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Search results for: conductive hydrogels
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Structure and transport properties of triple-conducting BaxSr1−xTi1−yFeyO3−δ oxides
PublicationIn this work, BaxSr1−xTi1−yFeyO3−δ perovskite-based mixed conducting ceramics (for x = 0, 0.2, 0.5 and y = 0.1, 0.8) were synthesized and studied. The structural analysis based on the X-ray diffraction results showed significant changes in the unit cell volume and Fe(Ti)–O distance as a function of Ba content. The morphology of the synthesized samples studied by means of scanning electron microscopy has shown different microstructures...
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The effect of plate size on the natural convective heat transfer intensity of horizontal surfaces
PublicationW pracy przedstawiono badania wpływu rozmiarów płyty prostokątnej poziomej na intensywność wymiany ciepła w warunkach konwekcji swobodnej. Zaproponowano dwa zakresy: dla płyt o wymiarze charakterystycznym mniejszym niż 0,1 m - 0,2 m intensywność konwekcyjnej wymiany ciepła jest odwrotnie proporcjonalna do szerokości płyty, dla płyt szerszych niż 0,2 m szerokość płyty nie wpływa znacząco na współczynnik konwekcyjnej wymiany ciepła....
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Experimental and numerical study on spontaneous ignition of hydrogen and hydrogen-methane jets in air
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Influence of hydrogen on a nanocrystalline high-entropy oxide with application potential in hydrogen technologies
PublicationThe influence of hydrogen on a (Co0⋅2Cu0⋅2Mg0⋅2Ni0⋅2Zn0.2)O HEO with a rock salt structure was studied. Two forms of this HEO (nanopowder and sinter) were prepared via mechanochemical synthesis (MS) and additional heat treatment, respectively. The chemical stability of the synthesized samples in a pure hydrogen atmosphere was investigated using Sievert’s technique. High-pressure hydrogenation at 250 ◦C had no noticeable effect...
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Inductive Bifilar Coil Based Wireless Charging System for Autonomous Electric Boat
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A novel concept for tissue-metal detection and differentiation using an inductive proximity sensor
PublicationIn this paper a novel application of inductive proximity sensors for detection of living tissue by means of measurements of the coil impedance changes at different frequencies is described. The mathematical analyses utilizing Bessel function estimation include detected object size and its distance from a sensor. The main aim of this study is to prove the possibility of distinguishing between metal objects and living tissues. The...
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The effect of convective heating and microwave heating on antioxidant enzymes in pooled mature human milk
PublicationThe effects of convective and microwave heating at constant temperature (62.5, 66 and 70 °C) on the activity of antioxidant enzymes (superoxide dismutase, SOD; catalase, CAT; glutathione peroxidase, GPx) in pooled mature human milk were compared. Activities of the enzymes were determined using spectrophotometric kits. Activity of GPx decreased significantly in the first stage of heating when milk samples were warmed to pasteurisation...
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Ion conduction in beryllium-alumino-silicate glasses doped with sodium or sodium and lithium ions
PublicationElectrical properties of beryllium-alumino-silicate glasses containing sodium ions or sodium and lithium ions were studied with impedance spectroscopy technique over a frequency range from 10 mHz to 1 MHz and at temperature range from 213 to 473 K. The frequency- and temperature-dependent conductivity spectra of individual single alkali glasses were superimposed by means of the Summerfield scaling. Mixed-alkali glasses do not overlap...
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High-conducting Bi4V2-xFexO11-δ ceramics containing Fe2O3 nanocrystals: Structure and properties
PublicationThe topography, structure, thermal, magnetic, and electrical properties of Bi4V2-xFexO11-δ ceramics substituted with x = 0.5 and 0.7 Fe were studied. The microscope analysis showed the presence of iron-rich nanocrystals formed on the Bi-Fe-V-O grains. The X-ray diffraction studies confirmed that grains are built mostly of tetragonal Bi4V1.5Fe0.5O10.5 phase. Thermal properties analysis showed an order-disorder type γ ↔ γʹ phase...
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Natural convective heat transfer from isothermal horizontal, vertical and inclined plates - a review
PublicationW artykule przedstawiono przegląd otrzymanych przez różnych badaczy korelacji eksperymentalych, teoretycznych i numerycznych, opisujących wymianę ciepła od izotermicznych płyt o różnym kącie pochylenia. Przedstawiono model matematyczny zjawiska. Opisano stosowane metody badawcze i wskazano przyczyny rozbieżności pomiędzy przedstawionymi przez wielu autorów wynikami.
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Could graphene construct an effective conducting network in a high-power lithium ion battery?
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Study of free convective boundary layer of isothermal lateral surface of axisymmetrical horizontal body
PublicationPrzedstawiono rozwiązanie równań Naviera-Stokesa i Fouriera-Kirchhoffa we współrzędnych tau i sigma. Pierwsza jest styczną a druga normalną do konwekcyjnych linii prądu, wzdłuż jakich porusza się ogrzany od powierzchni płyn. Wynik w postaci równania na grubość warstwy przyściennej zweryfikowano dla granicznych przypadków ciała obrotowego o poziomej osi symetrii (stożka poziomego i kołowej pionowej płyty).
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Performance of a single layer fuel cell based on a mixed proton-electron conducting composite
PublicationMany of the challenges in solid oxide fuel cell technology stem from chemical and mechanical incompatibilities between the anode, cathode and electrolyte materials. Numerous attempts have been made to identify compatible materials. Here, these challenges are circumvented by the introduction of a working single layer fuel cell, fabricated from a composite of proton conducting BaCe0.6Zr0.2Y0.2O3-δ and a mixture of semiconducting...
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Mechanism of hopping conduction in Be–Fe–Al–Te–O semiconducting glasses and glass–ceramics
PublicationElectrical properties of beryllium-alumino-tellurite glasses and glass–ceramics doped with iron ions were studied using impedance spectroscopy. The conductivity was measured over a wide frequency range from 10 mHz to 1 MHz and the temperature range from 213 to 473 K. The D.C. conductivity values showed a correlation with the Fe-ion concentration and ratio of iron ions on different valence states in the samples. On the basis of...
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Free convective heat transfer structures as a function of the width of isothermal horizontal rectangular plates
PublicationZaprezentowano rezultaty badań eksperymentalnych konwekcyjnej wymiany ciepła od izotermicznych płyt prostokątnych skierowanych ku górze. Na podstawie przeprowadzonych wizualizacji zaproponowano dwa modele struktur przepływu. Rozwiązania analityczne dla tych modeli przedstawiono w postaci zależności liczb Nusselta Rayleigh'a. Stwierdzono, że przepływ koncentryczny występuje dla małych wartości liczb Ra, szczególnie w przypadku płyt...
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Injectable poloxamer/graphene oxide hydrogels with well‐controlled mechanical and rheological properties
PublicationAlthough significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological...
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Comprehensive study on graphene hydrogels and aerogels synthesis and their ability of gold nanoparticles adsorption
PublicationGraphene hydrogels were prepared by ascorbic acid-assisted gelation of graphene oxide (GO) aqueous suspensions both in acidic and basic conditions. Different mass ratio of ascorbic acid (AA) to GO was used (namely 20:1 and 10:1). In order to eliminate the influence of AA on the final structure of hydrogels, samples without AA were prepared by a hydrothermal gelation of GO in an autoclave. An in-depth structural characterization...
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Determination of Changes in Viscosity of Hydrogel Depending on Shear Rates
PublicationThe datasets entitled Determination of changes in viscosity of hydrogel depending on shear rate contain the results of viscosity measurements using a Brookfield viscometer, with different kinds of spindles and shear rates. The data allowed the used hydrogel preparations to be characterised and their functional parameters, as substances modifying the rheology of thickeners and determining the effect of shear rate on the viscosity...
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Gold nanocubic structures agglomeration when put on conductive surfaces
Open Research DataThis dataset contains Dynamic EIS results obtained for the gold electrodes with non-functionalized gold nanocubes (AuNC) deposited at its surface. The deposition was the following: 2 uL of the solvent containing CTAB as the surfactant was put on the electrode and dried, the same procedure was applied 5 times. Afterward, the electrode was immersed in...
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Gold nanocubic structures agglomeration when put on conductive surfaces
Open Research DataThis dataset contains SEM images of gold nanocubes (AuNC), which were deposited at the conductive Si wafer surface and dried. The deposition method, the solvent used and AuNC concentration have a significant influence on the homogeneous distribution and their agglomeration at the surface, further influencing the electrochemical characteristics of the...
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Gold nanocubic structures agglomeration when put on conductive surfaces
Open Research DataThis dataset contains SEM images of gold nanocubes (AuNC), which were deposited at the conductive Si wafer surface and dried. The deposition method, the solvent used and AuNC concentration have a significant influence on the homogeneous distribution and their agglomeration at the surface, further influencing the electrochemical characteristics of the...
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Gold nanocubic structures agglomeration when put on conductive surfaces
Open Research DataThis dataset contains SEM images of gold nanocubes (AuNC), which were deposited at the conductive Si wafer surface and dried. The deposition method, the solvent used and AuNC concentration have a significant influence on the homogeneous distribution and their agglomeration at the surface, further influencing the electrochemical characteristics of the...
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Gold nanocubic structures agglomeration when put on conductive surfaces
Open Research DataThis dataset contains Dynamic EIS results obtained for the gold electrodes with non-functionalized gold nanocubes (AuNC) deposited at its surface. The deposition was the following: 2 uL of the solvent containing CTAB as the surfactant was put on the electrode and dried, the same procedure was applied 5 times. Afterward, the electrode was immersed in...
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Comparison of properties of the new electro-mechanical model and circumferential model of the inductive-dynamic drive
PublicationThe article presents a new electromechanical model of inductive-dynamic drive. The model is implemented in two environments: Maxwell for analyzing electrodynamic phenomena including moving of the disc and Ansys which allows for stress analysis on the basis of the volume forces imported from Maxwell. Additionally, a model validation by comparing with the existing circumferential model was carried out.
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Analysis of inductive power transfer systems for variable air gap and voltage supply frequency
PublicationThe paper describes an IPT system, by which electrical energy may be transmitted through a large air gap between coils without electrical connection. It presents theoretical and simulation analysis of IPT, which allows for supplying a receiver in the conditions of slow, in relation to the dynamics of power supply, changes in dimension of the air gap. The influence of frequency characteristics of the system on the possible selection...
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Comparative Evaluation of Multicoil Inductive Power Transfer Approaches Based on Z-source Network
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Novel Inductive Power Transfer Approach Based on Z-Source Network with Compensation Circuit
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Comparative Evaluation of Multicoil Inductive Power Transfer Approaches Based on Z-source Network
PublicationThis paper describes comparative evaluation between wireless power transfer topologies with utilization of Z-source network. Paper describes components calculation method. List of open-loop, close-loop simulations were conducted to compare both topologies. Spectrum of signals is also researched.
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Proton-Electron Hole Interactions in Sr(Ti,Fe)O3−δ Mixed-Conducting Perovskites
PublicationOxides in which total electrical conductivity is determined by the partial conductivities of three types of charge carriers i.e. holes/ electrons, oxygen ions, and protons are key components of well-functioning proton ceramic fuel cells. Apart from electrochemical properties also easily modified microstructure is an important feature of the electrodes. In the paper, a group of SrTi1−xFexO3−δ (STF, x = 0.2–0.8) perovskites prepared...
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The mechanical properties and conduction of solid polyurethane electrolytes depending on the methods of synthesis and LiClO4 content as addition
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ATTEMPTS OF THERMAL IMAGING CAMERA USAGE IN ESTIMATIONS OF THE CONVECTIVE HEAT LOSS FROM A VERTICAL PLATE
PublicationIn this paper a new method for determining heat transfer coefficients using a gradient method has been developed. To verify accuracy of the proposed method vertical isothermal heating plate with natural convection mechanism has been examined. This configuration was deliberately chosen, because of the fact that such case is historically the earliest and most thoroughly studied and its rich scientific documentation - the most reliable....
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Quantitative study of free convective heat losses from thermodynamic partitions using Thermal Imaging
PublicationThe following paper presents a simple method of determining the presence, distribution and values of heat losses from external building walls as thermodynamic partitions using a Thermal Imaging Camera (TIC). According to Fourier's equation, the value of heat loss is proportional to the temperature gradient ∂t/∂y|y=0 in air in the y direction perpendicular to the heated surface. Unfortunately, air temperature cannot be measured...
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Influence of nanoparticle concentration on convective heat transfer of water-Al2O3 nanofluids inside horizontal tubes
PublicationNanofluids came to be seen as a new generation of coolants, especially in single-phase systems. Conducted experiments indicate that the increase in thermal conductivity is not the only reason for the intensification of heat transfer when using nanofluids. Preliminary results of the experimental investigation of the forced convection heat transfer of water-Al2O3 nanofluids inside stainless steel tube with 8 mm internal diameter...
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Highly stable organic–inorganic junction composed of hydrogenated titania nanotubes infiltrated by a conducting polymer
PublicationA poly(3,4-ethylenedioxythiophene) conducting polymer doped with poly(2-styrene sulfonate) (pEDOT:PSS) was efficiently electrodeposited on a layer composed of ordered titania nanotubes. TiO2 nanotubes were formed during an anodization process and, after calcinations, a layer was subjected to hydrogen plasma. Hydrogenation leads to Ti(III) formation, a decrease in resistance, and a huge increase of donor density when compared with...
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Synthesis and Testing of BCZY/LNZ Mixed Proton–electron Conducting Composites for Fuel Cell Applications
PublicationA composite of BaCe0.6Zr0.2Y0.2O3–δ and Li2O:NiO:ZnO was investigated for fuel cell applications. The composite was successfully synthesized and its phase stability was confirmed at temperatures up to 900 °C. The influence of sintering and pressing aids on density was also investigated. Electrical properties were measured. DC electrical conductivity was about 8•10-4 S/m at 845 K. Open circuit voltage measurements in wet hydrogen...
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Influence of nanoparticle concentration on convective heat transfer of water-Al2O3 nanofluids inside horizontal tubes
PublicationThis work presents preliminary results of the experimental investigation of the forced convection heat transfer of water-Al2O3 nanofluids inside stainless steel tube with 8 mm internal diameter and 2000 mm length. Nanoparticles were tested at the concentrations of 0.01%, 0.1%, 1% and 5% by weight and the Reynolds number range encompasses laminar as well as turbulent flows.
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Understanding the capacitance of thin composite films based on conducting polymer and carbon nanostructures in aqueous electrolytes
PublicationIn this work electrochemical performance of thin composite films consisted of poly(3,4-ethylenedioxythiophene) (PEDOT), graphene oxide (GOx) and oxidized multiwalled carbon nanotubes (oxMWCNTs) is investigated in various sulphates (Li2SO4, Na2SO4, K2SO4, MgSO4) and acidic (H2SO4) electrolytes. Capacitance values, rate capability and cycling stability achieved for the composite layers are correlated with the electrolytes’ properties...
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Hyperbolic heat conduction at a microscopic sliding contact with account of adhesion-deformational heat generation and wear
PublicationDifferent non-Fourier models were proposed to simulate temperatures in materials subjected to extremely fast thermal disturbances, when the speed of heat propagation should be concerned. The present study investigated temperature and heat balance at a microscopic sliding contact during a single frictional interaction based on the Cattaneo-Vernotte hyperbolic heat conduction equation. Two fundamental features of friction, namely,...
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Nanosize effect of clay mineral nanoparticles on the drug diffusion processes in polyurethane nanocomposite hydrogels
PublicationStudies of swelling and release of naproxen sodium (NAP) solution by polyurethane nanocomposite hydrogels containing Cloisite® 30B (organically modified montmorillonite (OMMT)) have been performed. Polyurethane nanocomposite hydrogels are hybrid, nontoxic biomaterials with unique swelling and release properties in comparison with unmodified hydrogels. These features enable to use nanocomposite hydrogels as a modern wound dressing....
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The effect of changes in the concentration of hydroxypropylcellulose on the rheological stability of pectin hydrogels.
Open Research DataThe rheological characteristics of the pectin hydrogel modified by hydroxypropylcellulose (added in a concetration range from 0.1 to 0.55% m/m) were made on the basis of the viscosity assessment using a Brookfield viscometer with an LV SC4 - 25 spindle and a shear rate of 0,22 s-1 in the temperature range 19-96 ° C.The data allowed selection of optimal...
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Dietary antioxidants as a source of hydrogen peroxide
PublicationStudies of 54 antioxidants revealed that 27 of them, mainly polyphenols, generated hydrogen peroxide (H2O2) when added to Dulbecco’s modified Eagle’s medium (DMEM), other media used for culture of mammalian and yeast cells and phosphate-buffered saline. The most active antioxidants were: propyl gallate (PG), (−)-epigallocatechin gallate (EGCG) and quercetin (Q). Chelex treatment and iron chelators decreased H2O2 generation suggesting...
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Hydrogen generation using solar energy
PublicationWodór jest uważany za alternatywne i odnawialne źródło energii. Bezpośrednie wykorzystanie światła słonecznego do fotokatalitycznego lub fotoelektrochemicznego rozkładu wody może zapewnić w przyszłości ekonomicznie uzasadnione, alternatywne źródło wodoru. W pierwszym etapie naszych badań został zaprojektowany i zbudowany hybrydowy, fotowoltaiczno-elektrochemiczny układ, dokonujący konwersji energii promieniowania słonecznego na...
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Hydrogen migration in photodissociation of the pyridine molecules
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Hydrogen sulphide electrocatalytic gas sensor
PublicationIn this article measurement results of the electrocatalytic gas sensor in different concentrations of hydrogen sulphide are presented. Working principle of such sensor is based on electric current acquisition, while voltage ramp is applied to the sensor. During voltage sweep oxidation and reduction reactions occurs on the sensor electrodes. Obtained current-voltage plot has unique shape connected...
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Hydrogen generation using solar energy
PublicationWodór jest uważany za alternatywne i odnawialne źródło energii. Bezpośrednie wykorzystanie światła słonecznego do fotokatalitycznego lub fotoelektrochemicznego rozkładu wody może zapewnić w przyszłości ekonomicznie uzasadnione, alternatywne źródło wodoru. W wystąpieniu przedstawione zostały wyniki dotychczasowych prac związanych z hybrydową, fotowoltaiczno-elektrochemiczną instalacją do rozkładu wody oraz omówione zostały kierunki...
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Methods for the characterizing hydrogen degradation of materials
PublicationDokonano przeglądu różnych metod szacowania podatności na niszczenie wodorowe materiałów metalowych. Zaprezentowano charakterystyki warunków środowiskowych: standardowe składy środowisk ciekłych i gazowych, temperatury, warunki polaryzacji elektrochemicznej. Omówiono metody mechaniczne szacowania niszczenia wodorowego różniące się stanem naprężeń, w tym badania: przy stałym obciążeniu, stałym odkształceniu i stałej niskiej szybkości...
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Modified Inductive Multi-Coil Wireless Power Transfer Approach Based On Z-Source Network
PublicationThis article presents a non-conventional approach to a multi-coil wireless power transfer system based on a Z-source network. The novelty of the approach lies in the use of a Z-source as a voltage source for energy transmission through the wireless power transfer coils. The main advantage is in a reduced number of semiconductors. This paper provides the design approach, simulation and experimental study. Feasibility and possible...
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Physicochemical studies (BET) of nanoparticles used for 3D printable conductive composites
Open Research DataThis dataset contains physico-chemical examination of fillers used to fabricate new 3D printing-dedicated composites with poly-lactic acid (PLA), carbon black (CB) and nanodiamond fillers. Geometric surface area of the nanoparticles was studied by Brunauer–Emmett–Teller (BET) adsorption/desorption isotherms. Investigated samples: CB Ensaco 250G, detonation...
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Rheology of Variable Viscosity‐Based Mixed Convective Inclined Magnetized Cross Nanofluid with Varying Thermal Conductivity
PublicationCross nanofluid possesses an extraordinary quality among the various fluidic models to explore the key characteristics of flowing fluid during very low and very high shear rates and its viscosity models depend upon shear rate. The current study establishes the numerical treatment regarding variable viscosity‐based mixed convective inclined magnetized Cross nanofluid with var‐ ying thermal conductivities over the moving permeable...
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Influence of magnetic field on electronic conduction of (Bi,Pb)–Sr–Ca–Cu–O granular superconductors
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