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Ho2Pd1.3Ge2.7 – a ternary AlB2-type cluster glass system
PublicationWe report a successful synthesis of a ternary AlB2-type intermetallic compound. The phase purity was obtained by fine-tuning the Pd-Ge ratio out of the idealized 1-3. Attempts to synthesize an Er analogue were not successful. We discuss the instability of the Er analogue based on the atomic size ratio and also suggest that the increased stability of Ho2Pd1+xGe3−x in the Pd-rich range likely stems from a combination of atomic size...
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Dynamic Response of the Suspended on a Single Cable Footbridge
PublicationThe article presents numerical simulations, dynamic in situ load tests and a structural health monitoring (SHM) system installed in a suspended on a single cable footbridge. Numerical simulations performed prior to construction indicated the possibility of structural dynamics problems, finally confirmed in the course of dynamic test loading. In the dynamic load course the bridge deck developed vibrations displaying accelerations...
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Thermally activated persulfate-based Advanced Oxidation Processes — recent progress and challenges in mineralization of persistent organic chemicals: a review
PublicationThermally activated persulfate (TAP) finds application in Advanced Oxidation Processes for the removal of pollutants from contaminated water and soil. This paper reviewed the various cases of TAP in the environmental remediation. The pollutants such as individual pharmaceuticals, biocides, cyclic organic compounds, and dyes are considered in this review. It is interesting to note that most of the organic compounds undergo complete...
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PHYSICAL MODELLING OF GEOTECHNICAL STRUCTURES IN PORTS AND OFFSHORE
PublicationThe physical modelling of subsoil behaviour and soil-structure interaction is essential for the proper design of offshore structures and port infrastructure. A brief introduction to such modelling of geoengineering problems is presented and some methods and experimental devices are described. The relationships between modelling scales are given. Some examples of penetration testing results in centrifuge and calibration chamber...
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublicationTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Development and evaluation of thermosensitive hydrogels with binary mixture of Scutellariae baicalensis radix extract and chitosan for periodontal diseases treatment.
PublicationScutellaria baicalensis root displays anti-inflammatory and antibacterial properties due to the presence of flavonoids, particularly baicalin, baicalein, and wogonin. Our work aimed at developing thermosensitive hydrogels containing a binary mixture of S. baicalensis radix lyophilized extract and chitosan as a novel approach for periodontal diseases treatment....
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N-doped graphene quantum dot-decorated MOF-derived yolk-shell ZnO/NiO hybrids to boost lithium and sodium ion battery performance
PublicationSurface engineering at the nanoscale to obtain robust interface between metal oxides and quantum dots is essential for improving the performance and stability of battery materials. Herein, we designed and prepared novel N-doped graphene quantum dot-modified ZnO/NiO anode materials with a well-defined yolk-shell structure for lithium and sodium-ion batteries. NG QDs were assembled on the ZnO/NiO microspheres using three different...
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Experimental study and numerical simulation on porosity dependent direct reducibility of high-grade iron oxide pellets in hydrogen
PublicationThe transition to more environmentally friendly steel production methods has intensified research into hydrogen-based direct reduction (HyDR) of iron oxide pellets. The aim of this study is to systematically investigate the kinetics of the reduction process, the evolution of porosity and the resulting microstructural changes on the reduction behavior of high-quality pellets during HyDR of iron ore at different temperatures. A modified...
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Probabilistic seismic assessment of RC box-girder highway bridges with unequal-height piers subjected to earthquake-induced pounding
PublicationThis paper uses the probabilistic seismic assessment to study the effects of pounding and irregularity on the seismic behavior of typical concrete box-girder bridges with four levels of altitudinal irregularity. To extend the results for all bridges in the same class, uncertainty related to the earthquake, structural geometries, and materials are considered. Pounding is likely to take place in two cases: the first one concerns...
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One Year Evaluation of Material Properties Changes of Polylactide Parts in Various Hydrolytic Degradation Conditions
PublicationBiodegradable biocompatible materials are widely used in medical applications. Determining the possibility of using biodegradable materials depends on determining the changes in their parameters over time due to degradation. The current scientific research on biodegradable materials has presented results based on research methods characterized by the different geometry and cross-section size of the specimen, type of degradation...
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Simulating propagation of coherent light in random media using the Fredholm type integral equation
PublicationStudying propagation of light in random scattering materials is important for both basic and applied research. Such studies often require usage of numerical method for simulating behavior of light beams in random media. However, if such simulations require consideration of coherence properties of light, they may become a complex numerical problems. There are well established methods for simulating multiple scattering of light (e.g....
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Seismic Response Analysis of Knee-Braced Steel Frames Using Ni-Ti Shape Memory Alloys (SMAs)
PublicationShape Memory Alloys (SMAs) are known as active materials that can be widely used for structural purposes due to their flag-shape behavior under loading and reloading. Their unique characteristics provided a potential solution for civil engi-neers especially to model buildings with the capability of dissipating seismic en-ergy. In this study, the main purpose is to explore the seismic behavior of Knee-Braced Frames (KBFs) and...
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CaZnO-based nanoghosts for the detection of ssDNA, pCRISPR and recombinant SARS-CoV-2 spike antigen and targeted delivery of doxorubicin
PublicationOverexpression of proteins/antigens and other gene-related sequences in the bodies could lead to significant mutations and refractory diseases. Detection and identification of assorted trace concentrations of such proteins/antigens and/or gene-related sequences remain challenging, affecting different pathogens and making viruses stronger. Correspondingly, coronavirus (SARS-CoV-2) mutations/alterations and spread could lead to overexpression...
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Influence of CeO2 and TiO2 Particles on Physicochemical Properties of Composite Nickel Coatings Electrodeposited at Ambient Temperature
PublicationThe Ni-TiO2 and Ni-CeO2 composite coatings with varying hydrophilic/hydrophobic characteristics were fabricated by the electrodeposition method from a tartrate electrolyte at ambient temperature. To meet the requirements of tight regulation by the European Chemicals Agency classifying H3BO3 as a substance of very high concern, Rochelle salt was utilized as a buffer solution instead. The novelty of this study was to implement a...
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Temperature influences on shear stability of a nanosize plate with piezoelectricity effect
PublicationPurpose The purpose of this paper is to predict the mechanical behavior of a piezoelectric nanoplate under shear stability by taking electric voltage into account in thermal environment. Design/methodology/approach Simplified first-order shear deformation theory has been used as a displacement field. Modified couple stress theory has been applied for considering small-size effects. An analytical solution has been taken into account...
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Reduction of steel chimney vibrations with a pendlum damper.
PublicationKarman vortices observed around chimneys may induce dangerous structural vi-brations at certain wind velocities. The aim of this paper is to analyse theeffectiveness of pendulum damper in vibration reduction of a steel chimney. A two degree-of-freedom system is used to model the behaviour of the struc-ture equipped with a damper. The results of the study show that the use of pendulum with tuned frequency leads to significant...
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Magnetic properties of ferromagnetic Pu2Pt3Si5
PublicationThe structural, magnetic, and thermodynamic properties of a new plutonium based compound, Pu2Pt3Si5, are reported. Single crystals produced by a Sn-flux technique have been analyzed showing a ferromagnetic behavior at 58 K. Pu2Pt3Si5 crystallizes in the U2Co3Si5-type orthorhombic Iabm structure (s.g. 72) with atomic parameters a = 9.9226(2) Å, b = 11.4436(2) Å and c = 6.0148(1) Å. The effective (leff 0.74 lB/Pu) and saturated (rsat...
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On the Limiting distribution of Lempel Ziv'78 Redundancy for Memoryles Sources
PublicationWe show that the Lempel Ziv'78 redundancy rate tends to a Gaussian distribution for memoryless sources. We accomplish it by extending findings from our 1995 paper [3]. We present a new simplified proof of the Central Limit Theorem for the number of phrases in the LZ'78 algorithm. As in our 1995 paper, here we first analyze the asymptotic behavior of the total path length in a digital search tree (a DST) built from independent sequences....
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Crystal growth and properties of a binary intermetallic ZrBi2 compound
PublicationSingle crystals of ZrBi2 were grown by a self-flux method. The material adopts TiAs2 structure type with lattice parameters: a = 10.233(4) Å, b = 15.581(2) Å, c = 3.994(5) Å. Crystals of ZrBi2 were studied by means of magnetic susceptiblity, specific heat and resistivity measurements. The compound reveals a metallic-like behavior (RRR = 30). The Sommerfeld coefficient equals γ = 1.59(16) mJ mol-1 K-2 and Debye temperature ΘD =...
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Limiting distribution of Lempel Ziv'78 redundancy
PublicationWe show that the Lempel Ziv'78 redundancy rate tends to a Gaussian distribution for memoryless sources. We accomplish it by extending findings from our 1995 paper [3]. We present a new simplified proof of the Central Limit Theorem for the number of phrases in the LZ'78 algorithm. As in our 1995 paper, here we first analyze the asymptotic behavior of the total path length in a digital search tree (a DST) built from independent sequences....
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The ancient formula of master-apprentice relevance in contemporary architecture education.
PublicationThe universalization of the methodology for determining the quality of European higher education exposes the aspect of supporting the student in the education process, which takes the form of tutoring or supervising - a modern form of ancient master-apprentice relationship. The 'master' in architectural education has lawful building qualification and is a member in national architect association - a sine qua non with respect to...
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Pressure in charge. Neglected parameter in hydrothermal synthesis turns out to be crucial for electrochemical properties of ammonium vanadates
PublicationAmmonium vanadates are of great interest as they exhibit unusual electrical and sensory properties.(NH4)2V6O16and (NH4)2V10O25$8H2O with various morphology were obtained in the hydrothermalsynthesis under controlled temperature and pressure. It was shown, that the pure (NH4)2V10O25$8H2Owas obtained under 50 bar of initial pressure, whereas lower pressure lead to the mixture of twocompounds. The influence of the pressure was studied...
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Trust in Electronic Word-of-Mouth (eWOM): the concept and the most important determinants
PublicationeWOM and trust in it is now the most important factor in determining buyers' purchasing behavior. Familiarity with the determinants of trust establishes the formation of appropriate marketing activities. However, the growing number of new forms of eWOM and its increasingly complex and multidimensional nature have created a lot of confusion. The article aims to organize the concepts related to trust in eWOM, to indicate the most...
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Pedestrian Safety in Road Traffic in Poland
PublicationEvery third road accident in Poland involves a pedestrian as a participant or, most of the time, a casualty. Pedestrian accidents are usually the result of complex situations and the outcome of a number of factors related to driver and pedestrian behaviour and road infrastructure. Safety depends largely on how well the traffic condition is perceived and on visibility in traffic. The paper presents the results of analyses of methodologies...
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Assessing unsignalised pedestrian crossings
PublicationThe lack of pedestrian safety on crossings is a complex problem and one that is influenced by a number of factors such as the law, road traffic culture, the road and traffic. This paper will focus on the last two by presenting a method for assessing pedestrian crossings for their geometry and roadside using data from 930 pedestrian crossings in Warsaw. The authors of this paper have attempted to systematise the process of assessment...
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FEM approach to modeling of an irregular trabecular structure
PublicationThe aim of the study is elaboration of a method for creating irregular scaffolds that can be used to model the behaviour of trabecular bone placed in the proximal epiphysis of the femur. The scope of the study encompasses creating six numerical models of irregular scaffolds (two solid irregular scaffolds, two shell irregular scaffolds and two shell irregular scaffolds with fortification) and performing numerical analysis of the...
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On the Bending of Multilayered Plates Considering Surface Viscoelasticity
PublicationWe discuss the bending resistance of multilayered plates taking into account surface/interfacial viscoelasticity. Within the linear surface viscoelasticity we introduce the surface/interfacial stresses linearly dependent on the history of surface strains. In order to underline the surface viscoelasticity contribution to the bending response we restrict ourselves to the elastic behaviour in the bulk. Using the correspondence principle...
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The particle method for simulation of self-organization phenomena
PublicationThe aim of the work was to design, implement, and use, in a number of experiments, an abstract software environment (an artificial world)suitable for modelling systems consisting of many moving and interactingobjects distributed in space. The environment, named DigiHive, is directed towards modeling of complex systems manifested by processes of self-organization, self-reproduction and self modifications. The environment is mainly...
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Frequency of use, moral incongruence, and religiosity and their relationships with self-perceived addiction to pornography, internet use, social networking and online gaming
PublicationBackground and Aims Moral incongruence involves disapproval of a behaviour in which people engage despite their moral beliefs. Although considerable research has been conducted on how moral incongruence relates to pornography use, potential roles for moral incongruence in other putative behavioural addictions have not been investigated. The aim of this study was to investigate the role of moral incongruence in self‐perceived...
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Selected elements of the methodology and method of designing amphibious flood rescue vehicles
PublicationThe methodology of designing amphibious flood rescue vehicles at the preliminary stage of the design process has been presented. The study has been focused on the properties of such vehicles when afloat, with their on-land behaviour and performance characteristics having been left aside. In the study, a general assumption has been made that the amphibious flood rescue vehicles should be designed as, above all, watercraft that additionally...
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Experimental study on polymer mass used to repair damaged structures
PublicationA new method of repairing damaged structures by injecting the cracks with specially designed polymer mass (flexible two-component grout based on polyurethane resin) has been recently proposed. The technique is mainly dedicated to damaged masonries, especially historical structures where minimum intervention is permitted. The cracks are filled with the special injection, forming the flexible joints bonding the disrupted structural...
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Finite-element analysis of a base-isolated multi-storey steel building under seismic motions
PublicationNumerical simulation of the seismic behaviour of a multi-storey steel building, both fixed-base and base-isolated, under the 1940 El Centro earthquake was performed in this paper. The analyzed 4-storey building was decoupled from the shaking ground with the Polymeric Bearings, which can be considered a proposal of a new seismic isolation system. It consists of rectangular-shaped blocks made of a specially prepared flexible polymeric...
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On implementation of fibrous connective tissues’ damage in Abaqus software
PublicationConnective fibrous tissues, such as tendons and ligaments, in humans and animals exhibit hyperelastic behaviour. The constitution of the material of these tissues is anisotropic due to the presence of the collagen fibres, where one family of fibres is the typical case. Traumatic events and/or aging may sometimes lead to the damage of the tissue. The study of motion of affected joints or limbs is usually not permitted in vivo. This...
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Corrugated Sheeting as a Member of a Shear Panel Under Repeated Load—Experimental Test
PublicationIn stressed-skin design, the cladding stiffening effect on structures is taken into account. However, the “traditional” design is more usual, wherein this effect is neglected. Even if the diaphragm actions are not regarded, in particular cases such as big sheds (and others), the parasitic (unwanted) stressed-skin action may occur with the result of leakage or even failure. The structures of this kind have already been built. Thus,...
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Photocatalytic decolourization of Rhodamine-B dye by visible light active ZIF-8/BiFeO3 composite
PublicationIn this work, preparation of ZIF-8 supported BiFeO3 photocatalyst by ultrasound cavitation technique was reported. The synthesized materials were characterized using solid UV absorption spectroscopy, Raman Spectroscopy, and SEM. The catalytic function of synthesized photocatalyst under ultraviolet and visible light was examined for the decolourization of Rhodamine-B (Rh-B) dye. To understand the action of the photocatalyst on Rh-B...
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Size effect at aggregate level in microCT scans and DEM simulation – Splitting tensile test of concrete
PublicationThe paper describes an experimental and numerical study of size effect on concrete cylindrical specimens in splitting tensile test. Own experimental campaign was performed on specimens with 5 various diameters from D = 74, 105, 150, 192 and 250 mm with hardboard loading strips (distributed load according to standard methods) scaled proportionally to the specimen diameter. The crack opening-control system was applied to obtain the...
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DRESS SYNDROME AS SERIOUS SKIN HYPERSENSITIVITY REACTIONS ASSOCIATED WITH OLANZAPINE: CASE REPORT
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LATE ONSET PSYCHOSIS – A CASE REPORT
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PREVALENCE OF METABOLIC SYNDROME AMONG PATIENTS WITH SCHIZOPHRENIA FROM LONG CARE UNIT IN FORENSIC PSYCHIATRY PROGRAM: AN OBSERVATIONAL STUDY
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Wyznaczanie współczynnika przejmowania ciepła podczas wrzenia w przepływie dwutlenku węgla (Prediction of flow boling heat transfer coefficient for carbon dioxide in minichannels)
PublicationW pracy przedstawiono wyniki obliczeń uzyskane za pomocą własnego modelu półemirycznego dla wybranych danych eksperymentalnych dla wrzenia w przepływie dwutlenku węgla. Metoda obliczeniowa została zweryfikowana z danymi eksperymentalnymi Docoulombiera i innych (2011) oraz Mastrullo i innych (2009). Badania eksperymentalne dotyczą pełnego zakresu zmienności stopnia suchości oraz zakresu prędkości masowej G=200-1200 kg/m2s. rozwijany...
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The experimental research on RC columns, loaded at sign-variable eccentricity
PublicationThe research focuses on testing the behaviour of the reinforced concrete columns compressed at a variable eccentricity. The fact of possible variable eccentricity in compressed columns is not considered in the current calculation procedures. The objective of the research was to examine whether indeed the load history has no impact and whether the reinforced concrete columns compressed at eccentric of variable sign could be analysed...
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A novel formulation of 3D spectral element for wave propagation in reinforced concrete
PublicationThe paper deals with numerical simulations of wave propagation in reinforced concrete for damage detection purposes. A novel formulation of a 3D spectral element was proposed. The reinforcement modelled as the truss spectral element was embedded in the 3D solid spectral finite element. Numerical simulations have been conducted on cuboid concrete specimens reinforced with two steel bars. Different degradation models were considered...
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Strain gauges monitoring of arch bridge over the Vistula river in Toruń during construction
PublicationIn 2013 one of the biggest Polish road bridges over the Vistula was built in Torun. Considering the use of original engineering solutions and innovative assembly it was decided on monitoring of strain gauges and assessment of building’s behaviour during its construction. The research was aimed at determining the degree of strain and the assessment of proper work of main arch girders during assembly phases. This work presents the...
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Can we really solve an arch stability problem?
PublicationWe bring attention to the problem of solving nonlinear boundary-value problems for elastic structures such as arches and shells. Here we discuss a classical problem of a shear-deformable arch postbuckling. Considering a postbuckling behaviour of a circular arch we discuss the possibility to find numerically a solution for highly nonlinear regimes. The main attention is paid to the problem of determination of all solutions. The...
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Finite element simulation of cross shaped window panel supports
PublicationThe aim of the work is to verify suitability of cross-shaped window panel supports for mullion-transom wall systems. The Finite Element Method (FEM) is chosen to determine the behaviour of stainless steel elements under loading. The advanced non-linear numerical simulations are carried out using an implicit FEM software package MSC.Marc. This study is proposed to initiate the comprehensive investigation of mechanical properties...
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Mechanical compatibility of implants used in hernia repair with abdominal wall
PublicationThe paper deals with a membrane model of a synthetic surgical mesh for treatment of abdominal hernia. The authors analyse the compatibility of two implant types with the human wall: Dualmesh Gore and Proceed. The finite element method is applied to simulate tjhe behavior of the proposed model. Due fact that recurrences are usually caused by connection failure, this study is focused on reaction forces in supports representing the...
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Development of polyurethanes for bone repair
PublicationThe purpose of this paper is to review recent developments on polyurethanes aimed at the design, synthesis, modifications, and biological properties in the field of bone tissue engineering. Different polyurethane systems are presented and discussed in terms of biodegradation, biocompatibility and bioactivity. A comprehensive discussion is provided of the influence of hard to soft segments ratio, catalysts, stiffness and hydrophilicity...
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Fracture of aluminium joints bonded with epoxy adhesive reinforced by mmt nanoparticles
PublicationCrack propagation behavior was studied for aluminium/aluminum adhesive joints bonded with two epoxy adhesives: pure and reinforced with clay nanoparticles. The focus was also on the novel use of the constant displacement rate test to study adhesion/adhesives efficiency. The epoxy systems studied were: Epidian E6 produced from bisphenol A and epichlorohydrin, (''Organika -Sarzyna'' Poland); pure or strengthened with montmorillonit...
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Analysis of the dynamic influences on the Lowland Gate in Gdańsk
PublicationThe Lowland Gate has been built in 1626. It is one of the best-preserved historical buildings in Gdansk. The structure is still of the city's infrastructural importance as through it goes a road connecting two districts. The Gate is now so neglected that it is hard to appreciate its value. The main purpose of the investigation carried out was to determine the harmfulness of the traffic on the structure as well as the reasons of...
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Nonlinear viscoelasticity in Three Dimensional filler reinforced rubber composites and nanocomposites
PublicationThis chapter describes the influence of three-dimensional nanofillers used in elastomers on the nonlinear viscoelastic properties. In particular, this part focuses and investigates the most important three-dimensional nanoparticles, which are used to produce rubber nanocomposites. The rheological and the dynamic mechanical properties of elastomeric polymers, reinforced with spherical nanoparticles, like POSS, titanium dioxide and...