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Search results for: CEMENT MILL
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Artificial Intelligence Technologies in Education: Benefits, Challenges and Strategies of Implementation
PublicationSince the education sector is associated with highly dynamic business environments which are controlled and maintained by information systems, recent technological advancements and the increasing pace of adopting artificial intelligence (AI) technologies constitute a need to identify and analyze the issues regarding their implementation in education sector. However, a study of the contemporary literature reveled that relatively...
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PublicationThe main aim of the project is to improve interpersonal communication and promote better functionality in the City of Hamburg. An important element is to satisfy the needs of people living and working in diff erent districts. In our project, we sought to give people an outlet and enabled the possibility of creating landscapes. The unusual advantage of the city is that it allows the use of waterways, which in turn become a link...
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Convenient and efficient synthesis of functionalized unsymmetrical Z-alkenyl disulfanes
PublicationWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical Z-alkenyl disulfanes under mild conditions in moderate to good yields. The designed method is based on the reaction of Z-alkenyl thiotosylates with thiols in the presence of base. The developed method allows the preparation of unsymmetrical Z-alkenyl disulfanes bearing additional hydroxy, carboxy, or amino functionalities.
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Convenient and Efficient Synthesis of Functionalized 2-Sulfenylindoles
PublicationA simple, efficient, and practical sulfenylation at the C2 position of N-tosylindoles under mild conditions was developed. The designed transformation is based on the reaction of N-tosylindoles with BuLi and S-alkyl, and S-aryl phosphorodithioates or thiotosylates to produce 2-sulfenylindoles in moderate to high yields. The presence of additional hydroxy, carboxy, or amino functionalities did not disturb the formation of products
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Convenient and efficient N-methylation of secondary amines under solvent-free ball milling conditions
PublicationIn the present work, we report the development of a rapid, efcient, and solvent-free procedure for the N-methylation of secondary amines under mechanochemical conditions. After optimization of the milling parameters, a vibrational ball mill was used to synthesize 26 tertiary N-methylated amine derivatives in a short time of 20 min (30 Hz frequency) and high yields ranging from 78 to 95%. An exception was compounds having a hydroxyl...
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Characterization of herbal teas containing lime flowers – Tiliae flos by HPTLC method with chemometric analysis
PublicationLinden trees are a source of food products called lime flowers (Tiliae flos), traditionally used in the form of infusion for the treatment of feverish colds and coughs. Lime flowers should include flowers of Tilia cordata Mill, T.x europaea L., and T. platyphyllos Scop. or a mixture of these. The aim of current research was to establish a fast, sensitive HPTLC (high-performance thin-layer chromatography) method that would allow...
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Recycled Polyethylene terephthalate (PET) as Construction Material in Civil Engineering: A Review
PublicationIn general, the quantity of plastics of all types consumed annually all over the world has been growing in a phenomenal way. The manufacturing processes, service industries and municipal solid wastes (MSW) generate numerous waste plastic materials. The increasing awareness about the environment has tremendously contributed to the concerns related with disposal of the generated wastes. It is believed that the management of solid...
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Boron Difluoride Complexes of Carbamoyl Meldrum's Acids
Publication5-[Hydroxy(aryl/alkylamino)methylene]-2,2-dimethyl-1,3-dioxane-4,6-diones react with BF3•Et2O in mild conditions leading to the formation of boron difluoride complexes of carbamoyl Meldrum's acids. The X-ray structure has been obtained for one representative complex. The obtained new compounds are fairly stable at standard ambient conditions and easily isolable.
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Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides
PublicationWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical alkynyl sulfides under mild conditions in good yields. The designed method is based on the reaction of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-disulfanyl derivatives with lithium acetylides. The developed method allows the preparation of unsymmetrical alkynyl sulfides bearing additional hydroxyl, carboxyl, or amino functionalities.
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Diastereoselective Synthesis of Z‐Alkenyl Disulfides from α‐Thiophosphorylated Ketones and Thiosulfonates
PublicationWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical Z‐alkenyl disulfides under mild conditions in moderate to good yields. The designed method is based on the reaction of α‐thiophosphorylated carbonyl compounds with thiotosylates in the presence of a base. The developed method allows the preparation of unsymmetrical Z‐alkenyl disulfides bearing additional hydroxy, carboxy, or ester functionalities
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Non-Destructive Testing of a Sport Tribune under Synchronized Crowd-Induced Excitation Using Vibration Analysis
PublicationThis paper presents the concept of repairing the stand of a motorbike speedway stadium. The synchronized dancing of fans cheering during a meeting brought the stand into excessive resonance. The main goal of this research was to propose a method for the structural tuning of stadium stands. Non-destructive testing by vibration methods was conducted on a selected stand segment, the structure of which recurred on the remaining stadium...
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The Medical Relevance of Toxoplasma Infections in Terms of the Safety of Blood Recipients under Immunosuppression—A Meta-Analysis
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Immunizing the Hillcast Method against the Known-Plaintext Attack using Periodic Key Exchange
PublicationThis paper considers a Joint Fingerprinting and Decryption method, called Hillcast, for the copyright protection and traitor tracing in case of Video on Demand services. Because the method is based on the Hill cipher, it is vulnerable to a known-plaintext attack. The goal of this paper is to present an efficient periodic key exchange mechanism to make this method secure without compromising its scalability, imperceptibility or...
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Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2
PublicationThe monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula R2P-C(=O)-O-B(NR2)2 in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
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Application of soil nailing technique for protection and preservation historical buildings
PublicationSoil nailing is one of the recent in situ techniques used for soil improvement and in stabilizing slopes. The process of soil nailing consists of reinforcing the natural ground with relatively small steel bars or metal rods, grouted in the pre-drilled holes. This method has a wide range of applications for stabilizing deep excavations and steep slopes. Soil nailing has recently become a very common method of slope stabilisation...
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Tensile validation tests with failure criteria comparison for various GFRP laminates
PublicationThe paper studies the mechanical properties of glass fibre reinforced polymers (GFRP) with various types and orientation of reinforcement. Analyzed specimens manufactured in the infusion process are made of polymer vinyl ester resin reinforced with glass fibres. Several samples were examined containing different plies and various fibres orientation [0, 90] or [+45, –45]. To assess the mechanical parameters of laminates, a series...
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A literature survey of the influence of preform reheating and stretch blow moulding with hot mould process parameters on the properties of PET containers – part 2.
PublicationThe hot fill process is an inexpensive conventional filling technology for high-acidity products (pH < 4.5). It allows certain drinks (sensitive beverages such as fruit and vegetable juices, nectars, soft drinks, vitaminised water) to be stored at ambient temperature without the need for chemical preservatives. The primary feature of the bottles used in the hot fill process is their temperature stability, i.e. the ability to retain...
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A literature survey of the influence of preform reheating and stretch blow molding with hot mold process parameters on the properties of PET containers. Part I.
PublicationThe hot fill process is an inexpensive conventional filling technology for high-acidity products (pH < 4.5). It allows certain drinks (sensitive beverages such as fruit and vegetable juices, nectars, soft drinks, vitaminized water) to be stored at ambient temperature without the need for chemical preservatives. The primary feature of the bottles used in the hot fill process is their temperature stability, i.e. the ability to retain...
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Zastosowanie nowatorskich materiałów geosyntetycznych w konstrukcjach oporowych z gruntu zbrojonego
PublicationArtykuł prezentuje metodę projektowania stromych skarp wznoszonych z gruntów słabo przepuszczalnych, zbrojonych geosiatkami drenującymi. Z analiz przeprowadzonych dla różnej wodoprzepuszczalności gruntu i różnej geometrii skarpy wynika, że pionowy rozstaw i długość zbrojenia mają istotne znaczenie dla stateczności skarpy. Dla gruntów słabo przepuszczalnych, o typowych wartościach współczynników ściśliwości objętościowej oraz konsolidacji,...
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DDQ-mediated synthesis of functionalized unsymmetrical disulfanes
PublicationWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical disulfanes under mild conditions in good yields. The designed method is based on the reaction of bis(5,5- dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfane with thiols in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). The developedmethod allows the preparation of unsymmetrical disulfanes bearing additional hydroxy, carboxy,...
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The organophosphorus sulfenyl bromides as versatile reagents for cysteine derivatives functionalization by unsymmetrical disulfide bond formation
PublicationWe have developed a convenient method for the synthesis of L-cysteine unsymmetrical disulfides under mild conditions with good to excellent yields. Described method is based on the straightforward preparation of the organophosphorus sulfenyl bromide readily available from bis-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl) disulfide. The unsymmetrical disulfides can be obtained for L-cysteine derivatives and thiols bearing neutral...
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Application of nonmetallic frustrated cations in the activation of small molecules
PublicationThe concept of nonmetallic frustrated cations has been used in small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated...
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A novel architecture for e-learning knowledge assessment systems
PublicationIn this paper we propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. Our research proved that such architecture, while well suited for didactic content distribution systems is ill-suited for knowledge assessment products....
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A novel architecture for e-learning knowledge assessment systems
PublicationIn this paper we propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. Our research proved that such architecture, while well suited for didactic content distribution systems is ill-suited for knowledge assessment products....
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A novel architecture for e-learning knowledge assessment systems
PublicationAbstract. In this paper we propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. Our research proved that such architecture,while well suited for didactic content distribution systems is ill-suited for knowledge assessment...
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A Highly Scalable, Modular Architecture for Computer Aided Assessment e-Learning Systems
PublicationIn this chapter, the authors propose a novel e-learning system, dedicated strictly to knowledge assessment tasks. In its functioning it utilizes web-based technologies, but its design differs radically from currently popular e-learning solutions which rely mostly on thin-client architecture. The authors' research proved that such architecture, while well suited for didactic content distribution systems is ill-suited for knowledge...
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MOF/TiO2 erythrocyte-like heterostructures decorated by noble metals for use in hydrogen photogeneration and pollutant photodegradation
PublicationVarious metal–organic framework (MOF)/TiO2 heterostructures can be obtained by the partial hydrolysis or calcination of Ti-based MOFs. By adjusting the hydrolysis and calcination steps of NH2-MIL-125 (Ti), a novel photoactive material composed of a MOF (NH2-MIL-125 (Ti)) and TiO2, with a unique “erythrocyte” shape, was developed. Furthermore, modification of the composition prepared by the partial hydrolysis of NH2- MIL-125 (Ti)...
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Correlation between natural frequencies and buckling load in a stiffened shell
PublicationThe paper deals with correlation between natural frequencies and buckling load of a stiffened shell composed of corrugated sheets and vertical stiffeners (columns). The simplified shell segment represents the buckling behaviour of a whole silo with sparsely distributed columns. The paper covers variants of linear buckling anal-yses, dynamic eigenvalue analyses and geometrically non-linear analyses of a segment modelled with shell...
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Efficient Method for the Synthesis of Functionalized Basic Maleimides
PublicationA three-step procedure involving Diels-Alder condensation of maleic anhydride with furane, formation of N-substituted imide upon reaction with appropriate diamine and a final retro Diels-Alder regeneration of the maleic carbon-carbon double bond is proposed for an unequivocal synthesis of N-substituted basic maleimides. The novel method is characterized by mild reaction conditions, easy work-up, high yields and no need for additional...
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Fabrication of Composite Polyurethane/Hydroxyapatite Scaffolds Using Solvent-Casting Salt Leaching Technique
PublicationScaffolds are porous three-dimensional structures which are used to fill bone losses and make them possible to cells to grow. Many different structural and biological properties are required from them: porosity, mechanical strength and biocompability. The present research is aimed at development of composite polyurethane/hydroxyapatite scaffolds by using the solvent-casting salt leaching method. The SEM examinations were applied...
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Calculation of Resonance in Planar and Cylindrical Microstrip Structures Using a Hybrid Technique
PublicationA hybrid technique was employed for the analysis of the resonance frequency of thin planar and cylindrical microstrip structures with the patches of arbitrary geometry. The proposed technique utilizes a combination of Galerkin’s moment method and a finite-element method (FEM). In this approach, an FEM is adopted to calculate the patch surface current densities, and a method of moments is utilized to calculate the resonance frequencies...
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Wykorzystanie tomografii komputerowej przy analizie jakości zacementowania - migracja gazu
PublicationArtykuł przedstawia opis zjawiska znanego w wiertnictwie otworowym jako migracja gazu. Opisano główne przyczyny powstawania tego negatywnego zjawiska polegającego na przepływie gazów a także płynów w zaczynie cementacyjnym lub kamieniu cementowym. Przygotowano próbki imitujące zacementowany odcinek rur okładzinowych. Skupiono się na wykorzystaniu tomografii komputerowej, oraz analizie zrekonstruowanego trójwymiarowego obrazu, w...
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Assessment of the application of CEM III with exposed aggregate as an alternative to CEM I for road pavements
PublicationThe article presents a results of study on the impact of replacing CEM I SR3/NA by CEMIII/A LH/HSR/NAon the mechanical properties and durability of pavement concrete with exposed aggregate. Was used granite aggregate and washed sand. Water/cement () ratio in the tested concretes constituted 0.35 and 0.4 and part of the cement was replaced with a 5% addition of natural pozzolana – zeolite. Compressive strength tests were performed...
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Residents' Perception of Intangible Benefits and Costs Associated with Hosting Major Sporting Events
PublicationThe main purpose of this paper is to estimate on the basis of inhabitants’ perception the overall composite and aggregated scores of two major sporting events held in Ergo Arena hall, on the border of Gdańsk and Sopot, in northern Poland. The indirect aim is to identify the determinants affecting the monetary offers of the locals of the two cities. The research results unveil that major sporting events may determine the appearance...
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Residents’ Perception of Intangible Benefits and Costs Associated with Hosting Major Sporting Events
PublicationThe main purpose of this paper is to estimate on the basis of inhabitants’ perception the overall composite and aggregated scores of two major sporting events held in Ergo Arena hall, on the border of Gdańsk and Sopot, in northern Poland. The indirect aim is to identify the determinants affecting the monetary offers of the locals of the two cities. The research results unveil that major sporting events may determine the appearance...
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Diaryl Sulfide Derivatives as Potential Iron Corrosion Inhibitors: A Computational Study
PublicationThe present work aimed to assess six diaryl sulfide derivatives as potential corrosion inhibitors. These derivatives were compared with dapsone (4,4′-diaminodiphenyl sulfone), a common leprosy antibiotic that has been shown to resist the corrosion of mild steel in acidic media with a corrosion efficiency exceeding 90%. Since all the studied compounds possess a common molecular backbone (diphenyl sulfide), dapsone was taken as the...
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Politiceskaja pressa o rosijsko-ukrainskich otnoszenijach i sobytiach w Krymu = Polish press covering russian- ukrainian relations and events in Crimea
PublicationThe paper made a review of opinions expressed by the most widely read Polish newpapers on the issue of Ukraine-Russian relations and events in Crimea in the period from early December 2013 till late March 2014. The author has brought to light attitudes to the events in Ukraine perceived while having in mind preserving security of Poland in political, economic and societal aspects. The EC policy towards the Russian Federation and...
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A convenient method for the preparation of functionalized N-acylsulfenamides from primary amides.
PublicationWe have developed a convenient method for the synthesis of functionalized N-acylsulfenamides under mild conditions and in moderate to good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives with nitrogen nucleophiles generated from primary amides or imides and sodium hydride. The developed method allows for the preparation of N-acylsulfenamides bearing...
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High temperature drying of beech with content of tension wood
PublicationThe presented artcle is focused on comparison of tension and normal wood of beech (Fagus sylvatica L.) in a high-temperature drying process. Samples of 26 mm thickness were selected from sapwood zone with different angle of growth rings. The article evaluated properties of tension and normal wood before and after drying process. Properties which are monitored were moisture, moisture gradients, covering tests, colour changes and...
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Design of dimensionally stable composites using efficient global optimization method
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The influence of high temperature wood drying conditions using air-steam mixture on its properties
PublicationThe results of properties change of beech wood after drying process are presented. The wood taken to experiments was from northern part of Pomeranian region in Poland. Before the main high temperature drying process using air-steam mixture, wood was initially dried in an open air conditions. The high temperature drying process was conducted at temperature 120oC, humidity 48%, flow rate of drying medium 2.5m/s and atmospheric pressure....
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High Temperature Drying Process of Beech Wood (Fagus sylvatica L.) with Different Zones of Sapwood and Red False Heartwood
PublicationThis study examined the changes in the properties of beech wood (Fagus sylvatica L.) after intense drying. Beech wood with false red heartwood was selected as the test specimen. The test samples had dimensions of 50 mm thickness, 180 mm width, and 350 mm length. The specimens were divided into two groups, false red heartwood and sapwood. These specimens were selected with different angles of the growth rings (radial and tangential)....
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The impact of drying and steaming processes on surface color changes of tension ad normal beech wood
PublicationThe aim of the article is to present the influence of high temperature to selected properties of beech wood (Fagus sylvatica L.). The properties such as moisture content, color changes and longitudinal warping were analyzed. The quality of beech wood is determined based on structure and properties of wood, frequency of defects in wood material. The tension wood is considered as an important wood defect causing negative alterations...
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The influence of the drying process on the deformation of the beech and oak wood samples
PublicationThe influence of the drying process conditions on the deformation of the beech and oak wood. The results of the deformation of beech wood (Fagus sylvatica L.) and oak wood (Quercus robur) after drying process are presented. The drying process was carried out in the same drying schedule for each wood species. During each of schedules 40 pieces of wood were dried. The samples were divided into two groups. The first group of tested...
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Reply to the ‘Comment on “Spectroscopic properties and location of the Ce3+ energy levels in Y3Al2Ga3O12 and Y3Ga5O12 at ambient and high hydrostatic pressure”’ by Y. Wang, M. Głowacki, M. Berkowski, A. Kamińska and A. Suchocki, Phys. Chem. Chem. Phys., 2019, 21, DOI: 10.1039/C8CP06154H
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Cykl obrazów: CZŁOWIEK WOBEC| uwspólnienie udział w ogólnopolskiej wystawie zbiorowej EMOTIONAL ECOLOGY / EKOLOGIA EMOCJONALNA. Ekologia, humanizm, etyka. Świadomość historii wzornictwa i nowe ścieżki rozwojowe jako element procesu. | cykl: ‘Design w procesie’
Publication„Zależności pomiędzy organizmami i miejscem ich przebywania, są obszarem zainteresowania kreatorek i kreatorów. Czerpią oni impuls płynący z emocji własnych i innych organizmów. W efekcie synergii emocji, powstaje perspektywa przestrzeni naturalnej. Ekologia opiera się na systemie wymiany pomiędzy miejscem przebywania a kreatorami. Relacja ta zachodzi dokładnie pomiędzy jednostką a środowiskiem społecznym i naturalnym. Człowiek...
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Emulsification alters simulated gastrointestinal proteolysis of β-casein and β-lactoglobulin
PublicationWe have studied the effect of the adsorption of milk proteins at the oil-water interface on their digestibility in simulated gastrointestinal environment. The investigations aimed to characterize how both the breakdown of the adsorbed proteins and the interactions with physiological surfactants, phosphatidylcholine (PC) and bile salts (BS), influence structural transformations of model, protein-stabilized food emulsions in the...
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<i>Plasmodium knowlesi</i> as a Threat to Global Public Health
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Investigation of morphological and electrical properties of the PMMA coating upon exposure to UV irradiation based on AFM studies
PublicationCelem badania było określenie wpływu promieniowania ultrafioletowego na morfologię powierzchni powłoki i na jej właściwości elektryczne. Cienka powłoka z polimetakrylanu metylu została nałożona na podłoże stalowe metodą zanurzeniową. Oceny stanu przed ekspozycją UV i w jej trakcie dokonywano przy użyciu mikroskopu sił atomowych. Na obrazach AFM zaobserwowano pojawienie się mikropęknięć. Celem zweryfikowania czy wykryte nieciągłości...
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Opracowanie dogodnej metody tworzenia wiązań S-C o hybrydyzacji atomu węgla sp oraz sp2
PublicationBadania przeprowadzone w Katedrze Chemii Organicznej Wydziału Chemicznego Politechniki Gdańskiej na przestrzeni ostatnich kilku lat, pokazały wszechstronność pochodnych kwasu neopentylidenofosforoditiowego. Dotychczasowe wyniki badań doprowadziły mnie do opracowania nowych strategii syntetycznych, umożliwiających otrzymywanie związków zawierających wiązanie C-S o hybrydyzacji atomu węgla sp oraz sp2. Analizując wyniki badań opracowałam...