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Wyniki wyszukiwania dla: IR(III) AND RH(III) HALF-SANDWICH COMPLEXES
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Processing, physico-mechanical and thermal properties of reclaimed GTR and NBR/reclaimed GTR blends as function of various additives
PublikacjaIn this work, ground tire rubber (GTR) was mechano-chemically reclaimed in the presence of bitumen and various additives. During studies three types of processing and curing additives: (i) peptizer P300; (ii) vulcanization accelerator tetramethylthiuram disulfide (TMTD) and (iii) organic peroxide di(2-tert-butyl-peroxyisopropyl)benzene (BIB1) were applied to enhance reclaiming of GTR. Reclaiming process was evaluated by oscillating...
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Wykorzystanie PIX 112 do usuwania jonów arsenu z wody podziemnej w procesie koagulacji powierzchniowej w złożu filtru piaskowo-piroluzytowego
PublikacjaArtykuł jest podsumowaniem badań przeprowadzonych w skali ułamkowo-technicznej oraz doświadczeń z trzyletniej eksploatacji niewielkiej stacji oczyszczania wody podziemnej. Wykazano, że zastosowanie koagulacji powierzchniowej związkami żelaza (dawkowanie koagulantu, napowietrzanie/mieszanie, filtracja przez złoże kwarcowo-piroluzytowe), pozwala skutecznie usunąć zawarte w ujmowanej wodzie jony arsenu do ilości zgodnej z wymaganiami...
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Zróżnicowanie państw Unii Europejskiej ze względu na stopień decentralizacji fiskalnej
PublikacjaArtykuł miał na celu porównanie stopnia decentralizacji wydatkowej w krajach UE. Oprócz celu głównego obrano cele szczegółowe, takie jak: identyfikacja cech państw, w których średni poziom decentralizacji wydatkowej był zbliżony, konfrontacja wyników z rezultatami przedstawianymi w literaturze, sprawdzenie przydatności metody analizy skupień do grupowania obiektów (krajów), gdy zmienną jest decentralizacja wydatkowa. Zakres badań...
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Ni/cerium Molybdenum Oxide Hydrate Microflakes Composite Coatings Electrodeposited from Choline Chloride: Ethylene Glycol Deep Eutectic Solvent
PublikacjaCerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced, due to the existence of some microcracks caused by large microflakes. Multielemental analysis of the solution, in which coatings are exposed and the qualitative changes in the surface...
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The Toolbox of Methods for Multidirectional Characterization of Dietary Nucleic Acids; Verification for Raw and Processed Food Products
PublikacjaCurrently, the nutritional value of food is associated mainly with components such as proteins, carbohydrates, and lipids. However, another important macromolecules present in many foods are dietary nucleic acids (dietNA), i.e., DNA as well as both coding and non-coding RNAs. In the context of food chemistry and nutrition, dietNA are nowadays vastly neglected. In consequence, there are no dedicated methodologies to characterize...
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Reclaimed rubber in-situ grafted with soybean oil as a novel green reactive plasticizer in SBR/silica compounds
PublikacjaPolymer recycling and biodegradable polymeric materials are two major routes towards the sustainable development of polymer materials which contributes to the management of waste. In this regard, an eco-friendly approach is presented wherein high reclaiming degree of ground tire rubber (GTR) was achieved by low-temperature oxidation under swollen action of soybean oil. In-situ reclaimed GTR with soybean oil was cured into reactive...
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Numerical modelling of different airbag folding patterns and their influence on occupant responses in frontal vehicle impact
PublikacjaThis paper presented a procedure for airbag folding for the application in occupant safety studies and analysed the influence of different airbag folding patterns on the occupant severity in frontal impact. Airbags were folded in two patterns: zig-zag and top-roll, using two folding techniques: Initial Metric Method and Explicit Folding. The explicit folding was found to be more expensive in terms of preparation time. However,...
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Badania odbiorcze mostu (próbne obciążenie).
PublikacjaMost III Tysiąclecia im. Jana Pawła II jest elementem Trasy Sucharskiego w Gdańsku, łączącej ul. Elbląską od strony południowej nad Martwą Wisłą z węzłem Wosia Budzysza i dalej portem Północnym. Most oddano do użytku w październiku 2001r. Jego budowa była, z punktu widzenia realizacji, przedsięwzięciem wysoce oryginalnym w skali kraju, gdyż to właśnie tutaj po raz pierwszy w Polsce zastosowano montaż wspornikowy przy budowie mostu...
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Projekt Trasy Henryka Sucharskiego.
PublikacjaMost III Tysiąclecia im. Jana Pawła II jest elementem Trasy Sucharskiego w Gdańsku, łączącej ul. Elbląską od strony południowej nad Martwą Wisłą z węzłem Wosia Budzysza i dalej portem Północnym. Most oddano do użytku w październiku 2001r. Jego budowa była, z punktu widzenia realizacji, przedsięwzięciem wysoce oryginalnym w skali kraju, gdyż to właśnie tutaj po raz pierwszy w Polsce zastosowano montaż wspornikowy przy budowie mostu...
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Endometrial nitric oxide production and nitric oxide synthases in the equine endometrium: Relationship with microvascular density during the estrus cycle
PublikacjaNitric oxide (NO) plays an important role in angiogenesis and in the regulation of the blood flow. This study was carried out to investigate (i) the effects of endogenous estrogens and progestins and exogenous progesterone (P(4)) (5 ng/ml or 1 microg/ml) or estradiol 17beta (E(2)beta) (50 pg/ml or 1 microg/ml) on in vitro endometrial NO synthesis; (ii) the presence of different isoforms of NO synthase;...
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Postępy w rozwoju standardu IEEE 802.11 i jego zastosowań
PublikacjaW prezentowanej serii artykułów skoncentrowano się na przedstawieniu najnowszych rozszerzeń standardu IEEE 802.11 - podstawy bardzo popularnej techniki Wi-Fi, umożliwiających realizację transmisji z szybkościami przekraczającymi 1 Gbit/s (część I), a także na nowych obszarach zastosowań tych sieci (część II). Nieustanna poprawa parametrów tych sieci (tj. szybkości i jakości pracy), a także coraz lepsza wydajność i komfort wykorzystania...
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Heat Dissipation from the Power Cable in the Casing Pipe
PublikacjaThe current carrying capacity of a power cable determines its ability to carry a specific current and is related to the efficiency of dissipation of heat generated in the cable laid in a specific environment. The studies were conducted in order to determine how the characteristics of the medium around the cable affected its temperature, and thus the ability of the cable to transmit electricity. The experimentation in the lab and...
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Usuwanie arsenu z wody podziemnej w procesie zintegrowanym - koagulacja/mikrofiltracja
PublikacjaW pracy przedstawiono wyniki badań przeprowadzonych w skali ułamkowo technicznej nad zastosowaniem procesu koagulacji (współwytrącania) jonami żelaza, zintegrowanego z mikrofiltracją, do usuwania arsenu z wody podziemnej, zawierającej ok. 40 μg As/l, 0,70 mg Fe/l oraz 0,09 mg Mn/l. Jako koagulant zastosowano wodny roztwór siarczanu żelaza (III), w dawkach od 0,5 do 18 mg Fe/l. W badaniach wykorzystano rurowe membrany mikrofiltracyjne...
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Quality of graphical markers for the needs of eyewear devices
Publikacjain this paper we propose to cast the problem of identification of people, objects or places into an application for smart glasses that decodes information from graphical markers. We focus on analyzing different factors that can have influence on the processes of the automatic recognition of information from a code. The research we present aims at reviewing recognition performances in function of: size of a marker, distance from/to...
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Organic-inorganic composites consisted of poly(3,4-ethylenedioxythiophene)and Prussian Blue analogues
PublikacjaThe organic-inorganic material consisted of poly(3,4-ethylenedioxythiophene) (pEDOT) and copper hexacyanoferrate (Cuhcf) was synthesized. The pEDOT film with Fe(CN)63−/4− as counter-ions potentiodynamically polarized in aqueous CuCl2 electrolyte brings about stable hybrid material (pEDOT/Cuhcf) performing single redox activity of FeII/III at a formal potential Ef = 0.61 V (vs. Ag/AgCl/0.1 M KCl) and less clearly shaped two redox...
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Spatial variability of throughfall in a stand of Scots pine (Pinus sylvestris L.) with deciduous admixture as influenced by canopy cover and stem distance
PublikacjaVegetation cover affects the amount of precipitation, its chemical composition and its spatial distribution, and this may have implications for the distribution of water, nutrients and contaminants in the subsurface soil layer. The aim of this study was a detailed diagnosis of the spatio-temporal variability in the amount of throughfall (TF) and its chemical components in a 72-year-old pine stand with an admixture of oak and birch....
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A method to monitor urinary carbon dioxide in patients with septic shock
PublikacjaSevere sepsis and septic shock are life-threatening conditions with mortality rates exceeding 31% (Levy et al., 2012) [1]. Septicemia was the most expensive US hospital condition in 2011 (Torio and Andrews, 2006)[2]. Urinary carbon dioxide may provide rapid, clinically useful information about a patient’s status, empowering physicians to intervene earlier and improve septic shock mortality. The objective of this paper is to validate...
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Status report on high temperature fuel cells in Poland – Recent advances and achievements
PublikacjaThe paper presents recent advances in Poland in the field of high temperature fuel cells. The achievements in the materials development, manufacturing of advanced cells, new fabrication techniques, modified electrodes and electrolytes and applications are presented. The work of the Polish teams active in the field of solid oxide fuel cells (SOFC) and molten carbonate fuel cell (MCFC) is presented and discussed. The review is oriented...
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Zmiany w krajobrazie kulturowym wywołane rekonstrukcją grodziska średniowiecznego w Owidzu Gmina Starogard Gdański
PublikacjaW referacie autorzy przedstawiają wyniki działań projektowych i inwestycyjnych związanych z rekonstrukcją wczesnośredniowiecznego grodziska w Owidzu, w gminie Starogard Gdański, wraz z infrastrukturą towarzyszącą. Grodzisko w Owidzu jest jednym z większych rozpoznanych grodzisk wczesnośredniowiecznych w Polsce Północnej. Zajmuje obszar ponad 2ha i posiada własną formę krajobrazową. Grodzisko zlokalizowane jest w zakolu rzeki Wierzyca,...
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MRI assessment of ectopic fat accumulation in pancreas, liver and skeletal muscle in patients with obesity, overweight and normal BMI in correlation with the presence of central obesity and metabolic syndrome
PublikacjaPurpose: Obesity, defined as a body mass index (BMI) exceeding 30 kg/m2, is a serious health problem, which can be called an epidemic on a global scale and is one of the most important causes of preventable death. The aim of this study was to assess ectopic fat accumulation in pancreas, liver and skeletal muscle in patients with obesity, overweight and normal BMI in correlation with metabolic syndrome (MetS). Patients and methods:...
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Stannates, titanates and tantalates modified with carbon and graphene quantum dots for enhancement of visible-light photocatalytic activity
PublikacjaMost efforts in heterogeneous photocatalysis are focused on development of new and stable photoactive materials efficient in degradation of various pollutants under visible-light irradiation. In this regard, the wide-bandgap perovskite semiconductors, i.e., SrTiO3 (titanate), SrSnO3 (stannate) and AgTaO3 (tantalate), were prepared by a solvothermal method, and then modified with carbon quantum dots (CQDs) or graphene quantum dots...
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Experience based knowledge representation for Internet of Things and Cyber Physical Systems with case studies
PublikacjaCyber Physical Systems and Internet of Things have grown significant attention from industry and academia during the past decade. The main reason behind this interest is the capabilities of such technologies to revolutionize human life since they appear as seamlessly integrating classical networks, networked objects and people to create more efficient environments. However, enhancing these technologies with intelligent skills becomes...
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Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitance
PublikacjaThe paper discusses the synthesis, photoelectrochemical and electrochemical behaviour of titania nanotube arrays modified by a pyrolyzed metal-organic framework (MOF). A poly(3,4–ethylenedioxyphene) (PEDOT) matrix with an embedded inorganic network of iron hexacyanoferrate (BP) covering TiO2 nanotubes (TNT) is used as a MOF for the further sintering procedure, resulting in a novel, thin film of carbonaceous wrap supported Fe catalytic...
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Deep eutectic solvents – A new platform in membrane fabrication and membrane-assisted technologies
PublikacjaDeep eutectic solvents (DESs) are a new class of solvents that can offset some of the primary drawbacks of typical solvents and ionic liquids (ILs). Since DESs fall into the guidelines of “Twelve Principles of Green Chemistry”, their implementation in several types of applications has exponentially increased over the last years. The usage of DESs has been directed to the designing, manufacture and purification of new materials...
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Lanthanide ions (Eu3+, Er3+, Pr3+) as luminescence and charge carrier centers in Sr2TiO4
PublikacjaA series of strontium orthotitanate (Sr2TiO4) samples doped with 2% of a mole of europium, praseodymium, and erbium were obtained using the solid-state synthesis method. The X-ray diffraction (XRD) technique confirms the phase purity of all samples and the lack of the influence of dopants at a given concentration on the structure of materials. The optical properties indicate, in the case of Sr2TiO4:Eu3+, two independent emission...
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Metabolic Profiles of New Unsymmetrical Bisacridine Antitumor Agents in Electrochemical and Enzymatic Noncellular Systems and in Tumor Cells
PublikacjaNew unsymmetrical bisacridines (UAs) demonstrated high activity not only against a set of tumor cell lines but also against human tumor xenografts in nude mice. Representative UA compounds, named C-2028, C-2045 and C-2053, were characterized in respect to their physicochemical properties and the following studies aimed to elucidate the role of metabolic transformations in UAs action. We demonstrated with phase I and phase II enzymes...
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Transformation of polyvinyl chloride (PVC) into a versatile and efficient adsorbent of Cu(II) cations and Cr(VI) anions through hydrothermal treatment and sulfonation
PublikacjaThe reuse of waste polyvinyl chloride (PVC) has drawn much attention as it can reduce plastic waste and associated pollution, and provide valuable raw materials and products. In this study, sulfonated PVC-derived hydrochar (HS-PVC) was synthesized by two-stage hydrothermal treatment (HT) and sulfonation, and shown to be a versatile adsorbent. The reoval of Cu(II) cations and Cr(VI) anions using HS-PVC reached 81.2 ± 1.6% and 60.3...
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Thermoplastic starch nanocomposites using cellulose-rich Chrysopogon zizanioides nanofibers
PublikacjaGreen thermoplastic starch (TPS) nanocomposite films aided by cellulose nanofibers (CNFs) from Chrysopogon zizanioides roots were developed and characterized. When compared to other lignocellulosic fibers, Chrysopogon zizanioides roots revealed exceptionally high cellulose content (~48%). CNFs were separated using an environmentally friendly acid isolation technique that included three stages: (i) alkali treatment; (ii) bleaching;...
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Symulacje biomolekularne jako narzędzie do badania mechanizmów rozpoznania i wiązania pomiędzy białkami
PublikacjaBiałka pełnią wielorakie funkcje w organizmach żywych, jednak rzadko działają samodzielnie. W zdecydowanej większości przypadków współpracują one między sobą tworząc makrokompleksy o precyzyjnie zorientowanych podjednostkach. Oddziaływania międzybiałkowe wzbudzają więc duże zainteresowanie, jako że w istotny sposób odpowiadają za aktywność biologiczną białek. Choć do tej pory opracowano wiele metod doświadczalnych badania oddziaływań...
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Group-9 Transition-Metal Suboxides Adopting the Filled-Ti2Ni Structure: A Class of Superconductors Exhibiting Exceptionally High Upper Critical Fields
PublikacjaTi2Ni and the related η-carbide structure are known to exhibit various intriguing physical properties. The Ti2Ni structure with the cubic space group Fd3̅m is surprisingly complex, consisting of a unit cell with 96 metal atoms. The related η-carbide compounds correspond to a filled version of the Ti2Ni structure. Here, we report on the structure and superconductivity in the η-carbide-type suboxides Ti4M2O with M = Co, Rh, and Ir....
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The Comparison of the Web GIS Applications Relevant for 4D Models Sharing
PublikacjaThe paper presents results of the project: Cultural Heritage Through Time (CHT 2, http://cht2-project.eu) realized accomplished within the framework of the “Joint Programming Initiative in Cultural Heritage” JPI-CH (http://www.jpi-culturalheritage.eu) by an international consortium: Politecnico di Milano (IT), Newcastle University (UK), Salamanca University (ES), and Stanislaw Staszic Scientific Association SSSA (a non-profit...
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Technological solutions for boosting hydrogen role in decarbonization strategies and net-zero goals of world shipping: Challenges and perspectives
PublikacjaFacing the problems concerning greenhouse gas (GHG) emissions from international ocean shipping has meant that the latest regulations of the International Maritime Organization, issued on 1st January 2023, have come into force, with the aim of reducing GHG emissions from maritime activities. Hydrogen has been suggested as an alternative fuel to achieve decarbonization ambitions in the near future. Although hydrogen has been investigated...
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Metoda hydrofitowa jako przykład zastosowania inżynierii ekologicznej w oczyszczaniu ścieków ze źródeł punktowych i obszarowych
PublikacjaOczyszczalnie hydrofitowe są obiektami, których praca symuluje warunki hydrauliczne oraz siedliskowe naturalnych ekosystemów bagiennych i jako takie są doskonałym przykładem zastosowania inżynierii ekologicznej. Nazwa angielska - "constructed wetlands" - oddaje istotę tych obiektów jako terenów podmokłych "skonstruowanych", czyli zaprojektowanych przez człowieka. Usuwanie zanieczyszczeń organicznych, związków biogennych, a także...
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The correlation of fractal dimension to fracture surface slope for fatigue crack initiation analysis under bending-torsion loading in high-strength steels
PublikacjaIn this study, the fractal dimension of fatigue fracture surfaces is investigated in order to find an alternative failure loading indicator. Some of many metrological factors are generalized by reducing the fracture surface structure to one factor and develop an entire fracture surface procedure by analyzing the impact of surface slope and calculation resolution. Three notched geometries are studied under cyclic bending-torsion:...
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Debonding of coin-shaped osseointegrated implants: Coupling of experimental and numerical approaches
PublikacjaWhile cementless implants are now widely used clinically, implant debonding still occur and is difficult to anticipate. Assessing the biomechanical strength of the bone–implant interface can help improving the understanding of osseointegration phenomena and thus preventing surgical failures. A dedicated and standardized implant model was considered. The samples were tested using a mode III cleavage device to assess the mechanical...
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Role of Silicon in Counteracting Cadmium Stress in Pea Plants (Pisum sativum L.): Insights Into Cadmium Binding Mechanisms and Pectin Methylesterase Activity
PublikacjaPurpose: The aim of this study was to investigate the role of silicon (Si) in counteracting a cadmium (Cd) stress to pea plants (Pisum sativum L.) and to identify the mechanism by which Cd is bound within pea roots. Methods: These goals were achieved through (i) a histochemical study of Cd localization in pea roots, (ii) spectrophotometric determination of pectin content and the activity...
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Inżynieria sejsmiczna w Polsce
PublikacjaTrzęsienie ziemi, które nawiedziło 11 III 2011 Japonię oraz fala tsunami, która była jego efektem, spowodowały śmierć kilkunastu tysięcy osób oraz olbrzymie straty materialne. Awaria w uszkodzonej w wyniku tego kataklizmu elektrowni jądrowej Fukishima jest nadal jednym z najważniejszych tematów podejmowanych przez media na całym świecie. Również w Polsce rozgorzała dyskusja na temat zagrożenia sejsmicznego w naszym kraju, szczególnie...
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Optymalizacja alokacji modułów programistycznych w rozproszonym systemie szkolenia wojskowego
PublikacjaW pracy przedstawiono system metodologiczny do wyznaczania i oceny przydziałów modułów programistycznych w rozproszonym systemie informatycznym, bazującym na systemie MOODLE, wspomagającym zdalne nauczanie i szkolenie wojskowe. Opracowano modele matematyczne rozproszonych systemów komputerowych, na podstawie których sformułowano zadania optymalizacji wielokryterialnej. Główny nacisk położono na zastosowanie algorytmów ewolucyjnych...
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Nowe aplikacje technologii hydrofitowej w gospodarce komunalnej
PublikacjaW pracy przedstawiono doświadczenia pracowników Wydziału Inżynierii Lądowej i Środowiska Politechniki Gdańskiej odnoszące sie do nowych zastosowań metody hydrofitowej w zagospodarowaniu ścieków i osadów ściekowych. W artykule przedstawiono wyniki badań dotyczące obiektów hydrofitowych: (I) lokalnych przeznaczonych do biologicznego oczyszczania ścieków (pochodzących od 15 do 750 mieszkańców) znajdujących się w Darżlubiu, Wieszynie,...
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Mechanisms of Damage to DNA Labeled with Electrophilic Nucleobases Induced by Ionizing or UV Radiation
PublikacjaHypoxia—a hallmark of solid tumors—makes hypoxic cells radioresistant. On the other hand, DNA, the main target of anticancer therapy, is not sensitive to the near UV photons and hydrated electrons, one of the major products of water radiolysis under hypoxic conditions. A possible way to overcome these obstacles to the efficient radio- and photodynamic therapy of cancer is to sensitize the cellular DNA to electrons and/or ultraviolet...
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Photocatalytically Active TiO2/Ag2O Nanotube Arrays Interlaced with Silver Nanoparticles Obtained from the One-Step Anodic Oxidation of Ti–Ag Alloys
PublikacjaThe development of a photocatalyst with remarkable activity to degrade pollutants in aqueous and gas phase requires visible lightresponsive stable materials, easily organized in the form of a thin layer (to exclude the highly expensive separation step). In this work, we present a one-step strategy for synthesizing material in the form of a self-organized TiO2/Ag2O nanotube (NT) array interlaced with silver nanoparticles (as in a...
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Investigating the Impact of Curing System on Structure-Property Relationship of Natural Rubber Modified with Brewery By-Product and Ground Tire Rubber
PublikacjaThe application of wastes as a filler/reinforcement phase in polymers is a new strategy to modify the performance properties and reduce the price of biocomposites. The use of these fillers, coming from agricultural waste (cellulose/lignocellulose-based fillers) and waste rubbers, constitutes a method for the management of post-consumer waste. In this paper, highly-filled biocomposites based on natural rubber (NR) and ground tire...
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Hybrid TiO2–Polyaniline Photocatalysts and their Application in Building Gypsum Plasters
PublikacjaHybrid materials of conjugated polymer and titanium(IV) oxide have attracted considerable attention concerning their potential benefits, including (i) ecient exploitation of visible light, (ii) a high adsorption capacity for organic contaminants, (iii) and eective charge carriers separation. The new class of the photocatalysts is promising for the removal of environmental pollutants in both aqueous and gaseous phases. For the first...
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CaO-based high temperature CO2 sorbents – Literature review
PublikacjaThe use of CaO-based adsorbents has a high potential to capture CO2 from various systems due to its high reactivity with CO2, high capacity, and low cost of naturally derived CaO. The application of CaO-based sorbents to remove carbon dioxide is based on a reversible reaction between CaO and CO2. However, multiple carbonation/calcination cycles lead to a rapid reduction in the sorption capacity of natural CaO, and therefore efforts...
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Can Web Search Queries Predict Prices Change on the Real Estate Market?
PublikacjaThis study aims to explore whether the intensity of internet searches, according to the Google Trends search volume index (SVI), is a predictor of changes in real estate prices. The motivation of this study is the possibility to extend the understanding of the extra predictive power of Google search engine query volume of future housing price change (shift direction) by (i) the introduction of a research approach that combines...
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Discrimination of hospital isolates of Acinetobacter baumannii using repeated sequences and whole genome alignment differential analysis
PublikacjaAn optimized method for bacterial strain differentiation, based on combination of Repeated Sequences and Whole Genome Alignment Differential Analysis (RS&WGADA), is presented in this report. In this analysis, 51 Acinetobacter baumannii multidrug-resistance strains from one hospital environment and patients from 14 hospital wards were classified on the basis of polymorphisms of repeated sequences located in CRISPR region, variation...
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Modeling protein structures with the coarse-grained UNRES force field in the CASP14 experiment
PublikacjaThe UNited RESidue (UNRES) force field was tested in the 14th Community Wide Experiment on the Critical Assessment of Techniques for Protein Structure Prediction (CASP14), in which larger oligomeric and multimeric targets were present compared to previous editions. Three prediction modes were tested (i) ab initio (the UNRES group), (ii) contact-assisted (the UNRES- contact group), and (iii) template-assisted (the UNRES-template...
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Level of public finances decentralization in European Union countries
PublikacjaResearch background: Despite of the universality of the implementation in democratic countries the principle of decentralization resulting from the belief that it is an instrument to improve the efficiency of public funds management, both the scope of public services and the level of decentralization in individual countries are not identical. Purpose of the article: Comparison the scope of fiscal decentralization...
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Synthesis, crystal structure and cytotoxic activity of ruthenium(II) piano-stool complex with N,N-chelating ligand
PublikacjaA mononuclear compound of the general formula [(η6-p-cymene)RuIICl(2,2′-PyBIm)]PF6 has been synthesized from a bidentate N,N-donor ligand, viz. 2,-(2′-pyridyl)benzimidazole (2,2′-PyBIm) and the corresponding chloro-complex [(η6-p-cymene)Ru(μ-Cl)Cl]2 (precursor). The isolated coordination compound was characterized by IR, UV–vis and 1H, 13C NMR spectroscopies. The single crystal X-ray analysis of the complex reveals that the asymmetric...
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Nutritional and Pharmaceutical Properties of Bioactive Compounds in Organic and Conventional Growing Kiwifruit
PublikacjaThe bioactivity of two kiwifruit’s cultivars growing under organic and conventional conditions were studied and compared. The bioactive compounds were extracted with water and ethanol using similar conditions which are applied in pharmaceutical applications and for daily fruit consumption such as tea drink. Antioxidant radical scavenging assays [ferric-reducing/antioxidant power (FRAP); cupric reducing antioxidant capacity (CUPRAC);...