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Search results for: SODIUM DODECYL SULFATE SODIUM 1-ALKYLSULFONATES CRITICAL MICELLE CONCENTRATION MICELLAR AGGREGATION NUMBER THERMODYNAMIC PARAMETERS FLUORESCENCE SPECTROSCOPY CONDUCTIVITY MOLECULAR DYNAMICS
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Empirical Probability Distributions with Unknown Number of Components
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Lower bound on the paired domination number of a tree
PublicationW pracy przedstawione jest ograniczenie dolne dla liczby dominowania parami oraz scharakteryzowane są wszystkie drzewa ekstremalne.
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Graphs with convex domination number close to their order
PublicationW pracy opisane są grafy z liczbą dominowania wypukłego bliską ilości ich wierzchołków.
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Advanced sensitivity analysis of the impact of the temporal distribution and intensity of rainfall on hydrograph parameters in urban catchments
PublicationKnowledge of the variability of the hydrograph of outflow from urban catchments is highly important for measurements and evaluation of the operation of sewer networks. Currently, hydrodynamic models are most frequently used for hydrograph modeling. Since a large number of their parameters have to be identified, there may be problems at the calibration stage. Hence, sensitivity analysis is used to limit the number of parameters....
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Multicomponent ionic liquid CMC prediction
PublicationWe created a model to predict CMC of ILs based on 704 experimental values published in 43 publications since 2000. Our model was able to predict CMC of variety of ILs in binary or ternary system in a presence of salt or alcohol. The molecular volume of IL (Vm), solvent-accessible surface (Sˆ), solvation enthalpy (DsolvGN), concentration of salt (Cs) or alcohol (Ca) and their molecular volumes (Vms and Vma, respectively) were chosen...
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Determination of chlorine concentration using single temperature modulated semiconductor gas sensor
PublicationA periodic temperature modulation using sinusoidal heater voltage was applied to a commercial SnO2 semiconductor gas sensor. Resulting resistance response of the sensor was analyzed using a feature extraction method based on Fast Fourier Transformation (FFT). The amplitudes of the higher harmonics of the FFT from the dynamic nonlinear responses of measured gas were further utilized as an input for Artificial Neural...
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Electrochromic foil-based devices: optical transmittance and modulation range, effect of ultraviolet irradiation,and quality assessment by 1/f current noise
PublicationPrzedstawiono technologię wytwarzania elementów wykazujących zjawisko elektrochromizmu - zmiany transmitancji optycznej pod wpływem gromadzenia ładunku. Pokazano, że zastosowanie warstwy odbijającej może poprawić stopień zmian transmitancji optycznej. Ponadto, pokazano, że zjawiska losowe generujące szum typu 1/f w tych elementach może być wykorzystane do oceny ich jakości.
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Study on the concentration of acids by membrane distillation
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Computational fluid dynamics simulation of heat transfer from densely packed gold nanoparticles to isotropic media
PublicationThis work aims to determine and compare heat generation and propagation of densely packed gold nanoparticles (Au NPs) induced by a resonant laser beam (532 nm) according to the Mie theory. The heat flux propagation is transferred into the materials, which here are: silica glass; soda-lime-silica glass; borosilicate glass; polymethyl methacrylate (PMMA); polycarbonate (PC); and polydimetylosiloxane (PDMS). This analysis aims to...
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Assessment of blood–brain barrier permeability using micellar electrokinetic chromatography and P_VSA-like descriptors
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A multiparameter simulation-driven analysis of ship response when turning concerning a required number of irregular wave realizations
PublicationThe growing implementation of Decision Support Systems on modern ships, digital-twin technology, and the introduction of autonomous vessels cause the marine industry to seek accurate modeling of vessel response. Despite the contemporary 6DOF models can be used to predict ship motions in irregular waves, the impact of their stochastic realization is usually neglected and remains under-investigated. Especially in the case of turning, differences...
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Design and experimental validation of a single-stage PV string inverter with optimal number of interleaved buck-boost cells.
PublicationIncreasing converter power density is a problem of topical interest. This paper discusses an interleaved approach of the efficiency increase in the buck-boost stage of an inverter with unfolding circuit in terms of losses in semiconductors, output voltage ripples and power density. Main trends in the power converter development are reviewed. A losses model was designed and used for the proposed solution to find an optimal number...
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Limitations of Integrative Passive Samplers as a Tool for the Quantification of Pharmaceuticals in the Environment – A Critical Review with the Latest Innovations
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Porównanie wydajności modyfikacji algorytmu Proof-number search uwzględniających wartości remisowe
PublicationProof-number search to znana rodzina algorytmów służących do wyznaczania wartości pozycji w nielosowych grach dwóch graczy z pełną informacją. W wersji podstawowej pn-search doskonale radzi sobie z wyszukiwaniem strategii wygrywającej jednego z graczy. Jednak istnieje wiele znanych gier, w których obydwaj gracze posiadają jedynie strategię remisującą (Młynek, Awari, Warcaby). W niniejszej pracy porównano wydajność dwóch modyfikacji...
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Challenges of modern assessment of safety of ships in critical conditions. Options for preliminary design
PublicationW pracy przedstawiono wyniki badań na temat zastosowania formalnej metody oceny bezpieczeństwa statków w stanie uszkodzonym w stosunku do obecnej metody, opartej na przepisach zawartych w konwencji SOLAS rozdział II-1, części A, B i B-1. Przedstawiono elementy analizy bezpieczeństwa obejmujące identyfikację zagrożeń i scenariuszy wypadków, ocenę zagrożeń, ocenę ryzyka i kontrolę ryzyka. Podano przykłady obliczeniowe i wnioski praktyczne.
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Microwave-Reactor-Based Preparation of Red Iron Oxide Pigment from Waste Iron Sulfate
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Finite Resolution Dynamics
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Endothelial dysfunction due to eNOS uncoupling: molecular mechanisms as potential therapeutic targets
PublicationNitric oxide (NO) is one of the most important molecules released by endothelial cells, and its antiatherogenic properties support cardiovascular homeostasis. Diminished NO bioavailability is a common hallmark of endothelial dysfunction underlying the patho‑ genesis of the cardiovascular disease. Vascular NO is synthesized by endothelial nitric oxide synthase (eNOS) from the substrate L‑arginine (L‑Arg), with tetrahydrobiopterin...
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Noise effect on parameters of quiet sonar with code modulation
PublicationEarlier publications of the paper authors have shown that the use of code keying mixed with the CW FM sound signal allows the significant reduction in the distance measurement error, compared to classic silent CW FM sonar. In addition to the code modulation parameters, the magnitude of this error is influenced by the received input acoustic noise. The article shows the dependence of the input signal-to-noise ratio and the sound...
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Identification of inertia, damping and stiffness parameters for low pressure steam turbine framework.
PublicationW pracy przedstawiono metodę identyfikacji masy tłumienia i sztywności kadłuba części niskoprężnej turbiny parowej 200MW.
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Molecular structures of two E-azobenzocrown ethers
PublicationRentgenowska analiza strukturalna monokryształów posłużyła do scharakteryzowania struktury izomerów E dwóch azobenzokoron: 13- i 16-członowej. Oba związki krystalizują w układzie jednoskośnym. W komórce elementarnej, w każdym przypadku znajdują się dwie niezależne cząsteczki, różniące się konformacją, szczególnie łańcucha eterowego. Porównując konformacje ''wolnych'' makrocykli z konformacjami ich kompleksów z jonami metali wskazano,...
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Minimal number of periodic points of smooth boundary-preserving self-maps of simply-connected manifolds
PublicationLet M be a smooth compact and simply-connected manifold with simply-connected boundary ∂M, r be a fixed odd natural number. We consider f, a C1 self-map of M, preserving ∂M . Under the assumption that the dimension of M is at least 4, we define an invariant Dr(f;M,∂M) that is equal to the minimal number of r-periodic points for all maps preserving ∂M and C1-homotopic to f. As an application, we give necessary and sufficient...
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Systems engineering approach to functional safety and cyber security of industrial critical installations
PublicationThis chapter addresses the systems engineering approach to integrated functional safety and cybersecurity analysis and management regarding selected references, standards and requirements concerning critical installations and their industrial automation and control system (IACS). The objective is to mitigate the vulnerability of industrial installations that include the information technology (IT) and the operational technology...
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Systems engineering approach to functional safety and cyber security of industrial critical installations
PublicationThis chapter addresses the systems engineering approach to integrated functional safety and cybersecurity analysis and management regarding selected references, standards and requirements concerning critical installations and their industrial automation and control system (IACS). The objective is to mitigate the vulnerability of industrial installations that include the information technology (IT) and the operational technology...
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A solid phase extraction–ion chromatography with conductivity detection procedure for determining cationic surfactants in surface water samples
PublicationA new analytical procedure for the simultaneous determination of individual cationic surfactants (alkyl benzyl dimethyl ammonium chlorides) in surface water samples has been developed. We describe this methodology for the first time: it involves the application of solid phase extraction (SPE – for sample preparation) coupled with ion chromatography–conductivity detection (IC-CD – for the final determination). Mean recoveries of...
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Noise sources in Raman spectroscopy of biological objects
PublicationWe present an overview of noise sources deteriorating the quality of the recorded biological Raman spectra and the ability to determine the specimen composition. The acquired Raman spectra exhibit intense additive noise components or drifts because of low intensity of the scattered light. Therefore we have to apply expensive or bulky measurement setups to limit their inherent noise or to apply additional signal processing to reduce...
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X-ray Photoelectron Spectroscopy of Carboxylic Acids as Corrosion Inhibitors of Aluminium Alloys
PublicationThe datasets, titled X-ray Photoelectron Spectroscopy studies of citric acid adsorption on aluminium alloy 5754 in alkaline media and X-ray Photoelectron Spectroscopy studies of various carboxylic acids adsorption on aluminium alloys in alkaline media, contain XPS studies of the corrosion inhibitory action of selected dicarboxylic acids towards commercially available aluminium alloy 5754 in alkaline media at pH=11. These datasets...
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Conductivity of two-dimensional composites with randomly distributed elliptical inclusions
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Conductivity and superconductivity of (Bi,Pb)-Sr-Ca-Cu-O
PublicationAmorficzny materiał (Bi,Pb)4Sr3Ca3Cu4Ox w zależności od warunków wygrzewania może być albo granulastym materiałem albo silnie nieuporządkowanym metalem. Przejście do stanu nadprzewodzącego zachodzi w materiałach, w których Josephsonowskie sprzężenie między granulami jest silniejsze niż oddziaływania Coulombowskie.
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Conductivity and superconductivity of (Bi,Pb)–Sr–Ca–Cu–O
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Electrical conductivity of nanocrystalline Sm-doped CeO2 thin film.
PublicationGęste i nanokrystaliczne filmy tlenku ceru domieszkowane 20% samarem przygotowane na szafirze oraz próbki ceramiczne zostały przygotowane z prekursorów polimerowych. Ich konduktacja elektryczna była badana w funkcji temperatury i skorelowana z wielkością krystalitów. Model blokowo-warstwowy przewiduje mniejszą konduktacje próbki gdy wielkości krystalitów są mniejsze, w przypadku gdy rezystancja obszarów międzyziarnowych jest większa...
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The contribution of blood-flow-induced conductivity changes to measured impedance
PublicationW pracy rozwazane sa zmiany przewodnosci zachodzace w anizotropowym osrodku i ich wplyw na mierzona rezystancje. Uzyskano to za pomoca rozszerzenia wzoru Geselowizta na przypadki anizotropowe. Wykazano, ze tylko te skladowe zmian przewodnosci wplywaja na mierzona rezystancje, dla ktorych odpowiadajacy im skladnik pola eklektrycznego byl niezerowy.Wyniki te zastosowanu do zmian rezystywnosci wywolanych zmiananmi przewodnosci plynacej...
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Identification of plate dynamic parameters for structural health monitoring
PublicationPraca przedstawia technikę wyznaczania parametrów modalnych wykorzystywanych w diagnostyce konstrukcji. Modalna masa, sztywność, tłumienie i postacie drgań wyznaczone są dla prostokątnej stalowej płyty na podstawie badań eksperymentalnych. Teoretyczne parametry modalne otrzymaneo z modelu MES. Omówiony został wpływ dodatkowej masy na parametry modalne konstrukcji.This paper presents a technique for modal parameters estimation for...
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Influence of Protonation State on the Excited State Dynamics of a Photobiologically Active Ru(II) Dyad
PublicationThe influence of ligand protonation on the photophysics of a ruthenium (Ru) dyad bearing the 2-(1-pyrenyl)-1H-imidazo[4,5-f][1,10]-phenanthroline (ippy) ligand was investigated by time-resolved transient absorption spectroscopy. It was found that changes in the protonation state of the imidazole group led to changes in the electronic configuration of the lowest lying excited state. Formation of the fully deprotonated imidazole...
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Characterization of nano-silica vegetable grease with diffusing wave spectroscopy DWS and Raman spectroscopy
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Nonconventional 1,8-Diazafluoren-9-One Aggregates for Green Light Enhancement in Hybrid Biocompatible Media
PublicationOrganic aggregates currently play a prominent role, mainly for their unique optoelectronic properties in the aggregated state. Such properties can be related to the aggregates’ structure and the molecular packing mode. In the literature, we have well-established models of H and J aggregates defined based on the molecular exciton model. However, unconventional aggregates, the most unrecognized forms, have been generating interest...
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SEI Growth and Depth Profiling on ZFO Electrodes by Soft X-Ray Absorption Spectroscopy
PublicationZnFe2O4 (ZFO) Li-ion batteries (LIBs) represent a reliable, affordable, and safe energy storage technology for use in portable application. However, current LIB active materials (graphite, lithium/transition metal spinel or layered oxides, olivine structures) can store only limited energy since they rely on insertion storage based on solid-state host-guest interactions. Moreover, performances and durability of the cells are strongly...
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Spatiotemporal dynamics of the active perirheic zone in a natural wetland floodplain
PublicationAbstract The ecologically and biogeochemically significant perirheic zone is a part of the floodplain where waters originating from both the river and adjacent floodplain are present. In this study, we investigate the spatiotemporal dynamics of the active perirheic zone, i.e. river and floodplain waters and their transient mixing extent. This is achieved by using the Hydraulic Mixing-Cell method, a complement to a fully integrated...
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Molywood: streamlining the design and rendering of molecular movies
PublicationMotivation High-quality dynamic visuals are needed at all levels of science communication, from the conference hall to the classroom. As scientific journals embrace new article formats, many key concepts – particularly in structural biology – are also more easily conveyed as videos than still frames. Notwithstanding, the design and rendering of a complex molecular movie remain an arduous task. Here, we introduce Molywood, a robust...
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Electromagnetic Control and Dynamics of Generalized Burgers’ Nanoliquid Flow Containing Motile Microorganisms with Cattaneo–Christov Relations: Galerkin Finite Element Mechanism
PublicationIn our research work, we have developed a model describing the characteristics of the bio-convection and moving microorganisms in the flows of a magnetized generalized Burgers’ nanoliquid with Fourier’s and Fick’s laws in a stretchable sheet. Considerations have been made to Cattaneo–Christov mass and heat diffusion theory. According to the Cattaneo–Christov relation, the Buongiorno phenomenon for the motion of a nanoliquid in...
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The flux compression generator load parameters selection
PublicationComputer simulation results of the flux compression generator (FCG) loaded with an inductor has been presented in this paper. Simulation research has been performed in order to select the parameters of FCG load coil properly. The influence of the load inductance and resistance on the current gain factor and the magnetic field energy accumulated in a load coil has been investigated.
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Stability of the TinF4n+1− and GenF4n+1− superhalogen anions and the acidity of the HTi F4+1 and HGe F4+1 (n = 1–3) superacids
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A Novel Ru(II) Polypyridine Black Dye Investigated by Resonance Raman Spectroscopy and TDDFT Calculations
PublicationThe optical properties of a new(bipyridine)2Ru(4H-imidazole) complex presenting a remarkablebroad absorption in the visible range are investigated. Thestrong overlap of the absorption with the solar radiationspectrum renders the studied complex promising as a blackabsorber and hence as a starting structure for applications inthe field of dye-sensitized solar cells. The correlations betweenstructural and electronic features for...
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Estimation of the minimal number of periodic points for smooth self-maps of odd dimensional real projective spaces
PublicationLet f be a smooth self-map of a closed connected manifold of dimension m⩾3. The authors introduced in [G. Graff, J. Jezierski, Minimizing the number of periodic points for smooth maps. Non-simply connected case, Topology Appl. 158 (3) (2011) 276-290] the topological invariant NJD_r[f], where r is a fixed natural number, which is equal to the minimal number of r-periodic points in the smooth homotopy class of f. In this paper smooth...
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Influence of hydrochloric acid concentration and type of nitrogen source on the electrochemical performance of TiO2/N-MoS2 for energy storage applications
PublicationIn this work, nitrogen-doped molybdenum sulfide was directly deposited on titanium dioxide nanotubes substrate (TiO2/N-MoS2) during hydrothermal synthesis. The study focuses on the influence of hydrochloric acid concentration used for the synthesis, with the results indicating its essential role in thioacetamide hydrolysis and thus in the effectiveness of the N-MoS2 deposition. The electrode material itself is characterized by...
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Fatty acids as molecular carriers in cleavable antifungal conjugates
PublicationConjugates composed of C2-18 fatty acid (FA) residues as a molecular carrier and 5-fluorocytosine (5-FC) as an active agent, released upon the action of intracellular esterases on the ester bond between FA and “trimethyl lock” intramolecular linker, demonstrate good in vitro activity against human pathogenic yeasts of Candida spp. The minimal inhibitory concentrations (MIC) values for the most active conjugates containing caprylic...
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Absorption spectroscopy setup for determination of whole human blood and blood–derived materials spectral characteristics
PublicationA dedicated absorption spectroscopy system was set up using tungsten-halogen broadband source, optical fibers, sample holder, and a commercial spectrometer with CCD array. Analysis of noise present in the setup was carried out. Data processing was applied to the absorption spectra to reduce spectral noise, and improve the quality of the spectra and to remove the baseline level. The absorption spectra were measured for whole blood...
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The content of biogenic amines in Rondo and Zweigelt wines and correlations between selected wine parameters
PublicationThe purpose of this study was to evaluate the content of biogenic amines (BAs) in wines using dispersive liquid–liquid microextraction–gas chromatography–mass spectrometry (DLLME-GC–MS). An additional objective was to assess the correlations between selected parameters characterizing the samples such as the content of BAs, sugars, and organic acids, pH, and total acidity. Wines produced from the same grape variety in which alcoholic...
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A critical review on electrospun membranes containing 2D materials for seawater desalination
PublicationElectrospun nanofibers are a cutting-edge class of membranes which have been applied in several molecular separations. These membranes can be well designed and tailored due to the versatility of the electrospinning process. Eminently, electrospun membranes, once implemented in membrane processes, are an alternative in removing salts and some other minerals from water, so-called desalination, for producing drinking water. Such membranes...
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Influence of Added Water Mass on Ship Structure Vibration Parameters in Virtual and Real Conditions
PublicationModelling of ship structures in a virtual environment is now standard practice. Unfortunately, many engineers forget to consideri the influence of added water on the frequency values and the amplitude of natural vibrations. The article presents the effect of water damping on the frequency values of the individual natural vibration modes. The tests were carried out in two stages. First, the mentioned values were determined using...