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Water uptake kinetics and electrical transport in BaCe0.6Zr0.2Y0.1M0.1O3−δ (M = Tb, Pr, Fe) protonic conductors
PublikacjaBaCe0.6Zr0.2Y0.1M0.1O3−d (M = Fe, Pr, Tb) is a mixed conducting oxide in which three mobile charge carriers – oxygen ion, electron/hole, and protonic defects – are present. These types of materials have gained much interest as electrode materials for protonic ceramic fuel cells (PCFCs) and protonic ceramic electrolysis cells (PCECs). In this study, the water uptake and oxygen transport properties of different BaCe0.6Zr0.2Y0.1M0.1O3−d...
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Studies on the charge density distribution in p-substituted phenylnitrenium cation
PublikacjaAniline and its derivatives are known to be mutagenic. This activity is caused by the formation of phenylnitrenium cations during aniline oxidation. Reactivity of the positively charged chemical species can be measured by means of s+ substituent constant. In this paper charge density distribution in p-substituted nitrenium cations and reactivity indices such as, hardness η, electronegativity χ , and electrophilicily ω were analyzed....
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Concrete-domain reasoning techniques in knowledge cartography
PublikacjaWiele zjawisk w świecie rzeczywistym opisujemy korzystając z liczb i symboli. W ramach naszej pracy jako punkt wyjścia traktujemy podejście kartograficzne opracowane na potrzeby wnioskowania z ontologii opartych na logice opisowej i pozwalające na efektywne przetwarzanie baz wiedzy zwierających dużą liczbę osobników. Niniejszy artykuł przedstawia rozszerzenie podejścia kartograficznego pozwalające na wnioskowanie z wartości symbolicznych,...
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Affronter la distance et la séparation : l'utilisation des médias sociaux par les migrants dans leurs relations interpersonnelles
PublikacjaL'augmentation progressive de la mobilité, de l'interconnectivité et de l'instabilité, la transformation du travail et de l'emploi et celle de la communication (Castells, 2010) ont contribué à l’émergence d’une déracinés et séparés de leur foyer évoluent vers de nouvelles perspectives les migrants comme des sujets mobiles et interconnectés qui, grâce aux TIC, peuvent entretenir des relations et des connexions à distance les...
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Failure analysis of a high-speed induction machine driven by a SiC-inverter and operating on a common shaft with a high-speed generator
PublikacjaDue to ongoing research work, a prototype test rig for testing high-speed motors/generators has been developed. Its design is quite unique as the two high- speed machines share a single shaft with no support bearings between them. A very high maximum operating speed, up to 80,000 rpm, was required. Because of the need to minimise vibration during operation at very high rotational speeds, rolling bearings were used. To eliminate...
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Production of six-degrees-of-freedom (6DoF) navigable audio using 30 Ambisonic microphones
PublikacjaThis paper describes a method for planning, recording, and post-production of six-degrees-of-freedom audio recorded with multiple 3rd order Ambisonic microphone arrays. The description is based on the example of recordings conducted in August 2020 with the Poznan Philharmonic Orchestra using 30 units of Zylia ZM-1S. A convenient way to prepare and organize such a big project is proposed – this involves details of stage planning,...
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EXPERIMENTAL AND NUMERICAL INVESTIGATION ON SPECIMEN GEOMETRY EFFECT ON THE CTOD VALUE FOR VL-E36 SHIPBUILDING STEEL
PublikacjaThere are special cases in the marine industry, where additional material tests, such as the fracture toughness test, must be performed. Additional fracture toughness tests, such as CTOD (Crack Tip Opening Displacement), are typically performed on three-point bend specimens. The dimension that defines all the specimen dimensions is the thickness of the material to be tested. It is recommended by classification societies (e.g. DNVGL)...
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Bifractal receiver operating characteristic curves: a formula for generating receiver operating characteristic curves in credit-scoring contexts
PublikacjaThis paper formulates a mathematical model for generating receiver operating characteristic (ROC) curves without underlying data. Credit scoring practitioners know that the Gini coefficient usually drops if it is only calculated on cases above the cutoff. This fact is not a mathematical necessity, however, as it is theoretically possible to get an ROC curve that keeps the same Gini coefficient no matter how big a share of lowest...
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The Opening of Central and Eastern European Countries to Free Trade: A Critical Assessment
PublikacjaThree decades after the fall of the Berlin wall and one and a half decades after the Big Bang enlargement of the European Union (2004-2007), we revisit contrasting narratives about the benefit of both free trade and the EU enlargement for Central and Eastern European (CEE) countries. We distinguish old, pre-2004 EU countries from CEE countries that joined the EU in 2004-2007, as well as from the CEE countries that have not become...
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Price bubbles in commodity market – A single time series and panel data analysis
PublikacjaThis paper examines thirty-five commodities, grouped into three market sectors (energy, metals, agriculture & livestock) in terms of the occurrence of price bubbles. The study was based on monthly data for each commodity separately and, in a panel approach, for selected sectors and for all commodities combined. The GSADF test and its version for panel data – panel GSADF – were used to identify bubbles. The beginning and end of...
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Influence of Road Wetness on Tire-Pavement Rolling Resistance
PublikacjaRolling resistance of tires is one of the most important factors influencing energy consumption of road vehicles, especially on rural roads. For practical reasons, most of rolling resistance measurements are usually performed for dry road conditions. Based on the fact that roads are wet during a considerable time over the year and as part of the projects MIRIAM, ROLRES and ROSANNE, the TUG (Technical University of Gdańsk) in Poland...
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Heterogeneity of quaternary structure of glucosamine-6-phosphate deaminase from Giardia lamblia
PublikacjaThe oligoHis-tagged versions of glucosamine-6- phosphate deaminase from Giardia lamblia (GlmNagB-HisN, GlmNagB-HisC) were constructed and purified to hear homogeneity, and their kinetic and structural properties were compared to those of the wild-type enzyme (GlmNagB). Introduction of the oligoHis tag at the GlmNagB C-terminus resulted in almost complete loss of the catalytic activity, while the catalytic properties of GlmNagB-HisN...
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Expression of Deinococcus geothermalis Trehalose Synthase Gene in Escherichia coli and Its Enzymatic Properties
PublikacjaA novel trehalose synthase gene from Deinococcus geothermalis (DSMZ 11300) containing 1,692 bp reading-frame encoding 564 amino acids was amplified using PCR. The gene was ligated into pET30Ek/LIC vector and expressed after isopropyl alfa-D-thiogalactopyranoside induction in Escherichia coli BL21(DE3)pLysS. The recombinant trehalose synthase (DgeoTreS) containing a His6 tag at the C-terminus was purified by metal affinity chromatography...
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The significance of the properties of water for the working cycle of the kinesin molecular motor
PublikacjaExplicit solvent molecular dynamics simulations were performed in this study to investigate and discuss several aspects of the influence of the properties of water on the working cycle of a molecular motor from the kinesin superfamily. The main objects of attention were: the binding of the neck linker and the association of the kinesin and the tubulin. The docking of the neck linker is considered a crucial event during the working...
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Speciation of heavy metal compounds in samples of biota from marine ecosystems
PublikacjaIt has become increasingly evident that the toxicity, mobility, bioavailability and bioaccumulation of metals are dependent on the particular physico-chemical form in which the element occurs in the environment. Special attention is paid to metals, which are essential for the proper functioning of organisms if present in appropriate amounts but are toxic if in excess (i.e. Se, Cr, Zn), and also to non-essential elements (i.e. Hg,...
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THE THERMODYNAMIC ANALYSIS OF THE SZEWALSKI HIERARCHIC VAPOUR CYCLE COOPERATED WITH THE SYSTEM OF HEAT RECOVERY
PublikacjaIn this paper, thermodynamic analysis of the Szewalski hierarchic vapour cycle cooperated with the system of heat recovery from exhaust gases are presented. According to that purpose, the CFM (Computation Flow Mechanics [1,3]) approach has correctly been used. The whole system consists of the first traditional steam cycle, the second organic Rankine cycle (ORC) and system of heat recovery with use of water with temperature 90...
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Hydrographic echosounder for sounding inland waters.
PublikacjaNowy model echosondy zaprojektowanej specjalnie dla instytucji administrującymi śródlądowymi drogami wodnymi, sztucznymi i naturalnymi zbiornikami oraz morskimi wodami przybrzeżnymi jest opisany. Podstawowym wymogiem wynikającym z sondażu wód płytkich jest pomiar możliwie najmniejszych głębokości. Przez zastosowanie oddzielnych przetworników (nadawczego i odbiorczego) i ich wytłumienie oraz przez wprowadzenie układu TVG o dużej...
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Bio-inspired Decisional DNA in Machinas and other Man-made Systems: The Way Forward
PublikacjaArtificial bio-inspired intelligent techniques and systems supporting smart, knowledge-based solutions of real world problems which are currently researched very extensively by research teams around the world, have enormous potential to enhance automation of decision making and problem solving for a number of diverse areas including design, manufacturing, Information Technology (IT), social communities of practice, and economics...
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Analysis of Signalized Intersections in the Context of Pedestrian Traffic
PublikacjaGdynia is a city in the Pomeranian Voivod e ship of Poland with a population of about 250,000. It faces a growing motorization rate th at needs to be addressed. Car ownership in Gdynia now exceed s 500 vehicles per 1000 residents. Travel by public transport is decreasing and the rate of walking and cycling remains low. It is necessary to reverse these negative trends by implementing solu tions based...
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Stabilność napięciowa podsystemu elektroenergetycznego
PublikacjaW referacie przedstawiono problem przeciążenia mocą bierną systemu elektroenergetycznego oraz metodologię analiz stabilności napięciowej podsystemów elektroenergetycznych. W celu potwierdzenia przyjętych założeń wykonano obliczenia symulacyjne stabilności napięciowej dla podsystemu. W badaniach analizowano dociążenia mocą czynną, mocą bierną oraz mocą z utrzymaniem wyjściowego tg(fi) pojedynczych węzłów oraz podsystemów. Uzyskane...
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Environmental degradation of titanium alloy in artificial saliva
PublikacjaThe titanium and its alloys are potentially prone to hydrogen embrittlement, including those proposed for dental implants. The research has been aimed to assess a susceptibility to environment-enhanced degradation of the Ti-13Zr-13Nb alloy in artificial saliva with or without hydrofluoric acid, subject or not to cathodic polarisation. The results have shown that even if artificial saliva is safe environment, both cathodic polarization...
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Reactions of solute species at an electrode modified with titanocene functionalized polypyrrole film: ferrocene and titanocene dichloride
PublikacjaPo raz pierwszy zbadano możliwość intermediacji ładunku poprzez centra tytanocenowe polimeru modyfikowanego chemicznie związanymi grupami dichloro tytanocenowymido polipirolu. Badano reakcje elektrodowe ferrocenu i dichlorotytanocenu. Wykazano aktywność elektrodową w zakresie potencjałów redoks pary Ti(IV/TiIII)w stosunku do reakcji redoks ferrocenu i reakcji dichlorotytanocenu. Wykazano, że centra TcCl2 polimeru są zadowalająco...
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Interactions between components of SrTi0.98 Nb0.02O3-δ-YSZ and SrTi0.98 Nb0.02O3-δ -CeO2 composites
PublikacjaComposites consisting of SrTiO3-based perovskite and either yttria-stabilized zirconia or ceria were investigated. The mechanical compatibility and possible inter-diffusion between phases were characterized by scanning electron microscopy, X-ray diffraction, and energy-dispersive X-ray spectroscopy. A gradual disappearance of Ce-containing phases with an increase in the temperature of reduction in hydrogen was noticed. Moreover,...
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Structure and water uptake in BaLnCo2O6−δ (Ln =La, Pr, Nd, Sm, Gd, Tb and Dy)
PublikacjaThe structure of BaLnCo2O6-δ (Ln =La, Pr, Nd, Sm, Gd, Tb and Dy) was studied by the means of synchrotron radiation powder X-ray diffraction, neutron powder diffraction and Transmission Electron Microscopy (TEM), while water uptake properties were analysed with the use of thermogravimetry (TG) and water adsorption isotherms. The structure refinement revealed that the dominant phase in all compositions was orthorhombic with an ordering...
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Optimization of carbamazepine photodegradation on defective TiO2-based magnetic photocatalyst
PublikacjaIn this work, carbamazepine (CBZ) degradation over defective Fe3O4@SiO2/d-TiO2/Pt photocatalyst was studied. Within the titania structure, Ti vacancies and Pt nanoparticles were introduced to enhance the photocatalyst’s light absorption and influence charge carriers’ mobility. For the carbamazepine degradation, process parameters, e.g., temperature, flux intensity, photocatalyst loading, aeration, pH, and addition of H2O2, were optimized...
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Cadmium complex possessing simultaneously silanethiolato- and dithiocarbamato-ligands. A novel single-source precursor of cadmium sulfide
PublikacjaThermal decomposition of suitable coordination compounds may be used as efficient route for fabrication of semiconducting layers. A new potential CdS precursor—a cadmium complex with all-sulfur Cd-coordination sphere [Cd{l-SSi(OBut)3}(S2CNC4H8)]2 (1) —has been prepared and its properties are investigated. The complex was obtained in the reaction between dimeric bis(tri-tert-butoxysilanethiolato) cadmium(II) [Cd{SSi(OBut)3}2]2 and...
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The bile salt/phospholipid ratio determines the extent of in vitro intestinal lipolysis of triglycerides: Interfacial and emulsion studies
PublikacjaThis study focused on the protein-stabilised triglyceride (TG)/water interfaces and oil-in-water emulsions, and explored the influence of varying molar ratios of bile salts (BSs) and phospholipids (PLs) on the intestinal lipolysis of TGs. The presence of these two major groups of biosurfactants delivered with human bile to the physiological environment of intestinal digestion was replicated in our experiments by using mixtures...
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Consensus conference: Implementing treatment recommendations on yttrium-90 immunotherapy in clinical practice – Report of a European workshop
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Evaluation of Machine Learning Methods for the Experimental Classification and Clustering of Higher Education Institutions
PublikacjaHigher education institutions have a big impact on the future of skills supplied on the labour market. It means that depending on the changes in labour market, higher education institutions are making changes to fields of study or adding new ones to fulfil the demand on labour market. The significant changes on labour market caused by digital transformation, resulted in new jobs and new skills. Because of the necessity of computer...
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Charakterystyka frakcji oleju palmowego otrzymanych na drodze wielostopniowej krystalizacji
PublikacjaPrzeprowadzono wielostopniową frakcjonowaną krystalizację oleju palmowego z acetonu. Stosując temperatury krystalizacji od 25 do 0C, otrzymano siedem frakcji znacznie różniących się budową chemiczną i właściwościami fizycznymi. We frakcjach oznaczono skład kwasów tłuszczowych metodą GLC oraz zawartość triacylogliceroli metodą HPLC. Zbadano też właściwości fizyczne otrzymanych frakcji. Oznaczono zawartości fazy stałej metodą pulsacyjnego...
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Parametric Study on a Performance of a Small Counter-Rotating Wind Turbine
PublikacjaA small Counter-Rotating Wind Turbine (CRWT) has been proposed and its performancehas been investigated numerically. Results of a parametric study have been presented in this paper.As parameters, the axial distance between rotors and a tip speed ratio of each rotor have been selected.Performance parameters have been compared with reference to a Single Rotor Wind Turbine (SRWT).Simulations were carried out with Computational Fluids...
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Corrugated Sheeting as a Member of a Shear Panel Under Repeated Load—Experimental Test
PublikacjaIn stressed-skin design, the cladding stiffening effect on structures is taken into account. However, the “traditional” design is more usual, wherein this effect is neglected. Even if the diaphragm actions are not regarded, in particular cases such as big sheds (and others), the parasitic (unwanted) stressed-skin action may occur with the result of leakage or even failure. The structures of this kind have already been built. Thus,...
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Actual field corrosion rate of offshore structures in the Baltic Sea along depth profile from water surface to sea bed
PublikacjaThe paper presents the results of field electrochemical investigations on the corrosion rate of carbon steel in seawater of the Baltic Sea at the location of the Baltic Beta production rig. The measurements were conducted throughout the year in seawater at different depths from the sea surface to the sea bed (about 75 m). The results revealed corrosion aggressiveness of the seawater along the entire depth profile. There was...
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Computer support of analysis optical spectra measurements
PublikacjaVerification of measurement errors has a big impact on assessment of accuracy of conducted measurements and obtained results. In many cases computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with Fabry-Perot interferometer working in the transmission mode. In measurement setup, a 1310 nm superluminescent...
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Computer Support of Analysis of Optical Spectra Measurements
PublikacjaThe verification of measurement errors has a big impact on the assessment of the accuracy of conducted measurements and obtained results. In many cases, computer simulation results are compared with measurement results in order to evaluate measurement errors. The purpose of our research was to check the accuracy of measurements made with a Fabry–Perot interferometer working in the transmission mode. In the measurement setup, a...
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Removal of Siloxanes from Model Biogas by Means of Deep Eutectic Solvents in Absorption Process
PublikacjaThe paper presents the screening of 20 deep eutectic solvents (DESs) composed of tetrapropylammonium bromide (TPABr) and glycols in various molar ratios, and 6 conventional solvents as absorbents for removal of siloxanes from model biogas stream. The screening was achieved using the conductor-like screening model for real solvents (COSMO-RS) based on the comparison of siloxane solubility in DESs. For the DES which was characterized...
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Pressure effects on the electronic structure and superconductivity of (TaNb)0.67(HfZrTi)0.33 high entropy alloy
PublikacjaEffects of pressure on the electronic structure, electron-phonon interaction, and superconductivity of the high entropy alloy ( TaNb ) 0.67 ( HfZrTi ) 0.33 are studied in the pressure range 0–100 GPa. The electronic structure is calculated using the Korringa-Kohn-Rostoker method with the coherent potential approximation. Effects of pressure on the lattice dynamics are simulated using the Debye-Grüneisen model and the Grüneisen...
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Explanation of Reduction of Pressure Forces in Turbine Chamber Seals
PublikacjaThe paper describes a chamber seal reducing the aerodynamic forces created in shroud seals. Asymmetrical pressure distribution (due to rotor-stator eccentricity) in the blade tip clearance leads to the creation of pressure forces acting on the blade shroud. By increasing the volume above the shroud, the pressure distribution becomes more uniform on the whole shroud circumference and the effect of rotor eccentricity is reduced....
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Accurate rolling resistance Rolling resistance measurements can be influenced by a number of factors
PublikacjaTire rolling resistance is one of the most difficult-to-measure parameters of the tire/ pavement interface, especially if road measurements are required. First of all, it is necessary to measure a fairly small force in the system that is heavily loaded by other forces and subjected to many adverse effects causing measurement errors. The second problem is related to the fact that tire rolling resistance depends on many factors,...
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THE EFFECT OF NOTCH DEPTH ON CTOD VALUES IN FRACTURE TESTS OF STRUCTURAL STEEL ELEMENTS
PublikacjaIn elements of steel structures working at low temperatures, there is a risk of appearance of brittle fracture. This risk is reduced through the use of certified materials having guaranteed strength at a given temperature. A method which is most frequently used to determine brittle fracture toughness is the Charpy impact test, preformed for a given temperature. For offshore structures intended to work in the arctic climat e, the...
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Service time distribution influence on end-to-end call setup delay calculation in networks with Session Initiation Protocol
PublikacjaThe most important GoS parameter for networks with SIP protocol is end-to-end call setup delay. So far there were no coherent models allowing calculation of these parameters for networks with SIP protocol. Few models were developed but they are insufficient. In the paper we propose model which allows end-to-end call setup delay calculation for networks with SIP protocol. The model is using chain of M/G/1/K models and is applicable...
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Reaktywność wybranych siarkowych i selenowych pochodnych kwasu fosforowego
PublikacjaKilka lat temu byliśmy w stanie zademonstrować, nowa reakcję redukcji wiązania N-O pod wpływem anionu kwasu tio oraz seleno fosforowego, biegnącą mechanizmem SET. W toku dalszych naszych prac ustaliliśmy, że kwas ditiofosforowy jest donorem zarówno protonu jak i atomu wodoru, natomiast anion kwasu ditiofosforowego jest doskonałym nukleofugiem oraz donorem pojedynczego elektronu. W kolejnym etapie badań stwierdziliśmy, że zarówno...
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Borders of Digital Art in the Context of the Information Society
PublikacjaThe article shows the relationship between the development of information technologies, the characteristics of the information society and digital art. The broad possibilities of the digital world related to recording, storing and processing data (cyber text, big data, smart services) and the creation of virtual worlds are pointed out. The influence of the development of information technologies on the character of the works of...
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Social media and efficient computer infrastructure in smart city
PublikacjaSocial media require an efficient infrastructures of computer and communication systems to support a smart city. In a big city, there are several crucial dilemmas with a home and public space planning, a growing population, a global warming, carbon emissions, a lack of key resources like water and energy, and a traffic congestion. In a smart city, we expect an efficient and sustainable transportation, efficient management of resources...
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Methylmercury and total mercury content in soft tissues of two bird species wintering in the Baltic Sea near Gdansk, Poland
PublikacjaOf the various forms of Hg occurring in nature, (mono) methylmercury (MeHg) is an especially toxic form and practically all forms of Hg can be converted into MeHg as a result of natural processes. Total mercury (THg) and MeHg were determined in tissues of two piscivorous birds: razorbill Alca torda and black-throated loon Gavia arctica to provide baseline data on current mercury concentrations for liver, kidneys and pectoral muscle...
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Explanation of Reduction of Pressure Forces in Turbine Chamber Seals
PublikacjaThe paper describes a chamber seal reducing the aerodynamic forces created in shroud seals. Asymmetrical pressure distribution (due to rotor-stator eccentricity) in the blade tip clearance leads to the creation of pressure forces acting on the blade shroud. By increasing the volume above the shroud, the pressure distribution becomes more uniform on the whole shroud circumference and the effect of rotor eccentricity is reduced....
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Nonlinear Modeling in Time Domain Numerical Analysis of Stringed Instrument Dynamics
PublikacjaMusical instruments are very various in terms of sound quality with their timbre shaped by materials and geometry. Materials' impact is commonly treated as dominant one by musicians, while it is unclear whether it is true or not. The research proposed in the study focuses on determining influence of both these factors on sound quality based on their impact on harmonic composition. Numerical approach has been chosen to allowed independent...
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Technical Engine for Democratization of Modeling, Simulations, and Predictions
PublikacjaComputational science and engineering play a critical role in advancing both research and daily-life challenges across almost every discipline. As a society, we apply search engines, social media, and se- lected aspects of engineering to improve personal and professional growth. Recently, leveraging such aspects as behavioral model analysis, simulation, big data extraction, and human computation is gain- ing momentum. The nexus...
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Preparation and Characterization of Microsphere ZnO ALD Coating Dedicated for the Fiber-Optic Refractive Index Sensor
PublikacjaWe report the fabrication of a novel fiber-optic sensor device, based on the use of a microsphere conformally coated with a thin layer of zinc oxide (ZnO) by atomic layer deposition (ALD), and its use as a refractive index sensor. The microsphere was prepared on the tip of a single-mode optical fiber, on which a conformal ZnO thin film of 200 nm was deposited using an ALD process based on diethyl zinc (DEZ) and water at 100 °C....
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Experimental Verification of the CFD Model of the Squeeze Film Lifting Effect
PublikacjaAbstract: The presented study shows the results of the research into the squeeze film levitation phenomena. The system introduced in the investigation is composed of a vibrating surface, air squeeze film, and the surface of the body freely suspended over the film. The use of the CFD (Computational Fluid Dynamics) model used in the system allows us to determine the steady state, periodic behavior of the air film (described by Navier–Stokes,...