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Search results for: TRIPLE HELIX
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Structure and Stability Characterization of Natural Lake Pigments Made from Plant Extracts and Their Potential Application in Polymer Composites for Packaging Materials
PublicationNatural dyes were extracted from various plant sources and converted into lake pigments based on aluminum and tin. Three different plants (weld, Persian berries, and Brazilwood) were chosen as representative sources of natural dyes. High-performance liquid chromatography (HPLC) and triple-quadrupole mass spectrometry (QqQ MS) were used to identify dyestuffs in the raw extracts. The natural dyes and lake pigments were further characterized...
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Optoelectronic properties of curved carbon systems
PublicationSystematic investigation of optoelectronic properties of curved carbon systems has been performed and the results have been compared with the representatives of flat carbon systems. Moreover, the application of third order dispersion corrected density functional tight binding method (with third order corrections of self-consistent charges) including Becke-Johnson dumping (DFTB3-D3(BJ)) has been validated in order to obtain reliable...
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Theoretical Investigation of the Electron-Transfer Dynamics and Photodegradation Pathways in a Hydrogen-Evolving Ruthenium-Palladium Photocatalyst
PublicationTime-dependent density functional theory calcula- tions combinedwith the Marcus theory of electron transfer (ET) were app lied on the molecular photocatalys t [(tbbpy) 2 Ru(tpph z)PdC l 2 ] 2 + in order to elucidate thelight-in- duced relaxation pathways populated upon excitation in the longer wavelength range of its absorption spectrum. The computational resultsshow that after the initial excitation, metal (Ru) to ligand (tpphz)chargetransfer...
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Average Size of a Suffix Tree for Markov Sources
PublicationWe study a suffix tree built from a sequence generated by a Markovian source. Such sources are more realistic probabilistic models for text generation, data compression, molecular applications, and so forth. We prove that the average size of such a suffix tree is asymptotically equivalent to the average size of a trie built over n independentsequences from the same Markovian source. This equivalenceis only known for memoryless...
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The Importance of Demand and Environment for Defining and Establishing the Role of Data Stewards
PublicationData stewardship is now a central part of FAIR research data management. Although various types of positions called data stewards have been created at academic institutions over the last years, no demand-oriented, formal model of data stewardship and the associated roles exist so far. This workshop report presents the outcomes of the panel discussion “The Importance of Demand and Environment for Defining Data Stewardship” held...
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Trichloridobis(ethyldiphenylphosphine)-(tetrahydrofuran)molybdenum(III)
PublicationIn the mononuclear title compound, [MoCl3(C4H8O)(C14H15P)2], obtained by the reaction of trichlorotris(tetrahydrofuran)molybdenum(III) and ethyldiphenylphosphine in tetrahydrofuran (THF) solution, the MoIII atom is six-coordinated by one O atom of a THF molecule, two P atoms from two ethyldiphenylphosphine ligands and three Cl atoms in a distorted octahedral geometry. The C atoms of the THF molecule are disordered over two positions...
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Ocena wzmocnienia podłoża metodą wymiany dynamicznej na podstawie próbnych obciążeń kolumn
PublicationAnaliza wykonanego wzmocnienia słabego podłoża gruntowego pod nasyp drogowy w technologii kolumn DR na przykładzie obwodnicy Brodnicy. Omówienie warunków geotechnicznych podłoża i zastosowanych rozwiązań. Analiza wsteczna na podstawie wyników próbnych obciążeń kolumn oraz pomiarów osiadań wzmocnionego podłoża całego obszaru. Porównanie uzyskanych wyników i wnioski.
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Practical application of in motion charging: Trolleybuses service on bus lines
PublicationNight charging and fast charging are currently the two most common systems for charging electric buses. Despite the fact that numerous trial installations were started, neither of these two systems has obtained unqualified approval of the users. The alternative is to charge vehicles in motion (the so-called In Motion Charging), which combines the advantages of trolleybus transport and of electric buses: the main supply source are...
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Asymptomatic Bacteriuria in Kidney Transplant Recipients—A Narrative Review
PublicationUrinary tract infections (UTIs) are the most prevalent complications in kidney transplant (KTx) recipients. The most frequent finding in this group of patients is asymptomatic bacteriuria (ASB). Here, we provide an overview of the available evidence regarding ASB in KTx recipients, including its etiopathology, clinical impact and management. There is a growing body of evidence from clinical trials that screening for and treating...
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Time-current tripping characteristics of RCDs for sinusoidal testing current
PublicationLow-voltage electrical installations are verified initially – before being put into operation, as well as periodically – during their utilization. According to the IEC standards, the scope of the verification includes measurements of both the tripping current and the disconnection time of residual current devices (RCDs). Experiences in RCDs testing show that disconnection times of two or more similar RCDs can be quite different....
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Bis(diethylamido-[kappa]N)(diethylamine-[kappa]N)bis(2,6-diisopropylphenylamido-[kappa]N)zirconium(IV)
PublicationIn the title compound, [Zr(C12H18N)2(C4H10N)2(C4H11N)] or [Zr(HNC6H3iPr2)2(NEt2)2(HNEt2)], which was obtained by the reaction of Zr(NEt)4 with iPr2C6H3NH2, the Zr IV atom is in a trigonal–bipiramidal geometry in which the N atoms from two iPr2C6H3NH and one NEt2 ligand occupy the equatorial positions, and the N atoms of an NEt2 and an Et2NH ligand occupy the apical positions. An intramolecular N—HN contact occurs. There are two...
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The electronic structure of p-xylylene and its reactivity with vinyl molecules
PublicationThe electronic states of p-xylylene molecule were described at the multi-configurational CASSCF/MRMP2 level of theory. The closed-shell singlet state representing the quinoidal p-xylylene molecule was pre-dicted to be the ground electronic state whereas the triplet (benzoidal) and the singlet open-shell states were found to be much higher in energy (by 159 and 423 kJ/mol, respectively, as found at the CASSCF(8,8)/6-31+G(d) level)....
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Behavioral state classification in epileptic brain using intracranial electrophysiology
PublicationOBJECTIVE: Automated behavioral state classification can benefit next generation implantable epilepsy devices. In this study we explored the feasibility of automated awake (AW) and slow wave sleep (SWS) classification using wide bandwidth intracranial EEG (iEEG) in patients undergoing evaluation for epilepsy surgery. APPROACH: Data from seven patients (age [Formula: see text], 4 women) who underwent intracranial depth electrode...
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The carbohydrate glycosylphosphatidylinositol anchor chain under mechanical stress
PublicationCarbohydrates have quite complicated micro heterogenic structure which may undergo different structural transitions. Due to their extreme flexibility it is very difficult to investigate such structural changes experimentally. In these studies we want to predict what structural and conformational changes are possible in the carbohydrate
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Właściwości otoczki hydratacyjnej wokół różnych konformacji poliseryny - analiza wyników dynamiki molekularnej
PublicationRozpuszczalnik w istotny sposób wpływa na preferencje peptydu do przyjmowania określonej struktury drugorzędowej. Przykładem tego może być fakt, iż w przypadku polialaniny stabilność konformacji helikalnej w wodzie jest niższa aniżeli w próżni, podczas gdy w przypadku poliseryny mamy do czynienia ze zjawiskiem odwrotnym. W celu lepszego zrozumienia tego zjawiska badano właściwości otoczek hydratacyjnych dookoła czterech konformacji...
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Precypitacja mikrocząstek w układach emulsyjnych w reaktorze petlicowym z mieszaniem
PublicationZaproponowano metodę wytwarzania drobnokrystalicznego osadu w układach emulsyjnych generowanych w strefie wznoszenia pętlicowego reaktora kolumnowego z mieszaniem. Precypitacja CaCO3 zachodzi w mikroreaktorach, których rolę pełnią krople wodnych roztworów CaCl2 i Na2CO3 stanowiących fazy zdyspergowane w dwóch mieszanych emulsjach. Stwierdzono, że ze wzrostem emulgatora maleje rozmiar cząstek CaCO3. Rozmiary kryształów rosną ze...
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Proteomic and Metabolomic Changes in Psoriasis Preclinical and Clinical Aspects
PublicationSkin diseases such as psoriasis (Ps) and psoriatic arthritis (PsA) are immune-mediated inflammatory diseases. Overlap of autoinflammatory and autoimmune conditions hinders diagnoses and identifying personalized patient treatments due to different psoriasis subtypes and the lack of verified biomarkers. Recently, proteomics and metabolomics have been intensively investigated in a broad range of skin diseases with the main purpose...
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Novel Investigation of Higher Order Spectral Technologies for Fault Diagnosis of Motor-Based Rotating Machinery
PublicationIn the last decade, research centered around the fault diagnosis of rotating machinery using non-contact techniques has been significantly on the rise. For the first time worldwide, innovative techniques for the diagnosis of rotating machinery, based on electrical motors, including generic, nonlinear, higher-order cross-correlations of spectral moduli of the third and fourth order (CCSM3 and CCSM4, respectively), have been comprehensively...
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Expedited Yield Optimization of Narrow- and Multi-Band Antennas Using Performance-Driven Surrogates
PublicationUncertainty quantification is an important aspect of engineering design, also pertaining to the development and performance evaluation of antenna systems. Manufacturing tolerances as well as other types of uncertainties, related to material parameters (e.g., substrate permittivity) or operating conditions (e.g., bending) may affect the antenna characteristics. In the case of narrow- or multi-band antennas, this usually leads to...
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Roofing Materials as Pollution Emiters - Concentration Changes During Runoff
PublicationThe influence of roofing material on concentration of pollutants in roof runoff waters and changes of pollution concentration in time were investigated. In field studies four roofing material types were taken into consideration - ceramic tile, bituminous membrane, asbestos tile and zinc sheeting. Samples were collected since November 2007 to March 2008, anions, cations, metals, PAHs, pesticides and PCB were determined. The existence...
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Dimensional Synthesis of Coupled-Resonator Pseudoelliptic Microwave Bandpass Filters with Constant and Dispersive Couplings
PublicationIn this paper, we propose a novel technique for the dimensional synthesis of coupled-resonator pseudoelliptic microwave filters with constant and dispersive couplings. The proposed technique is based on numerical simulations of small structures, involving up to two adjacent resonators, and it accounts for a loading effect from other resonators by replacing them with terminations coupled through appropriately scaled inverters. The...
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Magnetic field effects in dye-sensitized and organic solar cells
PublicationThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. The aim of this thesis is to understand the electronic processes limiting the operation of efficient solar cells with particular emphasis on the role of electronic states endowed with magnetic dipole moment. The research work is divided into two parts. The first part deals...
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Inhibitors of angiogenesis in cancer therapy – synthesis and biological activity
PublicationAngiogenesis is the process of formation of new capillaries from preexisting blood vessels. Angiogenesis is involved in normal physiological processes, and plays an important role in tumor invasion and development of metastases. Vascular endothelial growth factor (VEGF) plays a key role in angiogenesis. VEGF is a mitogen for vascular endothelial cells and stimulates their proliferation. By inhibiting the biological activity of...
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Description of the Dataset Hanow – Praecepta de Arte Disputandi – Transcription and Photographs
PublicationThis article briefly characterises the “Hanow – Praecepta de arte disputandi – transcription and photographs” research dataset. The dataset was created based on photographs and transcriptions of the manuscript of the Latin lectures on the rules of effective discussion (the title of the manuscript: Praecepta de arte disputandi) by Michael Chris-toph Hanow (1695–1773), professor of Gdańsk Academic Gymnasium. The original document...
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Turre cum capellis suis – identification of an earlier phase of the Holy Cross church at Tar – Stancija Blek (Tar-Vabriga – Torre-Abrega, Istria)
PublicationThe paper reports the results of the first campaign of excavations at the Church of the Holy Cross near Stancija Blek (Tar-Vabriga – Torre-Abrega municipality, Istria), which is close to the multiphase settlement of Old Tar. A trial trench behind the rear wall of the church and along its southern perimetral wall revealed an earlier building and one grave. Though the uncovered remains are scanty, several distinct architectural...
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Long way to awareness. Architecture and Aesthetic at the crossroads
PublicationThe architectural criticism is not invited to the common analysis of the architecture together with the aesthetics. The aesthetics judges entireties whereas criticism describes the architecture from the aesthetic point of view without using common scientific language. Research areas are not located in the joint research space! The result is the ambiguity of critical judgments, the ambiguous estimation of an architectural work....
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Analysis of results of large-scale multimodal biometric identity verification experiment
PublicationAn analysis of a large set of biometric data obtained during the enrolment and the verification phase in an experimental biometric system installed in bank branches is presented. Subjective opinions of bank clients and of bank tellers were also surveyed concerning the studied biometric methods in order to discover and to explore relations emerging from the obtained multimodal dataset. First, data acquisition and identity verification...
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Pursuing Listeners’ Perceptual Response in Audio-Visual Interactions - Headphones vs Loudspeakers: A Case Study
PublicationThis study investigates listeners’ perceptual responses in audio-visual interactions concerning binaural spatial audio. Audio stimuli are coupled with or without visual cues to the listeners. The subjective test participants are tasked to indicate the direction of the incoming sound while listening to the audio stimulus via loudspeakers or headphones with the head-related transfer function (HRTF) plugin. First, the methodology...
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A Study on Audio Signal Processed by "Instant Mastering"
PublicationAn increasing amount of music produced in home- and project-studios results in development and growth of "automatic mastering services". The presented investigation explores changes introduced to audio signal by various online mastering platforms. A music set consisting of 10 songs produced in small facilities was processed by eight on-line automatic mastering services. Additionally, some laboratory-constructed signals were tested....
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Wybrane elementy logistycznej obsługi klienta
PublicationMarketing relacji zakłada wynegocjowaną obietnicę obsługi, która na rynku transportu miej-skiego oznacza pewność zrealizowania usługi przewozowej dla określonego pasażera, w danej relacji, danym środkiem transportu, po określonej cenie, w oczekiwanych warunkach przewozu i w założonym przez organizatora transportu zbiorowego czasie. Uniwersalność zasad obsługi klienta powoduje, że Zarząd Komunikacji Miejskiej w Gdyni od początku...
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Influence of reduction process on the structural and mechanical properties of (Pb,Bi)-(Si,Ge)-O oxide glasses
PublicationThe effect of the reduction process in H2 at 380 °C on the microstructure and elemental composition of a glass Bi0.4Pb0.2Si0.4Ox has been investigated. It has been shown that after reduction a clearly separated top layer with a thickness of approx. 50 µm was formed on the surface of the sample. This layer is depleted of oxygen and has higher electrical conductivity than the interior of the glass. It has also been found that some...
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FEX a Fingers Extending eXoskeleton for Rehabilitation and Regaining Mobility
PublicationThis paper presents the design process of an exoskeleton for executing human fingers’ extension movement for the rehabilitation procedures and as an active orthosis purposes. The Fingers Extending eXoskeleton (FEX) is a serial, under-actuated mechanism capable of executing fingers’ extension. The proposed solution is easily adaptable to any finger length or position of the joints. FEX is based on the state-of-art FingerSpine serial...
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1,3-Di-<i>n</i>-butylthiourea
PublicationIn the title compound, C9H20N2S, the n-butyl groups are in syn and anti positions in relation to the C=S bond. In the crystal, two molecules are connected by two N-H···S=C hydrogen bonds into a centrosymmetric dimer. Another N-H···S=C hydrogen bond links the dimers, forming layers with a hydrophilic interior and a hydrophobic exterior, which spread across the (100) plane. Interlacing of the...
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Catena-Poly[[(tetrahydrofuran-[kappa]O)lithium(I)]-bis([mu]-trimethylsilanolato-[kappa]2O:O)-gallium(III)-bis([mu]-trimethylsilanolato-[kappa]2O:O)-[(tetrahydrofuran-[kappa]O)lithium(I)]-[mu]-bromido]
PublicationThe title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethylsilanolate ligands and one tetrahydrofurane...
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Modernity and postmodernity in architectural education
PublicationThe purpose of this article is to present a philosophical education strategy for architecture and interior architecture faculties. The approach is the result of trial and error in lectures and debates with students of philosophical courses in these fields. The presented article is not a result of empirical research, but rather a report on the problems encountered and proposals for their solution. The experience gained from conducting...
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Wpływ procesu redukcji na właściwości strukturalne i mechaniczne szkieł tlenkowych z grupy (Pb,Bi)-(Si,Ge)-O = Influence of reduction process on the structural and mechanical properties of (Pb,Bi)-(Si,Ge)-O oxide glasses
PublicationThe effect of the reduction process in H2 at 380 °C on the microstructure and elemental composition of a glass Bi0.4Pb0.2Si0.4Ox has been investigated. It has been shown that after reduction a clearly separated top layer with a thickness of approx. 50 µm was formed on the surface of the sample. This layer is depleted of oxygen and has higher electrical conductivity than the interior of the glass. It has also been found that some...
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Engineering TADF, Mechanochromism, and Second Harmonic Up- conversion Properties in Regioisomeric Substitution Space
PublicationThis research article explores the distinct TADF efficiency of three donor-acceptor based regio-isomers: DPAOCN (ortho- isomer), DPAMCN (meta-isomer), and DPAPCN (para-isomer). DPAPCN exhibits maximum TADF efficiency in both solution and solid-state with an impressive reverse inter-system crossing (RISC) rate of ~ 106 s-1; the underlying cause being the minimum singlet-triplet splitting energy or ∆EST and maximum SOC (spin-orbit...
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Solubility of Methane in Water: Some Useful Results for Hydrate Nucleation
PublicationIn this paper, the solubility of methane in water along the 400 bar isobar is determined by computer simulations using the TIP4P/Ice force field for water and a simple LJ model for methane. In particular, the solubility of methane in water when in contact with the gas phase and the solubility of methane in water when in contact with the hydrate has been determined. The solubility of methane in a gas–liquid system decreases as temperature...
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Global EM-Driven Optimization of Multi-Band Antennas Using Knowledge-Based Inverse Response-Feature Surrogates
PublicationElectromagnetic simulation tools have been playing an increasing role in the design of contemporary antenna structures. The employment of electromagnetic analysis ensures reliability of evaluating antenna characteristics but also incurs considerable computational expenses whenever massive simulations are involved (e.g., parametric optimization, uncertainty quantification). This high cost is the most serious bottleneck of simulation-driven...
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Chromatographic and Spectroscopic Identification and Recognition of Natural Dyes, Uncommon Dyestuff Components, and Mordants: Case Study of a 16th Century Carpet with Chintamani Motifs
PublicationA multi-tool analytical practice was used for the characterisation of a 16th century carpet manufactured in Cairo. A mild extraction method with hydrofluoric acid has been evaluated in order to isolate intact flavonoids and their glycosides, anthraquinones, tannins, and indigoids from fibre samples. High-performance liquid chromatography coupled to spectroscopic and mass spectrometric detectors was used for the identification of...
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Development of a Formability Prediction Model for Aluminium Sandwich Panels with Polymer Core
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Parametry mechaniczne platformy roboczej na podstawie badań DMT
PublicationNośność platformy roboczej określana jest w sposób analogiczny do nośności podłoża uwarstwionego, w którym warstwa wierzchnia zbudowana z gruntu niespoistego spoczywa na słabonośnym podłożu z gruntu spoistego. Badanie DMT wykorzystano do wyznaczenia parametrów wytrzymałościowych podłoża (kąta tarcia wewnętrznego warstwy górnej i wytrzymałości na ścinanie bez odpływu podłoża słabonośnego) oraz do wyznaczenia modułu odkształcenia...
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Cost-Efficient Multi-Objective Design of Miniaturized Microwave Circuits Using Machine Learning and Artificial Neural Network
PublicationDesigning microwave components involves managing multiple objectives such as center frequencies, impedance matching, and size reduction for miniaturized structures. Traditional multi-objective optimization (MO) approaches heavily rely on computationally expensive population-based methods, especially when exe-cuted with full-wave electromagnetic (EM) analysis to guarantee reliability. This paper introduces a novel and cost-effective...
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4-(Cyclic-amidino)phenols. Preparation and Use in a Diamidine Synthesis
PublicationThe Pinner synthesis was applied to the prepn. of phenols 4-substituted with cyclic amidines in high yields from readily available 4-HOC6H4C(OMe):NH.HCl and aliph. diamines. An alternative attempt was made to convert 4-HOC6H4CSNH2 to 4-(1,4,5,6-tetrahydro-5-hydroxy-2-pyrimidinyl)phenol. A procedure for the prepn. of 3,6-bis(4-hydroxyphenyl)-1,2,4,5-tetrazine is reported. The syntheses of 2,4-bis[4-(4,5-dihydro-1H-imidazol-2-yl)phenoxy]pyrimidine...
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Molecular geometry and optical activity of helically chiral N-nitrosamines derived from 1,2,3,4-tetrahydro- and 1,2,3,4,7,8,9,10-octahydro-1,10-phenanthroline
PublicationX-ray crystallographic analysis of the title N-nitrosamines revealed that they assume helical conformations in the solid state. Nitrosamines 1b and 2b were resolved by inclusion crystallization with optically active diols (TADDOLs). The absolute configuration of the guest molecules in the complexes 1b·3b and 2b·3b was assigned as M. The optical activity of the resolved compounds is manifested by their solid state CD spectra, which...
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Ammonium <i>O</i>,<i>O</i>'-diethyl dithiophosphate
PublicationIn the title compound, NH4+·(C2H5O)2PS2−, the ammonium cation is connected by four charge-assisted N−H···S hydrogen bonds to four tetrahedral O,O'-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Interlacing of the external ethyl groups...
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Images of the Seabed of the Gulf of Gdansk Obtained by Means of the Parametric Sonar
PublicationThe main goal of this paper is to present results of the experimental investigation of the seabed by means of parametric echosounder in the form of chosen images. The phenomena of nonlinear interaction between two parallel beams of high intensity gives as a results very narrow beam of low frequency wave, that enables to penetrate the sea bottom. The first step of our investigations was calibration of all the elements of the measuring...
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The Role of Inflammatory Cytokines in the Pathogenesis of Colorectal Carcinoma-Recent Findings and Review
PublicationThe inflammatory process plays a significant role in the development of colon cancer (CRC). Intestinal cytokine networks are critical mediators of tissue homeostasis and inflammation but also impact carcinogenesis at all stages of the disease. Recent studies suggest that inflammation is of greater importance in the serrated pathway than in the adenoma-carcinoma pathway. Interleukins have gained the most attention due to their...
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Materiały biozgodne i specjalnego przeznaczenia
PublicationW książce przedstawiono ogólną charakterystykę materiałów używanych w medycynie i laboratoriach klinicznych. Opisano wyjaławianie materiałów medycznych; mteriały okulistyczne, soczewki kontaktowe, szkła okularowe, enzymatyczne oczyszczanie soczewek kontaktowych, płyny, krople i maści do oczu; materiały dentystyczne: wiertła, pasty szlifierskie, wypełnienia; materiały na implanty metalowe, ceramiczne, z tworzyw sztucznych; cementy...
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Measurements of transmission properties of Acoustic Communication Channels
PublicationTough transmission properties of shallow water acoustic channels (SWAC) highly limit the use of underwater acoustic communication (UAC) systems. An adaptive matching of modulation and signaling schemes to instantaneous channel conditions is needed for reliabledata communications. This creates, however, unique challenges for designers when compared to radio transmission systems. When communication system elements are in move, the...