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Search results for: CROSS-LINKING REAGENTS
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Synthesis and antimicrobial activity of amino acid and peptide derivatives of mycophenolic acid
PublicationThe series of 16 novel amino acid and peptide mycophenolic acid (MPA) derivatives was obtained as potential antibacterial agents. Coupling of MPA with respective amines was optimized with condensing reagents such as EDCI/DMAP and T3P/TEA. Amino acid analogs were received both as methyl esters and also with the free carboxylic group. The biological activity of the products was tested on five references bacterial strains: Klebsiella...
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AGREE—Analytical GREEnness Metric Approach and Software
PublicationGreen analytical chemistry focuses on making analytical procedures more environmentally benign and safer to humans. The amounts and toxicity of reagents, generated waste, energy requirements, the number of procedural steps, miniaturization, and automation are just a few of the multitude of criteria considered when assessing an analytical methodology’s greenness. The use of greenness assessment criteria requires dedicated tools. We...
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Synthesis and biological evaluation of novel analogues of batracylin with synthetic amino acids and adenosine: an unexpected effect on centromere segregation in tumor cells through a dual inhibition of topoisomerase IIa and Aurora B
PublicationIn the search for new anticancer agents we designed and synthesized batracylin derivatives with linking synthetic amino acid side chains of different lengths and adenosine. Unexpectedly, we have found that in water and the culture media adenosine–amino acid–BAT conjugates form supramolecular structures and this prevents these compounds from entering cells. Consequently, these compounds exerted no biological activity when tested...
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Model and laboratory simulation of a induction motor for diagnostic purposes
PublicationStatistics say that bearings are this part of induction motors which is most susceptible to damage. The equipment employed for bearing diagnostics usually makes use of vibrations as the criterion for technical condition of the bearings. A faulty bearing results in additional motor vibrations. They are reflected in the harmonic content of stator currents. In certain operating conditions the current signal is the sole source of information...
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Scrutiny of power grids by penetrating PV energy in wind farms: a case study of the wind corridor of Jhampir, Pakistan
PublicationThis study examines the problems caused by intermittent renewable energy sources, especially wind farms, and suggests a different solar energy penetration strategy to improve their loading capacity. The study uses real-time data from a wind farm in Jhampir, Pakistan, to analyse and assess various aspects of grid stations connected to wind farms. Electrical Transient Analyzer Program is used to validate the results by linking...
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Skilled-Unskilled Wage Gap Versus Evolving Trade And Labour Market Structures in the EU
PublicationThis paper proposes an alternative approach to the empirical study of wage gap between workers with different educational levels in the enlarged EU. The analysis is based on sectoral database, linking labor market statistics and trade data at the level of 12 manufacturing sectors in a group of 20 European countries: selected New Member States (NMS-5) and former EU-15 economies, in the period 1995-2005. The results of the empirical...
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Discrete element method modelling of elastic wave propagation in a meso-scale model of concrete
PublicationThis paper deals with the accurate modelling of ultrasonic wave propagation in concrete at the mesoscopic level. This was achieved through the development of a discrete element method (DEM) model capable of simulating elastic wave signals comparable to those measured experimentally. The main objective of the work was to propose a novel methodology for constructing a meso-scale model of concrete dedicated to the analysis of elastic...
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Scrutiny of power grids by penetrating PV energy in wind farms: a case study of the wind corridor of Jhampir, Pakistan
PublicationThis study examines the problems caused by intermittent renewable energy sources, especially wind farms, and suggests a different solar energy penetration strategy to improve their loading capacity. The study uses real-time data from a wind farm in Jhampir, Pakistan, to analyse and assess various aspects of grid stations connected to wind farms. Electrical Transient Analyzer Program is used to validate the results by linking these...
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Ekspatrianta versus lokalny menedżer, czyli kto powinien kierować filią zagraniczną? = Expatriate versus host country manager - who should run a foreign subsidiary?
PublicationThere is ample literature on expatriate management that presents a parent company's point of view on this issue. A consideration of subsidiary management from the local perspective is missing. Relationships with foreigners (including expatriates) are cross-cultural interactions and their effectiveness is affected by cultural factors. Therefore, in this article there are questions that need to be answered:1. What role does an expatriate...
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Customizing nano-chitosan for sustainable drug delivery
PublicationChitosan is a natural polymer with acceptable biocompatibility, biodegradability, and mechanical stability; hence, it has been widely appraised for drug and gene delivery applications. However, there has been no comprehensive assessment to tailor-make chitosan cross-linkers of various types and functionalities as well as complex chitosan-based semi- and full-interpenetrating networks for drug delivery systems (DDSs). Herein, various...
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Comparison of Transmission Capacities of Two Regulation Systems: Lateral and in-phase Control Transformers
PublicationThis paper presents a comparison of regulation capabilities of lateral and in-phase control transformers in a selected node of a power system. Their regulation capabilities are presented, as well as cross-system exchange options.
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Sensitivity analysis of a composite footbridge
PublicationThis work include an example of sensitivity analysis for the design of a composite footbridge. A sandwich structure is used, consisting two high-strength skins separated by a core material. The analysis was conducted for two numerical models. The first one is a simple, single-span beam of a composite cross-section (laminate and foam), with different Young’s modulus for each material. Calculations were made by means of a MATLAB-based...
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Radioisotope measurements of the liquid-gas flow in the horizontal pipeline using phase method
PublicationThe paper presents application of the gamma-absorption method to a two-phase liquid-gas flow investigation in a horizontal pipeline. The water-air mixture was examined by a set of two Am-241 radioactive sources and two NaI(Tl) scintillation probes. For analysis of the electrical signals obtained from detectors the cross-spectral density function (CSDF) was applied. Results of the gas phase average velocity measurements for CSDF...
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Informal work in Poland - a regional approach
PublicationIn our paper we try to combine the theories explaining the prevalence of informal work, using a regional approach. Reviewing the literature, we observe that, there is no evidence to confirm that the relationships that occur in cross-country comparisons remain significant when we use regional data and analyse cross-regional variations. Our general question is therefore whether there is simply more informal work in less-developed...
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Assessment of Wooden Beams from Historical Buildings Using Ultrasonic Transmission Tomography
PublicationThe main goal of this study was non-destructive evaluation of wooden elements using ultrasonic waves. The inspection was carried out on wooden beams from a historical object. Elastic wave signals were processed by ultrasonic transmission tomography to obtain imaging of the internal structure of tested elements without disturbing their state and integrity. The focus was on the influence of wood anisotropy on the propagation of ultrasonic...
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Correlation–polarization effects in electron/positron scattering from acetylene: A comparison of computational models
PublicationDifferent computational methods are employed to evaluate elastic (rotationally summed) integral and differential cross sections for low energy (below about 10 eV) positron scattering off gas-phase C2H2 molecules. The computations are carried out at the static and static-plus-polarization levels for describing the interaction forces and the correlation–polarization contributions are found to be an essential component for the correct...
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Experimental tests and numerical simulations of full scale composite sandwich segment of a foot- and cycle- bridge
PublicationIn the paper experimental tests and numerical simulations of a full cross-section segment of ultimately designed foot-and cycle-bridge are presented. The experimental tests were conducted on element with length reduced to 3 m and unchanged (target) cross-section dimensions. The external skin of structure is GFRP laminate while internal core is PET foam. Several quasi-static tests were performed using hydraulic cylinder to generate...
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Polymeric metal‐containing ionic liquid sorbent coating for the determination of amines using headspace solid‐phase microextraction
PublicationThis study describes the design, synthesis, and application of polymeric ionic liquid sorbent coatings featuring nickel metal centers for the determination of volatile and semivolatile amines from water samples using headspace solidphase microextraction. The examined polymeric ionic liquid sorbent coatings were composed of two ionic liquid monomers (tetra(3-vinylimidazolium)nickel bis[(trifluoromethyl)sulfonyl]imide [Ni2+(VIM)4]...
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How to evaluate methods used in chemical laboratories in terms of the total chemical risk? – a ChlorTox Scale
PublicationReliable assessment of the health and environmental risk associated with the use of chemicals is critical to ob- jectively evaluate the greenness and whiteness of an analytical method. An objective and useful way of risk assessment should take into account all the relevant properties of used substances, their actual amounts needed for application of the method, and quantify the assessment result using a standardized unit. This...
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Sensitivity analysis of flexural and torsional buckling loads of laminated columns
PublicationThe paper concerns first order sensitivity analysis of flexural and torsional bucklin g loads of axiallycompressed thin-walled columns with bisymmetric or axisymmetric cross-section made of unidirectional fibre-reinforcedlaminate. The first variation of critical loads versus some variations of the column material properties and cross-sectionaldimensions is derived. Numerical examples dealing with simply supported I-columns are...
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Smart experience engineering to support collaborative design problems based on constraints modelling
PublicationEngineering design is a knowledge intensive process. Experts' experiences from different product life-cycle stages play a key role in problem solving during design decision making by linking up knowledge to find better solutions for a specific design problem. Different approaches have been used to support Collaborative and Concurrent Product Design, such as Constraint Satisfaction Problem (CSP) modelling. Additionally, due to the...
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Study on VR Application Efficiency of Selected Android OS Mobile Devices
PublicationCurrently, the number of scenarios for using VR (Virtual Reality) technology grows every year. Yet, there are still issues associated with it, related with the performance of the mobile device itself. The aim of this work is to perform an analysis of the effectiveness of virtual reality applications in case of mobile platforms. We put the main emphasis on examining the performance and efficiency of four different hardware and software...
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Integration of the sulfate reduction and anammox processes for enhancing sustainable nitrogen removal in granular sludge reactors
PublicationThe Anammox and Sulfate Reduction Ammonium Oxidation processes were compared in two granular sequencing batch reactors operated for 160 days under anammox conditions. It was hypothesized that increasing the concentration of SO42− may positively influence the rate of N removal under anaerobic conditions and it was tested whether SO42− reduction and anammox occur independently or are related to each other. The cooperation of N-S...
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The symmetric extendibility of quantum states
PublicationStudies on the symmetric extendibility of quantum states have become particularly important in the context of the analysis of one-way quantum measures of entanglement, and the distillability and security of quantum protocols. In this paper we analyze composite systems containing a symmetric extendible part, with particular attention devoted to the one-way security of such systems. Further, we introduce a new one-way entanglement...
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Analiza kosztów i czasu budowy domu jednorodzinnego w technologii drewna krzyżowo klejonego CLT
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Methylation effect in e−— scattering on methyl-substituted ethylenes
PublicationMethylation effect has been observed and studied in electron-scattering from selected hydrocarbon molecules. In measured total cross section (TCS) functions we have noticed energy shifts and changes in the intensity of observed structures.
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Positron-electron correlation-polarization potentials for the calculation of positron collisions with atoms and molecules
PublicationWe present correlation-polarization potentials for the calculation of scattering cross sections of positrons with atoms and molecules. The potentials are constructed from a short-range correlation term and a long-range polarization term. For the short-range correlation term we present four different potentials that are derived from multi-component density functionals. For the long-range polarization term we employ a multi-term...
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Novel Nonlinear High Order Technologies for Damage Diagnosis of Complex Assets
PublicationFor the first time worldwide, innovative techniques, generic non-linear higher-order unnormalized cross-correlations of spectral moduli, for the diagnosis of complex assets, are proposed. The normalization of the proposed techniques is based on the absolute central moments, that have been proposed and widely investigated in mathematical works. The existing higher-order, crosscovariances of complex spectral components are not sufficiently...
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Modelowanie przepływu pary przez okołodźwiękowe wieńce turbinowe z użyciem sztucznych sieci neuronoych
PublicationNiniejszy artykuł stanowi opis modelu przepływu pary przez okołodźwiękowe stopnie turbinowe, stworzonego w oparciu o sztuczne sieci neuronowe (SSN). Przedstawiony model neuronowy pozwala na wyznaczenie rozkładu wybranych parametrów w analizowanym przekroju kanału przepływowego turbiny dla rozpatrywanego zakresu wartości ciśnienia wlotowego.
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Dynamic Bayesian Networks for Symbolic Polyphonic Pitch Modeling
PublicationSymbolic pitch modeling is a way of incorporating knowledge about relations between pitches into the process of an- alyzing musical information or signals. In this paper, we propose a family of probabilistic symbolic polyphonic pitch models, which account for both the “horizontal” and the “vertical” pitch struc- ture. These models are formulated as linear or log-linear interpo- lations of up to fi ve sub-models, each of which is...
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Projektowanie układów ramowych z zastosowaniem analizy wrażliwości
PublicationW pracy przedstawiono przykład projektowania układów ramowych z zastosowaniem analizy wrażliwości. Rozważane układy ramowe rozwiązano autorskim programem napisanym w środowisku MATLAB, metodą elementów skończonych. Badano wpływ zmiany modułu Younga oraz wpływ zmiany wielkości przekroju poprzecznego na wybrane przemieszczenia ramy. Przedstawiono wyniki dla analizy wrażliwości jedno i wieloparametrycznej.
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Novel method of lung area extraction in chest perfusion computed tomography
PublicationChest perfusion computed tomography (pCT) is a useful technique in the medical diagnosis of how organs function. Perfusion CT scans are used to calculate perfusion parameters. In the case of automated methods of lung perfusion parameters calculation, the prior extraction of the lung area is desired to avoid unnecessary calculation in an area outside the lung cross-section and to avoid wasting time on processing signals of no diagnostic...
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Low-energy positron collisions with water: elastic and rotationally inelastic scattering
PublicationDifferential, integral and momentum transfer cross sections for the vibrationally elastic and rotationally inelastic scattering of positrons from water at low collision energy (E ≤ 10 eV) are reported. Several models within the R-matrix method are used to compute the body-fixed T-matrices, while the scattering calculations are performed within the fixed-nuclei approximation corrected with the standard Born-closure formula. These...
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Rapid Design Tuning of Miniaturized Rat-Race Couplers Using Regression-Based Equivalent Network Surrogates
PublicationA simple technique for fast design tuning of compact rat-race couplers is presented. Our approach involves equivalent circuit representation, corrected by nonlinear functions of frequency with coefficients extracted through nonlinear regression. At the same time, the tuning process connects two levels of coupler representation: EM simulation of the entire circuit and re-optimization of the coupler building blocks (slow-wave cells...
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Synthesis of 5-Substituted 1H-Tetrazoles from Nitriles in the Presence of Heterogeneous Catalyst
PublicationTetrazoles are five-membered heterocyclic compounds containing in their rings four nitrogen atoms. They have wide applications as corrosion inhibitors, analytical reagents, high-energy materials and gas generating compositions. Tetrazoles also play important role in coordination chemistry as ligands and in medicinal chemistry as metabolically stable surrogates for carboxylic acids. In recent years, investigation of new method of...
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Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples
PublicationDeveloped and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment...
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CORROSION TESTING OF SAMPLES ACCORDING TO ASTM G36
PublicationAt the end of the study, samples were found to have structures characteristic for intercrystalline corrosion. This indicates that the samples provided (fragments of the whole) were sensitized before starting the study in boiling MgCl2.On cross sections, fine cracks are observed on all samples tested.
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Towards classification of patients based on surface EMG data of temporomandibular joint muscles using self-organising maps
PublicationThe study considers the need for an effective method of classification of patients with a temporomandibular joint disorder (TMD). The self-organising map method (SOM) was applied to group patients and used together with the cross-correlation approach to interpret the processed (rectified and smoothed by using root mean square (RMS) algorithm) surface electromyography signal (sEMG) obtained from testing the muscles (two temporal...
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Low to intermediate energy elastic electron scattering from dichloromethane (CH2Cl2)
PublicationWe report a theoretical-experimental investigation of electron scattering by dichloromethane (CH2Cl2) in the low- and intermediate energy ranges. Experimental elastic differential cross sections (DCS), in the incident electron energy range of 0.5-800 eV and scattering angle range of 10°–130°, were measured using a crossed beam relative flow technique. Integral and momentum- transfer cross sections were determined from the experimental...
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Electron collisions with X(CH3)4 molecules (X = C, Si, Ge)
PublicationAbsolute grand-total cross sections (TCSs) for electron scattering from tetramethylmethane [C(CH3)4], tetramethylsilane [Si(CH3)4], and tetramethylgermane [Ge(CH3)4] molecules have been measured at electron-impact energies extending from around 0.5 to 300 eV in the linear electron-transmission experiment. The measured TCS energy dependences show very pronounced broad enhancement, peaking near 5.5 eV for Si(CH3)4 and Ge(CH3)4 molecules...
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Effects of Road Infrastructure on Pedestrian Safety
PublicationThe objective of the work was to identify risks for pedestrians that involve road infrastructure and roadside and to define how selected elements of geometry and traffic layout affect driver behaviour (speed on approaching pedestrian crossings). The results have helped to formulate recommendations on pedestrian crossing design. The research included an analysis of 2013-2017 statistics to identify the...
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Wstępny plan badań węzła z mimośrodem dodatnim w kratownicy z kształtowników o przekrojach poprzecznych otwartych. -(Autorka otrzymała wyróżnienie za tą publikację)
PublicationW celu określenia wpływu mimośrodowego przecinania się prętów w kratownicy z kształtowników giętych na zimno, o przekrojach poprzecznych otwartych na nośność i stateczność węzłów dźwigarów kratowych, opracowano model badawczy oraz przeprowadzono wstępną analizę numeryczną przedmiotowego węzła, w programie Marc Mentat. Uzyskane wyniki wskazują na potrzebę uzupełnienia obciążenia o parę sił poziomych w modelu badawczym.
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Political Sources of Government Redistribution in High-Income Countries
PublicationIn cross-national empirical work on income inequality and government redistribution, the greatest emphasis has been on the extremes of the income scale. Less work has been done on groups that are neither rich nor poor—the middle class. The lack of attention to this group is unfortunate for several reasons. Most obviously, the middle class, if defined as the three middle income quintile groups, is by far the largest income group,...
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Static electric multipole susceptibilities of the relativistic hydrogenlike atom in the ground state: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublicationThe ground state of the Dirac one-electron atom, placed in a weak, static electric field of definite $2^{L}$ polarity, is studied within the framework of the first-order perturbation theory. The Sturmian expansion of the generalized Dirac-Coulomb Green function [R. Szmytkowski, J. Phys. B: At. Mol. Opt. Phys. 30, 825 (1997); erratum R. Szmytkowski, J. Phys. B: At. Mol. Opt. Phys. 30, 2747 (1997)] is used to derive closed-form analytical...
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Solution of coupled integral equations for quantum scattering in the presence of complex potentials
PublicationIn this paper, we present a method to compute solutions of coupled integral equations for quantum scattering problems in the presence of a complex potential. We show how the elastic and absorption cross sections can be obtained from the numerical solution of these equations in the asymptotic region at large radial distances.
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Valence and lowest Rydberg electronic states of phenol investigated by synchrotron radiation and theoretical methods
PublicationWe present the experimental high-resolution vacuum ultraviolet (VUV) photoabsorption spectra of phenol covering for the first time the full 4.3–10.8 eV energy-range, with absolute cross sections determined. Theoretical calculations on the vertical excitation energies and oscillator strengths were performed using time-dependent density functional theory and the equation-of-motion coupled cluster method restricted to single and double...
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Positron scattering on molecular hydrogen: Analysis of experimental and theoretical uncertainties
PublicationExperiments performed in recent years on positron scattering from molecular hydrogen indicated a rise of the total cross section in the limit of zero energy, but essentially disagree on the amplitude of this rise. Mitroy and collaborators [J.-Y. Zhang et al., Phys. Rev. Lett. 103, 223202 (2009)] predicted a scattering length somewhat different from values deduced experimentally. Using a Markov chain Monte Carlo modified effective...
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Evaluation of the impact of geometry and plastic deformation on the stray magnetic field around the bone shaped sample
PublicationInfluence of two factors: the variable cross-section and the localized plastic deformation, which affect the stray magnetic field profile of a ferromagnetic sample have been studied. Evaluation of an effect size is based on the analysis of the stray magnetic field component which is tangential to the longest dimension of a sample. However, in order to describe the nature of the stray magnetic field, the normal component (perpendicular...
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Influence of anisotropic stiffness in numerical analyses of tunneling and excavation problems in stiff soils
PublicationIn the stiff overconsolidated soil deposits anisotropy influences small and intermediate strain stiffness and hence it has important impact on the results of discplacement preditcions in soil-structure modelling. The authors developed a cross-anisotropic soil model which combines both stress dependent and micro-structural anisotropy. The model is based on the anisotropic hyperelastic kernel for small strain stiffness. Reference...
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Market orientation and hotel performance: The mediating effect of creative marketing programs
PublicationThis work investigates the indirect effects between market orientation and hotel performance through creative marketing programs. The focus is on exploring the indirect effects between 1) customer orientation, competitor orientation, and cross-functional integration; and 2) hotel financial performance through two aspects of creative marketing programs, namely, novelty and meaningfulness. Through an empirical analysis using structural equation...