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Search results for: TAGUCHI GAS SENSORS
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Determination of solvents residues in vegetable oils and pharmaceuticals by headspace analysis and capillary gas chromatography.
PublicationPrzedstawiono wyniki zastosowania techniki analizy fazy nadpowierzchniowej w połączeniu z kapilarną chromatografią gazową do oznaczania wybranych rozpuszczalników organicznych w próbkach olejów jadalnych i produktów farmaceutycznych. Oznaczane rozpuszczalniki to: benzen, toluen, heksan oraz chlorowcopochodne węglowodorów alifatycznych. Opracowaną procedurę poddano walidacji. Wyznaczono granicę wytrzymalności, oznaczalności, liniowość...
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Development and evaluation of headspace gas chromatography method for the analysis of carbonyl compounds in spirits and vodkas
PublicationPrzedstawiono wyniki oznaczania związków karbonylowych (po przeprowadzeniu w pochodne przy użyciu odczynnika derywatyzującego - o-PFBHA) przy wykorzystaniu techniki analizy fazy nadpowierzchniowej w połączeniu z chromatografią gazową i detektorem wychwytu elektronów(ECD). Przedstawiono optymalizację metodyki oraz wyniki uzyskane podczas próbek rzeczywistych wybranych wyrobów spirytusowych.
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Reliability of flue gas desulphurisation installations - the essential condition of efficient air pollution control
PublicationW celu minimalizacji niekorzystnego wpływu SO2 i SO3 na środowisko naturalne w wielu instalacjach skrubery odsiarczające gaz spalinowy (FGD) stosowane są do usuwania tlenków siarki z gazów wylotowych. Ostre warunki pracy skruberów i dodatkowego osprzętu powodują problemy korozyjne w powszechnie stosowanych materiałach konstrukcyjnych a awarie wywierają długookresowy wpływ na środowisko. Opisano najnowsze doświadczenia związane...
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Radioisotope measurement of selected parameters of liquid-gas flow using single detector system
PublicationTo determine the parameters of two-phase flows using radioisotopes, usually two detectors are used. Knowing the distance between them, the velocity of the dispersed phase is calculated based on time delay estimation. Such a measurement system requires the use of two gamma-ray sealed sources. But in some situations it is also possible to determine velocity of dispersed phase using only one scintillation probe and one gamma-ray source....
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Furan Fragmentation in the Gas Phase: New Insights from Statistical and Molecular Dynamics Calculations
PublicationWe present a complete exploration of the different fragmentation mechanisms of furan (C4H4O) operating at low and high energies. Three different theoretical approaches are combined to determine the structure of all possible reaction intermediates, many of them not described in previous studies, and a large number of pathways involving three types of fundamental elementary mechanisms: isomerization, fragmentation, and H/H2 loss...
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Gas Composition Influence on the Properties of Boron-Doped Diamond Films Deposited on the Fused Silica
PublicationThe main subject of this study are molecular structures and optical properties of boron-doped diamond films with [B]/[C] ppm ratio between 1000 and 10 000, fabricated in two molar ratios of CH 4 -H 2 mixture (1 % and 4 %). Boron-doped diamond (BDD) film on the fused silica was presented as a conductive coating for optical and electronic purposes. The scanning electron microscopy images showed homogenous and polycrystalline surface...
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Signals features extraction in radioisotope liquid-gas flow measurements using wavelet analysis
PublicationKnowledge of the structure of a flow is significant for the proper conduct of a number of industrial processes. In this case, a description of a two-phase flow regimes is possible by use of the time-series analysis in time, frequency and state-space domain. In this article the Discrete Wavelet Transform (DWT) is applied for analysis of signals obtained for water-air flow using gamma ray absorption. The presented method was illustrated...
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Magnetoacoustic Heating of Plasma Caused by Periodic MagnetosoundPerturbations with Discontinuities in a Quasi-Isentropic Magnetic Gas
PublicationThe magnetoacoustic heating of plasma by harmonic or periodic saw-tooth perturbations at a trans-ducer is theoretically studied. The planar fast and slow magnetosound waves are considered. The wavevector may form an arbitrary angleθwith the equilibrium straight magnetic field. In view of variableθand plasma-β, the description of magnetosound perturbations and appropriate magnetosound heatingis fairly difficult. The scenario of...
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Determination of parent and methylated polycyclic aromatic hydrocarbons in water samples by dispersive liquid–liquid microextraction–two dimensional gas chromatography–time-of-flight mass spectrometry
PublicationPolycyclic aromatic hydrocarbons (PAHs) are contaminants frequently found in environmental waters. Owing to their toxic effects, it is important to develop analytical methodologies that allow their fast and reliable determination. Dispersive liquid–liquid microextraction (DLLME) allows a quick extraction of analytes with little organic solvent consumption. The best results regarding sample preparation are obtained when 40 mL of...
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An in situ derivatization – dispersive liquid–liquid microextraction combined with gas-chromatography – mass spectrometry for determining biogenic amines in home-made fermented alcoholic drinks
PublicationA novel dispersive liquid–liquid microextraction (DLLME) gas chromatography mass-spectrometry(GC–MS) method was developed for the determination of 13 biogenic amines in home-made wine sam-ples. The method allows to simultaneous extraction and derivatization of the amines providing a simpleand fast mode of extract enrichment. During the study, two different procedures were examined. Sta-tistical analysis was performed to choose...
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Application of dispersive liquid-liquid microextraction and gas chromatography with mass spectrometry for the determination of oxygenated volatile organic compounds in effluents from the production of petroleum bitumen
PublicationWepresent a new procedure for the determination of oxygenated volatile organic compounds in samples of postoxidative effluents from the production of petroleum bitumens using dispersive liquid–liquid microextraction and gas chromatography with mass spectrometry. The eight extraction parameters were optimized for 43 oxygenated volatile organic compounds. The detection limits obtained ranged from 0.07 to 0.82 g/mL for most of the...
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Application of dynamic headspace and gas chromatography coupled to mass spectrometry (DHS-GC-MS) for the determination of oxygenated volatile organic compounds in refinery effluents
PublicationThe paper presents a new procedure for the determination of oxygenated volatile organic compounds (O-VOCs) in postoxidative effluents from the production of petroleum asphalt using dynamic headspace coupled to gas chromatography-mass spectrometry in the selected ion monitoring (SIM) mode (DHSGC-MS). Among the GC capillary columns tested, a polar SLB-IL111 column with the ionic liquid stationary phase was found to be superior due...
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Application of Monoferrocenylsumanenes Derived from Sonogashira Cross-Coupling or Click Chemistry Reactions in Highly Sensitive and Selective Cesium Cation Electrochemical Sensors
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Silica-Based Ionogels: Nanoconfined Ionic Liquid-Rich Fibers for Headspace Solid-Phase Microextraction Coupled with Gas Chromatography–Barrier Discharge Ionization Detection
PublicationIn this work, hybrid silica-based materials with immobilized ionic liquids (ILs) were prepared by sol–gel technology and evaluated as solid-phase microextraction (SPME) fiber coatings. High loadings of the IL 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide ([C4MIM][TFSI]) were confined within the hybrid network. Coatings composition and morphology were evaluated using scanning electron microscopy and energy dispersive...
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A Highly Selective Biosensor Based on Peptide Directly Derived from the HarmOBP7 Aldehyde Binding Site
PublicationThis paper presents the results of research on determining the optimal length of a peptide chain to eectively bind octanal molecules. Peptides that map the aldehyde binding site in HarmOBP7 were immobilized on piezoelectric transducers. Based on computational studies, four Odorant Binding Protein-derived Peptides (OBPPs) with dierent sequences were selected. Molecular modelling results of ligand docking with selected peptides were...
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Green, simple analytical method for biogenic amines determination in fruit juice samples using salting-out assisted liquid-liquid microextraction and gas chromatography-mass spectrometry
PublicationSalting-out assisted liquid-liquid microextraction (SALLME) was integrated with the derivatization procedure to establish a one-step sample pre-treatment approach for rapid analysis of 14 biogenic amines (BAs) in fruit juices. The methodology consists of salting-out of analytes, derivatization with ethyl chloroformate (ECF), extraction with ethyl acetate (EtAc), and the analysis of the derivatized BAs using gas chromatography-mass...
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Monitoring the BTEX Volatiles during 3D Printing with Acrylonitrile Butadiene Styrene (ABS) Using Electronic Nose and Proton Transfer Reaction Mass Spectrometry
PublicationWe describe a concept study in which the changes of concentration of benzene, toluene, ethylbenzene, and xylene (BTEX) compounds and styrene within a 3D printer enclosure during printing with different acrylonitrile butadiene styrene (ABS) filaments were monitored in real-time using a proton transfer reaction mass spectrometer and an electronic nose. The quantitative data on the concentration of the BTEX compounds, in particular...
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Graphene oxide, reduced graphene oxide and composite thin films NO2 sensing properties
PublicationA graphene oxide (GO), reduced graphene oxide (RGO) and poly(3,4-ethylenedioxytiophene)-reduced graphene oxide (PEDOT-RGO composite) gas sensors were successfully fabricated using an electrodeposition method. The electrodeposition was carried out in aqueous GO dispersions. To obtain RGO and PEDOT-RGO, the electrochemical reduction of GO and PEDOT-GO was carried out in 0.1 M KCl at a constant potential of −0.85 V. The GO, RGO and PEDOT-RGO...
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Gas‐Phase Removal of Indoor Volatile Organic Compounds and Airborne Microorganisms Over Mono‐ and Bimetal‐Modified (Pt, Cu, Ag) Titanium(IV) Oxide Nanocomposites
PublicationThe photocatalytic deactivation of volatile organic compounds and mold fungi using TiO2 modified with mono‐ and bimetallic (Pt, Cu, Ag) particles is reported in this study. The mono‐ and bimetal‐modified (Pt, Cu, Ag) titanium(IV) oxide photocatalysts were prepared by chemical reduction method and characterized using XRD, XPS, DR/UV‐Vis, BET and TEM analysis. The effect of incident light, type and content of mono‐ and bimetallic...
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Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide using gas–liquid chromatography
PublicationBased on gas–liquid chromatography (GLC) retention data, activity coefficients at infinite dilution of 39 different solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide ([HDABCO][NTf2]) have been determined. Measurements covered a broad range of types of organic solutes including alkanes, alcohols, ketones, benzene derivatives and McReynold’s compounds. Activity coefficients were...
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Application and optimization of headspace solid-phase microextraction (HS-SPME) coupled with gas chromatography - flame-ionization detector (GC-FID) to determine products of the petroleum industry in aqueous samples
PublicationA simple and solvent-free analytical method has been optimized for the determination of hydrocarbons (C6 - C20) from products of the petroleum industry in aqueous samples. Extraction and analysis was carried out using headspace solid-phase microextraction (HS-SPME) and gas chromatography coupled with flame-ionization detector (GC-FID). A ZB-5 capillary column (30 m × 0.25 mm inner diameter, 0.25 µm film thickness) was used for...
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LABORATORY STAND FOR INVESTIGATIONS OF THE QUICK - CHANGING TEMPERATURE OF GAS FLOWING IN THE PISTON COMPRESSOR OUTLET CHANNEL
PublicationThis paper presents a laboratory stand, created as a part of work on the doctor dissertation, intended for investigation of heat and flow processes taking place in the Espholin H3S piston compressor outlet channel. The test stand elements and their configuration within the stand are described. Discussed are also problems connected with the quick-changing measurement technique, solutions which have been proposed so far in that technology...
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ANN based evaluation of the NOx concentration in the exhaust gas of a marine two-stroke diesel engine
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Continuous Monitoring of Thermooxidative Degradation Products of Polystyrene by Membrane Extraction with Sorbent Interface and Gas Chromatography
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Durability evaluation of Ni‐Cr‐Mo super alloys in a simulated scrubbed flue gas environment
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Influence of Analyte Flow Rate on Signal and Response Time of the Amperometric Gas Sensor with Nafion Membrane
PublicationW publikacji przedstawiono rezultaty badań nad wpływem zmian objętościowego natężenia przepływu gazu na sygnał i czas odpowiedzi prototypowego czujnika ditlenku siarki z membraną nafionową. Porównywano właściwości czujników różniących się materiałem elektrody pracującej oraz składem roztworu elektrolitu wewnętrznego. Zastosowano elektrody pracujące wykonane z napylonych próżniowo na powierzchnię membrany nafionowej złota i platyny....
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Monitoring of volatile organic compounds (VOCs) in atmospheric air. Part I. On-line gas analyzers
PublicationThe paper reviews the subject literature concerning the analytical instruments routinely used for monitoring volatile organic compounds in atmospheric air. The analyzers are classified as stationary or mobile according to their ease of transport. Stationary DOAS (Differential Optical Absorption Spectroscopy) analyzer is characterized, as are MIMS (Membrane Introduction Mass Spectrometry), MESI (Membrane Extraction with Sorbent...
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Studies on development of headspace - gas chromatographic determination of volatile fatty acids in troublesome environmental samples
PublicationBadania nad opracowaniem procedur oznaczania LKT w silnie zanieczyszczonych próbkach środowiskowych za pomocą techniki analizy fazy nadpowierzchniowej w połączeniu z chromatografią gazową z wykorzystaniem detektora płomieniowo-jonizacyjnego na etapie oznaczeń końcowych. Dobrano warunki ekstrakcji LKT do fazy nadpowierzchniowej oraz warunki chromatograficzne. Metodyka pozwala oznaczać LKT w bardzo skomplikowanych próbkach ciekłych...
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A comparison of three solvent-free techniques coupled with gas chromatography for determining trihalomethanes in urine samples
PublicationDążenie do oznaczania lotnych analitów organicznych w próbkach płynów biologicznych charakteryzujących się złożonym, a często zmiennym składem matrycy, stanowi siłę napędową do działań analityków w zakresie poszukiwania nowych rozwiązań metodycznych i aparaturowych. Publikacja ta przedstawia porównanie trzech technik zastosowanych do tych celów: technikę analizy fazy nadpowierzchniowej z generacją strumienia ciekłego sorbentu...
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Evaluation of the High-Pressure Gas Transmission Network Impact for Environmental - Construction Phase and Network Operation
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Reliability-operational analysis of fixed gas fire extinguishing equipment integrated with fire signalling systems
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Application of gas chromatographic data and 2D molecular descriptors for accurate global mobility potential prediction
PublicationMobility is a key feature affecting the environmental fate, which is of particular importance in the case of persistent organic pollutants (POPs) and emerging pollutants (EPs). In this study, the global mobility classification artificial neural networks-based models employing GC retention times (RT) and 2D molecular descriptors were constructed and validated. The high usability of RT was confirmed based on the feature selection...
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Application of gas chromatography-olfactometry (GC-O) in analysis and quality assessment of alcoholic beverages - a review
PublicationW ostatnich latach prowadzone są intensywne badania nad aktywnością sensoryczną poszczególnych składników zapachów napojów alkoholowych i nad zależnościami pomiędzy zapachem, a składem chemicznym lotnej frakcji tych produktów z wykorzystaniem techniki chromatografii gazowej z detekcją olfaktometryczną (GC-O). GC-O jest techniką wykorzystującą możliwość oceny sensorycznej eluatu z kolumny chromatograficznej, przy czym dla każdego...
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Sample preparation for gas chromatographic determination of halogenated volatile organic compounds in environmental and biological samples
PublicationPodstawowym elementem przygotowania próbek środowiskowych i biologicznych do analizy jest etap izolacji i/lub wzbogacania polegający na przeniesieniu analitów z matrycy pierwotnej charakteryzującej się złożonym i często zmiennym składem (próbka oryginalna) do matrycy wtórnej z równoczesnym usunięciem substancji przeszkadzających (izolacja)i zwiększeniem stężenia analitów do poziomu powyżej granicy oznaczalności stosowanego przyrządu...
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Experimental and mathematical modelling study of gas combustion under the high-temperature and oxygen-deficient oxidizers
PublicationPraca przedstawia wyniki badań eksperymentalnych i modelowania numerycznego wpływu parametrów utleniacza za długość i objętość płomienia przy spalaniu paliwa gazowego w środowisku o wysokiej temperaturze i ubogim w tlen.
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Determination of carbon monoxide, methane and carbon dioxide in refinery hydrogen gases and air by gas chromatography
PublicationW pracy przedstawiono metodę oznaczania śladowych zawartości tlenku węgla, metanu oraz dwutlenku węgla w rafineryjnych gazach wodorowych oraz powietrzu; granica oznaczalności metody wynosi odpowiednio 0,15, 0,15 oraz 0,20 mikro-gram/litr. Zaprezentowano w pracy prostą modyfikację chromatografu gazowego wyposażonego w detektor płomieniowo-jonizacyjny (FID). Zastosowano kolumnę typu PorapakQ, dodatkowo połączono szeregowo z krótką...
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Minimizing Greenhouse Gas Emissions From Ships Using a Pareto Multi-Objective Optimization Approach
PublicationTo confront climate change, decarbonization strategies must change the global economy. According to statements made as part of the European Green Deal, maritime transport should also become drastically less polluting. As a result, the price of transport must reflect the impact it has on the environment and on health. In such a framework, the purpose of this paper is to suggest a novel method for minimizing emissions...
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Remote Sensing in Vessel Detection and Navigation
PublicationThe Special Issue (SI) “Remote Sensing in Vessel Detection and Navigation” highlighted a variety of topics related to remote sensing with navigational sensors. The sequence of articles included in this Special Issue is in line with the latest scientific trends. The latest developments in science, including artificial intelligence, were used. The 15 papers (from 23 submitted) were published.
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Response of a New Low-Coherence Fabry-Perot Sensor to Hematocrit Levels in Human Blood
PublicationIn this paper, a low-coherence Fabry-Perot sensor with a spectrally measured signal processing response to the refractive index of liquids is presented. Optical fiber sensors are potentially capable of continuous measuring hematocrit levels in blood. Low-coherence Fabry-Perot interferometric sensors offer a robust solution, where information about the measurand is encoded in the full spectrum of light reflected from the sensing...
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Properties of Nasicon-based CO2 sensor with Bi8Nb2O17 reference electrode
PublicationGas sensors are useful for the carbon dioxide concentration monitoring in many applications. The major challenge is to develop a potentiometric sensor working without the necessity of a reference gas and without a need of the reference electrode encapsulation. Important issue is a selection of reference electrode material, which should provide stable reference potential. For example as reference electrode material in sensor based...
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Instrumentation optical fibres for wave transformation, signal processing, sensors, and photonic functional components, manufactured at Białystok University of Technology in Dorosz Fibre Optics Laboratory
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Study of the NO2 sensing mechanism of PEDOT-RGO film using in situ Raman Spectroscopy
PublicationIn this work, the mechanism of the NO2 reaction with PEDOT-RGO composite film has been investigated via in situ Raman spectroscopy. Reduced graphene oxide (RGO), poly(3,4-ethylenedioxytiophene)-reduced graphene oxide (PEDOT-RGO) and poly(3,4-ethylenedioxytiophene)/ClO4− (PEDOT/ClO4−) films were fabricated using an electrodeposition method and used as resistance sensors of gaseous nitrogen dioxide. The experimental results indicate...
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Application of single drop extraxtion (SDE) gas chromatography method for the determination of carbonyl compounds in spirits and vodkas
PublicationW pracy przedstawiono metodę oznaczania związków karbonylowych w spirytusach i wódkach, wykorzystującą do izolacji i wzbogacania technikę mikroekstrakcji do pojedynczej kropli (SDE)po derywatyzacji analitów O-(2,3,4,5,6-pentafluorobenzylo)hydroksylaminą. Określono optymalne parametry izolacji i wzbogacania aldehydów z roztworów alkoholowych (objętość próbki, objętość kropli, zawartość alkoholu, temperaturę i czas ekstrakcji)....
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Zagrożenia środowiska podczas eksploatacji gazociągów podmorskich = Environmental threats during oparation of subsea gas pipelines
PublicationPrzedstawiono wybrane zagadnienia eksploatacji gazociągów podmorskich, w tym zagrożenia dla rekreacyjnego i gospodarczego korzystania z morza. Uszkodzenie gazociągu podmorskiego jest zazwyczaj spowodowane korozją, działaniami morskimi lub zagrożeniami naturalnymi. W określonych warunkach mogą wytrącić się kryształy hydratów węglowodorów gazowych, co może prowadzić do zablokowania linii przesyłowej
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Identification of organic acids as potential biomarkers in the urine of autistic children using gas chromatography/mass spectrometry
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Direct Screening ofWater Samples for Benzene Hydrocarbon Compounds by Headspace Liquid-Phase Microextraction--Gas Chromatography
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Direct screening of ground water samples for fuel oxygenates by headspace liquid phase microextraction–gas chromatography
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Low-energy positron scattering from gas-phase tetrahydrofuran: A quantum treatment of the dynamics and a comparison with experiments
PublicationIn this paper we report new quantum calculations of the dynamics for low-energy positrons interacting with gaseous molecules of tetrahydrofuran. The new quantum scattering cross sections are differential and integral cross sections at collision energies between 1.0 and 25.0 eV and include a careful treatment of the additional effects on the scattering process brought about by the permanent dipole moment of the target molecule....
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Ammonia in Fly Ashes from Flue Gas Denitrification Process and its Impact on the Properties of Cement Composites
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Headspace solid-phase microextraction and gas chromatography-olfactometry analysis of raw spirits of different organoleptic quality
PublicationCelem pracy było określenie, ktore związki wnoszą wkład w aromat destylatów rolniczych i wskazać te z nich które mogą powodować obniżenie ich właściwości organoleptycznych. W badaniach zastosowano ekstrakcję lotnych analitów z fazy nadpowierzchniowej techniką mikroekstrakcji do fazy nadpowierzchniowej w połączeniu z chromatografia gazową z detekcja olfaktometryczną . Znaleziono 40 zsubstancji, które mogą być markerami jakości organoleptycznej