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Search results for: PHOSPHORUS CONTAINING GROUPS
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Triplet Formation and Triplet‐Triplet Annihilation Upconversion in Iodine Substituted Non‐Orthogonal BODIPY‐Perylene Dyads
PublicationBODIPY-perylene dyads have emerged as useful metal free sensitizers for triplet-triplet annihilation upconversion (TTAUC), these dyads are capable of efficient triplet generation via spinorbit charge transfer intersystem crossing (SOCT-ISC). This important route to triplet formation requires dyads in which two moieties are oriented perpendicular to each other. In this contribution, we give a deeper insight on the behavior of recently...
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Analysis of friction ridge evidence for trace amounts of paracetamol in various pharmaceutical industries by Raman spectroscopy
PublicationThe detection of potentially harmful substances presents a multifaceted challenge. On one hand, it can directly save lives, on the other, it can significantly aid and enhance police work, thereby increasing the effectiveness of investigations. The research conducted in this study primarily aims to identify paracetamol in fingerprints, considering situations involving direct contact of a person with paracetamol either chronically...
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New Transparent Flame-Retardant (FR) Coatings Based on Epoxy-Aluminum Hypophosphite Nanocomposites
PublicationThe present study investigated the flame-retardant (FR) effect of transparent epoxy coating containing aluminum hypophosphite (AHP) nanoparticles (NPs) on polylactic acid (PLA) sheets used as a typical model of combustible polymeric material. First, AHP NPs (≤60 nm) were prepared by a specific two-stage wet milling process and deeply analyzed (morphology, thermal/mechanisms of degradation under nitrogen and air). The thermal properties...
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Effect of oxidation and in vitro intestinal hydrolysis on phospholipid toxicity towards HT29 cell line serving as a model of human intestinal epithelium
PublicationOxidation of food-derived phospholipids (PLs) can influence nutrient digestion and induce oxidative stress in gastrointestinal epithelium. In this study, hen egg yolk PL fraction was used to evaluate the effect of lipoxygenase (LOX)-induced PL oxidation on the rate of PL hydrolysis catalyzed by pancreatic phospholipase A2 (PLA2) in the presence of bile salts (BSs). Then, PL/BS solutions containing native or oxidized PLs were used...
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Advanced oxidation processes (AOPs) based wastewater treatment - unexpected nitration side reactions - a serious environmental issue: A review
PublicationChemical compounds containing nitro group (nitro-products) are a one of toxic by-products, that can be formed during wastewater treatment processes. In case of presence of nitrite or nitrate ions, the formation of nitro-products during advanced oxidation processes (AOPs) is very common. It is caused by the reactive nitrogen species (RNs) such as nitrate radical (NO3•), nitrite radical (NO2•), nitrogen oxide radical (NO•) and peroxynirite...
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The Influence of Sulfate on Anaerobic Ammonium Oxidation in a Sequencing Batch Reactor
PublicationAnaerobic ammonia-oxidizing bacteria have a more comprehensive metabolism than expected - there may be other electron acceptors that oxidize ammonium nitrogen under anaerobic conditions, in addition to the well-known nitrite nitrogen, one of which is sulfate in the sulfammox process. Sulfate-containing compounds are part of the medium for the anammox process, but their concentrations are not particularly high (0.2 g MgSO4 ∙ 7H2O/dm3...
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A novel approach for processing CaAlSiON glass-ceramics by spark plasma sintering: Mechanical and electrical properties
PublicationLithium containing glassy materials can be used as solid electrolytes or electrode materials for lithium-ion batteries due to their high energy density. Conventional melt-quenched Ca11Al14Si16O49N10 glass powder containing 24 e/o N, doped with Li-ions (1, 3, and 6 wt. %) and sintered by spark plasma sintering technique (SPS) was studied. The benefits of using SPS to produce glass-ceramics are rapid heating rates compared to conventional...
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Preparation of methanation catalysts for high temperature SOEC by β-cyclodextrin-assisted impregnation of nano-CeO2 with transition metal oxides
PublicationThe aim of this work was to prepare and examine the catalytic activity of nanometric CeO2 decorated with transition metal oxides – Ni, Co, Cu, Fe and Mn – towards a high-temperature methanation process under SOEC CO2/H2O simulated co-electrolysis conditions. Samples were prepared using the wet impregnation method via the conventional process and with the addition of native cyclodextrin. The influence of β-cyclodextrin (βCD) onto...
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Odpowiedzialność kierownicza w biznesie – zagadnienia procesowe i rodzajowe
PublicationCelem podjętych prac było przeprowadzenie rozważań nad zagadnieniami powstawania, ponoszenia, podejmowania oraz pociągania do odpowiedzialności kierowniczej. Kontynuacja badań nad odpowiedzialnością kierowniczą została oparta na sformułowanej wcześniej definicji. Umożliwiło to procesowe ujęcie przedmiotu eksploracji. W procesie tym wyróżniono fazy: przywołania, przyjęcia oraz poniesienia odpowiedzialności kierowniczej. Przeprowadzone...
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Adenocarcinoma, NOS - Male, 56 - Tissue image [6210730043063071]
Open Research DataThis is the histopathological image of RECTOSIGMOID JUNCTION tissue sample obtained in Medical University Gdańsk and deposited in ZMDL-GUMED. The sample image was taken using: Pannoramic 250 3DHistech slide scanner (20x magnification) and saved to DICOM format.
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Value of tax preferences by areas of support and types of taxes in 2013
Open Research DataThese data contain information prepared by the Ministry of Finance on the value of tax preferences by areas of support and types of taxes in 2013.
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Value of tax preferences by areas of support and types of taxes in 2014
Open Research DataThese data contain information prepared by the Ministry of Finance on the value of tax preferences by areas of support and types of taxes in 2014.
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Value of tax preferences by areas of support and types of taxes in 2011
Open Research DataThese data contain information prepared by the Ministry of Finance on the value of tax preferences by areas of support and types of taxes in 2009.
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Value of tax preferences by areas of support and types of taxes in 2009
Open Research DataThese data contain information prepared by the Ministry of Finance on the value of tax preferences by areas of support and types of taxes in 2009.
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Value of tax preferences by areas of support and types of taxes in 2010
Open Research DataThese data contain information prepared by the Ministry of Finance on the value of tax preferences by areas of support and types of taxes in 2010.
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Value of tax preferences by areas of support and types of taxes in 2012
Open Research DataThese data contain information prepared by the Ministry of Finance on the value of tax preferences by areas of support and types of taxes in 2012.
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Sulfammox process_task 1
Open Research DataAnaerobic ammonia-oxidizing bacteria have a more comprehensive metabolism thanexpected - there may be other electron acceptors that oxidize ammonium nitrogen under anaerobicconditions, in addition to the well-known nitrite nitrogen, one of which is sulfate in the sulfammoxprocess. Sulfate-containing compounds are part of the medium for the anammox process,...
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Comparison of antimicrobial activity of selected, commercially available wound dressing materials
PublicationOBJECTIVE: The aim of our study was to examine the antimicrobial potential of eight selected, commercially available wound dressings containing different antimicrobial agents: silver, chlorhexidine acetate, povidone-iodine, and manuka honey. METHOD: The materials were tested against four reference strains of bacteria: Staphylococcus aureus (PCM 2051), Staphylococcus epidermidis (PCM 2118), Pseudomonas aeruginosa (ATCC 27853),...
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SEM micrographs of the topography of Cu-Sn-TiO2 nanocomposite coatings
Open Research DataThe dataset contains the scanning electron microscopy (SEM) micrographs of nanocomposite Cu-Sn-TiO2 coatings electrodeposited from oxalic acid bath containing Cu and Sn salts as well as TiO2 nanoparticles under various treatments: mechanical stirring, ultrasonic or none. The details of the electrodeposition process are presented in the readme file attached...
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Test of the antimicrobial properties against Staphylococcus aureus of the innovative CS-2a preservative.
Open Research DataThe dataset contains the results of a single series of determinations of the antimicrobial properties against Staphylococcus aureus of the innovative CS-2 a preservative in the solution of model fluids.During the test, the infected product is inoculated (on Baird-Parker Agar) at specified intervals (0 min. and after 1 day-24 h of incubation ). This...
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Test of the antimicrobial properties against Listeria monocytogenes of the innovative CS-2b preservative.
Open Research DataThe dataset contains the results of a single series of determinations of the antimicrobial properties against Listeria monocytogenes of the innovative CS-2 b preservative in the solution of model fluids.During the test, the infected product is inoculated (on Oxford Agar) at specified intervals (0 min. [Listeria cs2b 0] and after 1 day-24 h of incubation...
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Electrochemical studies for screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Open Research DataThis dataset contains electrochemical examination of SPCE paste and SPCE containing boron-doped diamond BDD foils. The studies include kinetics analyses with cyclic voltammetry and electrochemical impedance spectroscopy with different redox probes: hexacyanoferrate(III) and Hexaammineruthenium(III) and potentiostatic open circuit potential at different...
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Influence of the presence of rhamnolipids and ionic cross-linking conditions on the mechanical properties of alginate hydrogels.
Open Research DataThe dataset contains the results of determination the effect of rhamnolipids concentration, calcium chloride concentration and ionic cross-linking time on the mechanical properties of alginate hydrogels prepared by immersing the alginate mixture limited by the dialysis membrane in an appropriate cross-linking solution containing calcium ions. The mechanical...
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Facile preparation of extremely photoactive boron-doped TiO2 nanotubes arrays
PublicationDoping of TiO2 nanotube arrays with boron was realized via electrochemical treatment of as-anodized titania immersed in electrolyte containing boric acid. The photoactivity of doped and pure titania was examined by means of photoelectrochemical and photocatalytic response under UV-vis irradiation. The results showed that photocurrent density of B-TNTs is remarkably higher (7.5 times) than density of pure TiO2 nanotube arrays. Furthermore,...
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ASIC Design Example of Complex SoC with FPGA Prototyping
PublicationThe paper presents an example of the System on a Chip design, where the FPGA prototyping has been used. Two FPGA prototypes have been realized. The first FPGA prototype uses AVNET board containing Xilinx Virtex4 device accompanied by custom board with required devices. The second FPGA prototype has been built using the custom PCB with Xilinx Virtex-4 XC4VLX60 FPGA accompanied by all needed external components. The final system...
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Imidazolium silanethiolates relevant to the active site of cysteineproteases. A cooperative effect in a chain of NH(+)...S(-) hydrogenbonds
PublicationThree imidazolium silanethiolates relevant to the active site of cysteine proteases have been synthesized and investigated by X-ray diffraction, IR spectroscopy and computational methods. As indicated by crystallographic and FT-IR data in the solid state, the transfer of proton from thiol to imidazole takes place and a thiolato-imidazolium ion pair is formed. The FT-IR spectra of crystalline imidazolium silanethiolates exhibit...
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ASIC Design Example of Complex SoC with FPGA Prototyping
PublicationThe paper presents an example of the System on a Chip design, where the FPGA prototyping has been used. Two FPGA prototypes have been realized. The first FPGA prototype uses AVNET board containing Xilinx Virtex4 device accompanied by custom board with required devices. The second FPGA prototype has been built using the custom PCB with Xilinx Virtex-4 XC4VLX60 FPGA accompanied by all needed external components. The final system...
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Determination of thiocyanate (biomarkers of ETS) and other inorganic ions in human nasal discharge samples using ion chromatography
PublicationEnvironmental tobacco smoke (ETS) is a mixture of air and tobacco smoke containing more than 4000 chemical substances. In view of the health risks of many of these substances, studies are needed to determine biomarkers of exposure to ETS constituents in people who actively or passively are exposed to the toxic compounds. The methodologies for determining most biomarkers from saliva, urine and blood samples are known, but methods...
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Design, synthesis, and molecular docking of new 5-HT reuptake inhibitors based on modified 1,2-dihydrocyclopenta[b] indol-3(4H)-one scaffold
PublicationA new group of serotonin reuptake inhibitors containing 1,2-dihydrocyclopenta[b]indol-3(4H)-one scaffoldwas synthesized, starting from indole 5-((1H-indol-3-yl)(1,3-dioxane-4,6-diones as a key intermediates. Following three transformations including intramolecular cyclization and formation of imines, a series of new ligand for human serotonin transporter was obtained. The ability of these ligands to inhibit human TS3 serotonin transporter...
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Sliding bearings with sintered bronze bush lubricated by contaminated water with solid particles – Theoretical and experimental studies
PublicationSliding journal bearings lubricated with water coming directly from the environment are a solution used in shipbuilding, pumps and hydropower. However, the working fluid or surrounding water cannot always be filtered because of design limitations, which often causes the problem of premature wear of these sensitive bearings. The research conducted made it possible to assess the wear of sliding bearings lubricated with water containing...
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Inhibitive effect of sodium molybdate on corrosion of AZ31 magnesium alloy in chloride solutions
PublicationIn this work, corrosion inhibition of the AZ31 magnesium alloy was investigated in NaCl solutions containing different amounts of sodium molybdate inhibitor. Electrochemical, hydrogen evolution, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. The results showed that Na2MoO4 inhibitor provides reliable inhibition at high concentrations (150 mM). Surface examination...
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A competition between two- and three-body dissociation channels in photo-double-ionization of tetrahydro-2H-pyran and 3,4-dihydro-2H-pyran molecules
PublicationVarious molecules possess structures consisting of the heterocyclic rings containing oxygen atoms. These substances often play a significant role in many different fields of chemistry, medicine, and biology. Due to a specific atomic composition and bond arrangement, many of these molecules retain unique electronic properties, which may be probed by diverse spectroscopic techniques, including those utilizing synchrotron radiation....
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Cross-linking of epoxy-oligomeric mixtures in the presence of modified phenol-formaldehyde resins
PublicationCross-linking of epoxy oligomeric mixtures consisting of industrial epoxy resin ED-20, oligoetheracrylate TGM-3, peroxide derivative of epoxy resin ED-24 and phenol-formaldehyde oligomer with unsaturated methacrylate fragments or peroxide groups was studied in the presence of polyethylenepolyamine at room temperature and heated to 383, 403 or 423 K for 15, 30, 45, 60 and 75 minute. The influence of mixture composition, temperature...
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The Implementation of the Taxonomic Spatial Measure of Development in the Analysis of Convergence in the Standard of Living
PublicationThe main goal of this paper is to analyse the existence of the social convergence in the European Union between 19952012. The social convergence refers to a reduction in the dispersion of the standard of living across countries. A taxonomic spatial measure of development was used as the standard of living approximation. The use of the new approach proposed by E. Antczak allowed for an explanation of the disparities in the analysed...
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Myths and facts about women aged 50+
PublicationThis study attempts to confront the three stereotypes attributed to women aged 50+ in Poland: the one related to women being interested in retiring as early as possible, the other related to the lack of educational activity and reluctance to acquire new knowledge and skills, and the third related to the image of a grandmother focused on looking after her grandchildren. The author’s aim is to present rational arguments in favour...
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Slurry Erosion -Design of Test Devices
PublicationDegradation of material caused by impacts of a solid particle (erodent) suspended in a liquid is called slurry erosion and is a major problem in the hydropower and maritime industry. Slurry erosion depends on many factors, e.g. liquid and erodent velocity, size, shape, angle of impact, hardness and number of erodents, and strength of a target material. The various types of test devices have been designed to investigate an effect...
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Synthesis and properties of carboxy derivative of Epidian 6 monomethacrylate (in English)
PublicationWe present the synthesis of an oligomer with carboxy and methacrylic groups based on Epidian 6. The effect of the catalyst nature and amount, solvent nature and process temperature on the rate of the reaction between Epidian6 monomethacrylate and adipic acid was examined at 313, 323 and 333 K in the presence of 4-dimethylaminopyridine, 1,4-diazobicyclo[2.2.2]octane, and benzyltriammonium chloride. The synthesized oligomer was characterized...
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Fractional neutron point kinetics equations for nuclear reactor dynamics – Numerical solution investigations
PublicationThis paper presents results concerning numerical solutions to a fractional neutron point kinetics model for a nuclear reactor. The paper discusses and expands on results presented in (Espinosa-Paredes et al., 2011). The fractional neutron point kinetics model with six groups of delayed neutron precursors was developed and a numerical solution using the Edwards’ method was proposed (Edwards et al., 2002). The mathematical model...
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PUBLIC SPACES FOR LOCAL LIFE / Shared values in diversified urban communities as a foundation for participatory provision of local public spaces, 23-27 May 2017, Ljubljana Slovenia
PublicationThe Urban Planning Institute of the Republic of Slovenia (UIRS) and partners hosted a 5-day international event addressing participatory planning of local urban public space in socially, economically and ethnically diverse communities. The event was structured in three interrelated activities: a seminar, a workshop and a field-trip. Special emphasis was given to the means of revealing shared values that local inhabitants and other...
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Stability of roof trusses stiffened by trapezoidal sheeting and purlins
PublicationIn the article linear buckling analysis of a set of steel trusses braced by purlins and trapezoidal sheeting are conducted. The buckling load factor due to the height of a corrugated sheeting profile is investigated in parametric studies. The minimal height of trapezoidal sheeting required for preventing the sheeting and chords of the trusses against the buckling is obtained. Two groups of models are considered: “axial” model as...
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BUILDING SMARTSLOW_SLOWSMART IN NOWY PORT- THE MULIDISICIPLINARY EDUCATIONAL EXPERIMENT OF JOINT DESIGN STUDIO
PublicationThis study presents the results of students’ work from Hafen City University in Hamburg and Gdansk University of Technology, carried out as part of a joint studio dealing with Nowy Port problem area. It refers to the methodology and design proposals, as well as to individual projects of students from Gdansk University of Technology - Spatial Management and Architecture. The aim of this study is to present framework project guidelines...
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Activated persulfate and peroxymonosulfate based advanced oxidation processes (AOPs) for antibiotics degradation – A review
PublicationSulfate radical AOPs (SR-AOP) were successfully utilized in degradation of antibiotics in water and wastewater treatment. The review discusses details on SR-AOPs mechanisms and applications for antibiotics degradation. The progress in this field was discussed, highlighting the most promising developments and remaining challenges. The applicability of SR-AOPs was summarized revealing the most susceptible and persistent to oxidation...
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Reactive Processing and Functionalization of Ground Tire Rubber
PublicationThe dynamic development of the automotive industry resulted in a sig- nificant increase in rubber wastes, especially end-of-life tires, which are a serious threat to the natural environment and human health. This situation has enforced the industry and academic research groups to search new and cost-effective methods for recycling waste tires. In this field of research, reactive processing and functionaliza- tion seem to be a...
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Właściwości elektryczne szkło-ceramiki zawierającej ferroelektryczną fazę BiV
PublicationKompozyty szklano - ceramiczne zawierające nanokryształy posiadają właściwości fizyczne, które nie są możliwe do uzyskania w innych materiałach. Dzięki możliwości wytworzenia szkło - ceramik posiadających kryształy o różnej wielkości (nano, mikro...) i różnorodnego typu, można w istotny sposób kontrolować właściwości elektryczne takich materiałów. Stała dielektryczna faz ferroelektrycznych jest bardzo wrażliwa na zmiany rozmiarów...
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AUTOMATYCZNA KLASYFIKACJA MOWY PATOLOGICZNEJ
PublicationAplikacja przedstawiona w niniejszym rozdziale służy do automatycznego wykrywania mowy patologicznej na podstawie bazy nagrań. W pierwszej kolejności przedstawiono założenia leżące u podstaw przeprowadzonych badan wraz z wyborem bazy mowy patologicznej. Zaprezentowano również zastosowane algorytmy oraz cechy sygnału mowy, które pozwalają odróżnić mowę niezaburzoną od mowy patologicznej. Wytrenowane sieci neuronowe zostały następnie...
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The aggregation of objects representing Katowice district buildings - scale 1:25000
Open Research DataThe process of automatic generalization is one of the elements of spatial data preparation for the purpose of creating digital cartographic studies. The presented data include a part of the process of generalization of building groups obtained from the national geodesy and cartography resource from BDOT10k (10k topographic database) [1].
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The aggregation of objects representing Katowice district buildings - scale 1:10000
Open Research DataThe process of automatic generalization is one of the elements of spatial data preparation for the purpose of creating digital cartographic studies. The presented data include a part of the process of generalization of building groups obtained from the national geodesy and cartography resource from BDOT10k (10k topographic database) [1].
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An Estimation of the Efficiency of Public Research Institutes in Poland – DEA Approach
PublicationObjective: The purpose of this paper is to measure and assess the efficiency of research institutes in Poland. The institutes operate on the basis of various legal frameworks, but they serve a common purpose and have a joint area of activity, research and development.Research Design & Methods: We used the SBM model, a component of the non-parametric Data Envelopment Analysis (DEA) methodology, to analyse the efficiency...
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Reducing Monitoring Costs in Industrially Contaminated Rivers: Cluster and Regression Analysis Approach
PublicationMonitoring contamination in river water is an expensive procedure, particularly for developing countries where pollution is a significant problem. This study was conducted to provide a pollution monitoring strategy that reduces the cost of laboratory analysis. The new monitoring strategy was designed as a result of cluster and regression analysis on field data collected from an industrially influenced river. Pollution sources in...
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Fast GC as a useful tool for authenticity assessment of kiwifruit
PublicationKiwifruit is one of the healthiest fruits due to its high content of biologically active substances and nutrients. The most popular species of Actinidia (kiwifruit) are the Actinidia deliciosa fruits called kiwi and Actinidia chinensis commonly called golden kiwi, while the lesser known species is Actinidia arguta known as mini kiwi. Bioactivities and nutrients of Actinidia are influenced by species and cultivars. It is very important...