Wyniki wyszukiwania dla: AUNPS/ITO ELECTRODES
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Electrochemical detection of 4,4',5,5'-tetranitro-1H,1'H-2,2'-biimidazole on boron-doped diamond/graphene nanowall electrodes
PublikacjaWe present a promising approach to the electroanalytical detection of a specific nitroaromatic explosive in landfill leachates (LLs) that originated from a municipal solid waste plant. The paper is focused but not limited to the sensing of 4,4',5,5'-tetranitro-1H,1'H-2,2'-biimidazole (TNBI) using differential pulse voltammetry and cyclic voltammetry. Highly electroactive nanocarbon was applied to determine low concentrations of...
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Gold nanoparticles and their coatings, their effect on cells and their interaction with radiation
PublikacjaTwo nanometre gold nanoparticles (AuNPs), bearing sugar moieties and/or polyethylene glycolamine (PEG-amine), were synthesised and evaluated for their in vitro toxicity and ability to radiosensitise cells with 220 kV and 6 MV X-rays, using four cell lines representing normal and cancerous skin and breast tissues. In addition to the observed intrinsic cancer-selective chemotoxicity, these AuNPs acted as radiosensitisers in combination with...
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Exemplary SEM images of polished cross sections of symmetrical cell with SrTi0.50Fe0.50O3-d electrodes and CGO-20 substrate sintered at 800 °C
Dane BadawczeThis dataset contains images of polished cross section of symmetrical cell with SrTi0.50Fe0.50O3-d electrodes and CGO-20 substrate sintered at 800 °C. Images were obtained using a PhenomXL (Thermo Fisher Scientific, the Netherlands) scanning electron microscope (SEM) with an accelerating voltage of 12 kV in a high vacuum mode.
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Probability distribution of flicker noise in AuNPdecorated graphene–Si Schottky barrier diode
PublikacjaWe present results of the probability distribution analysis of flicker noise generated in Au nanoparticle (AuNP) decorated graphene–Si Schottky barrier diodes with and without yellow light illumination (592 nm), close to the localized surface plasmon resonance in the AuNPs (586 nm). The AuNPs occupy imperfections in the single-layer graphene and reduce the flicker noise intensity generated in the graphene layer. The estimated probability...
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Cancer-selective, single agent chemoradiosensitising gold nanoparticles
PublikacjaTwo nanometre gold nanoparticles (AuNPs), bearing sugar moieties and/or thiol-polyethylene glycol-amine (PEG-amine), were synthesised and evaluated for their in vitro toxicity and ability to radiosensitise cells with 220 kV and 6 MV X-rays, using four cell lines representing normal and cancerous skin and breast tissues. Acute 3 h exposure of cells to AuNPs, bearing PEG-amine only or a 50:50 ratio of alpha-galactose derivative and...
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Improved electrocatalytic response toward hydrogen peroxide reduction of sulfanyl porphyrazine/multiwalled carbon nanotube hybrids deposited on glassy carbon electrodes
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Direct determination of paraquat herbicide by square-wave voltammetry by two-step transfer mechanism at heterogeneous boron-doped carbon nanowall electrodes
PublikacjaBoron-doped carbon nanowalls (B:CNW) versus boron-doped diamond (BDD) materials were investigated for the effective electrochemical detection of highly toxic herbicide paraquat (PQ). Depending on the surface morphology and functional groups of BDD and B:CNWs, the electrochemical absorption and detection of the target analyte PQ revealed different detection mechanisms. The surface absorption mechanism was mainly observed for BDD,...
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Distribution of Relaxation Times analysis results of impedance measured at 700 °C on porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures
Dane BadawczeThis dataset contains results of Distribution of Relaxation Times analysis (DRT) of impedance of symmetrical cells with porous SrTi0.30Fe0.70O3-d oxygen electrodes sintered at different temperatures (800 °C, 900 °C and 1000 °C). Electrochemical impedance spectroscopy were measured at 700 °C (syntetic air). The DRTTools Matlab GUI, available from prof....
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Distribution of Relaxation Times analysis results of impedance measured at 700 °C on porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures
Dane BadawczeThis dataset contains results of Distribution of Relaxation Times analysis (DRT) of impedance of symmetrical cells with porous SrTi0.50Fe0.50O3-d oxygen electrodes sintered at different temperatures (800 °C, 900 °C and 1000 °C). Electrochemical impedance spectroscopy were measured at 700 °C (syntetic air). The DRTTools Matlab GUI, available from prof....
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Distribution of Relaxation Times analysis results of impedance measured at 700 °C on porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures
Dane BadawczeThis dataset contains results of Distribution of Relaxation Times analysis (DRT) of impedance of symmetrical cells with porous SrTi0.65Fe0.35O3-d oxygen electrodes sintered at different temperatures (800 °C, 900 °C and 1000 °C). Electrochemical impedance spectroscopy were measured at 700 °C (syntetic air). The DRTTools Matlab GUI, available from prof....
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Performance of Haemophilus influenzae impedimetric biosensors based on screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Dane BadawczeThis dataset contains electrochemical impedance spectroscopy studies of SPCE electrodes containing boron-doped diamond BDD foils and functionalized towards detection of Protein D and Haemophilus influenzae.
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Scanning electrochemical micrographs of poly(lactic acid) 3D printed electrodes ablated by femtosecond laser
Dane BadawczeThe dataset contains the scanning electrochemical micrographs of the femtosecond laser (FSL) ablation at the surface of commercially available carbon black-filled poly(lactic acid) 3D printed electrode. The process is used for the increase of the charge transfer of this electrode in electrochemical studies.
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SEM images of symmetrical cell interface with Sr1.05Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at 800 °C, 900 °C and 1000 °C
Dane BadawczeThis dataset contains images of polished cross section of symmetrical cell interface with Sr1.05Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at three different temperatures 800 °C, 900 °C and 1000 °C. Images were obtained using a PhenomXL (Thermo Fisher Scientific, the Netherlands) scanning electron microscope (SEM) with an accelerating...
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SEM images of symmetrical cell interface with Sr1.00Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at 800 °C, 900 °C and 1000 °C
Dane BadawczeThis dataset contains images of polished cross section of symmetrical cell interface with Sr1.00Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at three different temperatures 800 °C, 900 °C and 1000 °C. Images were obtained using a PhenomXL (Thermo Fisher Scientific, the Netherlands) scanning electron microscope (SEM) with an accelerating...
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SEM images of symmetrical cell interface with Sr0.90Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at 800 °C, 900 °C and 1000 °C
Dane BadawczeThis dataset contains images of polished cross section of symmetrical cell interface with Sr0.90Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at three different temperatures 800 °C, 900 °C and 1000 °C. Images were obtained using a PhenomXL (Thermo Fisher Scientific, the Netherlands) scanning electron microscope (SEM) with an accelerating...
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SEM images of symmetrical cell interface with Sr0.95Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at 800 °C, 900 °C and 1000 °C
Dane BadawczeThis dataset contains images of polished cross section of symmetrical cell interface with Sr0.95Ti0.30Fe0.70O3-d electrodes and CGO-20 substrate sintered at three different temperatures 800 °C, 900 °C and 1000 °C. Images were obtained using a PhenomXL (Thermo Fisher Scientific, the Netherlands) scanning electron microscope (SEM) with an accelerating...
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Anna Lisowska-Oleksiak prof. dr hab.
OsobyAnna Lisowska-Oleksiak, born in 1952, has been working at GUT since 1977. Currently is employed at the Faculty of Chemistry as a full professor. She was employed as a research assistant at the University of St Andrews in the group of C. A. Vincent and P.G. Bruce (1991-1994). She completed a two-month research internship in CEA Grenoble (2011). Anna Lisowska-Oleksiak obtained her MSc in chemistry at Nicolaus Copernicus University...
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Surface activation by cyclic polarization in 1M HCl and its effects on the electrochemical response of CB-PLA 3D printed electrodes
Dane BadawczeThe dataset contains the electrochemical studies performed for surface activation of the CB-PLA 3D printed electrodes by electrolysis in 1M HCl solution. The studies were performed after treatment at different polarization ranges, as labeled in subfolder names. For each electrode the consecutive studies describe different samples, as labeled in subfolders:...
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Low-power microwave-induced fabrication of functionalised few-layer black phosphorus electrodes: A novel route towards Haemophilus Influenzae pathogen biosensing devices
PublikacjaIn this paper, various passivation schemes were applied at few-layer black phosphorus (FLBP) to achieve covalent functionalisation with 4-azidobenzoic acid, improving its electrochemical response intended for analytical and biosensing applications. The thermal and microwave assisted modification procedures in toluene and dime-thylformamide resulted in high reversibility of reactions on functionalised FLBP using a ferricyanide/ferrocya-nide...
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Electrocatalytic NADH Sensing using Electrodes Modified with 2‐[2‐(4‐Nitrophenoxy)ethoxy]ethylthio‐Substituted Porphyrazine/Single‐Walled Carbon Nanotube Hybrids
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Solid-Contact Ion-Selective Electrodes with Highly Selective Thioamide Derivatives of p-tert-Butylcalix[4]arene for the Determination of Lead(II) in Environmental Samples
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The BDD electrodes wettability modification by anodic polarization treatment
Dane BadawczeThe dataset contains the raw images, photographs obtained for the contact angle measurement at the surface of the boron-doped diamond (BDD) electrode. The measurements were carried out on after potentiodynamic polarization procedure, at various anodic polarization scan range (no polarization - HTBDD; 1.0 V; 1.4 V; 1.9 V; 2.5 V vs Ag|AgCl, scan rate...
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The photocatalytic activity of MoS2 electrodes under sunlight illumination
Dane BadawczeThis dataset contains the results of the photocatalytic activities of the MoS2 and MoS2 modified by SnO2 were assessed through the photocatalytic reduction of Cr6+ under the sunlight illumination. In the experiment, 20 mg of the catalyst was distributed in the K2Cr2O7 aqueous solution (50 mL, 100 mg•L-1). The mixed solution was stirred for 30 min to...
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Manganese–Cobalt Based Spinel Coatings Processed by Electrophoretic Deposition Method: The Influence of Sintering on Degradation Issues of Solid Oxide Cell Oxygen Electrodes at 750 °C
PublikacjaThis paper seeks to examine how the Mn–Co spinel interconnect coating microstructure can influence Cr contamination in an oxygen electrode of intermediate temperature solid oxide cells, at an operating temperature of 750 °C. A Mn–Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition, and subsequently sintered, following both the one-step and two-step sintering, in order to obtain significantly...
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Impedance Evaluation of the Effect of Ru[sub 0.3]Ti[sub 0.7]O[sub 2] on Electrochemical Properties of Polymeric Conducting Electrodes Used in Cathodic Protection
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Lower rim substituted tert-butylcalix[4]arenes. Part 10. New Pb(II)-selective electrodes based on tetrasubstituted calix[4]arenes amides
PublikacjaOpracowano elektrody selektywne na jony Pb(II) oparte na lipofilowych tetrapodstawionych amidowych pochodnych kaliks[4] arenu. Charakterystyki elektrod mają nachylenie nernstowskie w szerokim zakresie stężeń 10 (-1.3) do 10 (-7.2).
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Designing high-performance quasi-symmetrical solid oxide cells with a facile chemical modification strategy for Sr2Fe2−xWxO6−δ ferrites electrodes with in situ exsolution of nanoparticles
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Lower Rim Substituted tert-Butyl Calix[4]arenes (Part IV). Calix[4]arene-Crown Ethers as Ionophores in Plasticized PVC-membrane electrodes.
PublikacjaPrzedstawiono syntezę i charakterystykę trzech p-tert-butylokaliks[4]aren-koron-4, -5, -6 (związki 2 - 4 o różnej długości łańcucha polyoksaetylenowego łączącego distalne grupy OH). Syntezowane związki wykazują wysoką selektywność na kationy sodu, potasu lub cezu. Badano zależność pomiędzy stereochemiczną strukturą tych ligandów, a wyznaczonymi potencjometrycznie współczynnikami selektywności oraz wyznaczonymi stałymi trwałości...
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Lower rim substituted tert-Butylcalix[4]arenes. Part 13. Interaction of calix-hydroxamates with Fe(III) and Pb(II); studies in ion-selective membrane electrodes (ISE)
PublikacjaPrzedmiotem pracy są badania oddziaływań pomiędzy trzema wybranymi hydroksamowymi pochodnymi t-butylo-kaliks[4]arenu i jonami metali z wykorzystaniem membranowych elektrod jonoselektywnych (ISE). Elektrody zawierające jako materiał aktywny wymienione związki jonoforowe charakteryzują się nernstowskim nachyleniem i szerokim zakresem liniowości na jony Pb(II), a także dobrą selektywnością na jony Pb(II)w stosunku do jonów UO2(II),...
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Raman data of based on BDD, Mn-BDD, Mn-BDD(AN) electrodes
Dane BadawczeRaman spectra of samples : ion implanted BDD (Mn-BDD) films; prepared by high dose (1015-1017 ions/cm2) Mn ion implantation and post-annealing treatment.
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Jarosław Chojnacki prof. dr hab. inż.
OsobyUrodzony w 1961 w Bydgoszczy, absolwent Technikum Chemicznego im. I. Łukasiewicza w Bydgoszczy. Studia chemiczne ukończył na Wydziale Chemicznym Politechniki Gdańskiej w 1986 roku, broniąc pracy dotyczącej elektrod jonoselektywnych. Późniejsze badania związane były z syntezą organiczną i krzemoorganiczną a od 2002 roku z krystalografią. Praca doktorska dotyczyła silanotiolanów miedziowców, a dysertacja habilitacyjna (2010) opisywała...
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Effect of buffer layers on performance of organic photovoltaic devices based on copper phthalocyanine-perylene dye heterojunction
PublikacjaPraca przedstawia wyniki badań układu fotowoltaicznego złożonego z cienkich warstw organicznych tworzących złącze (CuPc i MePTCDI), elektrod (ITO i Ag) oraz z warstw buforowych (MoO3 przy ITO i BCP przy Ag).
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Electro-optical transducer based on indium-tin-oxide-coated optical fiber for analysis of ionized media
PublikacjaThe paper introduces a concept of an optical fiber based electro-optical transducer for monitoring of ionized media, such as low-temperature plasma. It utilizes optical fiber with a section of a core coated with tailored indium tin oxide (ITO) thin film and thus combines the optical phenomena of lossy-mode resonance (LMR) with the electrostatic probe. ITO is an optically transparent and electrically conductive material and if its...
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Lower Rim Substitutedp-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based onp-tert-Butyl-calix[4]arene Thioamides
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Lower rim substituted tert-butyl calix[4]arene (part VII): ionophoric properties of calix[4]arene-crown-6 derivatives in plasticized PVC-membrane electrodes and in solution.
PublikacjaW pracy przedstawiono syntezę i charakterystykę otrzymanych produktów (2-9), pochodnych p-tert-butylokaliks[4]-korony-6. Zdolności kompleksujące tych związków badano w elektrodach jonoselektywnych, stosując te związki jako jonofory w plastyfikowanej membranie PCW.Wyznaczono wartości stałych trwałości kompleksów z jonami metali I grupy. Stwierdzono, że selektywność kompleksowania zależy od rozmiaru i natury podstawnika wprowadzonego...
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Tailoring properties of indium tin oxide thin films for their work in both electrochemical and optical label-free sensing systems
PublikacjaThis work is devoted to the identification properties of indium tin oxide (ITO) thin films responsible for their possible application in combined optical and electrochemical label-free sensing systems offering enhanced functionalities. Since any post-processing would make it difficult to identify direct relation between deposition parameters and properties of the ITO films, especially when deposition on temperature-sensitive substrates...
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Optical investigations of electrochemical processes using a long-period fiber grating functionalized by indium tin oxide
Publikacjahe growing needs for fast and reliable sensing devices stimulate development of new technological solutions. In this work a new multi-domain sensing method is demonstrated where optical sensing device has been applied to enhance amount of data received during electrochemical analysis. Thin, optically transparent, high-refractive-index, and electrically conductive indium tin oxide (ITO) film was deposited using magnetron sputtering...
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Study on Combined Optical and Electrochemical Analysis Using Indium-tin-oxide-coated Optical Fiber Sensor
PublikacjaThe growing needs for fast and reliable sensing devices stimulate development of new technological solutions. In this work a new multi-domain sensing method is demonstrated where optical sensing device has been applied to enhance amount of data received during electrochemical analysis. Thin, optically transparent, high-refractive-index, and electrically conductive indium tin oxide (ITO) film was deposited using magnetron sputtering...
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides.
PublikacjaTetra podstawione tioamidowe pochodne para-tert-butylokaliks[4]arenu (1-5) zostały zastosowane jako jonofory w membranowych elektrodach jonoselektywnych (EJS) selektywne na kationy Pb(II). Wyznaczono współczynniki selektywności. Czwartorzędowe kaliks[4]aren-tioamidy (1,2) wykazują nadzwyczaj dobrą selektywność na kationy Pb(II) w porównaniu z kaliks[4]aren-amidami. Membrany z tymi ligandami wykazują dużą trwałość, a charakterystyki...
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Optical Detection of Ketoprofen by Its Electropolymerization on an Indium Tin Oxide-Coated Optical Fiber Probe
PublikacjaIn this work an application of optical fiber sensors for real-time optical monitoring of electrochemical deposition of ketoprofen during its anodic oxidation is discussed. The sensors were fabricated by reactive magnetron sputtering of indium tin oxide (ITO) on a 2.5 cm-long core of polymer-clad silica fibers. ITO tuned in optical properties and thickness allows for achieving a lossy-mode resonance (LMR) phenomenon and it can be...
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Morphological and electrochemical characterization of ceramic carbon foam electrodes water treatment applications
Dane BadawczeThis dataset contains morphological and electrochemical characterization of ceramic carbon foam employed as an electrode (CFFE) for the oxidation of a target pollutant. The dataset includes:
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The hydrogen evolution reaction (HER) performance of some FTO/MoS2/SnO2 electrodes
Dane BadawczeTo demonstrate the electrochemical performance of the FTO/MoS2/SnO2 for HER (hydrogen evolution reaction), the LSV (linear sweep voltammetry) was performed. The polarization curves of the obtained composite were measured in 1 M H2SO4 at room temperature with a scan rate 10 mV/s. For comparison, the LSV for the FTO, pure MoS2 and Pt plate electrode were...
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Photoelectric properties of WO3/tetracene hetrojunctions
PublikacjaPraca omawia własności fotowoltaiczne heterozłączy: WO3-tetracen. W pracy przedstawiono wyniki badań dwóch struktur planarnych: ITO/tetracen/Ag i ITO/WO3/tetracen/Ag. Badania obejmowały pomiary charakterystyk prądowo-napięciowych, zależności prądu zwarcia i napięcia rozwarcia od natężenia oświetlenia oraz spektralne charakterystyki prądu zwarcia.
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Modification of current-voltage characteristics of planar organic systems by nm-thick interlayer
PublikacjaEffect of nm-thick interlayer of copper phthalocyanine (CuPc) or perylene dye (MePTCDI) on current-voltage characteristics of planar organic systems is discussed in the work. The MePTCDI layer strongly limits injection of holes from ITO into CuPc, while CuPc limits injection of electrons from ITO into MePTCDI. In the systems with CuPc/MePTCDI heterojunction an explicit photovoltaic effect occurs.
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Topography studies of screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Dane BadawczeThis dataset contains topography examination of SPCE containing boron-doped diamond BDD foils done with scanning electron microscope. Different points mark different electrode spots: A) working electrode, B) reference electrode, C) counter electrode, D) pads.
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Electrochemical studies for screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Dane BadawczeThis dataset contains electrochemical examination of SPCE paste and SPCE containing boron-doped diamond BDD foils. The studies include kinetics analyses with cyclic voltammetry and electrochemical impedance spectroscopy with different redox probes: hexacyanoferrate(III) and Hexaammineruthenium(III) and potentiostatic open circuit potential at different...
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Electrochemical studies of symmetrical supercapacitors based on BDD, Mn-BDD, Mn-BDD(AN) electrodes
Dane BadawczeElectrochemical performance of a Supercapacitor device in PVA-H2SO4 gelled electrolyte: Cyclic voltammograms at varying scan rates ranging from 10 to 1000 mV s−1, galvanostatic charge-discharge curves with varying current density, cyclic stability (88000 charge-discharge cycles).
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Fabrication and Significant Photoelectrochemical Activity of Titania Nanotubes Modified with Thin Indium Tin Oxide Film
PublikacjaOrdered titanium dioxide nanotubes (TiO2NTs) modified with indium tin oxide (ITO) films were obtained via magnetron sputtering, in which ITO plate was used as a target, onto the as-anodized titania support followed by the calcination process. The morphology of fabricated material with deposited oxide was investigated using scanning electron microscopy. Raman and UV–Vis spectroscopies were utilized to characterize crystalline phase...
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La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone
PublikacjaInfiltration is a method, which can be applied for the electrode preparation. In this paper oxygen electrode is prepared solely by the infiltration of La0.6Sr0.4Co0.2Fe0.8O3‐δ (LSCF) into Ce0.8Gd0.2O2-δ (CGO) backbone. The use a polymer precursor as an infiltrating medium, instead of an aqueous nitrate salts solution is presented. It is shown that the polymer forms the single-phase perovskite at 600 °C, contrary to the nitrates...
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Materials for energy storage and conversion devices 2022/2023
Kursy OnlineElectrodes: Metals as electrodes in aqueous and non-aqueous systems, metal nanoparticles. Collectors current. 3D, 2D, 1 D carbons, carbon nanomaterials. Organic semiconductors "Synthetic metals" - p-type, n-type. Inorganic semiconductors: oxides, selenides, sulfides, others. Intercalated electrodes. Mixed conductors (MIEC). Photo-active semiconductor materials. Electrolytes. Water electrolytes in commercial products. Electroactive...
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Photovoltaic properties of a sandwich cell consisting of bromophosphorus phthalocyanine and titanium dioxide layers
PublikacjaPraca omawia wyniki badań doświadczalnych właściwości fotowoltaicznych układu: ITO/bromofosforowa ftalocyjanina/dwutlenek tytanu/tetracen/Au.
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Deciphering the Molecular Mechanism of Substrate-Induced Assembly of Gold Nanocube Arrays toward an Accelerated Electrocatalytic Effect Employing Heterogeneous Diffusion Field Confinement
PublikacjaThe complex electrocatalytic performance of gold nanocubes (AuNCs) is the focus of this work. The faceted shapes of AuNCs and the individual assembly processes at the electrode surfaces define the heterogeneous conditions for the purpose of electrocatalytic processes. Topographic and electron imaging demonstrated slightly rounded AuNC (average of 38 nm) assemblies with sizes of ≤1 μm, where the dominating patterns are (111) and...
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Chemical and structural studies of screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Dane BadawczeThis dataset contains chemical analyses and structural studies by XPS and Raman spectroscopy, carried out for SPCE containing boron-doped diamond BDD foils done with scanning electron microscope. Different points for XPS analysis mark different electrode spots: A) working electrode, B) reference electrode, C) counter electrode, D) pads.
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Photovoltaic effect in hybrid heterojunction formed from cadmium telluride and zinc perfluorophthalocyanine layers
PublikacjaPraca przedstawia wyniki badań zjawska fotowoltaicznego w planarnym układzie złożonym z następujących warstw: ITO, CdTe, perfluoroftalocyjanina cynku, BCP, Ag.
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Ex-situ XRD (X-ray Diffraction) results for electrodes under different charge/discharge states
Dane BadawczeEx-situ XRD was employed to analyze the energy storage mechanism of CPMD in ZICs system. The ZICs were firstly charged to 1.8 V from the open circuit voltage (at around 1.3 V), then discharge to 1.0 V and 0.2 V, and finally recharged to 1.0 V and 1.8 V. Sample abbreviations (CPMD) are in agreement with the markings used in the linked publication.
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Kryteria oceny skłonności do pękania opóźnionego
PublikacjaPrzedstawiono wyniki badań skłonności do pękania opóźnionego określanego metodą kołkową (implant) dla złącza spawanego ręcznie elektrodami otulonymi gatunku EB146 na stali kadłubowej AH36. Określono naprężenia krytyczne i parametr pękania alfa dla kontrolowanej zawartości wodoru dyfundującego w zakresie 2,88-15,55 ml/100gFe. Wyniki badań porównano z szacunkami skłonności do pękania opartymi o metodę Ito-Besseyo i temperaturę niezbędnego...
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Ocena kryteriów skłonności do pękania zimnego złączy spawanych.
PublikacjaPrzedstawiono wyniki badań skłonności do pękania opóźnionego określanego metodą kołkową (implant) dla złącza spawanego ręcznie elektrodami otulonymi gatunku EB146 na stali kadłubowej AH36. Określono naprężenia krytyczne dla kontrolowanej zawartości wodoru dyfundującego w zak-resie 2,88-15,55 ml/100gFe. Wyniki badań porównano z szacunkami skłonności do pękania opartymi o metodę Ito-Besseyo i temperaturę niezbędnego podgrza-nia wstępnego...
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Synergic Effect of Naphthylated Carbon Nanotubes and Gold Nanoparticles on Catalytic Performance of Hybrid Films Containing Bilirubin Oxidase for the Dioxygen Reduction
PublikacjaTo improve the direct electron transfer from a multicopper oxidase MvBOd to the glassy carbon electrode surface the naphthylated multiwall carbon nanotubes (Napht-MWCNTs) are ombined with gold nanoparticles (AuNPs) to form a conductive network at the electrode and to increase its working surface. Such approach allowed to eliminate the necessity of employing mediators to reach elevated current values. The enzyme stability was improved...
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Photoconduction in the archetype organic hole transporting material TPD
PublikacjaW pracy opisano mechanizm fotoprzewodnictwa w układzie ITO/warstwa TPD/Al oraz Al/warstwa TPD/Al, gdzie TPD oznacza dwaminę powszechne stosowaną jako transporter dziur w organicznych diodach EL.
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Images revealing the effect of local femtosecond laser ablation of conductive poly(lactic acid) 3D printed electrodes
Dane BadawczeThe dataset reveals the images of the femtosecond laser (FSL) ablation at the surface of commercially available carbon black-filled poly(lactic acid) 3D printed electrode. The process is used for the increase of the charge transfer of this electrode in electrochemical studies.
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Efficiency of exciton splitting in organic photovoltaic cells within EQE spectrum
PublikacjaThe paper presents a procedure of estimating the efficiency of exciton splitting at ED/EA interface. The procedure consists in evaluation of splitting of excitons into electron-hole pairs on the basis of the external quantum efficiency spectra of planar cells and spectra of absorbance of active organic layers. The fitting parameters are the exciton splitting probabilities at ED/EA interface. The presented procedure was applied...
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Lower Rim Substituted p-tert-Butyl Calix[4]arenes(V). Synthesis of New 5,11,17,22-tetrakis-p-tert-Butyl-25-27-bis(dialkoxyphosphorylmethoxy)calix[4] arenes and Cation Complexation Studies in Ion Selective Membrane Electrodes.
PublikacjaZaprezentowano syntezę i właściwości trzech nowych związków (2-4), bis podstawionych na dolnym obrzeżu grupami z resztą fosforylową. Związki te były badane jako jonofory w membranowych elektrodach jonoselektywnych (ISE) wykazując selektywność na kationy Rb+,K+ oraz duży i płaski kation guanidyniowyG+). Badano korelację pomiędzy stereo-strukturą związków a ich selektywnością w ISE. Stałe trwałości kompleksów z kationami metali...
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Olmesartan for the Delay or Prevention of Microalbuminuria in Type 2 Diabetes
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Excitons dissociation on pentacene-metal surface
PublikacjaBadano proces iniekcji nośników ładunku przez ekscytony z elektrod ITO i Mg do warstwy pentacenu. Stwierdzono, że energia ekscytonów tripletowych nie zawsze wystarcza do pokonania bariery potencjału powstającej na złączu elektroda - pentacen.
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Binder-induced surface structure evolution effects on Li-ion battery performance
PublikacjaA comparative investigation on binder induced chemical and morphological evolution of Li4Ti5O12 electrodes was performed via X-ray photoemission spectroscopy, scanning electron microscopy, and electrochemical measurements. Composite electrodes were obtained using three different binders (PAA, PVdF, and CMC) with 80:10:10 ratio of active material:carbon:binder. The electrochemical performances of the electrodes, were found to be...
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Supercapacitors - charge redistribution and restoring voltage
PublikacjaThe charge in supercapacitor is stored on electrodes and in electrolyte. The charges on electrodes create the Helmholtz double layer which is formed immediately with time constant of the order of seconds, while the charge storage in electrolyte is going on with time constant of the order of hundreds seconds. When the charged supercapacitor is shorted for few seconds, the charge from electrodes is discharged while the charge in...
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A Computationally Efficient Model for Predicting Successful Memory Encoding Using Machine-Learning-based EEG Channel Selection
PublikacjaComputational cost is an important consideration for memory encoding prediction models that use data from dozens of implanted electrodes. We propose a method to reduce computational expense by selecting a subset of all the electrodes to build the prediction model. The electrodes were selected based on their likelihood of measuring brain activity useful for predicting memory encoding better than chance (in terms of AUC). A logistic...
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Wpływ kształtu elektrody woltamperometrycznej na jej właściwości metrologiczne w dziedzinie czasu
PublikacjaW artykule omówiono właściwości metrologiczne elektrod woltamperometrycznych. Wykazano, że w przypadku oznaczania małych wartości stężeń jonów metali, elektrody te zachowują się tak jak przetworniki pomiarowe I rzędu. Ich właściwości metrologiczne opisuje czułość i stała czasowa. Wartości tych wielkości są uzależnione od mechanizmu transportu jonów do/od powierzchni elektrod oraz od ich kształtu. Wykonano symulacje wpływu kształtu...
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Anna Danuta Dettlaff dr inż.
OsobyTytuł magistra inżyniera uzyskała z wyróżnieniem w 2013 roku w Wydziale Chemii Analitycznej. W latach 2013-2017 była doktorantką na kierunku Technologia Chemiczna, podczas których zajmowała się pracą pt. "Badania nad nanokompozytami bazującymi na polimerach przewodzących oraz materiałach węglowych w celu zastosowania ich w superkondensatorach". W 2015 roku odbyła trzymiesięczny staż naukowy w Oldenburgu w Niemczech. Stopień doktora...
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Oznaczanie tlenu – od metody Winklera do czujników enzymatycznych (Determination of oxygen – from Winkler Method to enzymatic sensor)
PublikacjaMonitoring of dioxygen levels is of utmost importance from the view-point of life processes, medical diagnostics, nutrition and chemical industries. In all these measurements both low and high levels of this element are important. The common methods for the determination of dioxygen are the Winkler method, Clark electrode and pulsoxymeters. A new, already strong field of research can be now recognized – the development of miniaturized...
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PRĄDY WYRÓWNAWCZE W UZIOMACH FUNDAMENTOWYCH I SZTUCZNYCH
PublikacjaW artykule omówiono zasady wykonywania uziomów fundamentowych i sztucznych. Przedstawiono wyniki pomiarów prądów w instalacji zawierającej stal zbrojeniową w fundamencie, połączoną z układem uziomu sztucznego w ziemi wykonanym z stali ocynkowanej.
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Mobility measurements in oxide semiconductors
PublikacjaPraca zawiera wyniki badań właściwości elektrycznych, optycznych i strukturalnych cienkich warstw ito i sno2. badania wykazały, że cienkie warstwy tlenków metali wykazują rezystywność charakterystyczną dla półprzewodników. poziom transmisji światła w zakresie widzialnym pozwala zaliczyć badane warstwy do materiałów przezroczystych. badane cienkie warstwy wykonano metodą rozpylania magnetronowego.
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Voltage Dependence of Supercapacitor Capacitance
PublikacjaElectronic Double-Layer Capacitors (EDLC), called Supercapacitors (SC), are electronic devices that are capable to store a relatively high amount of energy in a small volume comparing to other types of capacitors. They are composed of an activated carbon layer and electrolyte solution. The charge is stored on electrodes, forming the Helmholtz layer, and in electrolyte. The capacitance of supercapacitor is voltage- dependent. We...
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SEM images of Solid Oxide Fuel Cell interface with La0.6Sr0.4Co0.2Fe0.8O3-δ oxygen electrodes sintered at 1050 °C before and after test
Dane BadawczeThis dataset contains cross section SEM images of Solid Oxide Fuel Cell interface with La0.6Sr0.4Co0.2Fe0.8O3-δ oxygen electrode sintered at 1050 °C before and after test. The cell was tested using Open Flanges™ test Set-up at 700 °C. During the test, the cell was aged for approximately 120 hours at a load of 0.5 A/cm^2. Images were obtained using...
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SEM images of Solid Oxide Fuel Cell interface with Sr0.95Ti0.30Fe0.70O3-d oxygen electrodes sintered at 800 °C before and after test
Dane BadawczeThis dataset contains cross section SEM images of Solid Oxide Fuel Cell interface with Sr0.95Ti0.30Fe0.70O3-d oxygen electrode sintered at 800 °C before and after test. The cell was tested using Open Flanges™ test Set-up at 700 °C. During the test, the cell was aged for approximately 120 hours at a load of 0.5 A/cm^2. Images were obtained using a FEI...
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Melamine-modified boron-doped diamond towards enhanced detection of adenine, guanine and caffeine
PublikacjaThis work describes the electrochemical method of boron-doped diamond (BDD) modification by poly-melamine to obtain organic film. The detection of adenine, guanine and caffeine were carried out by differential pulse wave voltammetry. The poly-melamine modified B-NCD electrodes exhibit excellent activity towards the electrochemical oxidation of all examined analytes. The poly-melamine modified BDD electrodes in all measurements...
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Preparation and characterization of Langmuir-Blodgett films of 16-membered azobenzocrown ether with naphthalene residue
PublikacjaOtrzymano i charakteryzowano filmy Langmuira-Blodgett 16-członowej azobenzokorony z resztą naftalenową. Monowarstwy Langmuira były z sukcesem przenoszone na stałe substraty z utworzeniem filmów LB. Filmy osadzone na elektrodach z ITO zostały również użyte jako elektrody w woltametrii cyklicznej i uzyskano rezultaty wskazujące na to, że filmy te wykazują wyraźną odpowiedź na jony metali.
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New bis(azobenzocrown)s with dodecylmethylmalonyl linkers as ionophores for sodium selective potentiometric sensors
PublikacjaNovel biscrowns 1 and 2 were synthesized from 13-membered azobenzocrown ethers containing bromoalkylenoxy chains in para position relative to the azo group. The synthesized diester molecules are dodecylmethylmalonic acid derivatives differing by the linker length. The synthesized compounds have the potential of being used as sodium ionophores in ion-selective electrodes. They were characterized and used as ionophores in classic...
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Kα1,2x-ray linewidths, asymmetry indices, and[KM]shake probabilities in elements Ca to Ge and comparison with theory for Ca, Ti, and Ge
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Application of wave spectra to mathematical model of multihull vessel
PublikacjaDynamiczne układy mechaniczne reprezentujące obiekty pływające są ściśle związane z procesami stochastycznymi. Zmienne stanu i parametry wejścia w tych modelach mają charakter probabilistyczny. Modele matematyczne takich układów są reprezentowane przez układy stochastycznych równań różniczkowych tworząc układy równań ''Ito''. W artykule zostały wyznaczone współczynniki transmitancji dla wybranych trzech widm falowania: Kongresu...
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Potentiometric taste sensor application for liquid product taste estimation
PublikacjaThe principles of taste sense and kinds of tastes (sweet, salty, sour, bitter, umami and fat) have been described. Food quality estimation by taste sense: organoleptic testing and sensory analysis has been presented. The principle of operation of potentiometric sensor composed of several Ion Selective Electrodes or All Solid State Electrodes with polymeric membranes and macromolecular chemical compounds sensitive to substances...
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Precise x-ray energies of gadolinium determined by a combined experimental and theoretical approach
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TASTE QUALITIES ESTIMATION BY TASTE SENSE AND ELECTROCHEMICAL SENSORS
PublikacjaThe principles of taste sense and kinds of tastes (sweet, salty, sour, bitter, umami and fat) have been described. Food quality estimation by taste sense: organoleptic testing and sensory analysis has been presented. The principle of operation of potentiom etric sensor composed of several Ion Selective Electrodes or All Solid State Electrodes with polymeric membranes and macromolecular chemical compounds sensitive to substances...
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Calix[4]arenes appended with thioamide moieties as powerful tool for heavy metals recognition
PublikacjaSelectivity of new thioamide derivatives was assessed using those ligands as sensor materials in ion-selective membrane electrodes and tested towards Pb2+ - selectivity. The influence of the nature of the thioamide function (linear, branched or cyclic substituents) on their ionophoric properties was investigated. Electrodes based on cyclic thioamide moieties are promising analytical tools for monitoring Pb2+ concentration in natural...
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Structure of high-resolution Kβ1,3 x-ray emission spectra for the elements from Ca to Ge
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublikacjaTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Studies on Aminoanthraquinone-Modified Glassy Carbon Electrode: Synthesis and Electrochemical Performance toward Oxygen Reduction
PublikacjaIn this paper, 9,10-anthraquinone (AQ) derivative-modified glassy carbon (GC) electrodes were studied towards the electrochemical reduction of oxygen in aqueous and non-aqueous solutions. The reaction of 1-chloro-9,10-anthraquinone with aliphatic diamines was applied for the synthesis of amino-9,10-anthraquinone derivatives. The obtained AQ derivatives were grafted onto the surface of glassy carbon electrodes by electropolymerisation...
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Au nanoparticles identifiction with the use of AFM Volta potential mapping
Dane BadawczeThe specific physical, chemical and electrochemical electrical properties of gold nanoparticles have led to their extensive use as high-performance chemical and biochemical sensors. The described properties relate to surface plasmon resonance, fluorescence quenching or enhancement, high electrical conductivity and light scattering. The described nanoparticles...
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Photoelectric properties of a novel MEH-PPV/F16ZnPc heterojunction
PublikacjaPhotoelectric properties of a novel poly[2-methoxy-5-(2-ethylhexyloxy-p-phenylenevinylen)] (MEH-PPV)/perfluorozincphthalocyanine (F16ZnPc) planar heterojunction provided with BCP and MoO3 buffer layers sandwiched between indium tin oxide (ITO) and Ag are shown. Efficient photogeneration of charge carriers at this junction is observed. Effect of bathocuproine (BCP) and MoO3 buffer layers on the performance of cells is analysed....
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Studies on Aminoanthraquinone-Modified Glassy Carbon Electrode: Synthesis and Electrochemical Performance toward Oxygen Reduction
PublikacjaIn this paper, 9,10-anthraquinone (AQ) derivative-modified glassy carbon (GC) electrodes werestudied towards the electrochemical reduction of oxygen in aqueous and non-aqueous solutions. The reaction of 1-chloro-9,10-anthraquinone with aliphatic diamines was applied for the synthesis of amino-9,10-anthraquinone derivatives. The obtained AQ derivatives were grafted onto the surface of glassy carbon electrodes by electropolymerisation...
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 16. Synthesis of 25, 26, 27, 28-tetrakis(piperidinethiocarbonylmethylene)-p-tert-butylcalix[4]arene and its interaction with metal ions
PublikacjaThe synthesis, characterisation and X-ray crystal structures of p-tert-butyl-calix[4]arenethioamide L and its complex with lead L-Pb2+ is reported. The cation-binding properties in solution have been assessed by liquid-liquid extraction of the metal picrates from water into dichloromethane and by stability constants determination in acetonitrile using UV-absorption spectrophotometry or potentiometry. The compound was used as active...
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Is the Solid Electrolyte Interphase an Extra-Charge Reservoir in Li-Ion Batteries?
PublikacjaAdvanced metal oxide electrodes in Li-ion batteries usually show reversible capacities exceeding the theoretically expected ones. Despite many studies and tentative interpretations, the origin of this extra-capacity is not assessed yet. Lithium storage can be increased through different chemical processes developing in the electrodes during charging cycles. The solid electrolyte interface (SEI), formed already during the first...
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Wpływ rodzaju zanieczyszczenia powierzchni odlewu ze staliwa LH14 na jakość napoin wykonanych elektrodą otuloną
PublikacjaNapawanie jest szeroko stosowaną metodą naprawiania powierzchni. Pozwala między innymi na uzupełnienie miejsc, w których uprzednio wystąpiły wżery korozyjne. Techniki napawania wykorzystywane są również do przywracania pierwotnego kształtu zużytych części. W pracy wykonano badania napoin wykonanych elektrodami otulonymi na czołowych powierzchniach cylindrycznych próbek ze staliwa LH14. Proces wykonywano dwoma rodzajami elektrod:...
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Electro-photoluminescence in organics
PublikacjaElektro-fotoluminescencję zaobserwowano w układzie ITO(+)/emiter/Ca(-), gdzie emiter wzbudzany światłem UV (350nm) zawierał dendrymer aminowy m-MTDATA, pochodną fenantroliny BPT i organiczny kompleks platyny PtL2Cl. Widmo fotoluminescencji pochodzi od singletowych ekscypleksów m-MTDATA:BPT i trypletowych ekscypleksów m-MTDATA:PtL2Cl. Ze wzrostem pola elektrycznego następuje wygaszanie ekscypleksów na skutek ich dysocjacji na nośniki...
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Organic electroluminescent devices containing phosphorescent molecules in molecularly doped hole transporting layer.
PublikacjaW pracy opisano mechanizm świecenia diody dwuwarstwowej diody elektroluminescencyjnej (EL) o zewnętrznej kwantowej wydajności świecenia osiągającej 9% fot./elektron. Warstwę transportującą elektrony tworzyła pochodna osadiazolu (PBD) otrzymana metodąnaparowania próżniowego. Warstwę transportującą dziury uzyskano przez wylanie roztworu poliwęglanu(PC), dendrymeru aminowego m-MTDATAoraz fosforyzującego kompleksu irydu Ir(ppy)3 i...
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Selection of Electrode Material for Inconel 617/P92 Steel SMAW Dissimilar Welds
PublikacjaThe present work aimed to investigate the microstructure and mechanical properties of the dissimilar shielded metal arc welded (SMAW) joint of Alloy 617 and P92 steel for advanced ultrasupercritical boilers. The SMAW joint was produced using three different types of electrodes, namely, ENiCrFe-3, ENiCrMo-3, and ENiCrCoMo-1. During microstructural observation of the welded joints, no possible cracking was detected in the weldments....
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Multi-DBD actuator with floating interelectrode for aerodynamic control
PublikacjaIn this paper the use of a floating inter-electrode in a multi-DBD (dielectric barrier discharge) plasma actuator is described. The multi-DBD plasma actuators with floating inter-electrodes were investigated to get a longer DBD on a dielectric surface and to maximise generated net airflow. Our actuator was used to control the boundary layer flow separation around NACA0012 airfoil model. The results of our investigations suggests...
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Weldability of S460ML High Strength Low Alloy Steel in Underwater Conditions
PublikacjaThe paper presents experimental evaluation of susceptibility of the high strength S460ML steel to cold cracking in the conditions of wet welding with the use of covered electrodes. From the results of Tekken tests it was found out that the investigated steel was characterised, in the conditions of the carried out experiments (underwater wet welding and air welding with rutile electrodes), of high susceptibility to cold cracking....
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Intensity Ratio of Kβ/Kα in Selected Elements from Mg to Cu, and the Chemical Effects of Cr Kα1,2 Diagram Lines and Cr Kβ/Kα Intensity Ratio in Cr Compounds
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A Comprehensive Analysis of Impedance of the Electrochemical Cell
PublikacjaA comprehensive impedance characteristics of two electrodes electrochemical cell has been pre sented. In this method a multisinusoidal current excitation signal is used. The change of potential of both the electrodes are all registered as a function of time. The proposed method gives the possibility of determining the impedance of both electrodes individually as well as the impedance of a twoelectrode system. Additional application...