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Wyniki wyszukiwania dla: NON-ADIABATIC CHEMISTRY
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Non-Contact Temperature Measurements Dataset
PublikacjaThe dataset titled The influence of the distance of the pyrometer from the surface of the radiating object on the accuracy of measurements contains temperature measurements using a selection of four commercially available pyrometers (CHY 314P, TM-F03B, TFA 31.1125 and AB-8855) as a function of the measuring distance. The dataset allows a comparison of the accuracy and measuring precision of the devices, which are very important...
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A Comparative Numerical Simulation Study of Turbulent Non-premixed CO/H2/N2 Syngas Jet Flames
PublikacjaIn the present work, numerical simulations of turbulent non-premixed syngas flame have been performed in Reynolds-Averaged Naver-Stokes turbulence approach using four turbulence-chemistry interaction models. To this aim, we used assumed beta PDF approach, Steady Laminar Flamelet model, Eddy Dissipation Concept and Partially Stirred Reactor model. Numerical results are compared and analysed with respect to two experiments from the...
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Steering is an essential feature of non-locality in quantum theory
PublikacjaA physical theory is called non-local when observers can produce instantaneous effects over distant systems. Non-local theories rely on two fundamental effects: local uncertainty relations and steering of physical states at a distance. In quantum mechanics, the former one dominates the other in a well-known class of non-local games known as XOR games. In particular, optimal quantum strategies for XOR games are completely determined...
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The chemistry of river–lake systems in the context of permafrost occurrence (Mongolia, Valley of the Lakes) Part II. Spatial trends and possible sources of organic composition
PublikacjaThe chemistry of river–lake systems located in Central Mongolia near the southern border of permafrost occurrence has not been well studied. The main aim of this paper is to summarize patterns in water chemistry in supply springs, rivers and lakes in relation to permafrost occurrence, as well as other natural and anthropogenic impacts. The analyses involved water samples taken from two river–lake systems: the Baydrag River–Böön...
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Color prediction from first principle quantum chemistry computations: a case of alizarin dissolved in methanol
PublikacjaThe electronic spectrum of alizarin (AZ) in methanol solution was measured and used as reference data for color prediction. The visible part of the spectrum was modelled by different DFT functionals within the TD-DFT framework. The results of a broad range of functionals applied for theoretical spectrum prediction were compared against experimental data by a direct color comparison. The tristimulus model of color expressed in terms...
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Production of new non-matrix reference material of ethene
PublikacjaThe main objective of the research is to produce new non-matrix reference materials of ethene. The study are based on thermal decomposition of surface compound chemically bonded with the surface of glass fibers coated with thin layer of aluminum. Positivehomogeneity test, stability test and organization of inter-laboratory comparison are leading to find new non-matrix reference materials which are indispensable tools in the analysis...
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Non-Isocyanate-Based Waterborne Polyurethanes
PublikacjaNon-isocyanate polyurethanes (NIPUs) are a greener alternative for the conventional polyurethanes synthesized using toxic and moisture-sensitive di- or polyisocyanates. The most often described method of NIPU synthesis involves the reaction of five-membered cyclic carbonates with amines, and resulting polymers containing primary and secondary hydroxyl groups (so they are also known as polyhydroxyurethanes), which can be further...
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A non-linear direct peridynamics plate theory
PublikacjaIn this paper a direct non-local peridynamics theory for thin plates is developed. Peridynamic points are assumed to behave like rigid bodies with independent translation and finite rotation degrees of freedom. The non-local mechanical interaction between points is characterized by force and moment vectors. The balance equations including the linear momentum, the angular momentum and the energy are presented. Peridynamic deformation...
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Environmental Role of Rime Chemistry at Selected Mountain Sites in Poland
PublikacjaThe results of field experiments on fog pollutantdeposition enhanced by local mountain climate, completed by thedendrochronological analysis of the forest response, are presentedin this paper. In spite of their low absolute altitude (1,000-1,600 ma.s.l), the Sudetes and the Silesian Beskid form a noticeable orographicbarrier for the airflow of the humid Atlantic air masses.This results in the increase of cloudiness and fog frequency...
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Green Analytical Chemistry in Determination of Volatile Fatty Acids in Wastewater
PublikacjaCharakterystyka metodyk oznaczania lotnych kwasów tłuszczowych w próbkach wodnych, opierających się na Zasadach Zielonej Chemii. Opis zastosowania techniki bezpośredniego dozowania próbki wodnej do chromatografu gazowego, techniki analizy fazy nadpowierzchniowej oraz techniki mikroestrakcji do fazy stacjonarnej.
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Dew and hoarfrost frequency, formation efficiency and chemistry in Wroclaw, Poland
PublikacjaThis article presents the results of a research study concerning a comparison of frequency, formation efficiency and basic physico-chemical properties of dew and hoarfrost in urban conditions. Longer than two-year series of measurements was carried out from 1 February 2008 to 10 March 2010 in Wroclaw, Poland. Sampling of atmospheric deposits was made by means of insulated plain passive radiative condensers, which allowed to collect...
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Assessment of Trajectories of Non-bankrupt and Bankrupt Enterprises
PublikacjaThe aim of this study is to show how long-term trajectories of enterprises can be used to increase the forecasting horizon of bankruptcy prediction models. The author used seven popular forecasting models (two from Europe, two from Asia, two from North America and one from Latin America). These models (five multivariate discriminant analysis models and two logit models) were used to develop 17-year trajectories separately for non-bankrupt...
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Determinants of the incidence of non-academic staff in European and US HEIs
PublikacjaIn this article, we contribute to the scant literature covering quantitative studies on the determinants of the non-academic staff incidence in higher education institutions by analysing how the proportion of non-academic staff is related to key features such as size, prestige, year of foundation and financial structure of universities. We apply nonlinear regression analysis to compare HEIs across Europe and the USA, taking into...
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Objectivity in the non-Markovian spin-boson model
PublikacjaObjectivity constitutes one of the main features of the macroscopic classical world. An important aspect of the quantum-to-classical transition issue is to explain how such a property arises from the microscopic quantum theory. Recently, within the framework of open quantum systems, there has been proposed such a mechanism in terms of the so-called spectrum broadcast structures. These are multipartite quantum states of the system...
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NON-LINE ANALYSIS OF STIFFNESS IN COMPRESSION CONDITIONS
PublikacjaThe analyzes were aimed at demonstrating the influence of parameters describing the deformation of the structure on the uncertainty of critical force, and the impact of technological imperfections on stress uncertainty in compression conditions. In a linear buckling analysis, the problem is considered only for the initial, permanent state of the stiffness matrix. In the case of demonstrating the influence of initial deformations...
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Identification of Non-stationary and Non-linear Drying Processes
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Non invasive optical cellular imaging in humans.
PublikacjaOne of the most appealing and still unsolved problems in biological and medical imaging is the possibility of noninvasive visualization of tissue in vivo with an accuracy of microscopic examination. A major difficulty to solve in biomedical imaging is a degradation of image quality caused by the presence of optical inhomogeneity of tissue. Is there any chance to develop a microscopic method that allows non-invasive observation...
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Chemistry of human breast milk – a comprehensive review of the composition and role of milk metabolites in child development
PublikacjaEarly nutrition has an enormous influence on a child's physiological function, immune system maturation and cognitive development. Human breast milk (HBM) is recognized as the gold standard for human infant nutrition. Accordingly to WHO report breastfeeding is consider as an unequalled way of providing ideal food to the infant, which is required for his healthy growth and development. HBM contains various macronutrients (carbohydrates,...
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Non-compulsory practical education programme for modernist heritage
PublikacjaA non-compulsory programme for students of architecture that contains more specialised topics beyond the basic subjects is an important educational tool. The advantages include classes in smaller groups, the possibility of practical exercises in real field conditions and the benefits of meeting professional practitioners. This type of programme is particularly useful for teaching architectural heritage of the 20th Century, its...
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On constitutive relations in the resultatnt non-linear theory of shells
PublikacjaThe authors summarize their current research in the field of constitutive modelling in the framework of non-linear 6-parameter shell theory. In particular the description of isotropic, multilayered composite and functionally graded shells is presented.
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A Method of Real-Time Non-uniform Speech Stretching
PublikacjaDeveloped method of real-time non-uniform speech stretching is presented.The proposed solution is based on the well-known SOLA algorithm(Synchronous Overlap and Add). Non-uniform time-scale modification isachieved by the adjustment of time scaling factor values in accordance with thesignal content. Dependently on the speech unit (vowels/consonants), instantaneousrate of speech (ROS), and speech signal presence, values of the scalingfactor...
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Non-Nutritive Bioactive Compounds in Food of Plant Origin
PublikacjaThe increasing knowledge on the health benefits of certain food ingredients, in particular, those of plant origin, opened the discussion of the possibility of using edible plants or their active components in the prevention of non-communicable diseases. The health-promoting properties of plant foods are related to the presence of non-nutritive compounds, mainly plant secondary metabolites, which can affect many biological mechanisms...
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On Non-holonomic Boundary Conditions within the Nonlinear Cosserat Continuum
PublikacjaWithin the framework of the nonlinear micropolar elastic continuum we discuss non-holonomic kinematic boundary conditions. By non-holonomic boundary conditions we mean linear relations between virtual displacements and virtual rotations given on the boundary. Such boundary conditions can be used for modelling of complex material interactions in the vicinity of the boundaries and interfaces.
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Review of non- welded piping technologies on offshore equipment projects
PublikacjaThe aim of this article are considerations on welded and non-welded tube connection technologies, with advantages and disadvantages of both. After choosing non-welded solutions as the assembly method of choice, the thesis progresses to describing the most widely-used tube connection technologies (JIC, Ermeto, retain ring flanges, flared tube flanges and other, minor, solutions) and their properties.
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On geometrically non-linear FEA of laminated FRP composite panels
PublikacjaThe paper presents a state-of-art review on Finite Element Analysis (FEA) of geometrically non-linear problems for laminated composite plates and shells made as fibre reinforced polymer (FRP) laminates. Besides a subjective overview of the historical development of geometrically non-linear FEA of laminated FRP composite panels, some remarks on possible future issues in this research area are given
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Bell-Type Inequalities from the Perspective of Non-Newtonian Calculus
PublikacjaA class of quantum probabilities is reformulated in terms of non-Newtonian calculus and projective arithmetic. The model generalizes spin-1/2 singlet state probabilities discussed in Czachor (Acta Physica Polonica:139 70–83, 2021) to arbitrary spins s. For s → ∞ the formalism reduces to ordinary arithmetic and calculus. Accordingly, the limit “non-Newtonian to Newtonian” becomes analogous to the classical limit of a quantum theory
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Non-enzymatic flexible glucose sensing platform based on nanostructured TiO2–Au composite
PublikacjaAll over the world the number of people suffering from diabetes and related complications is drastically growing. Therefore, the need for accurate, reliable and stable sensor for monitoring of glucose in human body fluids is becoming highly desirable. In this work we show that material composed of gold layers deposited onto TiO2 nanotubes (NTs) formed onto the flexible Ti foil exhibits great response toward glucose oxidation and...
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Adaptive Wavelet-Based Correction of Non-Anechoic Antenna Measurements
PublikacjaNon-anechoic measurements represent an affordable alternative to evaluation of antenna performance in expensive, dedicated facilities. Due to interferences and noise from external sources of EM radiation, far-field results obtained in non-ideal conditions require additional post-processing. Conventional correction algorithms rely on manual tuning of parameters, which make them unsuitable for reliable testing of prototypes. In this...
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Non‐Proteasomal Urine Activity in Bladder Cancer
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Social benefits valuation of hosting non-mega sporting events
PublikacjaPurpose In the study, an attempt was made to estimate the social benefits resulting from three non-mega sporting events organized in Ergo Arena located on the border of two cities in Poland. By attributing a value to intangible social benefits, the intangible effect was determined and compared to the expenditure incurred in the construction of Ergo Arena Hall. Design/methodology/approach In order to value social intangible effects...
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Acid-aided epoxy-amine curing reaction as reflected in epoxy/Fe3O4 nanocomposites: Chemistry, mechanism, and fracture behavior
PublikacjaThis work seeks to answer the question whether or not the presence of acid functional groups accelerate epoxyamine curing reaction. Epoxy/Fe3O4 nanocomposite was considered as a case, where discussions are based on chemistry, mechanism behind curing reactions and fracture behavior influenced by acid assistance to crosslinking. Fe3O4 magnetic nanoparticles (MNPs) with nanosilica decorative layer (B-MNP) were synthesized and subsequently...
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Non-Wave Variations in Temperature Caused by Sound in a Chemically Reacting Gas
PublikacjaA weakly nonlinear generation of non-acoustic modes in the field of sound in a gas is considered. An exotericchemical reaction of A->B type, which takes place in a gas, may be reversible or not. Two types of sound areconsidered, low-frequency and high-frequency as compared with the characteristic time of a chemical reaction.For both these cases, the governing equations of non-acoustic modes are derived and conclusions of the efficiencyof...
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Non-proportional full-order Luenberger observers of induction motors
PublikacjaThe paper recapitulates recently conducted investigations of non-proportional Luenberger observers, applied to reconstruction of state variables of induction motors. Three structures of non-proportional observers are analyzed, a proportional-integral observer, modified integral observer and observer with integrators. Criteria for gain selection of the observer are described, classical ones based on poles, as well as additional,...
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Introducing the concept of sustainable development into analytical practice: green analytical chemistry
PublikacjaW rozdziale przedstawiono innowacyjne techniki analityczne spełniające wymogi zrównoważonego rozwoju w kontekscie praktyki analitycznej. Przedstawiono bezrozpuszczalnikowe metody przygotowania próbek oraz przykłady calych procedur analitycznych spełniajacych warunek zielonej chemii analitycznej
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A Comprehensive Review of Chemistry, Sources and Bioavailability of Omega-3 Fatty Acids
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Rime and hoarfrost chemistry in Poland - an introductory analysis from meteorological perspective
PublikacjaPróbki szronu i sadzi pobierano odpowiednio w 6 i 3 miejscach, które reprezentują zarówno nizinne jak i górzyste części Polski. Niższe stężenia jonów stwierdzono zarówno w próbkach szronu jak i sadzi pobranych na terenie nizinnym. Wynika to ze stosunkowo wysokiej inwersji temperatury i mniej intensywnego krążenia atmosferycznego w tym regionie. Stwierdzono również różne wartości stosunku Na/Cl w próbkach sadzi i szronu zebranych...
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Design of selective substrates of proteinase 3 using combinatorial chemistry methods
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Some remarks on gas chromatographic challenges in the context of green analytical chemistry
PublikacjaOmówiono możliwości wprowadzenia zasad zielonej chemii analitycznej w odniesieniu do technik chromatograficznych.
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Tendencies of change in the chemistry of precipitation at three monitoring stations 1996-1999.
PublikacjaW pracy przedstawiono wyniki porównawczych badań składu próbek opadów deszczowych zebranych na trzech stacjach w okresie 1996-1999, (stacje te różnią się zdecydowanie ze względu na usytuowanie geograficzne). W postaci graficznej przedstawiono zaobserwowane tendencje w składzie zebranych próbek wód opadowych.
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Badania międzylaboratoryjne w chemii analitycznej. Interlaboratory tests in analytical chemistry.
PublikacjaW pracy dokonano podziału dostępnych badań międzylaboratoryjnych w zależności od założonego celu badań. Przedstawiono i scharakteryzowano podstawowe typy programów badań międzylaboratoryjnych oraz aspekt ich organizacji. Omówiono również wykorzystanie badań biegłości/porównań międzylaboratoryjnych w procesach akredytacji i nadzoru laboratoriów oraz możliwy sposób obróbki danych nadesłanych przez uczestników badań.
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CSR and innovation or CSR as non-technological innovation
PublikacjaThis chapter investigates the relationship between Corporate Social Responsibility (CSR) and innovation process. There is an ongoing discussion in the literature regarding this relationship, in particular on its one- or bidirectional nature and possible antecedents or mediating factors. This research addresses this gap and aims to provide more conceptual clarity and synthesize the different types of relationships between CSR and...
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Application of linear discriminant analysis to the study of dew chemistry on the basis of samples collected in Poland (2004-2005)
PublikacjaTechnikę analizy dyskryminacyjnej wykorzystano do klasyfikacji próbek rosy (zebranych w okresie sierpień 2004 - październik 2005 na terenie Gdyni, Gdańska, Mławy, Sopotu, Krakowa, w których oznaczono stężenia wybranych związków nieorganicznych i organicznych) na naturalnie wyłaniające się grupy oraz by zidentyfikować parametry fizykochemiczne odpowiedzialne za podobieństwa i różnice pomiędzy poszczególnymi miejscami pobierania...
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Non-ergodic fragmentation upon collision-induced activation of cysteine–water cluster cations
PublikacjaCysteine–water cluster cations Cys(H2O)3,6 + and Cys(H2O)3,6H+ are assembled in He droplets and probed by tandem mass spectrometry with collision-induced activation. Benchmark experimental data for this biologically important system are complemented with theory to elucidate the details of the collisioninduced activation process. Experimental energy thresholds for successive release of water are compared to water dissociation energies...
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Comparison of hydrochemistry and organic compound transport in two non-glaciated high Arctic catchments with a permafrost regime (Bellsund Fjord, Spitsbergen)
PublikacjaAn increase in air temperature related to climate change results in the retreat of glaciers, the degradation of permafrost, and the expansion of glacier-free areas in the polar regions. All these processes lead to changes in the Arctic landscape. They influence the hydrochemistry of streams and rivers fed by glaciers and thawing permafrost. In this study, we examine eighty two water samples from two non-glaciated catchments with...
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Opioid Growth Factor and its Derivatives as Potential Non-toxic Multifunctional Anticancer and Analgesic Compounds
PublikacjaIn this paper, we review the structure-activity relationship of OGF and its analogues. We highlight also OGF derivatives with analgesic, immunomodulatory activity and the ability to penetrate the blood-brain barrier and may be used as safe agents enhancing chemotherapy efficacy and improving quality of life in cancer patients. The reviewed papers indicate that Met-enkephalin and its analogues are interesting candidates for the...
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Positive solutions to Sturm–Liouville problems with non-local boundary conditions
PublikacjaIn this paper, the existence of at least three non-negative solutions to non-local boundary-value problems for second-order differential equations with deviating arguments α and ζ is investigated. Sufficient conditions, which guarantee the existence of positive solutions, are obtained using the Avery–Peterson theorem. We discuss our problem for both advanced and delayed arguments. An example is added to illustrate the results.
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Novel chalcone-derived pyrazoles as potential therapeutic agents for the treatment of non-small cell lung cancer
PublikacjaLung cancer is considered to account for approximately one-fifth of all malignant tumor-related deaths worldwide and is therefore one of the most lethal malignancies. Pyrazole scaffold possesses a wide range of biological and pharmacological activities, which play important roles in medicinal chemistry. The present study reports the synthesis and in vitro biological characterization of nine pyrazoles derived from chalcones as potential...
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How non-technological innovation saved the day by using ICT
PublikacjaCertainly, the current pandemic situation provides a lot of evidence of the need for non-technological innovations, both in the area of company organization and marketing. Socio-cultural innovations are not less important. Therefore, the role of non-technological innovation during the COVID-19 pandemic is discussed in the sixth chapter. Innovations supported by digital solutions have become a silent heroes for many companies as...
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Rethinking non-governmental organizations – at the crossroad of economics and civil society
PublikacjaThe article aims to close the existing knowledge gaps, show why non‑governmental organizations are founded and maintained, and elaborate and systematize the existing knowledge through an analysis of the existing subdisciplines within economics, laying the groundwork for the economics of non‑governmental organizations. The article was written based on a structured literature review with an approach similar to the grounded theory...
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Non-Linear Control of Electrical Machines Using Non-Linear Feedback
PublikacjaPrzedstawiono zasady nieliniowego sterowania oraz zastosowanie nielinowego sprzężenia zwrotnego do maszyn elektrycznych. Opisano nieliniowe sterowanie obcowzbudnym silnikiem prądu stałego. Zaprezentowano multiskalarne modele maszyn prądu przemiennego. Maszynę indukcyjną zamodelowano z wykorzystaniem strumienia wirnika oraz z wykorzystaniem strumienia stojana. MMultiskalarne modele maszyny indukcyjnej wykorzystano do nieliniowego...