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Effect of crystallization process at cryogenic conditions on the functional properties of the SUPERSTON alloy used in production the ship's propellers
PublikacjaThe purpose of this paper is to show results of laser treatment at cryogenic conditions of the SUPERSTON alloy used for ship's propellers. That modification process ought to bring beneficial changes of microstructure and residual stresses in the surface layer. During the laser remelting at cryogenic conditions the microstructure changes significantly. This is related to synergistic effects of the solidification rate, phase transformations...
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Underwater Welding of Duplex Stainless Steel
PublikacjaThe present work was conducted to assess the weldability of duplex stainless steel at underwater conditions. Interest of underwater welding of this steel grade is connected with necessity of preparing welding repair technologies for subsea pipelines widely used in offshore oil and gas industry. The GMA local cavity welding method was used in the investigations. Welded beads were performed underwater at 0.5 m depth and in the air....
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Oxidation Time Influence on the Structure of the Cobalt Base Clad Layer and Scale Morphology
PublikacjaZbadano wpływ czasu utleniania na mikrosrukutręi własności mechaniczne a w szczególności mikrotwardość, warstw wykonanych ze stopu kobaltu.Warstwy były wykonane za pomocą napawania plazmowego (PTA). Stop kobaltu podlegał utlenianiu w powietrzu w temperaturze 800 topni celsjusza w czasie 1, 22 i 200 godzin. w wyniku utleniania nastapiło uformowanie warstw zgorzeliny oraz nastapiły zmiany w mikrostrukturze. Zaobserwowano także zmiany...
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Wear and corrosion characteristics of the layers type (mn-p) formed on aluminium alloys
Publikacjaopisano multipleksową metodę wytwarzania warstw zawierających mangan i fosfor (mn-p) na stopach aluminium. przedstawiono wyniki badań mikrostruktury, właściwości tribologicznych i korozyjnych tych warstw. stwierdzono obecność tlenku manganu i fosforku manganu w wytworzonych warstwach oraz ich wysoką twardość, rzędu 1272 hv0,02. warstwy typu (mn-p) zmniejszają podatność stopu alsi13mg1cuni na korozję w 0,01 mh2so4.
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Indoor atmospheric degradation of historical metal objects studied by spectroscopic techniques
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Perovskites in Solid Oxide Fuel Cells
PublikacjaPrzeglądowa publikacja dotycząca wykorzystania ceramicznych materiałów perowskitowych w tlenkowych ogniwach paliwowych.
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Redundantly Actuated 3RRR Parallel Planar Manipulator - Numerical Analyses of its Dynamics Sensitivity on Modifications of its Platform’s Inertia Parameters
PublikacjaIn the paper, numerical analyses, as well as dynamics of a complex mechanism, are presented. Two objectives are crucial for the paper: inverse dynamic model is needed (dedicated to be use in the model predictive controller); an identification method is searched (some trajectory parameters are controlled, when specific trajectory is tracked under an open-loop model-based control), as selected parameters must be identified for the...
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Comparison of Single and Multi-Population Evolutionary Algorithm for Path Planning in Navigation Situation
PublikacjaIn this paper a comparison of single and multi-population evolutionary algorithm is presented. Tested algorithms are used to determine close to optimal ship paths in collision avoidance situation. For this purpose a path planning problem is defined. A specific structure of the individual path and fitness function is presented. Principle of operation of single-population and multi-population evolutionary algorithm is described....
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The effect of pre-hydrogen charging on corrosion behaviour of superduplex stainless steel welded joints
PublikacjaThe paper presents results of research undertaken to determine the influence of hydrogen on passivity and corrosion resistance of 2507 super duplex stainless steel welded joints. Butt welded joints were made with low heat input using flux corded arc welding (FCAW) method. Coupons of 5.0 x 5.0 mm were cut from the welded joints containing weld metal (WM), heat affected zone (HAZ) and parent metal (PM). Hydrogen was introduced...
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Deformation of the Structural Details of the Components Created by the Rapid Prototyping Method
PublikacjaThe paper present the results of preliminary research and describes the deformation of construction details within the process of producing small element employing a stereography system. The article discuses a scheme for changes in data conversion. Variation in construction details have been described on the basis of analysing photographs.
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Hardened Steel Surface Waviness Created by Rolling Burnishing Process
PublikacjaThe surface of the finishing machined parts is defined mainly by roughness parameters. Growing demands on the part, especially mating sliding or rolling, require the specification of additional parameters, such as waviness parameters, particularly when there is significant resistance to seizing or noise reduction. This paper presents surface waviness characteristics of hardened burnished steel.
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The Roughness of the Hardened Steel Surface Created by the Rolling-Burnishing Process
PublikacjaBurnishing hard materials can be used as an alternative finishing process. this paper presents the results of burnishing hardened steel. The article discusses surface deformation that occurs during this process and depends on the selected parameters of the geometric structure of the force applied for surface burnishing.
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Evaluation of Wear Resistance of Ti alloys used for elements friction of knee endoprosthesis
PublikacjaThe paper presents research results of resistance to abrasive wear of titanium alloys: Ti6Al4V (commonly used) and Til3Nb13Zr (alloy of new generation) in association with polyethylene (UHMW-PE) predisposed for elements on pair of the knee endoprosthesis. The results were analysed from the point of possibility of an use of new generation titanium alloys as components of such implants. The tests of resistance to abrasive wear of...
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Cavitation Erosion Resistance of Austenitic Stainless Steel after Glow-Discharge Nitriding Process
PublikacjaThis paper presents investigation of cavitation erosion resistance of nitrided austenitic stainless steel X5CrNi18-10. The diffusion layers were produced by using different parameters of atmosphere (N2:H2). The microstructure, chemical composition and phase identification of the modified layer were examined using scanning electron microscopy, glow-discharge optical emission spectrometer and X-ray diffractometry, respectively. Cavitation...
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Materials Design for the Titanium Scaffold Based Implant
PublikacjaThe main objective of here presented research is a design the scaffold/porous titanium(Ti) alloy based composite material demonstrating better biocompatibility, longer lifetime andbioactivity behaviour for load-bearing implants. The development of such material is proposed bymaking a number of consecutive tasks. Modelling the mechanical, biomechanical and biologicalbehavior of porous titanium structure and an elaboration of results...
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Optimization of Self-Organized TiO2 Nanotube Geometry on Ti and Ti Alloys Using Fuzzy Logic Reasoning
PublikacjaThe geometry of self-organized TiO2 nanotubes, obtained by electrochemicalanodization, has been determined by using fuzzy reasoning approach. The efficiency of TiO2nanotubular layer in biomedical applications depends on geometry and available surface area ofnanotubes, which can be determined by their diameter and length. The structure of nanotubesdepends on processing parameters of electrochemical anodization, like applied potential,anodization...
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Analysis of Ceramic Elements with Ring-Crack Defects in Lubricated Rolling Contact
PublikacjaThe properties of ceramics, specifically low density, high hardness, high temperature capability and low coefficient of thermal expansion are of most interest to rolling element manufacturers. Surface ring cracks on lubricating rolling contact fatigue failure has been studied using numerical fracture analysis. Such cracks are very often found on ceramic bearing balls and decrease fatigue life rapidly. The numerical calculations...
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Flexible dye-sensitized solar cells based on Ti/TiO2 nanotubes photoanode and Pt-free and TCO-free counter electrode system
PublikacjaFlexible dye-sensitized solar cells (DSSCs) are getting more attention compared to standard glass covered DSSCs due to their unique commercial applications (e.g. tents or sail surfaces) and the possibility of rolling up into a small, portable device. In this work, titania nanotubes (TiO2 NT) modified with titania nanoparticles (TiO2 NP) were photoelectrochemically characterized as an anode for flexible dye-sensitized solar cells....
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Electrodes consisting of PEDOT modified by Prussian Blue analogues deposited onto titania nanotubes – Their highly improved capacitance
PublikacjaIn this work we present the outstanding energy storage of prepared inorganic-organic heterojunction where hydrogenated ordered titania nanotubes (H-TiO2NT) were modified by the hybrid made of poly(3,4-ethylenedioxythiophene) (pEDOT) and iron hexacyanoferrate centres (Fehcf, Prussian Blue). The material TiO2NT/pEDOT:Fechf was obtained electrochemically by means of: anodization, hydrogenation and finally, electropolymerization of...
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Electrochemical performance of Co3O4/CeO2 electrodes in H2S/H2O atmospheres in a proton-conducting ceramic symmetrical cell with BaZr0.7Ce0.2Y0.1O3 solid electrolyte
PublikacjaThe electrochemical performance of Co3O4/CeO2 mixed oxide materials as electrodes, when exposed to H2S/H2O atmospheres, was examined employing a proton conducting symmetrical cell, with BaZr0.7Ce0.2Y0.1O3 (BZCY72) as the solid electrolyte. The impact of temperature (700–850 °C) and H2S concentration (0–1 v/v%) in steam-rich atmospheres (90 v/v% H2O) on the overall cell performance was thoroughly assessed by means of electrochemical...
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Multicomponent layers for aluminium alloys surface consolidation
PublikacjaThe main reason of the surface modification of the components such as pistons and cylinder blocks made of cast aluminium alloys is to obtain high hardness, wear and corrosion resistance of the working surface for larger lifetime of the motor-car and aircraft engines. In that aspect, the new conception of development - by hybrid method - of surface layers containing manganese, nitrogen, sulphur (Mn-N-S) and manganese, nitrogen,...
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Determination of ability of hydrotronic systems to start in low ambient temperatures
PublikacjaPrzedstawiono wyniki badań symulacji komputerowej zespołów układów hydrotronicznych w warunkach szoku termicznego. Pokazano metodę określania zdatności hydrotronicznych zespołów i układów podczas rozruchu w warunkach szoku termicznego.
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High temperature corrosion of evaporator tubes with thermal sprayed coatings
PublikacjaDegradation examinations of outer surface of low-emission steam boiler evaporator tubes are presented in the paper. Metallographic evaluation of scale morphology, its micro sites chemical composition analysis and distribution of elements on cross sections have been performed. Water-wall tubes were exposed in steam boiler for up to two years period. Common tubes made of 16Mo3 steel suffered sulphide and molten salts corrosions....
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Properties of surface layers of duplex stainless steel after burnishing processes
PublikacjaStress corrosion cracking resistance of cold worked layers of 25 Cr duplex stainless steel grade UR52N+ has been investigated. The surface layers were performed through burnishing treatment. The residual stresses at surface layers were determined using grazing angle incidence X-ray diffraction method (g-sin2 Ψ). Corrosion tests were performed with the use of Slow Strain Rate Test technique in boiling 35% MgCl2 solution. It has...
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Finishing of Ceramics in a Single-Disk Lapping Machine Configuration
PublikacjaPrzedstawiono metodę obróbki ceramiki technicznej na zmodifikowanej docierarce jednotarczowej z niezależnym napędem pierścienia prowadzącego. Omówiono przebieg obróbki z wykorzystaniem nowych narzędzi i zastosowaniem ziarna wiązanego.
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Cavitation wearing of the SUPERSTON alloy after laser treatment at cryogenic conditions
PublikacjaThe purpose of this paper is to demonstrate the method of laser remelting at cryogenic conditions of the SUPERSTON alloy and its influence on microstructure and cavitation wearing. The cavitation test was performed using the rotating disc facility in IPM PAN Gdansk. During the cavitation test, the mass loss of the material with different parameters of laser remelting was determined. Surface and cross-section microstructure of the...
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Research of hydrotronic variable displacement radial piston pump with electro -pneumatic control
PublikacjaThe paper presents the developed new electro-pneumatic control (pneumotronic) system for hydraulic fixed-displacement radial piston pump. Hydraulic fixed-displacement radial piston pump equipped with the proposed control system changes into hydrotronic variable-displacement radial piston pump. Pump flow rate control is realized by means of programmable logic controller, electro-pneumatic valves, pneumatic cylinders and a sensor.
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Port-Based Modelling of Distributed-Lumped Parameter Systems
PublikacjaThere in the paper is presented an uniform, port-based approach to modelling of both lumped and distributed parameter systems. Port-based model of the distributed system has been defined by application of bond graph methodology and distributed transfer function method (DTFM). The approach proposed combines versatility of port-based modelling and accuracy of distributed transfer function method. The concise representation of lumped-distributed...
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Effect of the Unit Pressure on the Selection Parameters of Intermetallic Coastings NiAl and Ni3Al after Platic Working
PublikacjaW artykule omówiono wpływ zgniotu na wybrane parametry warstwy międzymetalicznej NiAl i Ni3Al napawanej na stali C45 podanej obróbce plastycznej poprzez prasowanie na zimno.
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Modal Reduction and Analysis of Gyroscopic Systems
PublikacjaThe paper introduces the method of the modal reduction of systems that experience the Coriolis acceleration or gyroscopic effect component. In such cases corresponding system equations are non-self-adjoined. To solve the problem modal reduced model is built up for the system without Coriolis acceleration or gyroscopic effect terms. These phenomena are included by application of any lumping technique. Hence, the final reduced model...
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Analysis of Asymmetrical Rolling Process of Multilayer Plates
PublikacjaW niniejszej pracy przedstawiono wyniki badań numerycznych asymetrycznego procesu walcowania blach wielowarstwowych M1E-Al99,8-AlMg5. Modelowanie numeryczne procesu walcowania blach wielowarstwowych przeprowadzono w programie Forge 2D, którego obliczenia bazują na metodzie elementów skończonych. Przedstawione w pracy wyniki umożliwiły przeprowadzenie analizy procesu walcowania blach wielowarstwowych.
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Surface Roughness Model Components Created by Stereolithography Method
PublikacjaW pracy przedstawiono charakterystykę powierzchni elementów wykonywanych metodą stereolitografii. Opisano modele chropowatosci stosowane do opisywania powierzcni wraz z prezentacją formuł matematycznych. W oparciu o wyniki badań eksperymentalnych przeprowadzono częściową weryfikację modeli.
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Modeling and simulation of tool cycle in manufacturing cell
PublikacjaThe paper addresses issues concerning modeling and analysis of tool flow within a three-machine manufacturing cell used for small batch manufacturing of a definite spectrum of prismatic parts. The approach utilizes a method for job and tool allocation to work centers with limited number of machines and capacity of tool resources, based on the analysis of formalized relations: job - tool sets required. Selected tool flow control...
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Optimum Control of Gyroscopic Systems
PublikacjaThe problem of optimum control of transverse rotor vibrations with gyroscopic interactions has been described and solved in the paper. An integral performance index has been defined for such system in order to minimize vibration level of a chosen rotor point. For this reason, an efficient way of finding the weight coefficients of integral performance index for multi-degrees-of-freedom system with gyroscopic interactions has been...
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The domination of ionic conductivity in tetragonal phase of the organometal halide perovskite CH3NH3PbI3-xClx
PublikacjaOrganometal trihalide perovskites have recently gained extreme attention due to their high solar energy conversion in photovoltaic cells. Here, we investigate the contribution of iodide ions to a total conductivity of the mixed lead halide perovskite CH3NH3PbI3−xClx with a use of the modified DC Hebb–Wagner polarization method. It has been identified that an ionic conductivity dominates in tetragonal phase which is associated with room...
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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
PublikacjaSodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between...
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The σ-phase superconductors Nb20.4Rh5.7Ge3.9 and Nb20.4Rh5.7Si3.9
PublikacjaWe show that the previously unreported ternary σ phases Nb20.4Rh5.7Ge3.9 and Nb20.4Rh5.7Si3.9 are both superconductors with Tc values of approximately 1.9 K. The superconducting transitions were characterized through temperature-dependent magnetic susceptibility, electrical resistance, and specific heat measurements. The Sommerfeld constants, γ, for Nb20.4Rh5.7Ge3.9 and Nb20.4Rh5.7Si3.9 are 89(1) mJ mol-f.u.−1K−2 and 86(1) mJ mol-f.u.−1K−2...
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Two kinds of oxygen vacancies in lithium titaniate doped with copper as detected by EPR
PublikacjaLithium titanate (Li1+xTi2-xO4) doped with Cu2+ ions was synthesized by sol-gel processing method. The structure and morphology are characterized by X-ray Diffraction (XRD), X-ray Photoemission Spectroscopy (XPS), Scanning Electron Microscopy (SEM) and Electron Paramagnetic Resonance (EPR). Spin Hamiltonian parameters describing Zeeman and hyperfine interaction for 63Cu2+ ions were obtained from EPR spectra simulations. The spectra...
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Enhanced trap-assisted recombination in organic semiconductors
PublikacjaAn analytical model to describe the interaction of excitons and charge transfer states with deep traps is formulated for the case of molecular materials. Here, we have considered the influence of a trap-assisted recombination on this phenomenon. The final expression for the effective recombination rate has been derived from the Shockley–Read–Hall theory and kinetic equations which characterize different photophysical processes....
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Modelling of Ship’s Heeling and Rolling for the Purpose of Gantry Control Improvement in the Course of Cargo Handling Operations in Sea Ports
PublikacjaThe paper presents two proposals of models of interaction between a ship and cargo being loaded or discharged by a gantry in port, in terms of heeling and rolling of the vessel. The main purpose of such modelling is the need for improvement of gantry control with regard to faster operations thanks to more accurate estimation of level and moment of cargo release from a gantry hook or spreader. The study may be the contribution to...
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Ceramic composites for single-layer fuel cells
PublikacjaComposite materials consisting of acceptor doped lanthanum orthoniobate electrolyte phase (La0.98Ca0.02NbO4) and Li2O:NiO:ZnO semiconducting phase were synthesized. The precursor powder of La0.98Ca0.02NbO4 was prepared in nanocrystalline (mechanosynthesis) and microcrystalline (solid-state synthesis) form. The composite can be applied in a single-layer fuel cell, because of the presence of two phases acting as an anode and a cathode...
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Nonlinear electrical properties of glass-ceramics nanocomposites containing ferroelectric nanocrystallites of Bi2VO5.5
PublikacjaNonlinear A.C. impedance measurements were conducted in the 50BiV-50SrBAlO nanocomposite as a function of frequency, temperature and A.C. voltage. This material is ferroelectric below temperature of 730 K, and above 730 K is a good ion-conductor. For this nanocomposite a low A.C. voltage of 1 V rms is enough to observe high nonlinearities. The origin of these nonlinear effects depends on the temperature and frequency. In the high...
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Synthesis and properties of porous Sr 0.96 Y 0.04 Ti 1−x Nb x O 3
PublikacjaA series of porous, single phase Sr0.96Y0.04Ti1-xNbxO3 samples was obtained using a wet synthesis method (modified citrate sol-gel) method. Temperature-programmed reduction (TPR) and temperature-programmed oxidation (TPO) measurements have shown high stability of the obtained material in variable (oxidizing/reducing) atmospheres. All samples exhibit high conductivity in hydrogen atmosphere with the highest value (around 1S/cm)...
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Properties of LiMnBO3 glasses and nanostructured glass-ceramics
PublikacjaPolycrystalline LiMnBO3 is a promising cathode material for Li-ion batteries. In this work, we investigated the thermal, structural and electrical properties of glassy and nanocrystallized materials having the same chemical composition. The original glass was obtained via a standard melt-quenching method. SEM and 7Li solid-state NMR indicate that it contains a mixture of two distinct glassy phases. The results suggest that the...
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Copper and cobalt co-doped ceria as an anode catalyst for DIR-SOFCs fueled by biogas
PublikacjaThe nanocrystalline compounds of Co and Cu co-doped ceria (with up to 20 mol.% of dopants) were fabricated by the reverse microemulsion synthesis method. They were deposited in a form of layers on the surface of SOFC anode in an aim to act as electrochemically active materials for biogas reforming process. Fourier Transformed Infrared Spectroscopy was used to analyze a composition of outlet gases simultaneously with the tests of...
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Ion conduction in beryllium-alumino-silicate glasses doped with sodium or sodium and lithium ions
PublikacjaElectrical properties of beryllium-alumino-silicate glasses containing sodium ions or sodium and lithium ions were studied with impedance spectroscopy technique over a frequency range from 10 mHz to 1 MHz and at temperature range from 213 to 473 K. The frequency- and temperature-dependent conductivity spectra of individual single alkali glasses were superimposed by means of the Summerfield scaling. Mixed-alkali glasses do not overlap...
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Rotordynamic characteristics of a chamber seal
PublikacjaThe paper presents the results of numerical and experimental investigations into pressure forces generated in a turbine labyrinth seal of a modernized type. The experiments were performed on a single-stage air model turbine of the impulse type. The experiments were performed on a single-stage air model turbine of the impulse type. The experimental data were compared with theoretical results obtained by means of CFD Fluent Code....
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Structural Control of Photoinduced Dynamics in 4H-Imidazole- Ruthenium Dyes
PublikacjaThe photoinduced dynamics of a series ofterpyridine 4H-imidazole-ruthenium complexes, which constitutea new family of panchromatic dyes, is investigated. Thedynamics involves two excited states localized within the 4Himidazolesphere. Upon MLCT excitation, an excited state ispopulated, which is localized on the central part of the 4Himidazoleligand caused by its nonplanar conformation. Thepopulation of the second excited state is...
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Multimedia interface using head movements tracking
PublikacjaThe presented solution supports innovative ways of manipulating computer multimedia content, such as: static images, videos and music clips and others that can be browsed subsequently. The system requires a standard web camera that captures images of the user face. The core of the system is formed by a head movement analyzing algorithm that finds a user face and tracks head movements in real time. Head movements are tracked with...
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Spontaneous electron emission vs dissociation in internally hot silver dimer anions
PublikacjaReferring to a recent experiment, we theoretically study the process of a two-channel decay of the diatomic silver anion (Ag2-), namely the spontaneous electron ejection giving Ag2 + e- and the dissociation leading to Ag- + Ag. The ground state potential energy curves of the silver molecules of diatomic neutral and negative ion were calculated using proper pseudo-potentials and atomic basis sets. We also estimated the non-adiabatic...