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Low temperature rotary Stirling engine: conceptual design and theoretical analysis
PublikacjaThe use of low-temperature energy sources for electricity generation demands a dual focus: a substantial enhancement in the efficiency of energy conversion devices and a reduction in system production costs. Particularly in scenarios where low-temperature energy sources are scarce, this factor can be pivotal in facilitating widespread adoption of such technologies. The Stirling engine emerges as a promising solution capable of...
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Corrosion performance of super duplex stainless steel and pipeline steel dissimilar welded joints: a comprehensive investigation for marine structures
PublikacjaThis study investigates the corrosion behavior of dissimilar gas tungsten arc (GTA) welded joints between super duplex stainless steel (sDSS 2507) and pipeline steel (X-70) using electrochemical and immersion corrosion tests. The GTA welds were fabricated using ER2594 and ER309L fller metals. The study examined the electrochemical characteristics and continuous corrosion behavior of samples extracted from various zones of the weldments...
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The impact of graphene on the electrochemical performance of BiMeVOx catalysts in water splitting
PublikacjaThe development of efficient catalysts for electrochemical water splitting has become a significant contemporary challenge. Transition metal oxides, due to their unique electrochemical properties, have emerged as promising candidates. Among these, a group of BiMeVOx-based compounds shows particular potential for practical applications in hydrogen and oxygen evolution reactions. However, improvement is still necessary to achieve...
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Comparative Analysis of the Coffee and Cocoa Industry By-Products on the Performance of Polyethylene-Based Composites
PublikacjaThe application of plant-based by-products from the food industry as minimally processed functional fillers for polymeric composites is an increasingly popular trend among researchers and manufacturers. While minimizing the preprocessing of lignocellulosic fillers leads to an increase in the sustainability of the overall composite and a decrease of the carbon footprint, filler modification is usually indispensable to obtaining...
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MOF/TiO2 erythrocyte-like heterostructures decorated by noble metals for use in hydrogen photogeneration and pollutant photodegradation
PublikacjaVarious metal–organic framework (MOF)/TiO2 heterostructures can be obtained by the partial hydrolysis or calcination of Ti-based MOFs. By adjusting the hydrolysis and calcination steps of NH2-MIL-125 (Ti), a novel photoactive material composed of a MOF (NH2-MIL-125 (Ti)) and TiO2, with a unique “erythrocyte” shape, was developed. Furthermore, modification of the composition prepared by the partial hydrolysis of NH2- MIL-125 (Ti)...
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Dual-Setting Bone Cement Based On Magnesium Phosphate Modified with Glycol Methacrylate Designed for Biomedical Applications
PublikacjaMagnesium phosphate cement (MPC) is a suitable alternative for the currently used calcium phosphates, owing to beneficial properties like favorable resorption rate, fast hardening, and higher compressive strength. However, due to insufficient mechanical properties and high brittleness, further improvement is still expected. In this paper, we reported the preparation of a novel type of dual-setting cement based on MPC with poly(2-hydroxyethyl...
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Engineering TADF, Mechanochromism, and Second Harmonic Up- conversion Properties in Regioisomeric Substitution Space
PublikacjaThis research article explores the distinct TADF efficiency of three donor-acceptor based regio-isomers: DPAOCN (ortho- isomer), DPAMCN (meta-isomer), and DPAPCN (para-isomer). DPAPCN exhibits maximum TADF efficiency in both solution and solid-state with an impressive reverse inter-system crossing (RISC) rate of ~ 106 s-1; the underlying cause being the minimum singlet-triplet splitting energy or ∆EST and maximum SOC (spin-orbit...
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Unusual structural properties of water within the hydration shell of hyperactive antifreeze protein
PublikacjaMany hypotheses can be encountered explaining the mechanism of action of antifreeze proteins. One widespread theory postulates that the similarity of structural properties of solvation water of antifreeze proteins to ice is crucial to the antifreeze activity of these agents. In order to investigate this problem, the structural properties of solvation water of the hyperactive antifreeze protein from Choristoneura fumiferana were...
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Variable-fidelity CFD models and co-Kriging for expedited multi-objective aerodynamic design optimization
PublikacjaPurpose – Strategies for accelerated multi-objective optimization of aerodynamic surfaces are investigated, including the possibility of exploiting surrogate modeling techniques for computational fluid dynamic (CFD)-driven design speedup of such surfaces. The purpose of this paper is to reduce the overall optimization time. Design/methodology/approach – An algorithmic framework is described that is composed of: a search space reduction,...
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Further Developments of the Online Sound Restoration System for Digital Library Applications
PublikacjaNew signal processing algorithms were introduced to the online service for audio restoration available at the web address: www.youarchive.net. Missing or distorted audio samples are estimated using a specific implementation of the Jannsen interpolation method. The algorithm is based on the autoregressive model (AR) combined with the iterative complementation of signal samples. Since the interpolation algorithm is computationally...
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Maternal smoking Modulates Fatty Acid Profile of Breast Milk
PublikacjaAIM: We hypothesized that the fatty acid composition of breast milk can be affected by a smoking habit in the mother. Consequently, this study verified whether maternal smoking modulates, and if so to what extent, the breast milk fatty acid profile. METHODS: The study included 20 postpartum women who declared smoking more than five cigarettes daily throughout a period of pregnancy and lactation, and 136 non-smoking postpartum women....
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The reduction of auxiliaries power demand: The challenge for electromobility in public transportation
PublikacjaAn important role in the consumption of electric energy in urban transport are non-traction needs (auxiliaries), the main part of which is heating and air condition (HVAC). Auxiliaries are responsible for almost half of total energy consumption (normal weather conditions) and in the winter (or hot summer) it reaches up to 70% in daily scale. The reduction of energy used for non-traction needs is currently the main challenge related...
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The Quantum Efficiency Roll-Off Effect in Near-Infrared Organic Electroluminescent Devices with Iridium Complexes Emitters
PublikacjaThe electroluminescence quantum efficiency roll-off in iridium(III)-based complexes, namely Ir(iqbt)2(dpm) and Ir(iqbt)3(iqbt=1 (benzo[b]thiophen-2-yl)-isoquinolinate, dpm=2,2,6,6-tetramethyl-3,5-heptanedionate) utilized as near-infrared emitters in organic light emitting diodes with remarkable external quantum efficiencies, up to circa 3%, 1.5% and 1%, are measured and analyzed. With a 5–6 weight % of emitters embedded...
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Simulation-Driven Antenna Modeling by Means of Response Features and Confined Domains of Reduced Dimensionality
PublikacjaIn recent years, the employment of full-wave electromagnetic (EM) simulation tools has become imperative in the antenna design mainly for reliability reasons. While the CPU cost of a single simulation is rarely an issue, the computational overhead associated with EM-driven tasks that require massive EM analyses may become a serious bottleneck. A widely used approach to lessen this cost is the employment of surrogate models, especially...
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Ni/cerium Molybdenum Oxide Hydrate Microflakes Composite Coatings Electrodeposited from Choline Chloride: Ethylene Glycol Deep Eutectic Solvent
PublikacjaCerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced, due to the existence of some microcracks caused by large microflakes. Multielemental analysis of the solution, in which coatings are exposed and the qualitative changes in the surface...
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Light-improved glucose sensing on ordered Au-Ti heterostructure
PublikacjaNon-enzymatic electrochemical platforms sensitive towards glucose presence have attracted a worldwide attention during last decades. We report on influence of solar light onto response of gold-titanium heterostructures prepared via controllable approach. The material based on Au nanoparticles orderly distributed over the structured titanium foil was obtained by electrochemical anodization followed by chemical etching, magnetron...
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Permeability of the small intestinal mucus for physiologically relevant studies: Impact of mucus location and ex vivo treatment
PublikacjaThe small intestinal mucus is a complex colloidal system that coats the intestinal mucosa. It allows passage on nutrients/pharmaceuticals from the gut lumen towards the epithelium, whilst preventing it from direct contact with luminal microorganisms. Mucus collected from intestinal tissue is often used in studies looking at inter-mucosal transport of food particulates, drug carriers, etc. However, detaching the highly hydrated...
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Online sound restoration system for digital library applications.
PublikacjaAudio signal processing algorithms were introduced to the new online non-commercial service for audio restoration intended to enhance the content of digitized audio repositories. Missing or distorted audio samples are predicted using neural networks and a specific implementation of the Jannsen interpolation method based on the autoregressive model (AR) combined with the iterative restoring of missing signal samples. Since the distortion...
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The importance of the bottom layer in double-layer porous asphalt for noise reduction
PublikacjaDouble-layer porous asphalt concrete (DPAC) surfaces are generally considered to be the acoustically most effective low noise road surfaces ready for implementation. While DPAC used on highways in warm climates may have an average life of around 8 years, in Scandinavia with severe winter climate DPAC usually survive only about 3 years; partly due to wear of studded tyres. An ongoing project in Sweden, applying DPAC and single-layer...
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Potential reduction of traffic noise by the means of increased fleet of electric vehicles using a combination of low-noise tyres and low-noise road surfaces
PublikacjaIn the future, the number of zero-emission vehicles like electric and plug-in hybrid vehicles (in electric mode) is expected to be a substantial part of the vehicle fleet. In Norway, such vehicles already account for approximately 20 % of all new cars sold. Since these vehicles emit negligible noise related to the power-train, the tyre/road noise is the dominating noise source. In the LEO project, tyres designed for such cars have...
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Effect of composition on the thermal properties and structure of M-Al-Si-O-N glasses, M = Na, Mg, Ca
PublikacjaThe primary objective of this study is to explore the relationship between the composition, structure, and thermal characteristics of M-Al-Si-O-N glasses, with M representing sodium (Na), magnesium (Mg), or calcium (Ca). The glasses were prepared by melting in a quartz crucible at 1650 °C and AlN precursor (powder) was utilized as a nitrogen source. The measured thermal properties studied were glass transition temperature (Tg),...
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Silver nanoparticles incorporated with superior silica nanoparticles-based rice straw to maximize biogas production from anaerobic digestion of landfill leachate
PublikacjaTreating hazardous landfill leachate poses significant environmental challenges due to its complex nature. In this study, we propose a novel approach for enhancing the anaerobic digestion of landfill leachate using silver nanoparticles (Ag NPs) conjugated with eco-friendly green silica nanoparticles (Si NPs). The synthesized Si NPs and Ag@Si NPs were characterized using various analytical techniques, including transmission electron...
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Green and sustainable hydrogels based on quaternized chitosan to enhance wound healing
PublikacjaHydrogel-based biomaterials applied as wound dressings provide the wound with a moist environment, which facilitates tissue regeneration through granulation and re-epithelialization. The inherent flexibility and adjustable architecture of hydrogels enables incorporation of cells, antimicrobial drugs, growth factors, and bioactive compounds, which leads to expediting wound contraction and enhancing the regeneration process. The...
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Exploring novel Cd(ii) complexes with 5-methyl-4-imidazolecarboxaldehyde: synthesis, structure, computational insights, and affinity to DNA through switchSense methodology
PublikacjaA series of four Cd(II) complexes with 5-methyl-4-imidazolecarboxaldehyde (L) with different inorganic anions within or outside the coordination sphere of general formula: [CdCl2 L2 ] (1), [CdBr2 L 2] (2), [CdI2L 2] (3), and [CdL4 ](PF6 )2 ·3H2 O (4) was synthesized through one-step and two-step reactions, respectively. All complexes were obtained as colorless crystals without the need for recrystallization and exhibited solubi- lity...
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Comparative Analysis of the Cofee and Cocoa Industry By‑Products on the Performance of Polyethylene‑Based Composites
PublikacjaThe application of plant-based by-products from the food industry as minimally processed functional fillers for polymeric composites is an increasingly popular trend among researchers and manufacturers. While minimizing the preprocessing of lignocellulosic fillers leads to an increase in the sustainability of the overall composite and a decrease of the carbon footprint, filler modification is usually indispensable to obtaining...
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Superconductivity in a breathing kagome metals ROs2 (R = Sc, Y, Lu)
PublikacjaWe have successfully synthesized three osmium-based hexagonal Laves compounds ROs2 (R = Sc, Y, Lu), and discussed their physical properties. LeBail refinement of pXRD data confirms that all compounds crystallize in the hexagonal centrosymmetric MgZn2- type structure (P63/mmc, No. 194). The refined lattice parameters are a = b = 5.1791(1) Å and c = 8.4841(2) Å for ScOs2, a = b = 5.2571(3) Å and c = 8.6613(2) Å for LuOs2 and a =...
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Urban city lights. Light pollution as one of the effects of incorrectly designed external illumination. How can a successful lighting masterplan diminish its impact?
PublikacjaIn the modern world, artificial lighting brings many tangible benefits such as the ability to extend working hours and so increase production, recreational use of the city after dark, or the possibility to travel regardless of the time of day. However, this flexibility comes at a price and negatively impacts on the environment. One such negative phenomenon is Light Pollution ‐ a term used to describe excessive nighttime artificial...
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Evaluation of electrosynthesized reduced graphene oxide–Ni/Fe/Co-based (oxy)hydroxide catalysts towards the oxygen evolution reaction
PublikacjaIn this work, the specific role of the addition of graphene oxide (GO) to state-of-the-art nickel–iron (NiFe) and cobalt–nickel–iron (CoNiFe) mixed oxides/hydroxides towards the oxygen evolution reaction (OER) is investigated. Morphology, structure, and OER catalytic activity of the catalysts with and without GO were studied. The catalysts were fabricated via a two-step electrodeposition. The first step included the deposition...
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Design and synthesis of TiO2/Ti3C2 composites for highly efficient photocatalytic removal of acetaminophen: The relationships between synthesis parameters, physicochemical properties, and photocatalytic activity
PublikacjaIn this study, we report the potential of TiO2/Ti3C2 composite fabricated by oxidation of MXene for degradation of persistent organic pollutants. The effect of the synthesis conditions (time, temperature, and reaction environment) on the morphology, physicochemical properties, and photocatalytic activity was investigated. It was found that acetaminophen degradation was positively correlated with TiO2 content in the composite structure. Furthermore,...
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Decomposition of the induced magnetism degaussing problem for fast determination of currents in demagnetization coils wrapped outside an object under arbitrary external field conditions
PublikacjaSafe passage of ships in the presence of sea mines can be ensured by limiting or reducing the ship’s magnetic footprint. For vessels with plastic hulls, the main component that requires magnetic damping is the engine. Demagnetization of such an object can be achieved by wrapping it with coils and setting the direct current appropriately. For each specific geographic location, the currents in the coils can be determined iteratively...
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Detection of anomalies in bee colony using transitioning state and contrastive autoencoders
PublikacjaHoneybees plays vital role for the environmental sustainability and overall agricultural economy. Assisting bee colonies within their proper functioning brings the attention of researchers around the world. Electronics systems and machine learning algorithms are being developed for classifying specific undesirable bee behaviors in order to alert about upcoming substantial losses. However, classifiers could be impaired when used...
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Analysis of IMS/NGN Call Processing Performance Using Phase-Type Distributions Based on Experimental Histograms
PublikacjaThe paper describes our further research done with the proposed analytical and simulation traffic models of the Next Generation Network (NGN), which is standardized for delivering multimedia services with strict quality and includes elements of the IP Multimedia Subsystem (IMS). The aim of our models of a single IMS/NGN domain is to evaluate two standardized call processing performance parameters, which appropriate values are very...
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Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels
PublikacjaBiowaste chicken eggshell (ES) powder was applied as a potential cure modifier in epoxy/anhydride systems. Cure behaviour and kinetics of composites filled with very low content (0.1 wt% based on epoxy resin) of ES, calcium carbonate (CaCO3), and terpolymer-modified fillers, mES and mCaCO3, were discussed comparatively. Surface analysis was performed by X-ray photoelectron spectroscopy. Cure kinetics was investigated by differential...
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Digits Recognition with Quadrant Photodiode and Convolutional Neural Network
PublikacjaIn this paper we have investigated the capabilities of a quadrant photodiode based gesture sensor in the recognition of digits drawn in the air. The sensor consisting of 4 active elements, 4 LEDs and a pinhole was considered as input interface for both discrete and continuous gestures. Index finger and a round pointer were used as navigating mediums for the sensor. Experiments performed with 5 volunteers...
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Accuracy of a low-cost autonomous hexacopter platforms navigation module for a photogrammetric and environmental measurements
PublikacjaA photogrammetry and environmental measurements from an unmanned aerial vehicle (UAV) are a low-cost alternative for a traditional aerial photogrammetry. A commercial off-the-shelf products (COTS) offers a variety of cheap components that a suitable to be used on board a UAV. In this paper a low-cost navigation module based on Ublox NEO-M8N GPS and Pixhawk flight controller have been described, as a main extrinsic parameters source...
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CZYNNIKI DECYDUJĄCE O PRZYDATNOŚCI KOMPUTEROWEGO MODELU PRZEPŁYWÓW W SIECI WODOCIĄGOWEJ
PublikacjaW pracy poddano analizie wielozadaniowy proces tworzenia komputerowego modelu przepływów. W efekcie zidentyfikowano szereg czynników ograniczających obszar stosowania modelu w praktyce inżynierskiej. W zakresie pozyskiwania danych strukturalnych i operacyjnych wskazano potencjalne źródła błędów, które przyczyniają się do zmniejszenia dokładności odwzorowania stanu rzeczywistego. Specjalną rangę nadano specyfikacji czynników związanych...
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Adaptacyjny system oświetlania dróg oraz inteligentnych miast
PublikacjaPrzedmiotem rozprawy jest zbadanie praktycznej możliwości wykrywania w czasie rzeczywistym anomalii w systemie oświetlenia drogowego w oparciu o analizę danych ze inteligentnych liczników energii. Zastosowanie inteligentnych liczników energii elektrycznej (Smart Meter) w systemach oświetlenia drogowego stwarza nowe możliwości w zakresie automatycznej diagnostyki takich niepożądanych zjawisk jak awarie lamp, odstępstwa od harmonogramu...
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Badania nad rozdzielaniem grupowym i analityką składu grupowego olejów bazowych i smarowych, zwłaszcza o szerokim zakresie polarności składników
PublikacjaRozprawa to studia i badania nad rozdzielaniem i analityką składu grupowego olejów bazowych i smarowych o szerokim zakresie polarności składników. Studium literatury wykazało brak metodyk badania udziału frakcji naftowej i roślinnej w takich olejach oraz nieadekwatność w tym celu HPLC. Pierwsza część pracy to badania nad opracowaniem wielokrotnie zastosowanej w praktyce terenowej metodyki i wyposażenia dla zastosowania fluorescencji...
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Tworzenie miasta przyjaznego wszystkim
PublikacjaTworzenie miasta przyjaznego wszystkim, to zadnie, które jest prawdopodobnie celem wszystkich włodarzy miejskich. Czy nie jest tak, że każdy chciałby w takim mieście zamiesz-kać? Jednak zadanie to jest dość trudne, bo wymaga pogodzenia wielu aspektów życia mieszkańców. Obecnie do zagadnień środowiskowych związanych z szeroko rozumianą ekologią dochodzi zagadnienie dostosowania przestrzeni zgodnie z zasadami projektowania uniwersalnego....
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The Influence of Drying Temperature on Color Change of Hornbeam and Maple Wood Used as Surface and Inner Layers of Wood Composites
PublikacjaThe thermal treatment of wood changes its structure due to the degradation of wood polymers (cellulose, hemicellulose and lignin), so the physical properties of wood are either improved or degraded. Color changes apply not only to natural wood, but also to such wood composites for which some amount of glue is used in their construction (e.g., plywood, blockboard or laminboard). This article is focused on the analysis of hornbeam...
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Higher platelet counts correlate to tumour progression and can be induced by intratumoural stroma in non-metastatic breast carcinomas
PublikacjaBackground Platelets support tumour progression. However, their prognostic significance and relation to circulating tumour cells (CTCs) in operable breast cancer (BrCa) are still scarcely known and, thus, merit further investigation. Methods Preoperative platelet counts (PCs) were compared with clinical data, CTCs, 65 serum cytokines and 770 immune-related transcripts obtained using the NanoString technology. Results High normal...
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Recent Advances in Loop Heat Pipes with Flat Evaporator
PublikacjaThe focus of this review is to present the current advances in Loop Heat Pipes (LHP) with flat evaporators, which address the current challenges to the wide implementation of the technology. A recent advance in LHP is the design of flat-shaped evaporators, which is better suited to the geometry of discretely mounted electronics components (microprocessors) and therefore negate the need for an additional transfer surface (saddle)...
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A facile approach to fabricate load-bearing porous polymer scaffolds for bone tissue engineering
PublikacjaBiodegradable porous scaffolds with oriented interconnected pores and high mechanical are load-bearing biomaterials for bone tissue engineering. Herein, we report a simple, non-toxic, and cost-effective method to fabricate high-strength porous biodegradable scaffolds, composed of a polymer matrix of polycaprolactone (PCL) and water-soluble poly (ethylene oxide) (PEO) as a sacrificial material by integrating annealing treatment,...
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Direction of Arrival Estimation Based on Received Signal Strength Using Two-Row Electronically Steerable Parasitic Array Radiator Antenna
PublikacjaIn this paper, we present a novel approach to direction-of-arrival (DoA) estimation using two-row electronically steerable parasitic array radiator (ESPAR) antenna which has 12 passive elements and allows for elevation and azimuth beam switching using a simple microcontroller, relying solely on received signal strength (RSS) values measured at the antenna output port. To this end, we thoroughly investigate all 18 available 3D antenna...
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Residents' Perception of Intangible Benefits and Costs Associated with Hosting Major Sporting Events
PublikacjaThe main purpose of this paper is to estimate on the basis of inhabitants’ perception the overall composite and aggregated scores of two major sporting events held in Ergo Arena hall, on the border of Gdańsk and Sopot, in northern Poland. The indirect aim is to identify the determinants affecting the monetary offers of the locals of the two cities. The research results unveil that major sporting events may determine the appearance...
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Novel molecules containing structural features of NSAIDs and 1,2,3-triazole ring: Design, synthesis and evaluation as potential cytotoxic agents
PublikacjaFor the first time the template containing structural features of more than one NSAIDs and the 1,2,3-triazole ring was explored for the identification of potential cytotoxic agents. These new and complex molecules were predicted to be effective inhibitors of PDE4B by molecular modelling studies in silico. The multi-step synthesis of these compounds were carried out starting from the well-known drug nimesulide and involved the use...
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Investigation on the Sources and Impact of Trace Elements in the Annual Snowpack and the Firn in the Hansbreen (Southwest Spitsbergen)
PublikacjaWe present a thorough evaluation of the water soluble fraction of the trace element composition (Ca, Sr, Mg, Na, K, Li, B, Rb, U, Ni, Co, As, Cs, Cd, Mo, Se, Eu, Ba, V, Ge, Ga, Cr, Cr, P, Ti, Mn, Zr, Ce, Zn, Fe, Gd, Y, Pb, Bi, Yb, Al, Nb, Er, Nd, Dy, Sm, Ho, Th, La, Lu, Tm, Pr, Tb, Fe, In, Tl) and their fluxes in the annual snowpack and the firn of the Hansbreen (a tidewater glacier terminating in the Hornsund fjord, southwest...
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PTD4 Peptide Increases Neural Viability in an In Vitro Model of Acute Ischemic Stroke
PublikacjaIschemic stroke is a disturbance in cerebral blood flow caused by brain tissue ischemia and hypoxia. We optimized a multifactorial in vitro model of acute ischemic stroke using rat primary neural cultures. This model was exploited to investigate the pro-viable activity of cell-penetrating peptides: arginine-rich Tat(49–57)-NH2 (R49KKRRQRRR57-amide) and its less basic analogue, PTD4 (Y47ARAAARQARA57-amide). Our model included glucose...
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A Single-Carrier-Based Pulse-Width Modulation Template for Cascaded H-Bridge Multilevel Inverters
PublikacjaMultiplicity of the triangular carrier signals is a criterion for the extension of sinusoidal pulsewidth modulation, SPWM, to a number of output voltage levels per phase-leg in cascaded H-bridge (CHB) multilevel inverter (MLI). Considering medium and high voltage applications where appreciable number of output voltage levels from CHB MLI is needed, commensurate high number of carrier signals in either classical level- or phase-shifted...
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Industry-level analysis of COVID-19’s impact in emerging markets – evidence from Pakistan
PublikacjaPurpose – The main purpose of this study is to evaluate COVID-19’s impact on the emerging stock markets. Design/methodology/approach – To evaluate the influence of COVID-19, this study uses a novel method of event study methodology to measure the impact of COVID-19 on emerging stock markets. The research’s sample includes a total of 79 firms from 26 industries that are included in the KSE-100 Index from the Pakistan Stock Exchange....