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Hydrogen migration observed in fragmentation of the pyridine molecules in collisions with the H+, H2+, He+and He++cations
PublikacjaThe hydrogen atom migration preceding fragmentation of the pyridine molecules by the H+, H2+, He+ and He++ collisions has been investigated in the 5-2000 eV energy range. The pyridine molecule structure is lacking of the NH group, thus formation of the NH radicals is an evidence of the H atom relocation prior to the cation-induced fragmentation. The NH(A3Π) fragmentation yields measured by detecting its A3Π→X3Σ− fluorescence show...
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Sample Rate Conversion Based on Frequency Response Masking Filter
PublikacjaThe sample rate conversion with high resampling ratios requires low-pass digital filters with very narrow transition band which results in high computational complexity and makes filter design problematic. Therefore in this work we propose to use the FRM method, which breaks the filter with a narrow transition band into a group of filters with reduced design requirements. These decreases the number of non-zero coefficients and...
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Perforating systems in shale gas recovery
PublikacjaHydraulic fracturing is common method of shale gas recovery. Due to environmental, economical and technological problems many alternative technologies have been developed. One of the most promising group of technologies is based on perforating systems. This paper describes theoretical and practical aspects of best known technologies used to create perforations. New perforating/fracturing technologies which can replace hydraulic fracturing...
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Highly efficient maximum power point tracking control technique for PV system under dynamic operating conditions
PublikacjaThe application of small-scale electrical systems is widespread and the integration of Maximum Power Point Tracking (MPPT) control for Photovoltaic systems with battery applications further enhances the techno-economic feasibility of renewable systems. For this purpose, a novel MPPT control system using Dynamic Group based cooperation optimization (DGBCO) algorithm is utilized for PV systems. The population in the DGBCO is divided...
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Incorporation of the sulfur cycle in sustainable nitrogen removal systems - A review
PublikacjaIn wastewater treatment systems, sulfur (S) removal processes are generally based on heterotrophic sulfate (SO42−) reduction by sulfate reducing bacteria and S-dependent autotrophic denitrification by sulfur oxidizing bacteria. A combination of either two cycles (N and S) or three cycles (N, S and C) appears to be a viable approach to sustainable wastewater treatment, resulting in energy savings and reduction of sludge production....
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Anion recognition by phosphonium calix[4]arens: synthesis and physico-chemical studies
Publikacjap-tert-butylcalix[4]arenes in the cone conformation, di-and tetra substituted at the narrow rim with charged phosphonium groups have been synthesies and characterised.
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Visible light activity and photoelectrochemical properties of nitrogen-doped TiO2.
PublikacjaFotokatalizatory TiO2 domieszkowane azotem zostały zsyntetyzowane z propanolanu tytanu (IV) lub chlorku tytanu (IV) i tiomocznika. Żółte proszki otrzymane po ogrzewaniu w temperaturach 400-600 st.C fotokatalizowały mineralizację 4-chlorofenolu w zakresie światła widzialnego (delta większe lub równe 455nm. W odróżnieniu od uprzednio opublikowanych wyników, zsyntetyzowane fotokatalizatory nie zawierały siarki, lecz zamiast tego azot...
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The “autumn effect” in the gold market—does it contradict the Adaptive Market Hypothesis?
PublikacjaThe present study aims to verify the autumn effect in the gold market, first presented 10 years ago by Dirk Baur in the paper “The autumn effect of gold” and to investigate the calendar effects occurring for other precious metals. This empirical research is presented in a way to place the results obtained in the context of the Efficient Market Hypothesis (EMH) and the more current Adaptive Market Hypothesis (AMH). The study was...
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Voltage profiles improvement in a power network with PV energy sources – results of a voltage regulator implementation
PublikacjaThe constant increase in the number of photovoltaic (PV) energy sources in distribution networks is the cause of serious voltage problems. The networks built at least a dozen years ago are not provided for the installation of a large number of micro-sources. It happens that the previously properly functioning power networks are not able to provide to consumers power with the required parameters, after installing many PV sources....
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Shaping the New Vistula Spit Channel: Political, Economic, and Environmental Aspects
PublikacjaIn September 2022, the new shipping channel in Poland was opened for service. It connects the Port of Elbląg and the Gdańsk Bay in Poland, cutting through the Vistula Spit and the Vistula Lagoon. It was intended to enable direct access to the Baltic Sea from the Port of Elbląg without crossing Russian territory. Originally conceptualized decades ago, it has taken its final shape only recently. Its construction was associated with...
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E-Estonia as a role model? Some general considerations and applicability in France
PublikacjaEstonia has recently been widely recognised – in the policy circles, academia, as well as the media space – as one of the more advanced nation states when it comes to digital government (and governance) transformation (e.g. Margetts and Naumann, 2017; Heller, 2017). Ever greater attention Estonia attracted with the two most recent digital government initiatives, namely the e-Residency and the virtual data embassy, both first of...
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Optimizing of target detection and tracking processes realized on consoles of passive sonar with linear towed antenna
PublikacjaThe long-range passive towed sonar was first modernised a few years ago. Building on operator experience over that period, a concept was developed of optimising the tasks performed by sonar operators, and improving forms of imaging to inform about object detection and support object tracking. The concept was implemented and successfully tested during ships’ manoeuvres. The optimisation of operator tasks was designed to keep listening...
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1,3-Di-<i>n</i>-butylthiourea
PublikacjaIn the title compound, C9H20N2S, the n-butyl groups are in syn and anti positions in relation to the C=S bond. In the crystal, two molecules are connected by two N-H···S=C hydrogen bonds into a centrosymmetric dimer. Another N-H···S=C hydrogen bond links the dimers, forming layers with a hydrophilic interior and a hydrophobic exterior, which spread across the (100) plane. Interlacing of the...
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Chirp-rate estimation of FM signals in the time-frequency domain
PublikacjaNovel dynamic representations of a complex signal in the time-frequency domain including: a channelized instantaneous complex frequency (CICF), a complex local group delay (CLGD) and a channelized instantaneous chirp-rate (CICR) are introduced. The proposed approach is based on the use of the gradient of the short-time Fourier transform complex phase. An interpretation of the newly-introduced distributions especially of the CICR...
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Ella4Life virtual assistant - user centered design strategy - evaluation following labolatory tests
PublikacjaIn the paper, we summarize the evaluation of Anne4Care system after laboratory tests. A group of end users, seniors over 55 years of age, rated a virtual assistant by completing a questionnaire. The objectives of the pilot evaluations are mainly to assess the feasibility, usability, acceptance and functionality of the system and the ability of the potential target user to use the system and receive valuable information from it...
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Investigation of magnetic order in a new intermetallic compound Nd2PtGe3
PublikacjaIn the present study we report a successful synthesis of the new intermetallic compound Nd2PtGe3 by an arc-melting method. The powder X-ray diffraction analysis indicates that this compound crystallizes in an disordered variant of the AlB2-type structure (space group P6/mmm, no. 191) with lattice parameters a = 4.2455 Å and c = 4. 1933 Å. The compound exhibits a cluster-glass transition below Tf = 2.9 K, characterized through ac...
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Linking music data in executable documents
PublikacjaThis paper presents the application of Interactive Open Document Architecture (IODA) to music and video data. This architecture was design to create multilayer documents which consist of many files. The paper shows the method of creating media documents on the basis of IODA. These kind of documents were called IODA Media Documents (IMD). IMD have links that connect many different kinds of files containing music and video data....
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Towards detecting programmers’ stress on the basis of keystroke dynamics
PublikacjaThe article describes the idea of detecting stress among programmers on the basis of keystroke dynamics. An experiment with a group of students of artificial intelligence classes was performed. Two samples of keystroke data were recorded for each case, the first while programming without stress, the second under time pressure. A number of timing and frequency parameters were calculated for each sample. Then statistical analysis...
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The equivariant spectral flow and bifurcation of periodic solutions of Hamiltonian systems
PublikacjaWe define a spectral flow for paths of selfadjoint Fredholm operators that are equivariant under the orthogonal action of a compact Lie group as an element of the representation ring of the latter. This G-equivariant spectral flow shares all common properties of the integer valued classical spectral flow, and it can be non-trivial even if the classical spectral flow vanishes. Our main theorem uses the G-equivariant spectral flow...
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The effect of job-related stress on psychological well-being = Wpływ stresu zawodowego na dobrostan psychiczny
PublikacjaThe aim of the investigation was to evaluate the effect of job stress factors on psychological well-being of firemen. Goldberg's GHQ-12 for well-being evaluation, the Perceived Job Stress Questionnaire by Dudek et al. for job stress assessment, and indicator of participation in traumatic events were used. 19% of the firemen were qualified to the group with increased risk of mental disorders. Occupational stress had a strong impact...
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Vision-based motion analysis of kitesurfer
PublikacjaKitesurfing is a relatively recent phenomenon with raising popularity worldwide – a recently developed extreme water sport considered a high-risk injury sport. It combines elements of several other sports, in particular sailing, surfing, windsurfing, wakeboarding, and snowboarding. The main purpose of authors’ research in the present paper is to use a vision system technique for measuring a kitesurfer’s body movements in order...
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Ligation Mediated PCR methods, their possibilities and limitations
PublikacjaThe application of molecular diagnostics for bacterial strain typing or identifying bacteria at the strain level is of particular importance at present. However, among the many genotyping methods that are currently available, no single one is universally ideal. In this article, we thus review the Ligation Mediated PCR group methods as prospects from which to choose. We discuss different strategies for selecting the amplified PCR...
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Metody bezpośrednie wykrywania przyczyn biokorozji
PublikacjaW rozdziale omówiono teoretyczne podstawy oznaczania najważniejszych grup drobnoustrojów powodujących biokorozję
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Diaryl Sulfide Derivatives as Potential Iron Corrosion Inhibitors: A Computational Study
PublikacjaThe present work aimed to assess six diaryl sulfide derivatives as potential corrosion inhibitors. These derivatives were compared with dapsone (4,4′-diaminodiphenyl sulfone), a common leprosy antibiotic that has been shown to resist the corrosion of mild steel in acidic media with a corrosion efficiency exceeding 90%. Since all the studied compounds possess a common molecular backbone (diphenyl sulfide), dapsone was taken as the...
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Antibiotic-sterol interactions provide insight into the selectivity of natural aromatic analogues of amphotericin B and their photoisomers
PublikacjaAromatic heptaene macrolides (AHMs) belong to the group of polyene macrolide antifungal antibiotics. Members of this group were the first to be used in the treatment of systemic fungal infections. Amphotericin B (AmB), a non-aromatic representative of heptaene macrolides, is of significant clinical importance in the treatment of internal mycoses. It includes the all-trans heptaene chromophore, whereas the native AHMs contain two...
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ROYAL CHAPEL IN GDANSK. STUDY OF FACILITY INVENTORY WITH THE USAGE OF LASER SCANNING WITHIN THE FRAMES OF STUDENT PROJECT
PublikacjaThis article presents the photogrammetric works carried out during the architectural inventory of the Royal Chapel in the Main Town of Gdansk (Poland). The facility has the status of a monument of architecture and since decades it is covered by geodetic monitoring, realized with the participation of the Department of Geodesy of Faculty of Civil and Environmental Engineering of Gdańsk University of Technology . For several years,...
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Percepcja jakości usług zdrowotnych w ujęciu relacyjnym
PublikacjaW artykule zostały zaprezentowane podstawowe aspekty dotyczące jakości usług zdrowotnych. Autor odniósł się do głównych grup interesariuszy tego typu usług, a nastepnie zaprezentował model powiązań pomiędzy tego typu grupami a pacjentem. Zaprezentowane zostały także badania związane z głównymi determinantami jakości usług zdrowotnych w percepcji pacjentów, odnosząc się jednocześnie do ich oczekiwań względem poszczególnych grup...
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The II phase metabolism of endogenous and exogenous compounds, including antitumor chemotherapeutics
PublikacjaThe II phase metabolism, it is a set of metabolism and excretion pathways of endogenous as well as exogenous compounds including xenobiotics. UDP-glucuronyltransferases (UGTs; EC 2.4.1.17) are the most crucial representatives of II phase enzymes, which are responsible for the transformation of bilirubine and bile acids, steroids and thyroid hormones and lipids. Exogenous compounds, including drugs, carcinogens, environmental pollutants...
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Aktualne zagadnienia stosowania kanalizacyjnej studzienki rewizyjnej. Cz. III
PublikacjaZagadnienia szczególnych wymagań charakterystycznych dla grup konstrukcji. Problemy, konsekwencje. Charakterystyczne przykłady awarii.
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Nietypowe próbne obciążenia pali prefabrykowanych
PublikacjaOsiadanie grup palowych wciąż stanowi problem naukowy i inżynierski. Dotyczy to również małych grup palowych, dla pali usytuowanych w jednym rzędzie. W pracy przedstawiono wyniki próbnych obciążeń statycznych dwóch pali. W programie badawczym wykonano testy dla obu pali łącznie oraz oddzielnie. Różna charakterystyka krzywych osiadania wymaga dalszych weryfikacji przy uwzględnieniu zmiennych parametrów geotechnicznych i geometrycznych.
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Badanie stabilności prepolimerów estrouretanowych
PublikacjaPrepolimery estrouretanowe otrzymywano na podstawie oligoeestrolu ("Poles 55/20) i użytego w nadmiarze 4,4-iizocyjanianodifenylometanu. Określono wpływ szybkości obrotów trzpienia wiskozymetru, temperatury, procentowej zawartości grup NCO na wartości lepkości tych produktów. Oceniono stabilność prepolimerów w toku przechowywania w ciągu 4 tygodni (zmiana zawartości grup NCO). Budowę chemiczną uzyskanych prepolimerów ustalono...
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Motyw autonomii a oczekiwany i faktyczny poziom satysfakcji z prowadzenia działalności gospodarczej
PublikacjaMotyw autonomii jest niejednokrotnie wskazywany jako jeden z istotniejszych czynników skłaniających ludzi do założenia własnej działalności gospodarczej, choć nie dla każdego przedsiębiorcy jest równie ważny. W opracowaniu zaprezentowano wyniki badań przeprowadzonych w grupie początkujących przedsiębiorców. Osoby deklarujące kierowanie się motywem autonomii oczekiwały, że uzyskają wyższy poziom satysfakcji po roku prowadzenia działalności...
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Efficient removal of 2,4,6-trinitrotoluene (TNT) from industrial/military wastewater using anodic oxidation on boron-doped diamond electrodes
PublikacjaWith growing public concern about water quality particular focus should be placed on organic micropollutants, which are harmful to the environment and people. Hence, the objective of this research is to enhance the security and resilience of water resources by developing an efficient system for reclaiming industrial/military wastewater and protecting recipients from the toxic and cancerogenic explosive compound – 2,4,6-trinitrotoluene...
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Substancje groźne, niebezpieczne i pożyteczne. Tom 2. Związki organiczne
PublikacjaStreszczenie W drugim tomie prezentowanej książki przedstawione zostały informacje nt. związków organicznych, ich występowania, otrzymywania, właściwości oraz zagrożeń jakie one stwarzają, a także korzyści, jakich dostarczają. Do związków organicznych zaliczane są te substancje, które zawierają atom lub atomy węgla, z pewnymi wyjątkami (szczegóły w książce). Szacunkowo, liczba znanych związków organicznych sięga kilkudziesięciu...
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Using phase of short-term Fourier transform for evaluation of spectrogram performance
PublikacjaThe concept of spectrogram performance evaluation which exploits information on phase of short-term Fourier transform (STFT) is presented. A spectrograph which is time-frequency analyzing tool, is compared to a filter bank that demultiplexes a signal. Local group delay (LGD) and channelized instantaneous frequency (CIF) is obtained for each filtered component signal. In presented solution the performance is evaluated using so-called...
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Emotion Recognition Based on Facial Expressions of Gamers
PublikacjaThis article presents an approach to emotion recognition based on facial expressions of gamers. With application of certain methods crucial features of an analysed face like eyebrows' shape, eyes and mouth width, height were extracted. Afterwards a group of artificial intelligence methods was applied to classify a given feature set as one of the following emotions: happiness, sadness, anger and fear.The approach presented in this...
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Computational intelligence methods in production management
PublikacjaThis chapter presents a survey of selected computational intelligence methods used in production management. This group of methods includes, among others, approaches based on the artificial neural networks, the evolutionary algorithms, the fuzzy logic systems and the particle swarm optimization mechanisms. From the abovementioned methods particularly noteworthy are the evolutionary and the particle swarm algorithms, which are successfully...
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Emotion Recognition Based on Facial Expressions of Gamers
PublikacjaThis article presents an approach to emotion recognition based on facial expressions of gamers. With application of certain methods crucial features of an analyzed face like eyebrows' shape, eyes and mouth width, height were extracted. Afterwards a group of artificial intelligence methods was applied to classify a given feature set as one of the following emotions: happiness, sadness, anger and fear. The approach presented in this...
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The homometallic warwickite V 2 OBO 3
PublikacjaThe synthesis, structure and elementary magnetic characterization of the homometallic warwickite V2OBO3 are reported. The material adopts the orthorhombic warwickite structure type at room temperature, space group Pnma (No. 62) with lattice parameters a = 9.2317(1) Å, b = 3.1172(1) Å, and c = 9.5313(1) Å. Temperature-dependent magnetic susceptibility, electrical resistivity, and specific heat measurements show anomalies near 35 K,...
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Badanie stabilności chemicznej prepolimerów etero-uretanowych
PublikacjaPrepolimery eterouretanowe otrzymywano na podstawie oligoeterolu (Rokopolu D2002 lub PTMG 1000) i użytego w nadmiarze 4,4-diizocyjanianodifenylometanu. Określono wpływ szybkości obrotów trzpienia wiskozymetru, temperatury, procentowej zawartości grup NCOoraz rodzaju użytego oligoeterolu na lepkość otrzymanych produktów. Oceniono stabilność omawianych prepolimerów w toku przechowywania ich w ciągu 4 tygodni (zmiana zawartości...
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Electrochemical synthesis and characterization of nanocomposites based on poly(3,4-ethylenedioxythiophene) and functionalized carbon nanotubes
PublikacjaThis work is focused on new composite materials consisting of poly(3,4-ethylenedioxythiophene) (pEDOT) and functionalized multi-walled carbon nanotubes synthesized electrochemically. Three types of composites were synthesized: the first one containing carbon nanotubes with carboxyl groups (covalent functionalization), the second one containing oxidized carbon nanotubes ox-MWCNTs (with different oxygen-rich polar groups) (covalent...
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Deposition and characterization of organic polymer thin films using a dielectric barrier discharge with different C2Hm/N2 (m = 2, 4, 6) gas mixtures
PublikacjaOrganic polymer thin films have been deposited on Si(100) and aluminum coated glass substrates by a dielectric barrier discharge (DBD) operated at medium pressure using different C2Hm/N2 (m = 2, 4, 6) gas mixtures. The deposited films were characterized by various spectroscopic techniques. Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS) revealed the chemical functional groups present in the films. The surface...
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International architectural - urban - landscape design workshops to strengthen students’ education, capabilities and mobility
PublikacjaFive international architectural/urban/landscape workshops in Poland and Portugal between 2011 and 2015 are discussed in this article. The general aims of the workshops were to plan to connect divided city spaces, to harmonise them and make them attractive for different uses. The main task was to create in multicultural groups of students the vision of sustainable development in the context of architecture, urban and landscape...
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Upward convergence patterns in chosen environmental-related SDGs
PublikacjaSustainable development is a challenge facing humanity. EU countries not only strive to reach their specific objectives, but they also work collaboratively towards shared goals. There is a need to balance synergies and compromises to address these objectives effectively. When discussing countries' development and people's well-being, one often focuses on socio-economic development. However, it is crucial not to overlook the environmental...
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Chemical Pressure Tuning Magnetism from Pyrochlore to Triangular Lattices
PublikacjaGeometrically frustrated lattices combined with magnetism usually host quantum fluctuations that suppress magnetic orders and generate highly entangled ground states. Three-dimensionally (3D) frustrated magnets generally exist in the diamond and pyrochlore lattices, while two-dimensionally (2D) frustrated geometries contain Kagomé, triangular, and honeycomb lattices. In this work, we reported using chemical pressure to tune the magnetism...
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Soft-mode enhanced type-I superconductivity in LiPd2Ge
PublikacjaThe synthesis, crystal structure, and physical properties (magnetization, resistivity, heat capacity) in combination with theoretical calculations of the electronic structure and phonon properties are reported for intermetallic compounds LiPd2X (X = Si, Ge, and Sn). LeBail refinement of powder x-ray diffraction data confirms that all compounds belong to the Heusler family (space group Fm-3m, No. 225). The lattice parameter increases...
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Electrical properties and structure of lead-borate glass containing iron ions.
PublikacjaThe ac and dc conductivity in iron–lead-borate glass samples was investigated in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by the means of atomic force microscopy (AFM) and the crystalline phases (if present) were identified by the means of X-ray diffractometry. Two types of ac electrical behaviour were observed. The first group of glass samples which...
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Psychosocial risks associated with the profession of train driver
PublikacjaExcellent competencies as well as a good physical and mental health are required in train drivers’ profession. Despite the changes in the structure of employment the train drivers above 46 years and job tenure longer than 30 years are the largest group. The generation gap is becoming more pronounced, and its fulfilment will not be easy. It is related not only to training of new personnel but also promotion of healthy work environment...
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Evaluation of flavour profiles in e-cigarette refill solutions using gas chromatography–tandem mass spectrometry
PublikacjaMany flavour compounds that are present in e-liquids for e-cigarettes are responsible for specific tastes and smoking sensations for users. Data concerning content and specific types of flavours is often limited and unknown to users. The aim of the research was to define and compare flavour profiles of e-liquids with the same group taste from different manufacturers. Gas chromatography coupled with tandem mass spectrometry (GC–MS/MS)...
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Grupy producenckie jako beneficjenci restrukturyzacji rynków rolnych
PublikacjaW artykule przedstawiono zagadnienie integracji rynku na przykładzie funkcjonowania grup producenckich na rynkach rolnych, ze szczególnym uwzględnieniem roli producentów zbóż. Grupy producenckie ze względu na swoje zalety są ważnym podmiotem wokół którego można by stworzyć dobrze funkcjonujący system skupu i przechowalnictwa zbóż. Grupy producenckie działając w otoczeniu instytucjonalnym agrobiznesu są w kręgu oddziaływania różnych...