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Search results for: TANDEM MASS SPECTROMETRY
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A simplified energy dissipation based model of heat transfer for subcooled flow boiling
PublicationIn the paper a model is presented based on energetic considerations for subcooled flow boiling heat transfer. The model is the extension of authors own model developed earlier for saturated flow boiling and condensation. In the former version of the model we used the heat transfer coefficient for the liquid single-phase as a reference level, due to the lack of the appropriate model for heat transfer coefficient for the subcooled...
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A simplified energy dissipation based model of heat transfer for post-dryout flow boiling
Publicationmodel for post dryout mist flow heat transfer is presented based on considerations of energy dissipation in the flow. The model is an extension of authors own model developed earlier for saturated and subcooled flow boiling. In the former version of the model the heat transfer coefficient for the liquid singlephase convection as a reference was used, due to the lack of the appropriate model for heat transfer coefficient for the...
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Infrared techniques for natural convection investigations in channels between two vertical, parallel, isothermal and symmetrically heated plates
PublicationThe effect of the gap width between two symmetrically heated vertical, parallel, isothermal plates on intensity of natural convective heat transfer in a gas (Pr = 0.71) was experimentally studied using the balance and gradient methods. In the former method heat fluxes were determined based on measurements of the voltage and electric current supplying the heaters placed inside the walls. In the latter, heat fluxes were calculated...
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Temperature, velocity and mean turbulence structure in strongly heated internal gas flows. Comparison of numerical predictions with data
PublicationW pracy przedstawiono symulacje numeryczne przy użyciu szeregu modeli turbulencji celem analizy silnie ogrzewanego przepływu powietrza w pionowych rurach. Obliczenia porównano z danymi eksperymentalnymi. Analizowano modyfikacje pola prędkości, temperatury i turbulencji. W rozpatrywanych warunkach odnotowano silną wrażliwość obliczeń na silnie zmieniające się pole temperatury. Stwierdzono, że analizowane przypadki najlepiej odzwierciedla...
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Hydrodynamics and heat transfer in bubbly flow in the turbulent boundarylayer
PublicationW pracy przedstawiono oryginalne podejście do modelowania przepływu pęcherzykowego w warstwie przyściennej i w kanale. Podejście oparte jest na sumowaniu energii dyssypacji pochodzącej od przepływu ścinającego w kanale oraz dyssypacji pochodzącej od obecności pęcherzyków. W wyniku otrzymuje się naprężenia styczne ekwiwalentnego przepływu jednofazowego. Zaproponowano własne podejście do modelowania stopnia zapełnienia opisane równaniem...
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Natural convective heat transfer from isothermal cuboids
PublicationThe paper presents results of theoretical and experimental investigations of the convective heat transfer from isothermal cuboid. The analytical solution was performed taking into account complete boundary layer length and the manner of its propagation around isothermal cuboid. It arises at horizontal bottom surface and grows on vertical lateral surface of the block. After changing its direction, the boundary layer occurs above...
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Study of free convective heat transfer from horizontal conic.
PublicationPrzedstawiono teoretyczne rozważania i badania eksperymentalne konwekcji swobodnej od izotermicznej powierzchni poziomego stożka w przestrzeni nieograniczonej. Rozwiązanie przeprowadzono dla wprowadzonego krzywoliniowego układu współrzędnych, opartego na krzywej linii prądu wokół powierzchni stożkowej.
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The new concept of capillary forces aided evaporator for application in domestic organic rankine cycle
PublicationThis paper presents studies on the possibility of applying capillary forces induced in the porous structure to a modern design of evaporator. The potential application of such heat exchanger is for example an evaporator of the domestic micro combined heat and power (CHP) unit. One of the problems in the micro-CHP is excessive demand for pumping power. The proposed design helps in overcoming that issue. In the evaporator outlined...
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Heat transfer and pressure drop during flow boiling of pure efrigerants and refrigerant/oil mixtures in tube with porous coating
PublicationW pracy przedstawiono wpływ powłoki porowatej na średni współczynnik przejmowania ciepła oraz opory przepływu podczas wrzenia wybranych czynników chłodniczych wewnątrz poziomych rurek. Badania przeprowadzono dla techniczne czystych czynników chłodniczychR22, R134a i R407C oraz ich mieszanin z olejem poliestrowym 1% i 5% wrzących w rurkach wykonanych ze stali nierdzewnej, o wewnętrznej powierzchni gładkiej oraz z metaliczną powłoką...
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Modeling of natural convection with Smoothed Particle Hydrodynamics: Non-Boussinesq formulation
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Evaluating the influence of radiative heat flux on convective heat transfer from a vertical plate in air using an improved heating plate
PublicationThis article examines the influence of radiative heat flux on the accuracy of the results of free convective heat transfer in air. In order to carry out these tests, based on the experience gained during the operation of a plate heated on one side, compensated by a reverse heat loss flux counter-heater, a unique double-sided heating sandwich plate was designed and built, consisting of three thin epoxy resin plates reinforced with...
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An inverse algorithm for contact heat conduction problems with an interfacial heat source based on a first-order thermocouple model
PublicationInverse problems of contact heat conduction with an interfacial heat source are common in various fields of science, engineering and technology. In this study, an algorithm for their solution is developed based on an inverse parametric optimisation method with an impulse response function describing the heat partition and contact heat transfer. A first-order thermocouple model with a time constant parameter is embedded in the impulse...
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Comparison of heat transfer from single- and double-sided heated horizontal plate under free convection in air with constant heat flux condition
PublicationThis paper presents the results of an experimental and numerical study of convective heat transfer from a newly designed double-sided heated horizontal plate in air. To ensure equal heat transfer from both surfaces, the plate was equipped with two independently supplied electric heaters and resistance thermometers on each side. Minimizing the plate's thickness reduced lateral heat loss and improved measurement accuracy. The study...
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Experimental and numerical study of thermal and electrical potential of BIPV/T collector in the form of air-cooled photovoltaic roof tile
PublicationAmong renewable energy sources, Building-Integrated Photovoltaic/Thermal (BIPV/T) systems are gaining increasing interest. To improve their economic competitiveness, technologies that increase their efficiency are searched for. The paper is devoted to evaluating the impact of various air-cooling configurations on the thermal and electrical performance of a photovoltaic roof tile. A numerical model of the own experimental system...
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Jeffreys heat conduction in coupled semispaces subjected to interfacial heating
PublicationA Jeffreys heat conduction problem for coupled semispaces subjected to the action of an interfacial heat source was defined. An analytical solution of the problem was derived for a polynomial specific power of the heat source using the Laplace transform approach. The asymptotic and parametric analysis was performed for different ratios of thermal conductivities , thermal diffusivities , thermal relaxation times and coefficients...
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Recent advances of selected passive heat transfer intensification methods for phase change material-based latent heat energy storage units: A review
PublicationThe following article overviews recent studies regarding heat transfer enhancement methods, explicitly focusing on fins and coils utilization, in phase change material-based latent heat thermal energy storage systems. It discusses the influence of various geometrical and material parameters on the melting and solidification processes, as well as the orientation of the heat transfer surface within the storage tank. Additionally,...
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A novel concept of enhanced direct-contact condensation of vapour- inert gas mixture in a spray ejector condenser
PublicationAn analytical model of direct steam condensation (DCC) in the novel idea of spray ejector condenser (SEC) in the presence of inert gas has been developed. It is based on continuity, momentum and energy equations for the steam-carbon dioxide mixture and direct contact condensation mechanisms due to heat transfer and concentration. Crucial in the process of DCC is atomisation of the motive fluid in the ejector. The effect of atomised...
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A multi‑criteria approach to investigate spatial distribution,sources, and the potential toxicological effect of polycyclic aromatic hydrocarbons (PAHs) in sediments of urban retention tanks
PublicationBottom sediments deposited in retention tanks (RTs) located on two urban streams (Oliwski and Strzyza) in the central part of Gdansk (Poland) were analysed for polycyclic aromatic hydrocarbons’ (PAHs) content. PAHs were extracted from samples with methylene chloride, then the extracts were subjected to clean-up applying the solid phase extraction (SPE) method. Quantitative and qualitative determination of 16 PAHs was performed...
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SimLE Stardust: How an experiment evolved from student tinkering to a stratospheric research platform
PublicationStratospheric balloons are one of the most accessible methods of near space exploration. Their applications include capturing of extreme living organisms whose existence in the stratosphere has been suggested in the literature. These potential microorganisms would have evolved to survive the unique environment of low temperature, low pressure and high solar radiation. This makes the development of...
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DETERMINATION OF SURFACTANTS IN ENVIRONMENTAL SAMPLES. PART II. ANIONIC COMPOUNDS
PublicationSurfactants (SAA) with negative charge of polar group are named as anionic compounds. They are main constituent of most products containing synthetic surfactants. The linear alkylbenzene sulfonates (LAS), alkyl ethoxysulfates (AES) and alkyl sulfates (AS) are typically applied from this class of compounds. Those surfactants are ingredients of household detergents and cleaners, laundry detergents, cosmetic. Moreover they can be...
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Molecular transformation of dissolved organic matter in manganese ore-mediated constructed wetlands for fresh leachate treatment
PublicationThe organic matter (OM) and nitrogen in Fresh leachate (FL) from waste compression sites pose environmental and health risks. Even though the constructed wetland (CW) can efficiently remove these pollutants, the molecular-level transformations of dissolved OM (DOM) in FL remain uncertain. This study reports the molecular dynamics of DOM and nitrogen removal during FL treatment in CWs. Two lab-scale vertical-flow CW systems were...
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THEORETICAL POTENTIAL OF HYDROGEN PRODUCTION FROM TEXTILES WASTES IN POMERANIAN REGION BY MEANS OF DARK FERMENTATION
PublicationModel has been developed for calculating theoretical mass of hydrogen produced from textile wastes by mean of dark fermentation. As vegetable fibres wastes were chosen two mostly used — cotton and linen (flax). As the synthethic carbohydrate rich fiber was chosen viscose. In the background there were introduced: problems of dark fermentation, characteristics of textile material structure. Additionally pathways of the process...
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STUDY ON THE EFFECTIVENESS OF THE TURBINE CONDENSER AIR EXTRACTION SYSTEM USING HYDRO EJECTORS
PublicationThe aim of the paper is to investigate the effectiveness of the 18K380 steam turbine condenser air extraction system using hydro ejectors. Motivation for the analysis is a need of improvement of the energy conversion ratio of the power plant. To achieve this goal it is necessary to establish efficiency of each subsystem of the energy cycle. The air extraction system is not a highly power consuming system but it has great impact...
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Determination of dryout localization using a five-equation model of annular flow for boiling in minichannels
PublicationDetailed studies have suggested that the critical heat flux in the form of dryout in minichannels occurs when the combined effects of entrainment, deposition, and evaporation of the film make the film flow rate go gradually and smoothly to zero. Most approaches so far used the mass balance equation for the liquid film with appropriate formulations for the rate of deposition and entrainment respectively. It must be acknowledged...
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Centrifuge modelling of tapered wall jacked into dense sand
PublicationA series of static penetration tests of trapezoidal walls in dense Fontainebleau sand were performed in the geotechnical centrifuge at Gustave Eiffel University. The models of wall with three different shapes (straight profile with thickness D=16mm, 0.75 degree and 1.5 degree of taper angle) but with the same volume were used. The soil mass was instrumented with five stress cells located at two levels at 2D, 4D and 6D distance...
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Vessel Energy Requirement Prediction from Acceleration Stage Towing Tests on Scale Models
PublicationOne of the most crucial tasks for naval architects is computing the energy required to meet the ship’s operational needs. When predicting a ship’s energy requirements, a series of hull resistance tests on a scale model vessel is carried out in constant speed stages, while the acceleration stage measurements are ignored. Another important factor in seakeeping analysis is the ship’s hydrodynamic added mass. The second law of dynamics...
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Numerical Simulations for Transonic Flow in Control Valve
PublicationResults of numerical simulations for transonic flow in control valve are presented. The valve is the main part of an adaptive pneumatic shock absorber. Flow structure in the valve domain and the influence of the flow non-uniformity in the valve on a mass flow rate is investigated. Numerical simulation results are compared with experimental data.
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Inner-shell fragmentation of molecules into neutral fragments in high-Rydberg states induced by soft X-ray excitation with pulsed-field ionization
PublicationIn the present communication, we will show the results of measurements probing the production of neutral high-Rydberg fragments at the K edges of the molecules containing oxygen and nitrogen atoms. The experiments were performed at the Gas Phase beamline of the Elettra synchrotron radiation laboratory (Trieste, Italy), exploiting a combined soft X-ray excitation with pulsed-field ionization and ion time-of-flight (TOF) spectrometry...
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Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques
PublicationScientific interest in SOA influence on indoor air quality increases since last 20 years. It is well known, that particles of nano-sized diameter pose a threat for human health causing, among others: eye, upper airway irritation, inflammatory response in cells, worsening asthma, hypertension, diabetes, and central nervous dysfunction. Terpenes are reactive VOCs, commonly emitted in indoor air and considered to be SOA precursors...
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The effect of metal cluster deposition route on structure and photocatalytic activity of mono- and bimetallic nanoparticles supported on TiO2 by radiolytic method
PublicationTiO2 (P25) was modified with small and relatively monodisperse mono- and bimetallic clusters (Ag, Pd, Pt, Ag/Pd, Ag/Pt and Pd/Pt) induced by radiolysis to improve its photocatalytic activity. The as-prepared samples were characterized by X-ray fluorescence spectrometry (XRF), photoluminescence spectrometry (PL), diffuse reflectance spectroscopy (DRS), X-ray powder diffractometry (XRD), scanning transition electron microscopy (STEM)...
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Influence of permanent magnetic field on wear performance of dry sliding contacts
PublicationResults of experimental studies concerning the influence of permanent magnetic field on wear of dry sliding contact are presented.It was found that magnetic field of horizontal orientation is causing temporary reduction of material's hardness. It also facilitates and accelerates removal process of wear particles from the contact zone.Formation of bulges, consisting of accumulated and compacted anti-ferromagnetic material produced...
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Dissociative electron attachment to the radiosensitizing chemotherapeutic agent hydroxyurea
PublicationDissociative electron attachment to hydroxyurea was studied in the gas phase for electron energies ranging from zero to 9 eV in order to probe its radiosensitizing capabilities. The experiments were carried out using a hemispherical electron monochromator coupled with a quadrupole mass spectrometer. Diversified fragmentation of hydroxyurea was observed upon low energy electron attachment and here we highlight the major dissociation...
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A New Approach to Chemical Recycling of Polyamide 6.6 and Synthesis of Polyurethanes with Recovered Intermediates
PublicationA new efficient method for the chemical decomposition of polyamide 6.6 by the glycolysis and amino-glycolysis processes was proposed. The glycolysis was conducted using the mass excess of ethylene glycol (EG) as a decomposing agent in the presence of a catalyst. Also, a mixture of EG and triethylenetetramine was used as another decomposing agent in the amino- glycolysis process. The described process of decomposition did not...
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Interactions of telomeric proteins with nucleic acids: sequence recognition on intact and oxidatively damaged telomeres
PublicationTelomeres are complex nucleoprotein assemblies that play a vital role in the maintenance of functional ends of linear chromosomes. Telomeric DNA, composed of tandem repeats of the 5'-TTAGGG-3' motif, solves the so-called end replication problem: as chromosomes shorten with each cell division, no information is lost, and the telomere can be re-extended. In the cell, many protein factors regulate telomere length, nuclear positioning...
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Authentication of whisky due to its botanical origin and way of production by instrumental analysis and multivariate classification methods
PublicationHeadspacemass-spectrometry (HS-MS), mid infrared (MIR) and UV–vis spectroscopywere used to authenticate whisky samples from different origins and ways of production ((Irish, Spanish, Bourbon, TennesseeWhisky and Scotch). The collected spectra were processed with partial least-squares discriminant analysis (PLS-DA) to build the classification models. In all cases the five groups ofwhiskieswere distinguished, but the best resultswere...
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Electrochemistry meets enzymes: Investigation of the biotransformation pathway of C-1311 based on electrochemical simulation in comparison to in vitro methods.
PublicationThe knowledge of the metabolic pathways and the biotransformation of new drugs is one of the major challenges in pharmaceutical research. It is crucial for elucidation of degradation routes of the new biologically active compounds, especially in the area of possible toxicity. Conventional in vitro drug metabolism studies are based on incubating drug candidate with e.g. hepatocytes or, most importantly, liver cell microsomes and...
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Simultaneous determination of ibuprofen and its metabolites in complex equine urine matrices by GC-EI-MS in excretion study in view of doping control
PublicationA novel assay for the simultaneous determination of ibuprofen (IBU) and its four probable metabolites, 1-hydroxyibuprofen (1-OH IBU), 2-hydroxyibuprofen (2-OH IBU), 3-hydroxyibuprofen (3-OH IBU) and carboxyibuprofen (CBX IBU) in equine urine samples with the application of Gas Chromatography-Electron Ionization-Mass Spectrometry (GC-EI-MS) has been developed and elaborated. The new approach for sample preparation including minimizing...
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Composition and antimicrobial activity of fatty acids detected in the hygroscopic secretion collected from the secretory setae of larvae of the biting midge Forcipomyia nigra (Diptera: Ceratopogonidae)
PublicationThe hygroscopic secretion produced by the secretory setae of terrestrial larvae of the biting midge Forcipomyia nigra (Winnertz) was analysed using gas chromatography coupled with mass spectrometry (GC-MS). The viscous secretion is stored at the top of each seta and absorbs water from moist air. GC-MS analyses (four independent tests) showed that the secretion contained 12 free fatty acids, the most abundant of which were oleic...
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Keratinocyte-derived small extracellular vesicles supply antigens for CD1a-resticted T cells and promote their type 2 bias in the context of filaggrin insufficiency
PublicationIntroduction: Exosome-enriched small extracellular vesicles (sEVs) are nanosized organelles known to participate in long distance communication between cells, including in the skin. Atopic dermatitis (AD) is a chronic inflammatory skin disease for which filaggrin (FLG) gene mutations are the strongest genetic risk factor. Filaggrin insufficiency affects multiple cellular function, but it is unclear if sEV-mediated cellular communication...
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Rapana venosa consumption improves the lipid profiles and antioxidant capacities in serum of rats fed an atherogenic diet
PublicationIn the recent years, the consumption of seafood has increased. There are no results on the studies of Rapana venosa (Rv) as a supplementation to the diets. We hypothesized that Rv would increase antioxidant capacity and reduce blood lipids, based on the composition of bioactive compounds and fatty acids. Therefore, the aim of this investigation was to evaluate in vitro and in vivo actions of Rv from contaminated (C) and non-C (NC)...
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Wpływ termoplastycznych kompozycji napełnianych miałem gumowym na wybrane właściwości asfaltu drogowego
PublicationDynamiczny rozwój transportu samochodowego zmusza do wykonywania nawierzchni drogowych z materiałów o wysokiej wytrzymałości oraz odporności na odkształcenia trwałe, co znacznie wydłuża żywotność nawierzchni. Polskie przedsiębiorstwo BISEK Sp. z o.o. z Wrocławia we współpracy z Politechniką Wrocławską, jako pierwsze wykorzystało miał gumowy do modyfikacji asfaltów metodą mokrą. W chwili obecnej firma Lotos Asfalt Sp. z o.o. wprowadziła...
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Influence of processing conditions on crystal structure of BiNbO 4 ceramics
PublicationBismuth niobate (BiNbO4) has attracted attention as a low-fired ceramics with promising microwave application potential. It belongs to the bismutocolumbite oxides with similarly to scheelite-like stibiotantalite structure (SbTaO4) A3+B5+O4. Aim of the present research was to fabricate BiNbO4 ceramics by solid state reaction route from the mixture of simple oxides viz. Bi2O3, and Nb2O5, and study its phase composition as well as...
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Modal analysis of a steel grandstand
PublicationAmong the issues related to the idea of sustainable society is the safety of civil engineering structures devoted to satisfy different needs of people. One of the types of structures devoted to satisfy recreational needs are grandstands, which are used during sport events or music concerts. It is obligatory to consider interaction between structure and crowd load especially when the crowd movement involves rhythmic jumping, dancing,...
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MHD Casson flow across a stretched surface in a porous material: a numerical study
PublicationIn this study, we examine the nature of magnetohydrodynamic (MHD) Casson flow of fluid across a stretched surface in a porous material. It studies how the behaviour of Casson fluids is affected by a number of variables, including thermal radiation, chemical processes, Joule heating, and viscosity dissipation. The Keller box strategy, based on the finite difference method (FDM), is used to tackle the complex numerical problem. Graphical...
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From the pills to environment – Prediction and tracking of non-steroidal anti-inflammatory drug concentrations in wastewater
PublicationThe extend of environment pollution by pharmaceuticals is in a stage that required more automatic and integrated solutions. The non-steroidal anti-inflammatory drugs (NSAIDs) are one of the most popular pharmaceutical in the world and emerging pollutants of natural waters. The aim of the paper was to check the correlation of the sales data of selected NSAIDs (ibuprofen, naproxen, diclofenac) and their concentration in the WWTP...
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Mercury concentration and the absolute and relative sizes of the internal organs in cormorants Phalacrocorax carbo (L. 1758) from the breeding colony by the Vistula Lagoon (Poland)
PublicationThis work analyses the effect of mercury on the condition of cormorants (Phalacrocorax carbo) from an extensive breeding colony in northern Poland, the largest in Europe. A total of 55 birds (44 adults and 11 immature) were obtained. Total mercury (Hg) concentrations were measured in the liver, kidneys, breast muscles, heart, gullet (oesophagus), stomach, intestines, trachea, lungs and eyeballs. The total body mass (TBM) and empty...
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Experimental investigation of thermal energy storage in shell-and-multi-tube unit with nano-enhanced phase change material
PublicationThis paper deals with thermal energy storage with use of nanoparticle enhanced phase change material in shell-and-multitube unit. The experiments are conducted under atmospheric pressure. Paraffin wax and two different fatty acids are used as base phase change material. Graphite and multi-walled carbon nanotubes serve as nanoparticles. Graphite nanoparticles are tested at the concentrations of 0.1%, 1% and 5% by weight, while multi-walled...
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Structure versus hydrolytic and thermal stability of bio-based thermoplastic polyurethane elastomers composed of hard and soft building blocks with high content of green carbon
PublicationNowadays, sustainability plays a key role in the design and synthesis of new materials. One of the methods for the preparation of green materials is incorporation into their structure the monomers with a high content of green carbon. Therefore, the aim of this work was to investigate the influence of the type and molecular mass of two bio-based polyester polyols and bio-glycol on the properties of aliphatic partially bio-based...
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Report no: WOiO /II/46/2015 - Construction node verification test, estimation of breaking load (shear force) and destruction form
PublicationA new generation of tanks for LNG transportation has been designed. Mass reduction forced our customer to use three different materials: austenitic steel, aluminium alloy and LNG compressed wood between them. The expertise concerns structural node between tank foundation and suspension. Expertise contains: description of object of test, test principals, results and conclusions
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EFEKTYWNOŚĆ STOSOWANIA ZDERZAKÓW STYROPIANOWYCH POMIĘDZY ZDERZAJĄCYMI SIĘ KONSTRUKCJAMI STALOWYMI
PublicationPodczas wstrząsów sejsmicznych o różnym natężeniu, wielokrotnie obserwowano zjawisko zde-rzania się konstrukcji ze sobą sąsiadujących, co mogło prowadzić nawet do jej całkowitego zniszczenia. Na podstawie obserwacji, badań numeryczny i eksperymentalnych stwierdzono, że przyczyną kolizji jest niedostateczna przerwa pomiędzy konstrukcjami. Ponadto czynnikami, które również mogą doprowadzić do zderzeń są różnice w masach lub sztywnościach...