozdziału faz ciekłej i gazowej w siatce nieruchomej (ang. Volume of Fluid - VOF, metoda elementów dyskretnych (ang. Distinct Element Method, metoda elementów skończonych (MES)) został wykorzystany do zbadania odkształceń falochronu narzutowego i jego piaszczystego podłoża w wyniku oddziaływania falowania powierzchniowego. Wyniki analizy numerycznej...
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Speech Intelligibility Measurements in Auditorium
PublikacjaSpeech intelligibility was measured in Auditorium Novum on Technical University of Gdansk (seating capacity 408, volume 3300 m3). Articulation tests were conducted; STI and Early Decay Time EDT coefficients were measured. Negative noise contribution to speech intelligibility was taken into account. Subjective measurements and objective tests reveal high speech intelligibility at most seats in auditorium. Correlation was found between...
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Classifying the transformation products (TPs) of emerging contaminants (ECs) for prioritizing research into their impact on the environment and human health
PublikacjaOne of the first books to cover transformation products, rather than primary compounds, Transformation Products of Emerging Contaminants in the Environment gathers, specifies, synthesizes, and advances existing knowledge of the most important transformation product (TPs) of the main groups of emerging contaminants with potential concern to human health and the environment. This two-volume set for researchers and professionals covers...
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Clinical anatomy of the spatial structure of the right ventricular outflow trac
PublikacjaBackground. The right ventricular outflow tract (RVOT) is located above the supraventricular crest and reaches the level of the pulmonary valve. Detailed knowledge of the RVOT spatial structure and its morphology is extremely important for cardiac invasive therapeutic procedures. Objectives. To examine the spatial structure of the RVOT using virtual models of the right ventricle (RV) interior obtained post mortem. Material and...
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Engineering TADF, Mechanochromism, and Second Harmonic Up- conversion Properties in Regioisomeric Substitution Space
PublikacjaThis research article explores the distinct TADF efficiency of three donor-acceptor based regio-isomers: DPAOCN (ortho- isomer), DPAMCN (meta-isomer), and DPAPCN (para-isomer). DPAPCN exhibits maximum TADF efficiency in both solution and solid-state with an impressive reverse inter-system crossing (RISC) rate of ~ 106 s-1; the underlying cause being the minimum singlet-triplet splitting energy or ∆EST and maximum SOC (spin-orbit...
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Morphology and internal structure of small-scale washovers formed in the coastal zone of the semi-enclosed tideless basin, Gulf of Gdańsk, Baltic Sea
PublikacjaThis study explores the morphological features and internal structure of small-scale washovers along the southeastern Baltic Sea coast, providing insights into these most widespread yet often neglected deposits in the recent research of geomorphological and sedimentary record of storm surges. A 15-year-long record of morphological changes of the coast was acquired from regional orthophotos to analyse their geometry and spatial...
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Geometric working volume of a satellite positive displacement machine
PublikacjaThis article describes a method for determining the geometric working volume of satellite positive displacement machines (pump and motor). The working mechanism of these machines is satellite mechanism consisting of two non-circular gears (rotor and curvature) and circular gears (satellites). Two variants of the satellite mechanism are presented. In the first mechanism, the rolling line of the rotor is a sinusoid "wrapped" around...
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Ultrasound-Assisted Dispersive Liquid-Liquid Microextraction Using Deep Eutectic Solvents (DESs) for Neutral Red Dye Spectrophotometric Determination
PublikacjaDeep eutectic solvents (DES), which have low toxicity and are low cost, biodegradable, and easily synthesized, were used for the extraction of neutral red (NR) dye before its spectrophotometric analysis. DES, containing choline chloride as a hydrogen bond acceptor and phenol as a hydrogen bond donor with a molar ratio of 1:2, was used for the extraction of NR dye from aqueous media. The possible interaction of different DESs with...
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BUILDINGS AND CONSTRUCTIONS FROM BUILDING WASTE MATERIALS IN ACCORDANCE WITH THE NEW CIRCULAR ECONOMY TREND
PublikacjaMATERIALS April 18-22, 2022 / BOSTON, MA Abstract Book 3rd INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE & ENGINEERING Day 5 Friday, April 22, 2022 Parallel Sessio II- (Virtual EST Zone) pp. 154 3rd INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE & ENGINEERING APRIL 18-22, 2022 | BOSTON, MAAt: Boston, MAAffiliation: UNICEF at: USA BOSTONVolume: 2022
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A Method and Device for 3D Recognition of Cutting Edge Micro Geometry
PublikacjaA very useful method was successfully applied in the investigation of tools for machining wood and wood based composites. It allows scanning of the cutting edge micro geometry in three dimensions and reproducing it in a virtual space as a 3D surface. The application of the method opens new possibilities of studying tool wear by scanning, including the calculation of volume loss and other analysis of tool wedge geometry along and...
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SELECTED ASPECTS OF THE EVALUATION OF THE QUALITY OF GRAPE WINE
PublikacjaDevelopment of the domestic grape wine market has been presented. The number of grape wine producing entities, acreage, and volume of production over last five years are presented. The composition of red grape wine has been discussed involving health promoting aspects. Two methods of wine quality determination: analytical and sensory meth ods have been described. Physicochemical parameters influencing wine quali ty (acidity, sweetness)...
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Low-Coherence Interferometer with Nanocrystalline Diamond Films with Potential Application to Measure Small Biological Samples
PublikacjaThe study investigates a case of a low-coherence fiber-optic Fabry–Prerot interferometer with a nanocrystalline diamond (NCD) mirror. The method of achieving double density of interference fringes is proposed by the application of birefringent material in the cavity of the interferometer. It can be used to reduce sample volume in comparison to conventional interferometers. The use of a biocompatible diamond mirror makes it specifically...
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Mechanical Strength of MV Ship-switchgear During Fault Arc
PublikacjaIn the paper the analysis of pressure stressed in enclosure during fault arc inside switchgear is pre-sented as well. There is introduced the method based on determining stresses which are sum of tensile stresses (membrane) and deflection stresses. For tensile stresses nalysis the energy method, for unrestrainedly supported rectangular plate, was used. In the further part of the paper, the calculations and measurements results...
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Dielectric Properties of BiNbO<sub>4</sub>-Based Ceramic-Polymer Composites with 0-3 Connectivity
PublikacjaIn the present study two-phase BiNbO4//PVDF composites with 0-3 connectivity were studied by impedance spectroscopy within the frequency range Δν=100Hz-1MHz at room temperature. Polyvinylidene fluoride (PVDF) acted as a matrix whereas bismuth niobate (BiNbO4) powder acted as a dispersed phase. The volume fraction of the ceramic phase was cV=2, 4, 6, 8, 10, 16 and 20vol%. Analysis of the impedance data registered for composites...
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Interactions of N-alkyl-N-methylmorpholinium based ionic liquids with acetonitrile studied by density and velocity of sound measurements and molecular dynamics simulations
PublikacjaMorpholinium-based ionic liquids (ILs) and their mixtures with polar co-solvents are an interesting class of emerging electrolytes in electrochemistry that is relatively poorly studied. In this work, densities and sound velocities of four ILs, N-ethyl-N-methylmorpholinium tetrafluoroborate, N-butyl-N-methylmorpholinium tetrafluoroborate, N-octyl-N-methylmorpho-linium tetrafluoroborate and N-decyl-N-methylmorpholinium tetrafluoroborate...
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Determination of fuel combustion product in airport runoff water samples using liquid–liquid extraction with gas chromatography–spectrometry
PublikacjaDetermination of xenobiotics in samples of airport runoff water is both a complex and indispensable task due to an increasing threat resulting from the activities of numerous airports. The aim of this study was to develop, optimize, and validate a procedure based on liquid–liquid extraction (LLE) coupled with gas chromatography–mass spectrometry (GC–MS) for the determination of polycyclic aromatic hydrocarbons (PAHs). So far, no...
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Modelling of Diffusing Capacity Measurement Results in Lung Microangiopathy Patients. A novel Diagnostic Suppport
PublikacjaLung microangiopathy is a little known negative influence of diabetes mellitus on the functioning of the lungs. The aim of this study is to design a supportive method for diagnosing lung microangiopathy. This will be based on routinely performed pulmonary measurements as well as on investigation process modelling and data processing. A model of the diffusion of oxygen from the alveoli to the blood has been described with a set...
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Apparent molar volumes, expansibilities, and isentropic compressibilities of selected electrolytes in methanol
PublikacjaDensities of solutions of sodium bromide, sodium perchlorate, sodium tetraphenylborate, and tetraphenylphosphonium bromide in methanol at the temperatures ranging from 283.15 to 313.15 K have been measured. Ultrasound velocities for the above systems at T = 298.15 K have been determined. From the obtained data, the partial molar volumes and the partial molar isentropic compressibilities for electrolytes in solution have been estimated....
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Limiting Partial Molar Volumes of Tetra-n-Alkylammonium Perchlorates in N,N-dimethylacetamide, Triethylphosphate and Dimethyl Sulfoxide at 298.15 K
PublikacjaThe densities of tetraalkylammonium perchlorates R4NClO4(R = methyl, or ethyl, or propyl, or butyl) and ammonium perchlorate solutions in N, N - dimethylacetamide, dimethyl sulfoxide, and triethylphosphate have been measured over the whole composition range atT = 298.15 K. From these densities, apparent and limiting partial molar volumes of the electrolytes and ions...
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Application of Headspace Solid-phase Microextraction with Poly(1-vinyl-3- Hexylimidazolium Chloride) Polymeric Ionic Liquid Coating using GC - MS to Determine Volatile Fatty Acids in Dairy Wastewater
PublikacjaVolatile fatty acids were determined in this study using headspace solid-phase microextraction (HS-SPME) with a poly(1-vinyl-3-hexylimidazolium chloride) polymeric ionic liquid coated fiber followed by gas chromatography - mass spectrometry. Experimental parameters such as extraction time and temperature, sample volume as well as desorption time and temperature were optimized. Detection limits of the method were in the range of...
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Acoustic Heating Produced in the Thermoviscous Flow of a Shear-Thinning Fluid
PublikacjaThis study is devoted to the instantaneous acoustic heating of a shear-thinningfluid. Apparent viscosity of a shear-thinning fluid depends on the shear rate. Thatfeature distinguishes it from a viscous Newtonian fluid. The special linear combi-nation of conservation equations in the differential form makes it possible to derivedynamic equations governing both the sound and non-wave entropy mode inducedin the field of sound. These...
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Massive surveillance data processing with supercomputing cluster
PublikacjaIn recent years, increasingly complex algorithms for automated analysis of surveillance data are being developed. The rapid growth in the number of monitoring installations and higher expectations of the quality parameters of the captured data result in an enormous computational cost of analyzing the massive volume of data. In this paper a new model of online processing of surveillance data streams is proposed, which assumes the...
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Calculation methods of interaction of electromagnetic waves with objects of complex geometries
PublikacjaModeling of the electromagnetic interaction with different homogeneous or inhomo-geneous objects is a fundamental and important problem. It is relatively easy to solve Maxwellequations analytically when the scattering object is spherical or cylindrical, for example. How-ever, when it loses these properties all that is left for us is to useapproximation models, to ac-quire the solution we need. Modeling of complex, non-spherical,...
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Can Web Search Queries Predict Prices Change on the Real Estate Market?
PublikacjaThis study aims to explore whether the intensity of internet searches, according to the Google Trends search volume index (SVI), is a predictor of changes in real estate prices. The motivation of this study is the possibility to extend the understanding of the extra predictive power of Google search engine query volume of future housing price change (shift direction) by (i) the introduction of a research approach that combines...
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SILICA AEROGEL TOWARDS ANODES FOR LITHIUM-ION BATTERIES
PublikacjaAn increasing demand for electrochemical energy storage and conversion devices stimulates progress in research on electrode and electrolyte materials. In the field of electrodes materials, silicon is the one of the most promising anode materials for Li-ion batteries. However silicon has the drastic volume variation (around 3 times lower on extraction) during insertion and extraction of lithium ions. As an alternative, nanocomposites...
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A pore-scale thermo–hydro-mechanical model for particulate systems
PublikacjaA pore scale numerical method dedicated to the simulation of heat transfer and associated thermo–hydro-mechanical couplings in granular media is described. The proposed thermo–hydro-mechanical approach builds on an existing hydromechanical model that employs the discrete element method for simulating the mechanical behavior of dense sphere packings and combines it with the finite volume method for simulating pore space fluid flow...
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Optical Coherence Tomography for nanoparticles quantitative characterization
PublikacjaThe unique features of nanocomposite materials depend on the type and size of nanoparticles, as well as their placement in the composite matrices. Therefore the nanocomposites manufacturing process requires inline control over certain parameters of nanoparticles such as dispersion and concentration. Keeping track of nanoparticles parameters inside a matrix is currently a difficult task due to lack of a fast, reliable and cost effective...