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Unusual behavior of secondary amine group as a leaving group
PublikacjaIn our recent project we focused on reactivity of2,2-dimethyl-4,6-dioxane-1,3-dione carbamoilo- and thiocarbamoylo- derivatives as a ketenesource. Meldrum`s acid derivatives after thermal decomposition gives substituted keteneswith stoichiometric yield, that can be trapped with various spectrum of nucleophiles likealcohols, thiols, amine, imines etc. In case of5-[3-(dimethylamino)-sulfanyl-propyliden]-2,2-dimethyl-1,3-dioxane-4,6-dione...
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City as a product. Architecture as an Economic Instrument. Are Global Cities People-Friendly Places?
PublikacjaWhile spending time in our everyday urban environment do we ever think how particular architecture influences the economic value of that space? Space has its measurable financial value. From the economic point of view a place can be treated as a product that fights for appearing in tourists’ and investors’ consciousnesses. Space - treated as an object of demand and supply - becomes an element in a marketing game. To reach its...
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Online brand communities’ contribution to digital business models
PublikacjaAbstract Purpose – There is limited research examining social drivers and mediators of online brand community identification in the context of business models development. This study aims to identify them behind the social mechanisms and present essential factors which should be applied in business models to foster value co-creation. Design/methodology/approach – Data were collected from a convenience sample of 712 cases gathered among...
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Sources and composition of chemical pollution in Maritime Antarctica (King George Island), part 1: Sediment and water analysis for PAH sources evaluation in the vicinity of Arctowski station
PublikacjaThe paper presents a study regarding the identification of polycyclic aromatic hydrocarbons (PAHs) in fresh waters and surface sediments on the western shore of Admiralty Bay over four sampling seasons from 2017 to 2018. The results were compared to literature data from 2016 to provide a more comprehensive image of the environmental fate of PAHs over the years. The highest value of Σ PAHs was 82.9 ng/L and 445 ng/g dw in water...
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DIAGNOSTIC INFORMATION ANALYSIS OF QUICKLY CHANGING TEMPERATURE OF EXHAUST GAS FROM MARINE DIESEL ENGINE PART I SINGLE FACTOR ANALYSIS
PublikacjaIn this paper, attention was paid to the problem of low controllability of marine medium- and high-speed engines during operation, which significantly limits the parametric diagnosis. The measurement of quickly changing temperature of engine exhaust gas was proposed, the courses of which can be a source of diagnostic information. The F statistic of the Fisher-Snedecor distribution was chosen as a statistical tool. Laboratory tests...
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Synthesis and biological evaluation of fluorinated N-benzoyl and N-phenylacetoyl derivatives of 3-(4-aminophenyl)-coumarin-7-O-sulfamate as steroid sulfatase inhibitors
PublikacjaIn the present work, we report convenient methods for the synthesis of 3-(4-aminophenyl)-coumarin-7-O-sulfamate derivatives N-acylated with fluorinated analogues of benzoic or phenylacetic acid as steroid sulfatase (STS) inhibitors. The design of these potential STS inhibitors was supported by molecular modeling techniques. Additionally, computational docking methods were used to determine the binding modes of the synthesized inhibitors...
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Wpływ wysokiej osteotomii piszczelowej na mechanikę stawu kolanowego
PublikacjaW rozprawie podjęto próbę weryfikacji wpływu zabiegu chirurgicznego wysokiej osteotomii piszczelowej na mechanikę stawu kolanowego. Po wykonanym przeglądzie literatury, postawiono trzy hipotezy, które poddano weryfikacji na drodze badań numerycznych. Otrzymane wyniki zwalidowano poprzez badania nacisków powierzchniowych występujących w stawach kolanowych świni domowej, prowadzonych na maszynie do jednoosiowego ściskania. Praca...
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BADANIE WPŁYWU INDUKCJI REMANENCJI NA STAN PRZEJŚCIOWY JEDNOFAZOWEGO UKŁADU TRANSFORMATOROWEGO
PublikacjaW referacie przedstawiono wyniki badań eksperymentalnych i symulacyjnych wpływu indukcji remanencji w rdzeniu transformatora jednofazowego na jego stan przejściowy przy jego pracy jałowej. Badany obiekt jest układem transformatorowym o dwóch uzwojeniach nawiniętych na zwijanym z blachy anizotropowej rdzeniu w kształcie toroidu. Doświadczenia eksperymentalne polegały na rozładowywaniu kondensatora przez uzwojenie strony pierwotnej...
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Analysis of wave propagation in a bolted steel joint
PublikacjaThe paper presents results of numerical and experimental investigations of elastic wave propagation in a bolted single-lap joint. The research was carried out for both symmetric and antisymmetric Lamb wave modes. In experimental studies the PZT transducers were used to excite and register wave propagation signals. The controlled value of the torque during measurements was ensured by the use of high precision torque wrenches. Numerical...
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The energy consumption during the birch tree sap concentration process using the reverse osmosis system
PublikacjaBirch tree sap was concentrated by mens of the reversed osmosis technique. The energy consumption in a small-scale pilot apparatus was estimated. The threshold value for the water removal above which the specific energy consumption significantly increased was identified. Below the threshold value the reversed osmosis had low energy demand and could be an attractive method for the production of birch tree sap-based beverages.
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Social perception of technological innovations at sports facilities: justification for financing ‘white elephants’ from public sources? The case of Euro 2012 Stadiums in Poland
PublikacjaThe main purpose of the paper is to provide a monetary valuation of social benefits in connection with the hypothetical implementation of technological innovations at four Euro 2012 stadiums in Poland. Not only the construction of the sport’s arenas, but also the ongoing maintenance drain the pockets of Polish taxpayers. At the same time Euro 2012 stadiums remain underused, which familiarize the host cities with the concept of ‘white...
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Radio Channel Measurements in Body-to-Body Communications in Different Scenarios
PublikacjaThis paper presents body-to-body radio channel measurements at the 2.45 GHz band, for different body motion scenarios and on-body antenna placements, and both indoor and outdoor environments. Measurement equipment, investigated scenarios and considered environments are described, an initial analysis of results being presented. The mean path loss and the standard deviation depend on the mutual location of transmitting and receiving...
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Radio Channel Measurements in Body-to-Body Communications in Different Scenarios
PublikacjaThis paper presents body-to-body radio channel measurements at the 2.45 GHz band, for different body motion scenarios and on-body antenna placements, and both indoor and outdoor environments. Measurement equipment, investigated scenarios and considered environments are described, an initial analysis of results being presented. The mean path loss and the standard deviation depend on the mutual location of transmitting and receiving...
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Curve Curvature Analysis of a Grain Trajectories in Variable Honing of Cylindrical Holes of Thin Wall Cylinder Liners as a Honing Process Optimization Strategy
PublikacjaThe main problem of honing of thin wall cylinder liners is a thermal distortion of honed holes. The higher the value of the temperature of the honed workpiece, the greater its holes deformation. The paper presents a method of reducing the temperature occurring in the honing process as a result of the application of a variable honing kinematics conditions with particular emphasis on the analysis of the effect of the value of the...
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MARKETING STRATEGY - SPACE AS A PRODUCT.ARCHITECTURE AS A MARKETING DEVICE.
PublikacjaSpace has its measurable financial value. From the economic point of view place can be treated as a product that fights for appearing in tourists' and investors' consciousnesses. Space - treated as the object of demand and supply - becomes an element in a marketing game. To reach its maximal value the given space should be competitive to other spaces, from which it wants to stand out. However, in the field of architecture - and...
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Knowledge and intellectual capital in a library
PublikacjaThe article constitutes an attempt to focus on the issues connected with knowledge management and intellelectual capital in a library, that is meant as a knowledge-based organisation, supporting the process of creating knowledge. it was characterised as the process of knowledge management in the library environment and diferent approaches to intelelectual capital management that depends on accepted philosophical conception....
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Experimental study on the behaviour of steel columns under seismic-induced axial impact load
PublikacjaIt has been observed during major earthquakes that the so called soft-storey failure of an upper floor of a structure results in large impact load acting on structural members of the lower storeys. It may further lead to progressive collapse of the whole structure substantially intensifying human and material losses. Therefore, the aim of this paper is to investigate experimentally the behaviour of columns under bending (observed...
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Zeolitic imidazolate framework (ZIF-8) modified cellulose acetate NF membranes for potential water treatment application
PublikacjaIn this study, cellulose acetate (CA)-based nanofiltration membranes, modified with zeolitic imidazole framework-8 (ZIF-8) particles, were prepared with various ZIF-8 contents (0, 0.1, 0.25, 0.5, 1 and 2 wt%), to obtain membranes with improved flux and filtration performance by combining advantages of CA polymer and ZIF-8 metal-organic frameworks. Removal efficiency studies were carried out with bovine serum albumin and two different...
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Expression of Deinococcus geothermalis Trehalose Synthase Gene in Escherichia coli and Its Enzymatic Properties
PublikacjaA novel trehalose synthase gene from Deinococcus geothermalis (DSMZ 11300) containing 1,692 bp reading-frame encoding 564 amino acids was amplified using PCR. The gene was ligated into pET30Ek/LIC vector and expressed after isopropyl alfa-D-thiogalactopyranoside induction in Escherichia coli BL21(DE3)pLysS. The recombinant trehalose synthase (DgeoTreS) containing a His6 tag at the C-terminus was purified by metal affinity chromatography...
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Istota chmury wartości - założenia podstawowe
PublikacjaObserwacje efektów działań gospodarczych przedsiębiorstw wsparte badaniami literatury pozwoliły na zdiagnozowanie niedostatku w zakresie ogólnych modeli tworzenia wartości. Punktem wyjścia było określenie celu działania przedsiębiorstwa, który wykazuje immanentną dychotomię. Dążenie do realizacja tak ujętego celu jest podstawą do konfigurowania wartości generowanych przez przedsiębiorstwo. W tym zakresie wykorzystujące wyniki prac...
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Impulse Impedance Measurements of Lightning Protection Earthings
PublikacjaLightning protection earthing systems should be tested at currents with time parameters similar to those of lightnings. A method and definition of a measured value of impulse impedance are introduced. The impulse impedance was determined by a quotient of voltage drop on the tested earthing to a value of current in measure circuit. The usefulness of the impulse method for lightning protection evaluation is tested on radio base stations...
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DATA INTEROPERABILITY AND THE OPEN DATA ECOSYSTEM: ROLES AND RESEARCH AREAS
PublikacjaSustainability and value-creation are considered important parameters to measure the success of an open data system. Unfortunately, existing open data systems are not meeting their promises to achieve a sustainable and value-based open data system. Van Loenen et al. (2021) proposed a sustainable and value-creating open data ecosystem. According to their study, the open data ecosystem needs to be user-driven, inclusive, circular,...
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An effective method for studying intermolecular interactions in binary liquids with hydrogen bonds: FTIR spectra and ab initio calculations in the N-methylformamide - methanol system
PublikacjaMolecular complexes in methanol (MeOH)−N-methylformamide (NMF) mixtures were studied based on their FTIR-ATR spectra, to which two methods of analysis were applied: factor analysis and a quantitative version of the difference-spectra method. The mean composition of a complex between NMF and MeOH molecules over the whole range of mixture compositions was determined. Absorbing species differentiated with regard to the interaction...
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Fractional problems with advanced arguments
PublikacjaThis paper concerns boundary fractional differential problems with advanced arguments. We investigate the existence of initial value problems when the initial point is given at the end point of an interval. Nonhomogeneous linear fractional differential equations are also studied. The existence of solutions for fractional differential equations with advanced arguments and with boundary value problems has been investigated by using...
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Efficiency limit of excitonic photovoltaic cells under phosphor-based white LED illumination
PublikacjaThe limit of energy conversion of excitonic photovoltaic cells working under white light illumination generated by phosphor-based LED is analysed using the modified Giebink approach. Particularly, the impact of the optical energy gap and energy loss associated with the excitons dissociation at the heterojunction interface on power conversion efficiency of the device are discussed. From the results of our study it follows that the...
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Within- and between-firm wage inequalities and trade integration in GVC
PublikacjaThis paper examines between- (inter) and within- (intra) firm wage inequality using rich employer-employee data for 12 European countries. We confirm that much overall wage inequality is observed within sectors and within occupations. The share of the within- and between-firm components in overall wage inequality varies across countries. We estimate the link between involvement in global value chains (GVCs) and wages differentiating...
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Multi-response optimization on the effect of wet and eco-friendly cryogenic turning of D2 steel using Taguchi-based grey relational analysis
PublikacjaMaterial removal processes, including turning and milling, are still commonly used operations for manufacturing most of mechanical components in modern industry. Apart from the cutting parameters, the cooling method has the great impact on the technological efects and, above all, on the environmental friendliness of production. In this study, multi-response optimization on the efect of wet and cryogenic machining is performed during...
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Influence of steam cooking on pro-health properties of Small and Large variety of Momordica charantia
PublikacjaSteam cooking is one of the most common preparations of Momordicacharantia dishes. This method improved the tastiness of the fruits but at the same time, some changes occurred in the volatile and non-volatile parts of their food matrices. In this study, for the first time these properties were correlated with the found substances affecting the bioactivity of this fruit. Two varieties of Momordicacharantia were analysed and compared....
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Production of fuel briquette from solid waste biomass using natural resin as a binder
PublikacjaBackground: This research aimed to evaluate the use of natural resin as a binder for the production of fuel briquette from solid waste biomass.Methods: Proximate analyses were made for fuel briquette prepared from solid waste biomass using natural resin as a binder in comparison with using starch as a binder.Results: The results for density, percent content of moisture, percent content of volatile matter, percent...
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Production of fuel briquette from solid waste biomass using natural resin as a binder
PublikacjaAbstract Background: This research aimed to evaluate the use of natural resin as a binder for the production of fuel briquette from solid waste biomass. Methods: Proximate analyses were made for fuel briquette prepared from solid waste biomass using natural resin as a binder in comparison with using starch as a binder. Results: The results for density, percent content of moisture, percent content of volatile matter, percent content...
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Annual variability of heavy metal content in Svalbard reindeer faeces as a result of dietary preferences
PublikacjaDuring both winter and summer, Svalbard reindeer selectively feed on different types of vegetation that are not only a source of nutritional value, but also a place of heavy metal accumulation. In the present study, the content of cadmium, chromium, copper, iron, lead, nickel, manganese, and zinc in reindeer excrement was measured. The main aims were to determine the seasonal content of several heavy metals in Svalbard reindeer...
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Stability Analysis of Shunt Active Power Filter with Predictive Closed-Loop Control of Supply Current
PublikacjaThis paper presents a shunt active power filter connected to the grid via an LCL coupling circuit with implemented closed‐loop control. The proposed control system allows selective harmonic currents compensation up to the 50th harmonic with the utilization of a model‐based predictive current controller. As the system is fully predictive, it provides high effectiveness of the harmonic reduction, which is proved by waveforms achieved...
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Preparation and characterization of asphaltene based adsorbents for gas-solid adsorption systems
PublikacjaThe dissertation presents results of the experimental research on asphaltene-based adsorbents (support coated with asphaltene layer) for gas-solid adsorption systems, with special reference to volatile organic compounds (VOCs) removal from gas streams. Analysis of gas adsorption properties revealed that asphaltenes isolated from oxidized bitumen have strong affinity toward VOCs. Interactions with target gas molecules, and selectivity...
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Advantages of the Application of the Temper Bead Welding Technique During Wet Welding
PublikacjaThermo-mechanically rolled S460ML steel was chosen for welding in underwater wet welding conditions by covered electrodes. The main aim of this study was to check the weldability for fillet welds in a water environment by controlled thermal severity (CTS) tests and to check the influence of temper bead welding (TBW) on the weldability of the investigated steel. Non-destructive and destructive tests showed that S460ML steel has...
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ASSESSING THE POTENTIAL REPLACEMENT OF MINERAL OIL WITH ENVIRONMENTALLY ACCEPTABLE LUBRICANTS IN A STERN TUBE BEARING: AN EXPERIMENTAL ANALYSIS OF BEARING PERFORMANCE
PublikacjaT his study compares the performance of a plain bearing, with a similar structure to a tail shaft stern bearing, lubricated with either mineral oil or an environmentally acceptable lubricant (EAL). The main characteristic of the bearing is its length/diameter ratio of <1. Measurements are carried out with the bearing operating under loads from 0.5 to 1 MPa and seven speeds ranging from 1 to 11 rev/s. The bearing lubricated...
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Extracellular proteolytic activity of Deinococcus geothermalis
PublikacjaProduction of extracellular protease by extremophilic bacteria Deinococcus geothermalis cultivated in liquid media containing 0.1% (w/v) of peptone K, 0.1% yeast extract and 0.2% marine salt reached a maximum in 14 h of the cell growth at 45°C and pH 8.0. The enzyme was purified by a two-step procedure using fractionation by a graded ammonium sulphate precipitation technique and gel filtration on Sephadex G-100 column. Protease...
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Synthesis and biological evaluation of thiophosphate tricyclic coumarin derivatives as steroid sulfatase inhibitors
PublikacjaSteroid sulfatase (STS) enzyme inhibition is an important approach to the management of hormone-dependent breast cancer. In this paper, we report convenient methods for the synthesis and biological evaluation of thiophosphate tricyclic coumarin analogs exhibiting STS activity. The described methods are based on the straightforward preparation of 7-hydroxy-2,3-dihydro-1H-cyclopenta[c]chromen-2-one, 3-hydroxy- 7,8,9,10-tetrahydro-6H-benzo[c]chromen-6-one,...
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Evaluation of Body Surface Area Formulae Based on 3D Body Scans
PublikacjaHuman body surface area (BSA) is an established parameter for the calculation of chemotherapy drugs dosage, treatment of chronic hepatitis B, treatment of burns or for establishing a dosing regimen for antimicrobials. Although being a critical parameter, usage of modern 3D scanners, which would measure the exact BSA value, is often impossible in time-sensitive operations or for patients unable to withstand the scanning process....
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Experimental and Quantum Chemical Evaluation of 8-Hydroxyquinoline as a Corrosion Inhibitor for Copper in 0.1 M HCl
PublikacjaThe corrosion inhibition properties of 8-hydroxyquinoline (8-HQ) in 0.1 M HCl for copper have been investigated by using experimental (electrochemical impedance spectroscopy (EIS), dynamic electrochemical impedance spectroscopy (DEIS), and potentiodynamic polarization) and theoretical methods complemented by surface morphological examination with the aid of scanning electron microscopy (SEM) and electron dispersive X-ray spectroscopy...
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Assessing ecotoxicity, synergic and antagonistic actions of commonly used components of polymerization mixture in molecularly imprinted polymers preparation process
PublikacjaIncreasingly, the challenge is the optimal process of developing a suitable MIP-type sorptive material (taking into account its final form and application area), which is mainly related to the efficiency/effectiveness of the polymerization process. The lack of reaction or its low efficiency generates additional waste and puts it into the environmental cycle. The main aim of the performed research was the estimation of ecotoxicity,...
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Fabrication and Study of BiNbO4 Ceramics
PublikacjaAim of the present research was to fabricate and study crystalline structure as well as dielectric properties of BiNbO4 ceramics. In the present study BiNbO4 ceramics was fabricated by solid state reaction from the mixture of simple oxides viz. Bi2O3, and Nb2O5. Stoichiometric mixture of the powders was thermally analyzed so parameters of the thermal treatment were determined. The EDS measurements proved conservation of the chemical...
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Zdolności dynamiczne do budowania chmury wartości w modelach biznesów
PublikacjaObserwacja współczesnych metod tworzenia wartości daje podstawy do wyłonienia nowej logiki ich generowania. Analiza modeli wytwarzania wartości przez przedsiębiorstwa np. sieciowe wykazała, że formułują one chmury wartości. Struktury tych chmur są różnorodne, niejednolite, kłębiaste. Przeprowadzone prace pozwoliły na sformułowanie obrazów wartości generowanych przez twarde komponenty modeli biznesów. Osiągnięcie tych wyników pozwoliło...
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Using Redis supported by NVRAM in HPC applications
PublikacjaNowadays, the efficiency of storage systems is a bottleneck in many modern HPC clusters. High performance in the traditional approach – processing using files – is often difficult to obtain because of a model’s complexity and its read/write patterns. An alternative approach is to apply a key-value database, which usually has low latency and scales well. On the other hand, many key-value stores suffer from a limitation of memory...
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Power Surge Compensator based on a Four Level Diode Clamped Inverter for ship application. Average model
PublikacjaPaper presents continuous average value model of Power Surge Compensator based on a Four Level Diode Clamped Inverter with super capacitor as a energy storage device. This conditioner is design for power surge or fluctuation elimination, by compensating it with energy stored in ESD. Continuous average value model of multilevel S-PWM has been presented also. Summary of raised problem is a simulation model made in PowerSim Psim 8...
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Co-operation with local stakeholders: a crucial element of urban design
PublikacjaIn this article,the authors endeavour to illustratethe evolution of the role of local stakeholder in teaching urban planning by example of selected experiences in the Faculty of Architecture atGdańsk University of Technology(FA-GUT), Gdańsk, Poland. The timeframe covers the period from the political breakthrough in 1989 to the present. The background is composed of the social, economic and legal changes that have...
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Long-Term Measurement of Physiological Parameters – Child Dataset
PublikacjaThe dataset titled “Long-term measurement of physiological parameters – child is one dataset” of the bigger series named Long-term measurement of physiological parameters. The dataset contains physiological parameter measurements such as skin temperature and resistance, blood pulse, as well as the stress detection marker, which can have a value of 0 when there is no stress detected or 1 when stress appeared. Additionally, the dataset...
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The use of Response Surface Methodology for reliability estimation of aluminum silo subjected to wind load
PublikacjaAn axisymmetric aluminum silo model with a single, standardized geometric imperfection of its lateral surface is considered. The silo is wind – loaded only. The paper is focused on the critical, or limit value of wind pressure, both producing a loss of stability of the silo. This value is affected by vertical coordinate (position) of the imperfection and the angular relation between the imperfection and the wind direction. Reliability...
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Study of Direct Methanol Fuel Cell Process Dynamics Using Dynamic Electrochemical Impedance Spectroscopy
PublikacjaA new technique, which was developed to characterize the direct methanol fuel cell under work conditions, has been presented in this paper. The impedance measurements were made using dynamic electrochemical impedance spectroscopy research technique in the galvanostatic mode, using multiple sinusoidal excitation. Obtained results show, that together with an increase of the temperature and working load, the global impedance...
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Quantum communication complexity advantage implies violation of a Bell inequality
PublikacjaWe obtain a general connection between a quantum advantage in communication complexity and non-locality. We show that given any protocol offering a (sufficiently large) quantum advantage in communication complexity, there exists a way of obtaining measurement statistics which violate some Bell inequality. Our main tool is port-based teleportation. If the gap between quantum and classical communication complexity can grow arbitrarily...
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Tworzenie wartości dla akcjonariuszy w świetle nadzoru korporacyjnego
PublikacjaDuży odsetek spółek publicznych w Polsce nie tworzy wartości dla akcjonariuszy. Zaprezento-wano wyniki badań dotyczących wpływu struktur własności na efektywność działania spółek pu-blicznych. Badania te nie były w stanie wyjaśnić w wystarczającym stopniu zjawiska destrukcji warto-ści. Starano się wykazać, że jedną z przyczyn tego zjawiska jest transfer wartości. Zalicza się go do głównych problemów nadzoru korporacyjnego. Szczególna...