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Effect of alcohol consumption on the levels of volatile organohalogen compounds in blood and urine = Wpływ spożywania alkoholu na poziom lotnych związków chlorowcoorganicznych w krwi i moczu ludzkim
PublikacjaW pracy przedstawiono wyniki oznaczania lotnych związków chlorowcoorganicznych w próbkach moczu i krwi pochodzących od dawców w różny sposób narażonych na ekspozycje lotnych związków chlorowcoorgnicznych (styl życia: palenie papierosów, picie alkoholu, przyjmowanie lekarstw czy rodzaj wykonywanej pracy). Do izolacji i wzbogacania analitów z próbek moczu i krwi, wykorzystano technikę analizy fazy nadpowierzchniowej nad cienką warstwą...
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Volatile organohalogen compounds in human urine: the effect of environmental exposure
PublikacjaW pracy przedstawiono wyniki oznaczania lotnych związków chlorowcoorganicznych w próbkach moczu pochodzących m.in. od dawcow narazonych na kancerogeny w miejscu pracy i dawcow spozywajacych wode poddana procesowi uzdatniania przez chlorowanie. Do izolacji i wzbogacania analitów z moczu, posiadającego skomplikowaną matrycę, wykorzystano technikę analizy fazy nadpowierzchniowej nad cienką warstwą cieczy z samoczynną generacją ciekłego...
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Wynik analizy a jakość informacji środowiskowej. Opracowanie monograficzne z uwzględnieniem prac własnych
PublikacjaNa proces uzyskiwania wiarygodnych informacji o zanieczyszczeniu środowiska mają zasadniczy wpływ dwa aspekty:- wybór właściwych parametrów do monitorowania poziomu zanieczyszczenia;- odpowiednia jakość wyników oznaczania parametrów wytypowanych do monitoringu środowiska.Wyniki badań, przedstawione w niniejszym opracowaniu monograficznym, ujawniły, że stosowane techniki izolacji związków z grupy WWA i PCB z próbek wody, nie mogą...
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Analityka surfaktantów w próbkach środowiskowych
PublikacjaSurfaktanty stanowią grupę związków charakteryzujących się specyficznymi właściwościami fizykochemicznymi (m.in. amfifilowa budowa, zdolność rozpuszczania się w cieczach o różnej polarności, zdolność do tworzenia micelli) i z tego względu są one wykorzystywane w wielu sferach działalności człowieka. Związki powierzchniowo-czynne ulegają różnorodnym przemianom fizykochemicznym, co umożliwia ich migrację między różnymi elementami...
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Charakterystyka produktów utleniania fosfolipidów oraz określenie ich wybranych aktywności biologicznych w komórkach HT29 jako modelu ludzkiego przewodu pokarmowego
PublikacjaWyniki licznych badań epidemiologicznych wskazują, że rodzaj, ilość oraz jakość dostarczanych wraz z pożywieniem lipidów może przyczyniać się do ograniczenia bądź rozwoju chorób dietozależnych, takich jak otyłość, cukrzyca typu 2, miażdżyca czy nadciśnienie tętnicze. Rosnące zainteresowanie określeniem wpływu lipidów dostarczanych z pożywieniem na funkcjonowanie ludzkiego organizmu wymaga przeprowadzenia licznych badań, zarówno...
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Elementy psychologii w kontekście autonomii robotów
PublikacjaW niniejszym opracowaniu zaprezentowano szerokie spektrum zagadnień związanych z psychologią poznawczą w kontekście antropoidalnej robotyki. W szczególności omówiono sposób przetwarzania informacji u człowieka, od bodźca do reakcji, tak aby przedstawioną wiedzę można było wykorzystać przy projektowaniu robotów autonomicznych. Na początku pracy szczegółowo omówiono procesy poznawcze: percepcję sensoryczną, spostrzeganie,...
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Comparison of noise reduction methods in radiometric correlation measurements of two-phase liquid-gas flows
PublikacjaTwo-phase liquid-gas flows occur frequently in the mining, energy, chemical, and petrochemical industries. One of non-contact methods used to analyse these flows is the gamma ray absorption method. However, the signals received from radiation detectors contain a significant stochastic noise, which makes them difficult to analyse. The article describes four methods of noise reduction in cross-correlation measurements of water-air...
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Detection and Model of Thermal Traces Left after Aggressive Behavior of Laboratory Rodents
PublikacjaAutomation of complex social behavior analysis of experimental animals would allow for faster, more accurate and reliable research results in many biological, pharmacological, and medical fields. However, there are behaviors that are not only difficult to detect for the computer, but also for the human observer. Here, we present an analysis of the method for identifying aggressive behavior in thermal images by detecting traces...
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Chemical Composition of Atmospheric Air in Nemoral Scots Pine Forests and Submountainous Beech Forests: The Potential Region for the Introduction of Forest Therapy
PublikacjaStudies show that forests are one of the main recreational destinations. This can be explained by their beneficial effects on the health of their visitors, which can be attributed to compounds from the terpene group. The aim of this research was to determine the chemical composition of air in the interiors of Nemoral Scots pine forests and submountainous beech forests, with the determination of compounds of the terpene group. Samples...
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Determination of cyanide in urine and saliva samples by ion chromatography with pulsed amperometric detection
PublikacjaCommonly known as a highly toxic chemical, cyanide is also an essential reagent for many industrial processes. It naturally occurs in plant seeds as a cyanogenic glycosides. Another relatively common mode of cyanide exposure is inhalation of environmental tobacco smoke. This study concerns importance to determine cyanide ion in human biological samples. Urine and saliva samples were collected healthy volunteers exposed to tobacco...
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Processing, Performance Properties, and Storage Stability of Ground Tire Rubber Modified by Dicumyl Peroxide and Ethylene-Vinyl Acetate Copolymers
PublikacjaIn this paper, ground tire rubber was modified with dicumyl peroxide and a variable content (in the range of 0–15 phr) of ethylene-vinyl acetate copolymers characterized by different vinyl acetate contents (in the range of 18–39 wt.%). Modification of ground tire rubber was performed via an auto-thermal extrusion process in which heat was generated during internal shearing of the material inside the extruder barrel. The processing,...
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Opracowanie procedury oznaczania lotnych produktów utleniania olejów roślinnychtechniką statycznej analizy fazy nadpowierzchniowej = The development of a new procedure for determination of volatile oxidation products in edible oils with the use of static headspace analysis
PublikacjaW publikacji przedstawiono dobór optymalnych parametrów w celu opracowania nowej metody diagnozowania jakości olejów poprzez oznaczenie lotnych związków będących produktami reakcji utleniania olejów. Próbki rafinowanych olejów roślinnych przed analizą poddano procesowi przyspieszonego utleniania, stosując naświetlanie promieniowaniem ultrafioletowym (12 W, 254 nm). Jako technikę ekstrakcji lotnej frakcji próbki zastosowano statyczną...
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Determination of chlorinated solvents in industrial water and wastewater by DAI- GC-ECD
PublikacjaA very simple and quick analytical method, basedon direct aqueous injection, for determination of halogenatedsolvents in refinery water and wastewater, is described.There is a need to determine halogenated solvents in refinerywater streams, because they may originate from severalprocesses. There is also a need to develop methods enablingVOX to be determined in samples containing oil fractions.The method described enables simultaneous...
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Ordered titanium templates functionalized by gold films for biosensing applications – Towards non-enzymatic glucose detection
PublikacjaRecently, metal nanostructures evoke much interest due to application potential in highly sensitive detectors in biochemistry and medical diagnostics. In this work we report on preparation and characteristics of thin (1–100 nm) Au films deposited onto highly ordered structured titanium templates for SERS (Surface Enhanced Raman Spectroscopy) and electrochemical sensing. The Ti templates are formed by selective removal of TiO2 nanotubes...
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A Method of Fast and Simultaneous Calibration of Many Mobile FMCW Radars Operating in a Network Anti-Drone System
PublikacjaA market for small drones is developing very fast. They are used for leisure activities and exploited in commercial applications. However, there is a growing concern for accidental or even criminal misuses of these platforms. Dangerous incidents with drones are appearing more often, and have caused many institutions to start thinking about anti-drone solutions. There are many cases when building stationary systems seems to be aimless...
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Arithmetic Loophole in Bell's Theorem: Overlooked Threat to Entangled-State Quantum Cryptography
PublikacjaBell’s theorem is supposed to exclude all local hidden-variable models of quantum correlations. However,an explicit counterexample shows that a new class of local realistic models, based on generalized arith-metic and calculus, can exactly reconstruct rotationally symmetric quantum probabilities typical oftwo-electron singlet states. Observable probabilities are consistent with the usual arithmetic employedby macroscopic observers...
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Smartphones as tools for equitable food quality assessment
PublikacjaBackground: The ubiquity of smartphones equipped with an array of sophisticated sensors, ample processing power, network connectivity and a convenient interface makes them a promising tool for non-invasive, portable food quality assessment. Combined with the recent developments in the areas of IoT, deep learning algorithms and cloud computing, they present an opportunity for advancing wide-spread, equitable and sustainable food...
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Technology of an adhesive silicone film as drug carrier in transdermal therapy I. Analytical methods used for characterization and design of the universal elastomer layers
PublikacjaSilicone polymers possess unique properties, which make them suitable for many different applications, for example in the pharmaceutical and medical industry. To create an adhesive silicone film, the appropriate silicone components have to be chosen first. From these components two layers were made: an adhesive elastomer applied on the skin, and a non-adhesive elastomer on the other side of the film. The aim of this study was...
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Machine learning applied to acoustic-based road traffic monitoring
PublikacjaThe motivation behind this study lies in adapting acoustic noise monitoring systems for road traffic monitoring for driver’s safety. Such a system should recognize a vehicle type and weather-related pavement conditions based on the audio level measurement. The study presents the effectiveness of the selected machine learning algorithms in acoustic-based road traffic monitoring. Bases of the operation of the acoustic road traffic...
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Contour Analysis of Bleeding Regions in Endoscopic Images
PublikacjaThis paper investigates the problem of detecting bleeding regions in images acquired from endoscopic examinations of gastrointestinal tract. The purpose is to identify the characteristic features of bleeding areas' contours in order to develop an accurate method for discriminating between true bleeding regions and missed detections, which could lead to a significant reduction of the false alarm rate of existing blood-detection...
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Analysis of pesticide residue in fruits and vegetables using analytical analytical protocol based on application of QuEChERS technique and GC-ECD system
PublikacjaQuEChERS sample preparation method was used for the determination of 10 pesticides and their metabolites in fruits (apple, grape) and vegetables (tomato, paprika), coupled to gas chromatography with electron capture detector (GC-ECD). The experimental parameters including amount of the sample, types of solvents, extraction time and types of sorbent at the purification stage were optimized. The GC-ECD method was validated in terms...
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Clothes Detection and Classification Using Convolutional Neural Networks
PublikacjaIn this paper we describe development of a computer vision system for accurate detection and classification of clothes for e-commerce images. We present a set of experiments on well established architectures of convolutional neural networks, including Residual networks, SqueezeNet and Single Shot MultiBox Detector (SSD). The clothes detection network was trained and tested on DeepFashion dataset, which contains box annotations...
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The Thin-Layer Microchromatography (μTLC) and TLC–FID Technique as a New Methodology in the Study of Lubricating Oils
PublikacjaThis paper concerns the possibility of using TLC coupled with a flame ionization detector (FID) and micro-TLC (μTLC) as precursors for microfluidized devices of analytical techniques to identify and determine the presence and content of the petroleum/vegetable oil base in the lubricating oils applied in cutting devices (chainsaws). This research is related to the problem of ensuring, in compliance with the requirements of environmental...
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Forced Degradation Studies of Ivabradine and In Silico Toxicology Predictions for Its New Designated Impurities
PublikacjaAll activities should aim to eliminate genotoxic impurities and/or protect the API against degradation. There is a necessity to monitor impurities from all classification groups, hence ivabradine forced degradation studies were performed. Ivabradine was proved to be quite durable active substance, but still new and with insufficient stability data. Increased temperature, acid, base, oxidation reagents and light were found to cause...
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Current trends in analytical strategies for the determination of polybrominated diphenyl ethers (PBDEs) in samples with different matrix compositions – Part 2: New approaches to PBDEs determination
PublikacjaHerein, we review the latest technical solutions for polybrominated diphenyl ethers (PBDEs) determination in samples with different matrix compositions, largely focusing on gas chromatography but also presenting some liquid chromatography–based solutions. Moreover, we discuss the use of diverse sample injection techniques while considering the advantages and disadvantages of each injection system in the context of PBDEs analysis....
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Machine learning applied to acoustic-based road traffic monitoring
PublikacjaThe motivation behind this study lies in adapting acoustic noise monitoring systems for road traffic monitoring for driver’s safety. Such a system should recognize a vehicle type and weather-related pavement conditions based on the audio level measurement. The study presents the effectiveness of the selected machine learning algorithms in acoustic-based road traffic monitoring. Bases of the operation of the acoustic road traffic...
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A Surrogate-Assisted Measurement Correction Method for Accurate and Low-Cost Monitoring of Particulate Matter Pollutants
PublikacjaAir pollution involves multiple health and economic challenges. Its accurate and low-cost monitoring is important for developing services dedicated to reduce the exposure of living beings to the pollution. Particulate matter (PM) measurement sensors belong to the key components that support operation of these systems. In this work, a modular, mobile Internet of Things sensor for PM measurements has been proposed. Due to a limited...
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Cost-Efficient Measurement Platform and Machine-Learning-Based Sensor Calibration for Precise NO2 Pollution Monitoring
PublikacjaAir quality significantly impacts human health, the environment, and the economy. Precise real-time monitoring of air pollution is crucial for managing associated risks and developing appropriate short- and long-term measures. Nitrogen dioxide (NO2) stands as a common pollutant, with elevated levels posing risks to the human respiratory tract, exacerbating respiratory infections and asthma, and potentially leading to chronic lung...
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Wykorzystanie techniki chromatografii jonowej w analityce surfaktantów w próbkach wód powierzchniowych
PublikacjaSurfaktanty stanowią grupę związków charakteryzujących się specyficznymi właściwościami fizykochemicznymi i z tego względu są one wykorzystywane w wielu sferach działalności człowieka. Związki powierzchniowo-czynne ulegają różnorodnym przemianom fizykochemicznym, co umożliwia ich migrację między różnymi elementami środowiska i może prowadzić do jego zanieczyszczenia. Dlatego też istnieje konieczność określania losu środowiskowego...
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Real-time facial feature tracking in poor quality thermal imagery
PublikacjaRecently, facial feature tracking systems have become more and more popular because of many possible use cases. Especially in medical applications location of the face and facial features are very useful. Many researches have presented methods to detect and track facial features in visible light. However, facial feature analysis in thermography may also be very advantageous. Some examples of using infrared imagery in medicine include...
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Development of Intelligent Road Signs with V2X Interface for Adaptive Traffic Controlling
PublikacjaThe objective of this paper is to present a practical project of intelligent road signs, under which a series of new products for the regulation of traffic is being created. The engineering part of the project, described in this paper, was preceded by a series of experimental studies, the results of which were described in another paper accepted for publication at the MTS-ITS conference 2019, entitled "Comparative study on the effectiveness...
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Forced degradation studies of ivabradine and in silico toxicology predictions for its new designated impurities
PublikacjaAll activities should aim to eliminate genotoxic impurities and/or protect the API againstdegradation. There is a necessity to monitor impurities from all classification groups,hence ivabradine forced degradation studies were performed. Ivabradine was provedto be quite durable active substance, but still new and with insufficient stability data.Increased temperature, acid, base, oxidation reagents and...
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Understanding the early-stage release of volatile organic compounds from rapeseed oil during deep-frying of tubers by targeted and omics-inspired approaches using PTR-MS and gas chromatography
PublikacjaDuring deep-frying, a plethora of volatile products is emitted with the fumes. These compounds could act as oil quality indicators and change the indoor air composition leading to health risks for occupants. The presented experiments focus on deep-frying of different tubers in rapeseed oil at different frying temperatures. Here, two scenarios for real-time monitoring of volatile organic compounds (VOCs) using proton transfer reaction...
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Improvement of glass break acoustic signal detection via application of wavelet packet decomposition
PublikacjaThe main subject of the authors' research are non-contact methods of glass break detection based on analysis of the acoustic signal generated during the event. This problem has essential meaning for modern cost- effective alarm systems, particularly those installed into big buildings. The main difficulties of the matter are: transient character of the signal, great number of similar sounds (false signals, mainly accidental glass...
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Interrelationship between total volatile organic compounds emissions, structure and properties of natural rubber/polycaprolactone bio-blends cross-linked with peroxides
PublikacjaNatural rubber/polycaprolactone (NR/PCL) bio-based blends with different organic peroxides were prepared using an internal batch mixer and subsequently cross-linked at 170°C. Two types of commonly used organic peroxides, dicumyl peroxide and di(tert-butylperoxyisopropyl)benzene peroxide, were applied as free-radical initiator. Cross-linking efficiency of NR/PCL blends were investigated using oscillating disc rheometer measurements,...
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Key-Marker Volatile Compounds in Aromatic Rice (Oryza sativa) Grains: An HS-SPME Extraction Method Combined with GC×GC-TOFMS
PublikacjaThe aroma of rice essentially contributes to the quality of rice grains. For some varieties, their aroma properties really drive consumer preferences. In this paper, using a dynamic headspace solid-phase microextraction (HS-SPME) system coupled to a two-dimensional gas chromatography (GC×GC) using a time-of-flight mass spectrometric detector (TOFMS) and multivariate analysis, the volatile compounds of aromatic and non-aromatic...
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Diagnostyka cienkościennych żelbetowych sklepień kolebkowych w budynku zabytkowym. Część II
PublikacjaW artykule przedstawiono opis oraz wyniki oceny stanu technicznego konstrukcji przekrycia Hali Głównej Dworca Kolejowego Gdańsk Główny. Ze względu na prowadzone prace związane z remontem kapitalnym Dworca Głównego PKP w Gdań- sku zaistniała konieczność przeprowadzenia rewitalizacji poddasza Hali Głównej, obejmująca między innymi jego termomodernizację (ocieplenie wysklepek) oraz zabezpieczenie elementów wiązarów dachowych przed...
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Head-Space SPME for the Analysis of Organophosphorus Insecticides by Novel Silica IL-Based Fibers in Real Samples
PublikacjaThis work demonstrates the suitability of a newly developed ionic liquid (IL)-based silica SPME fiber for the determination of seven organophosphorus insecticides in cucumber and grapefruit samples by headspace solid-phase microextraction (HS-SPME) with a gas chromatography–flame ionization detector (FID). The sol-gel method released four different sorbent coatings, which were obtained based on a silica matrix containing ILs immobilized...
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Rapid method for the determination of organochlorine pesticides and PCBs in fish muscle samples by microwave-assisted extraction and analysis of extracts by GC-ECD
PublikacjaA procedure for the multiresidue determination of organochlorine pesticides and polychlorinated biphenyls in fish muscle samples has been developed. The method is based on the microwave-assisted extraction (MAE) of food samples from an acetonitrile-water (95 + 5, v/v) mixture followed by SPE cleanup of the extracts and analysis by GC with an electron capture detector. MAE operational parameters, such as the extraction solvent,...
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ATTEMPTS OF THERMAL IMAGING CAMERA USAGE IN ESTIMATIONS OF THE CONVECTIVE HEAT LOSS FROM A VERTICAL PLATE
PublikacjaIn this paper a new method for determining heat transfer coefficients using a gradient method has been developed. To verify accuracy of the proposed method vertical isothermal heating plate with natural convection mechanism has been examined. This configuration was deliberately chosen, because of the fact that such case is historically the earliest and most thoroughly studied and its rich scientific documentation - the most reliable....
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The estimation of total volatile organic compounds emissions generated from peroxide cured natural rubber/polycaprolactone blends
PublikacjaNatural rubber (NR)/polycaprolactone (PCL) blends at the ratio of 90/10% wt. (NR/PCL90/10) and 70/30% wt. (NR/PCL70/30), with a constant amount of dicumyl peroxide, were prepared by compounding in an internal mixer. Obtained NR/PCL bio-based blends were cured at three different temperatures (150 °C, 160 °C and 170 °C). The total content of volatile organic compounds (TVOC) as a function of the NR/PCL blends ratio, and their curing...
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A multi-analytical approach to the characterization of natural organic dyestuffs and inorganic substrates present in the 19th-century artistic oil paints manufactured by a French art materials supplier Richard Aines
PublikacjaThis paper presents a comprehensive analysis of artistic paints produced in the 19th century by a French art materials supplier Richard Ain`es. Improved mild extraction with hydrofluoric acid enabled the observation of intact organic dyes. Reversed-phase liquid chromatography with diode-array and mass spectrometry detection was utilised for the identification of 35 dyes present in yellow and red paint samples, and in selected plant...
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Method of reconstructing two-dimensional velocity fields on the basis of temperature field values measured with a thermal imaging camera
PublikacjaThis paper describes a novel numerical reconstruction procedure (NRP) of the velocity field during natural convective heat transfer from a two-sided, isothermal, heated vertical plate based only on the known temperature field obtained, e.g. with a thermal imaging camera. It has been demonstrated that with a knowledge of temperature distributions, the NRP enables the reconstruction of velocity fields by solving the Navier-Stokes...
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Deep learning-based waste detection in natural and urban environments
PublikacjaWaste pollution is one of the most significant environmental issues in the modern world. The importance of recycling is well known, both for economic and ecological reasons, and the industry demands high efficiency. Current studies towards automatic waste detection are hardly comparable due to the lack of benchmarks and widely accepted standards regarding the used metrics and data. Those problems are addressed in this article by...
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A hierarchical porous composite magnetic sorbent of reduced graphene oxide embedded in polyvinyl alcohol cryogel for solvent‐assisted‐solid phase extraction of polycyclic aromatic hydrocarbons
PublikacjaA hierarchical porouscomposite magnetic sorbent was fabricated and applied tothe dispersive solvent-assisted solid-phase extraction of five polycyclic aromatichydrocarbons. A sorbent was first prepared by incorporating graphene oxide,calcium carbonate, and magnetite nanoparticles into a polyvinyl alcohol cryo-gel. The graphene oxide was converted to reduced graphene oxide using ascorbicacid and a hierarchical porous structure was...
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Procedura przygotowania próbki do oznaczania wielopierścieniowych węglowodorów aromatycznych w produktach technicznych
PublikacjaW pracy opisano nową metodę przygotowania próbki w celu oznaczania śladowych zawartości wielopierścieniowych węglowodorów aromatycznych (WWA) w wysokowrzących produktach naftowych. Wartości granicy oznaczalności dla badanych WWA w materiałach tego typu mieściły się w przedziale od kilkudziesięciu ng/kg do poniżej dwudziestu ug/kg. Badania wykazały, że w celu oddzielenia większości zanieczyszczeń od analitów, bez ich znaczących...
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Integrated approach -the effective tool for pollution level control of sediments from lake turawskie = Kompleksowa ocena stopnia zanieczyszczenia osadów dennych jeziora turawskiego
PublikacjaTurawski zbiornik retencyjny wytypowany został do projektu pilotażowego spośród 14 obiektów zlewni Odry w ramach programu: "Stan ekologiczny jezior zaporowych w dorzeczu Odry i działania na rzecz jego poprawy". Celem projektu jest ocena stanu ekologicznego Jeziora Turawskiego dla uzyskania niezbędnych informacji mających służyć do zaprojektowania i wyboru metody jego remediacji. Jezioro Turawskie jest nizinnym zbiornikiem retencyjnym...
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Fast GC as a useful tool for authenticity assessment of kiwifruit
PublikacjaKiwifruit is one of the healthiest fruits due to its high content of biologically active substances and nutrients. The most popular species of Actinidia (kiwifruit) are the Actinidia deliciosa fruits called kiwi and Actinidia chinensis commonly called golden kiwi, while the lesser known species is Actinidia arguta known as mini kiwi. Bioactivities and nutrients of Actinidia are influenced by species and cultivars. It is very important...
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Application of Electronic Nose Based on Fast GC for Authenticity Assessment of Polish Homemade Liqueurs Called Nalewka
PublikacjaThe possibility of application of electronic nose based on fast GC for differentiation of three types of cherry liqueurs, namely Polish homemade liqueurs called nalewka, commercially available liqueurs labeled as nalewka, and commercial liqueurs, was investigated. This device was equipped with two parallel connected columns with different stationary phases coupled to two ultrasensitive flame ionization detectors (μ-FIDs). Four...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublikacjaThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...